EP1072326A3 - Oberflächenaktive Photoinitiatoren - Google Patents

Oberflächenaktive Photoinitiatoren Download PDF

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Publication number
EP1072326A3
EP1072326A3 EP00810649A EP00810649A EP1072326A3 EP 1072326 A3 EP1072326 A3 EP 1072326A3 EP 00810649 A EP00810649 A EP 00810649A EP 00810649 A EP00810649 A EP 00810649A EP 1072326 A3 EP1072326 A3 EP 1072326A3
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EP
European Patent Office
Prior art keywords
alkyl
stands
formula
surface active
photochemically
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00810649A
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English (en)
French (fr)
Other versions
EP1072326B1 (de
EP1072326A2 (de
Inventor
Gisèle BAUDIN
Tunja Jung
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
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Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of EP1072326A2 publication Critical patent/EP1072326A2/de
Publication of EP1072326A3 publication Critical patent/EP1072326A3/de
Application granted granted Critical
Publication of EP1072326B1 publication Critical patent/EP1072326B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S522/904—Monomer or polymer contains initiating group
    • Y10S522/905—Benzophenone group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicon Polymers (AREA)

Abstract

Die Erfindung betrifft die Verwendung von oberflächenaktiven Photoinitiatoren der Formel I
Figure 80000001
wobei die Einheiten statistisch oder in Blöcken angeordnet sind, und worin n für eine Zahl von 1 bis 1000 steht; m eine Zahl von 0 bis 100 darstellt; p eine Zahl von 0-10000 ist; x für die Zahl 1 steht, oder, wenn n 1 ist, auch für die Zahl 2 stehen kann; A1 und A2 z.B. C1-C18-Alkyl darstellen; oder A1 und A2 zusammen eine Einfachbindung bedeuten; R1, R2 und R3 z.B. unabhängig voneinander C1-C18-Alkyl, Phenyl oder C5-C8-Cycloalkyl bedeuten; R4 z.B. unsubstituiertes oder substituiertes C1-C18-Alkyl, unsubstituiertes oder substituiertes Phenyl oder C5-C8-Cycloalkyl ist; IN wenn x 1 bedeutet, für einen Rest der Formel
Figure 80000002
steht; oder IN wenn x 2 bedeutet, einen Rest der Formel
Figure 80000003
darstellt; R13 und R14 unabhängig voneinander z.B. C1-C12-Alkyl sind; Y z.B. -(CH2)a-O- bedeutet; X für OR15 oder N(R16)(R17) steht; R15 z.B. Wasserstoff oder C1-C4-Alkyl ist; R16 und R17 z.B. Wasserstoff oder C1-C12-Alkyl bedeuten; X1 z.B eine der Bedeutungen von X hat; und R18 z.B. -(CH2)a- bedeutet; in photochemisch, sowie photochemisch und thermisch kombiniert vernetzbaren Formulierungen.
EP20000810649 1999-07-29 2000-07-20 Oberflächenaktive Photoinitiatoren Expired - Lifetime EP1072326B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH139899 1999-07-29
CH139899 1999-07-29
US09/618,821 US6376568B1 (en) 1999-07-29 2000-07-18 Surface-active photoinitiators

Publications (3)

Publication Number Publication Date
EP1072326A2 EP1072326A2 (de) 2001-01-31
EP1072326A3 true EP1072326A3 (de) 2002-07-17
EP1072326B1 EP1072326B1 (de) 2008-09-17

Family

ID=25687536

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20000810649 Expired - Lifetime EP1072326B1 (de) 1999-07-29 2000-07-20 Oberflächenaktive Photoinitiatoren

Country Status (4)

Country Link
US (2) US6376568B1 (de)
EP (1) EP1072326B1 (de)
JP (1) JP4675461B2 (de)
BR (1) BR0003614A (de)

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US20040033317A1 (en) * 2000-12-13 2004-02-19 Gisele Baudin Surface-active photoinitators
US7237893B2 (en) * 2001-12-28 2007-07-03 Chang Shiao H Light adjustable lenses capable of post-fabrication power modification via multi-photon processes
MXPA04007993A (es) * 2002-03-06 2004-11-26 Ciba Sc Holding Ag Proceso enzimatico para la preparacion de fotoiniciadores que contienen grupos de silicio organicos.
DE10232828A1 (de) * 2002-07-19 2004-02-05 Goldschmidt Ag Verwendung von Antioxidantien in strahlenhärtbaren Beschichtungsmassen für die Herstellung von abhäsiven Beschichtungen
US6822063B2 (en) 2002-08-27 2004-11-23 Ecolab Inc. Highly durable waterborne radiation cured coating
DE10248111A1 (de) 2002-10-15 2004-04-29 Goldschmidt Ag Verwendung von Photoinitiatoren vom Typ Hydroxyalkylphenon in strahlenhärtbaren Organopolysiloxanen für die Herstellung von abhäsiven Beschichtungen
AU2004262823A1 (en) * 2003-08-08 2005-02-17 Calhoun Vision Light adjustable lenses capable of post-fabrication power modification via multi-photon processes
JP2005305689A (ja) * 2004-04-19 2005-11-04 Konica Minolta Medical & Graphic Inc 印刷版材料および印刷方法
EP1591097B1 (de) * 2004-04-30 2012-06-20 3M Deutschland GmbH Kationisch härtbare zwei-komponenten-Materialien enthaltend einen Edelmetallkatalysator
JP4993188B2 (ja) * 2006-03-29 2012-08-08 国立大学法人東北大学 樹脂配管
JP4941657B2 (ja) * 2007-04-06 2012-05-30 信越化学工業株式会社 有機ケイ素化合物及びその製造方法並びに光重合性組成物及び無機材料
JP5207837B2 (ja) * 2007-08-02 2013-06-12 富士フイルム株式会社 硬化性組成物、硬化膜、フォトスペーサーの製造方法、液晶表示装置用基板及び液晶表示装置
DE102007043048A1 (de) * 2007-09-11 2009-03-12 Byk-Chemie Gmbh Polypropylenoxid-haltige Polyether und deren Mischungen mit Poly(meth)acrylaten als Pulverlackverlaufmittel
RU2489450C9 (ru) 2007-10-17 2014-01-27 Басф Се Фотолатентные катализаторы на основе металлорганических соединений
CA2739102C (en) * 2008-11-13 2016-06-21 Novartis Ag Silicone hydrogel materials with chemically bound wetting agents
KR101706395B1 (ko) * 2008-12-01 2017-02-13 바스프 에스이 실세스퀴옥산 광개시제
WO2010077132A1 (en) 2008-12-31 2010-07-08 Draka Comteq B.V. Uvled apparatus for curing glass-fiber coatings
EP2388239B1 (de) 2010-05-20 2017-02-15 Draka Comteq B.V. Härtungsvorrichtung mit in einem Winkel gerichteter UV-LEDs
US8871311B2 (en) 2010-06-03 2014-10-28 Draka Comteq, B.V. Curing method employing UV sources that emit differing ranges of UV radiation
AU2011282603B2 (en) 2010-07-30 2014-01-30 Novartis Ag Amphiphilic polysiloxane prepolymers and uses thereof
EP2418183B1 (de) 2010-08-10 2018-07-25 Draka Comteq B.V. Verfahren zur Härtung beschichteter Glasfasern mit erhöhter UVLED-Intensität
EP2625216B1 (de) 2010-10-06 2019-06-05 Novartis AG Polymerisierbare kettenverlängerte polysiloxane mit seitenständigen hydrophilen gruppen
US8835525B2 (en) 2010-10-06 2014-09-16 Novartis Ag Chain-extended polysiloxane crosslinkers with dangling hydrophilic polymer chains
CN103168067B (zh) 2010-10-06 2015-08-05 诺华股份有限公司 可水处理的含硅氧烷预聚物及其用途
KR101385045B1 (ko) 2012-06-12 2014-04-14 제일모직주식회사 신규한 광개시제, 그 제조방법, 이를 포함하는 광중합성 조성물 및 이를 이용한 복합시트
KR20150091318A (ko) 2012-12-05 2015-08-10 헨켈 아게 운트 코. 카게아아 실리콘-상용성 광개시제
AT514594B1 (de) 2013-09-06 2015-02-15 Durst Phototech Digital Tech Photoinitiator
DE102014107518A1 (de) * 2014-05-28 2015-12-03 Heraeus Kulzer Gmbh Reaktiver Mikro-Applikator mit Metall enthaltenden Additiven zur Verwendung mit dental Adhäsiven
CN107406468B8 (zh) * 2014-08-29 2021-07-20 汉高股份有限及两合公司 有机硅改性的光引发剂以及其光致固化粘合剂组合物
ES2804199T3 (es) 2016-01-11 2021-02-04 Henkel IP & Holding GmbH Compuestos compatibles con silicona
EP3395793B9 (de) * 2017-04-24 2021-09-29 IGM Group B.V. Verfahren zur herstellung von alpha-funktionalisierten ketonen
EP3395806B1 (de) * 2017-04-24 2020-04-08 IGM Group B.V. Einfache oxidative funktionalisierung von alkylarylketonen
WO2021137090A1 (en) * 2019-12-30 2021-07-08 3M Innovative Properties Company Light and moisture curable compositions
JP7722248B2 (ja) 2022-04-22 2025-08-13 信越化学工業株式会社 光反応性オルガノポリシロキサン、その製造方法および光硬化性組成物
WO2025207169A2 (en) * 2024-02-28 2025-10-02 Ppg Industries Ohio, Inc. Additive manufacturing of transparent optical articles

Citations (9)

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US4587276A (en) * 1983-06-20 1986-05-06 Loctite Corporation Polyphotoinitiators
US4666953A (en) * 1985-03-28 1987-05-19 Loctite Corporation Silicone polyphotoinitiators
EP0281941A2 (de) * 1987-03-12 1988-09-14 Ciba-Geigy Ag Coreaktive Fotoinitiatoren
US4861916A (en) * 1985-04-03 1989-08-29 Merck Patent Gesellschaft Mit Beschrankter Haftung Photoinitiators for photopolymerization of unsaturated systems
WO1993000405A1 (de) * 1991-06-20 1993-01-07 Wacker-Chemie Gmbh Härtbare organo(poly)siloxanmassen
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US4559371A (en) * 1983-02-18 1985-12-17 Ciba Geigy Corporation Photocurable colored compositions employing alpha-amino phenone initiator
US4587276A (en) * 1983-06-20 1986-05-06 Loctite Corporation Polyphotoinitiators
US4666953A (en) * 1985-03-28 1987-05-19 Loctite Corporation Silicone polyphotoinitiators
US4861916A (en) * 1985-04-03 1989-08-29 Merck Patent Gesellschaft Mit Beschrankter Haftung Photoinitiators for photopolymerization of unsaturated systems
EP0281941A2 (de) * 1987-03-12 1988-09-14 Ciba-Geigy Ag Coreaktive Fotoinitiatoren
WO1993000405A1 (de) * 1991-06-20 1993-01-07 Wacker-Chemie Gmbh Härtbare organo(poly)siloxanmassen
US5776658A (en) * 1994-10-04 1998-07-07 Agfa-Gevaert Ag Silicone-compatible photoinitiators, and photosensitive mixtures comprising them
FR2750429A1 (fr) * 1996-06-27 1998-01-02 Essilor Int Materiau a base de silicone reticule comportant un photoamorceur fixe, son procede de preparation, produit polymerique hydrophile obtenu a partir de ce materiau et son procede de preparation, et nouveaux photoamorceurs
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Also Published As

Publication number Publication date
EP1072326B1 (de) 2008-09-17
US6376568B1 (en) 2002-04-23
US6693141B2 (en) 2004-02-17
EP1072326A2 (de) 2001-01-31
US20020107297A1 (en) 2002-08-08
JP2001081115A (ja) 2001-03-27
JP4675461B2 (ja) 2011-04-20
BR0003614A (pt) 2001-03-13

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