EP1331261A1 - Procès de nettoyage et désinfection de la vaiselle - Google Patents

Procès de nettoyage et désinfection de la vaiselle Download PDF

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Publication number
EP1331261A1
EP1331261A1 EP02001624A EP02001624A EP1331261A1 EP 1331261 A1 EP1331261 A1 EP 1331261A1 EP 02001624 A EP02001624 A EP 02001624A EP 02001624 A EP02001624 A EP 02001624A EP 1331261 A1 EP1331261 A1 EP 1331261A1
Authority
EP
European Patent Office
Prior art keywords
benzoic acid
cleaning
acid
dishes
microbiocidal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP02001624A
Other languages
German (de)
English (en)
Inventor
Birgit Kühnau
Wolfgang Dr. Wagemann
Jürgen Dr. Staffeldt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemische Fabrik Dr Weigert GmbH and Co
Original Assignee
Chemische Fabrik Dr Weigert GmbH and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Fabrik Dr Weigert GmbH and Co filed Critical Chemische Fabrik Dr Weigert GmbH and Co
Priority to EP02001624A priority Critical patent/EP1331261A1/fr
Publication of EP1331261A1 publication Critical patent/EP1331261A1/fr
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/18Glass; Plastics

Definitions

  • the invention relates to a method for machine cleaning and / or disinfecting dishes, in particular glass dishes and glasses, and the use of a specific detergent to this end.
  • DIN 10511 is used for mechanical commercial glass washing a temperature of at least for hygienic reasons 55 ° C is required. This is said to be in microbiological Adequate decontamination of the glasses can be achieved.
  • the invention has for its object a method of to create a simple, quick and safe cleaning of dishes, in particular Glass dishes allowed and sufficient disinfection (microbiological decontamination).
  • the invention distinguishes between a cleaning agent and a cleaning solution.
  • the detergent is one in the Usually liquid or solid concentrate that mixes with water ready-to-use cleaning solution is prepared. This Ready-to-use solution comes in with the dishes (dishes) Contact.
  • microbicide means in the context of the invention that an invention used cleaning solution the hygienic requirements in accordance with DIN 10511, section 5.3.2.
  • Dishes include those in catering and commercial catering usual everyday objects made of glass, porcelain, metal and plastic, such as glasses, mugs, cups, Plates, cutlery, pots, trays and the like.
  • glasses refers to the usual drinking vessels.
  • the invention has recognized that the method of the prior art Technology is disadvantageous in several ways.
  • the one provided there thermal disinfection is required to heat the Water a lot of energy, and can also after the rinsing process emit unpleasant vapors from the hot machine. Which are still called after the rinsing process Glasses cannot be reused immediately, especially not for serving cold drinks.
  • Chemical disinfection of the dishes is according to the invention or the glasses with benzoic acid or a microbiocidal benzoic acid derivative intended.
  • microbiocidal benzoic acid derivative hydroxybenzoic acids (salicylic acid and m- and p-hydroxybenzoic acid), also halogen and / or alkyl substituted Benzoic acids, especially chlorobenzoic acids such as p-chlorobenzoic acid.
  • Salicylic acid is according to the invention particularly preferred.
  • the temperature of the cleaning solution during the cleaning process well below the in DIN 5511 lower 55 ° C; preferred temperature ranges are 10-50 ° C, preferably 15-45 ° C further preferably 15 - 40 ° C. It is possible to use glasses at room temperature to clean and yet adequate disinfection (microbiocidal decontamination).
  • the pH of the cleaning solution is in the acidic range, preferably between 1 and 6, more preferably 2 and 5, further preferably 2 and 4.
  • a likewise preferred pH range is between 1 and 3.
  • the acidic pH causes that the benzoic acid or its derivatives in a technical relevant part is in undissociated form, because in this undissociated form is primarily microbiocidal is.
  • Another advantage of the acidic pH is the avoidance of lime deposits on glasses or in the used Dishwasher, the machine can also be used with normal tap water instead of using costly, fully desalinated (VE) water can be fed.
  • VE fully desalinated
  • the duration of the cleaning step can be between 10 s and 30 min, more preferably 30 s and 10 min, more preferably 30 s to 5 min, preferably 1 to 3 min.
  • a cleaning time of about 90 s is often provided.
  • the rinsing step follows the cleaning step.
  • the Rinse aid is used for the extensive removal of residues Cleaner solution and is said to be a quick, streak-free Allow dishes or glasses to dry. It can according to the invention either with fresh water (preferably softened or VE water), but is preferred Use of a conventional rinse aid, preferably with Fresh water is added to a rinse aid solution.
  • the Rinsing can take about 5 seconds to 2 minutes, but one is common Rinse time of about 15 s is provided.
  • a cleaning solution used according to the invention is usually from a cleaning agent (a concentrate) set that is preferably liquid. Are liquid concentrates easier to dose and commercial dishwashers are all around Rule set up for dosing liquid concentrates.
  • a detergent concentrate used according to the invention exhibits as ingredients benzoic acid and / or a microbiocidal Benzoic acid derivative. At least is also preferred an acid and / or buffer substance to adjust an acid pH value, since benzoic acid or its derivatives in the first Line are microbiocidal in their undissociated form.
  • the undissociated acid or its derivatives are only slightly water soluble; it can therefore in the formulation crystallize out as an aqueous concentrate. It is therefore preferred according to the invention, at least additionally an organic solvent for benzoic acid and / or to provide their derivatives, which is miscible with water and in Water is soluble.
  • Alcohols are preferred here, in particular monohydric and dihydric alcohols.
  • Glycols such as ethylene and propylene glycols, the higher of which Homologs and derivatives (e.g. diglycol ethers).
  • Aprotic can also be used dipolar solvents such as DMF (dimethylformamide), DMSO (dimethyl sulfoxide) and NMP (N-methylpyrrolidone).
  • Mineral acids are among the acids already mentioned (e.g. sulfuric acid, phosphoric acid, hydrochloric acid and Nitric acid) and organic acids are preferred.
  • organic Acids can be used, for example, formic acid, Acetic acid, propionic acid, glycolic acid, maleic acid, Malonic acid and homologues of malonic acid (succinic acid, Adipic acid etc.).
  • fruit acids such as for example citric acid, malic acid, tartaric acid and the like be used.
  • a formulated as a liquid concentrate Detergents can include surfactants and others known to those skilled in the art Auxiliary substances.
  • the detergent becomes a cleaning solution with water stated.
  • a concentration preferably arises in this solution the benzoic acid and / or the microbiocidal benzoic acid derivative from 0.001-1% by weight, preferably 0.001-0.5 % By weight, more preferably 0.005-0.1% by weight, more preferably 0.005-0.05 wt%.
  • concentrations mentioned ensure sufficient microbiocidal activity the cleaning solution even with short contact times and low temperatures from, for example, room temperature to 40 ° C.
  • the process according to the invention can be carried out in the usual commercial Dishwashers are carried out.
  • So-called One-tank machines are used in which the dishes remains stationary in the machine and cleaning as well Rinsing can be carried out sequentially at the same place.
  • detergent solution is circulated in the tank, then rinsing is carried out by spraying on (if necessary fresh water mixed with rinse aid) from special Rinse nozzles.
  • the method can also be used in so-called belt dishwashers in which the dishes are on one transport device successively different tanks, in particular a detergent tank and a rinse aid tank, passes.
  • Octylpyrrolidone is a common surfactant. Butyl diglycol and Isopropanol are solubilizers for the salicylic acid, which in this concentrate remains in solution as free acid and not crystallized.
  • a Winterhalter glass washer type GS 28 the tank is filled with detergent solution.
  • a cleaning solution a 0.2% aqueous solution of the detergent concentrate used from Example 1.
  • the temperature of the detergent solution is 40 ° C.
  • Used drinking glasses become 90 s with this cleaning solution cleaned while circulating the solution.
  • Rinse nozzles with rinse aid heated to 40 ° C Rinse water rinsed over the cleaned glasses.
  • a typical one Rinse aid can contain 10% by weight of n-surfactant and 3% by weight of citric acid contain (rest: water) and is in a concentration of 0.5 ml / l.
  • the entire program flow takes about 2 min. The glasses can then be removed from the machine taken and reused immediately.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
EP02001624A 2002-01-23 2002-01-23 Procès de nettoyage et désinfection de la vaiselle Ceased EP1331261A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP02001624A EP1331261A1 (fr) 2002-01-23 2002-01-23 Procès de nettoyage et désinfection de la vaiselle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP02001624A EP1331261A1 (fr) 2002-01-23 2002-01-23 Procès de nettoyage et désinfection de la vaiselle

Publications (1)

Publication Number Publication Date
EP1331261A1 true EP1331261A1 (fr) 2003-07-30

Family

ID=8185335

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02001624A Ceased EP1331261A1 (fr) 2002-01-23 2002-01-23 Procès de nettoyage et désinfection de la vaiselle

Country Status (1)

Country Link
EP (1) EP1331261A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1935972A1 (fr) * 2006-12-21 2008-06-25 JohnsonDiversey, Inc. Procédé de lavage d'un élément polycarbonate
EP2091997A4 (fr) * 2006-12-21 2012-01-04 Diversey Inc Procédé de lavage d'un article en polycarbonate
DE102015113641A1 (de) * 2015-08-18 2017-02-23 Bode Chemie Gmbh Desinfektionsmittel mit organischen Säuren

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0147102A2 (fr) * 1983-12-08 1985-07-03 Diversey Corporation Composition antimicrobienne diluable dans l'eau
GB2211093A (en) * 1987-10-21 1989-06-28 Unilever Plc Disinfectant compositions
EP0510945A2 (fr) * 1991-04-22 1992-10-28 Colgate-Palmolive Company Compositions détergentes liquides aqueuses à visco-élasticité linéaire, notamment pour lave-vaisselle automatique
WO1992021239A1 (fr) * 1991-06-04 1992-12-10 Ecolab Inc. Compositioin pour sterilisation constituee d'un melange d'acide carboxylique
WO1997043369A1 (fr) * 1996-05-09 1997-11-20 Unilever Plc Compositions repulsives pour les insectes comprenant des agents antimicrobiens et des tensio-actifs non ioniques
WO1999057235A1 (fr) * 1998-04-30 1999-11-11 Henkel Kommanditgesellschaft Auf Aktien Produit pour laver la vaisselle a action antibacterienne
DE10023438A1 (de) * 2000-05-12 2001-11-22 Henkel Kgaa Konzentrat zur Verdünnung unter Viskositätserhalt oder -erhöhung

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0147102A2 (fr) * 1983-12-08 1985-07-03 Diversey Corporation Composition antimicrobienne diluable dans l'eau
GB2211093A (en) * 1987-10-21 1989-06-28 Unilever Plc Disinfectant compositions
EP0510945A2 (fr) * 1991-04-22 1992-10-28 Colgate-Palmolive Company Compositions détergentes liquides aqueuses à visco-élasticité linéaire, notamment pour lave-vaisselle automatique
WO1992021239A1 (fr) * 1991-06-04 1992-12-10 Ecolab Inc. Compositioin pour sterilisation constituee d'un melange d'acide carboxylique
WO1997043369A1 (fr) * 1996-05-09 1997-11-20 Unilever Plc Compositions repulsives pour les insectes comprenant des agents antimicrobiens et des tensio-actifs non ioniques
WO1999057235A1 (fr) * 1998-04-30 1999-11-11 Henkel Kommanditgesellschaft Auf Aktien Produit pour laver la vaisselle a action antibacterienne
DE10023438A1 (de) * 2000-05-12 2001-11-22 Henkel Kgaa Konzentrat zur Verdünnung unter Viskositätserhalt oder -erhöhung

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1935972A1 (fr) * 2006-12-21 2008-06-25 JohnsonDiversey, Inc. Procédé de lavage d'un élément polycarbonate
EP2091997A4 (fr) * 2006-12-21 2012-01-04 Diversey Inc Procédé de lavage d'un article en polycarbonate
DE102015113641A1 (de) * 2015-08-18 2017-02-23 Bode Chemie Gmbh Desinfektionsmittel mit organischen Säuren

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