EP1332204B2 - Procede de nettoyage mecanique de textiles ou d'objets solides - Google Patents
Procede de nettoyage mecanique de textiles ou d'objets solides Download PDFInfo
- Publication number
- EP1332204B2 EP1332204B2 EP01988757.9A EP01988757A EP1332204B2 EP 1332204 B2 EP1332204 B2 EP 1332204B2 EP 01988757 A EP01988757 A EP 01988757A EP 1332204 B2 EP1332204 B2 EP 1332204B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- enzymes
- water
- cleaning
- detergent
- wash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000004753 textile Substances 0.000 title claims abstract description 8
- 239000007787 solid Substances 0.000 title description 2
- 102000004190 Enzymes Human genes 0.000 claims abstract description 50
- 108090000790 Enzymes Proteins 0.000 claims abstract description 50
- 239000003599 detergent Substances 0.000 claims abstract description 27
- 230000003197 catalytic effect Effects 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000002775 capsule Substances 0.000 claims description 12
- 239000012459 cleaning agent Substances 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- 229920005597 polymer membrane Polymers 0.000 claims description 2
- 230000032258 transport Effects 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 18
- 150000001720 carbohydrates Chemical class 0.000 description 7
- 235000014633 carbohydrates Nutrition 0.000 description 7
- 102000004169 proteins and genes Human genes 0.000 description 7
- 108090000623 proteins and genes Proteins 0.000 description 7
- 101150114468 TUB1 gene Proteins 0.000 description 5
- 239000000356 contaminant Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000007792 addition Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920003176 water-insoluble polymer Polymers 0.000 description 2
- 206010034016 Paronychia Diseases 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/42—Details
- A47L15/44—Devices for adding cleaning agents; Devices for dispensing cleaning agents, rinsing aids or deodorants
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/40—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using enzymes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
Definitions
- the invention is based on processes for the automated cleaning of textiles or solid objects, such as dishes, using water-soluble detergents and / or cleaning agents and enzymes.
- the invention has for its object to prevent the dissolution or inactivation of the enzymes and to avoid the rinsing of still usable enzymes.
- a machine for machine cleaning of textiles characterized in that it comprises a tub (1) with coupled inlet for water and detergent and for the circulation of liquor by an enzyme container (6), wherein the feed of water bypassing a detergent container (2) for the first phase of the water inlet is enabled and wherein, after a certain amount of accrued water covers the bottom of the tub (1) and has already wetted the laundry, a drain pump (3) is turned on and the accumulated water, as far as it is not bound in the laundry, through a drain line (4) at the bottom of the tub (1) and a Circulation line (5) is supplied to a Enzym structurier (6), where it receives a limited amount of stored enzymes (7) and transported into the tub (1), from where it receives the laundry items together with the laundry in turn wetting liquor, said after the end of the enzyme phase by switching off the pump (3) a detergent (8) from the detergent container (2) during the opening of a valve (9) flushed by inlet from the water network (10) and via a line (11) the tub (1
- the enzymes used can be removed from the washing process after use and reused in a later washing process.
- the enzymes are macroscopically encapsulated by means of a washable, but water-insoluble polymer membrane. As a result, the catalytic effect can take place through the membrane without the enzymes being distributed in the washing or cleaning liquor.
- the capsules consist of several interconnected hollow bodies, the enzyme-loaded membrane bodies are the easiest to keep out of the circulation of the liquor, for example during pumping.
- the hollow body can be connected to cartridges and / or plates and / or tubular bodies. As a result, they become a larger unit, which can be stopped mechanically most easily in the lye flow.
- the location is most conveniently protected by a filter against insoluble contaminants from the washing or cleaning liquor.
- capsules or hollow bodies are advantageously filled with set to different types of pollution enzymes. It is best to use a special enzyme for every type of contamination that occurs in machine-washable or cleaning processes.
- the ordinate O of the diagram in Fig. 1 contains unspecified scales for the amount of liquor L in the tub 1 of the washing machine in Fig. 2 , for the temperature T of the liquor and for the amounts of detergent W or enzymes E. On the abscissa A, an unspecified time scale Z is plotted.
- the inlet of water, bypassing a detergent container 2 for the first phase of the water inlet in Fig. 1 is in Fig. 2 not shown.
- the drain pump 3 turned on and the accumulated water, as far as it is not bound in the laundry, fed through the drain line 4 at the bottom of the tub and the circulation line 5 the Enzym representativeer 6.
- the Enzym capableer 6 There it takes up a limited amount of the stored enzymes 7 and transports them into the tub 1, from where it receives the items of laundry together with the laundry in turn wetting lye.
- the enzyme phase is terminated by switching off the pump 3.
- the detergent 8 is rinsed out of the detergent container 2 during the opening of the valve 9 by inlet from the water supply network 10 and fed via line 11 to the tub 1. Then, if necessary, with further supply of water until a desired amount of liquor L and heating the liquor by means of a heater not shown up to a desired temperature T, the detergent W act on the split proteins and carbohydrates and other contaminants on the laundry items and remove them from the laundry. Later they will be together pumped with the spent liquor in a manner not shown from the tub 1 in a sewage network.
- Enzymes 7 can be coated by innovations in process engineering (microsystems) with a thin, porous polymer membrane, which leaves the enzymes in a capsule, but allows an exchange of substances with the environment (required for the decomposition process of proteins and carbohydrates during washing).
- Such macroscopic capsules can be bundled in containers 12 (sieve-like cartridges or crosslinking of the individual capsules with one another into larger structures such as plates, tubular bodies, etc.) in appropriate amounts for the respective process and thus retained as part of the machine in the hydraulic circuit 3 to 6 .
- suitable filters 13 at the entrance and 14 at the exit of the enzyme container 6 may be provided upstream or the washing process should be designed accordingly.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Detail Structures Of Washing Machines And Dryers (AREA)
- Enzymes And Modification Thereof (AREA)
- Treatment Of Fiber Materials (AREA)
Claims (5)
- Machine pour le nettoyage à la machine de textiles, caractérisée en ce qu'elle comporte une cuve de lessive (1) avec une arrivée couplée pour l'eau et l'agent de lavage ainsi que pour faire circuler la lessive dans un récipient (6) contenant des enzymes, l'arrivée d'eau étant rendue possible en contournant un récipient (2) contenant de l'agent de lavage pour la première phase de l'arrivée d'eau et une pompe à lessive (3) étant mise en marche après qu'une certaine quantité d'eau arrivée recouvre le fond de la cuve de lessive (1) et a déjà mouillé le linge, et l'eau arrivée, dans la mesure où elle n'est pas liée dans le linge, étant amenée, par une conduite d'évacuation (4) au fond de la cuve de lessive et une conduite de circulation (5), à un récipient (6) contenant des enzymes où elle se charge d'une quantité limitée d'enzymes stockés (7) et les transporte vers la cuve de lessive (1) d'où le lot de linge les absorbe en même temps que la lessive qui, de son côté, mouille le linge, la coupure de la pompe (3) permettant, à la fin de la phase enzymatique, d'éliminer un agent de lavage (8) du récipient (2) contenant de l'agent de lavage pendant l'ouverture d'une vanne (9) par amenée en provenance du réseau de conduites d'eau (10) et de l'amener à la cuve de lessive (1) par une conduite (11),
des enzymes (E) à action catalytique étant ajoutés, moyennant l'utilisation d'enzymes et d'agents de lavage et/ou de nettoyage hydrosolubles, au processus de lavage ou de nettoyage contre des salissures typiques, à savoir aussi longtemps (t1) que leur action catalytique est souhaitée, et en ce que les enzymes (7) sont encapsulés macroscopiquement au moyen d'une membrane polymère perméable à la lessive, mais non hydrosoluble,
et en ce que les capsules (12) se composent de plusieurs corps creux reliés entre eux, les capsules (12) ou corps creux reliés étant disposés dans une machine destinée au nettoyage de textiles de manière fixe, mais interchangeable, à un endroit (6) accessible par la lessive de lavage ou de nettoyage. - Machine selon la revendication 1, caractérisée en ce que l'endroit (6) est protégé par un filtre (13, 14) contre les impuretés insolubles de la lessive de lavage ou de nettoyage.
- Machine selon l'une des revendications 1 à 2, caractérisée en ce que des capsules (12) ou corps creux sont remplis d'enzymes (7) adaptés à différents types de salissures.
- Machine selon la revendication 3, caractérisée en ce qu'un enzyme spécial est prévu pour chaque type de salissure qui se présente dans des processus de lavage ou de nettoyage utilisables en machine.
- Machine selon l'une des revendications 1 à 4, caractérisée en ce que les corps creux sont reliés pour constituer des cartouches et/ou des plaques et/ou des corps tubulaires.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10053416A DE10053416A1 (de) | 2000-10-27 | 2000-10-27 | Verfahren zum maschinellen Reinigen von Textilien oder festen Gegenständen |
| DE10053416 | 2000-10-27 | ||
| PCT/EP2001/012365 WO2002034873A1 (fr) | 2000-10-27 | 2001-10-25 | Procede de nettoyage mecanique de textiles ou d'objets solides |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP1332204A1 EP1332204A1 (fr) | 2003-08-06 |
| EP1332204B1 EP1332204B1 (fr) | 2008-12-24 |
| EP1332204B2 true EP1332204B2 (fr) | 2016-06-29 |
Family
ID=7661344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01988757.9A Expired - Lifetime EP1332204B2 (fr) | 2000-10-27 | 2001-10-25 | Procede de nettoyage mecanique de textiles ou d'objets solides |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US20030233710A1 (fr) |
| EP (1) | EP1332204B2 (fr) |
| KR (1) | KR100819656B1 (fr) |
| AT (1) | ATE418598T1 (fr) |
| DE (2) | DE10053416A1 (fr) |
| WO (1) | WO2002034873A1 (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8196441B2 (en) | 2008-07-01 | 2012-06-12 | Whirlpool Corporation | Household cleaning appliance with a dispensing system operable between a single use dispensing system and a bulk dispensing system |
| US8286288B2 (en) | 2008-07-01 | 2012-10-16 | Whirlpool Corporation | Method of indicating operational information for a bulk dispensing system |
| US8397544B2 (en) * | 2008-07-01 | 2013-03-19 | Whirlpool Corporation | Household cleaning appliance with a single water flow path for both non-bulk and bulk dispensing |
| US20100000264A1 (en) | 2008-07-01 | 2010-01-07 | Whirlpool Corporation | Method for converting a household cleaning appliance with a non-bulk dispensing system to a household cleaning appliance with a bulk dispensing system |
| US10138587B2 (en) | 2008-07-01 | 2018-11-27 | Whirlpool Corporation | Household cleaning appliance with a dispensing system operable between a single use dispensing system and a bulk dispensing system |
| US20110000511A1 (en) * | 2009-07-01 | 2011-01-06 | General Electric Company | Deep clean cycle |
| US10988881B2 (en) | 2017-07-06 | 2021-04-27 | Whirlpool Corporation | Fabric cleaning appliance with performance enhancement selector |
| USD863237S1 (en) | 2017-09-22 | 2019-10-15 | Whirlpool Corporation | Push button knob with illumination capabilities for a laundry treating appliance |
| US11541105B2 (en) | 2018-06-01 | 2023-01-03 | The Research Foundation For The State University Of New York | Compositions and methods for disrupting biofilm formation and maintenance |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4219620A1 (de) † | 1992-06-16 | 1993-12-23 | Licentia Gmbh | Verfahren zur Reinigungsmittelzugabe bei Haushalt-Geschirrspülmaschinen |
| WO1996015710A1 (fr) † | 1994-11-24 | 1996-05-30 | Unilever N.V. | Procede et composition destines au lavage industriel de vaisselle sans agent de blanchiment |
| DE19907764A1 (de) † | 1998-02-26 | 1999-11-04 | Il Yang Pharm Co Ltd | Verfahren zur Herstellung von magensaftresistentem Pankreatingranulat |
| EP0976819A1 (fr) † | 1998-07-17 | 2000-02-02 | The Procter & Gamble Company | Comprimé détergent |
| EP0979866A1 (fr) † | 1998-07-17 | 2000-02-16 | The Procter & Gamble Company | Comprimé détergent |
| WO2000050557A1 (fr) † | 1999-02-25 | 2000-08-31 | Henkel Kommanditgesellschaft Auf Aktien | Corps moules de produits de lavage et de nettoyage stables au stockage |
| WO2001025527A1 (fr) † | 1999-10-01 | 2001-04-12 | The Procter & Gamble Company | Distributeur de dose intelligent |
| WO2002029150A1 (fr) † | 2000-10-04 | 2002-04-11 | The Procter & Gamble Company | Dispositif de dosage intelligent |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3567076A (en) * | 1967-05-20 | 1971-03-02 | Zanussi A Spa Industrie | Rotary distributor assembly for washing machines |
| US4016040A (en) * | 1969-12-10 | 1977-04-05 | Colgate-Palmolive Company | Preparation of enzyme-containing beads |
| NL7016798A (fr) * | 1970-11-17 | 1972-05-19 | ||
| US3727434A (en) * | 1971-08-10 | 1973-04-17 | Gen Electric | Additive dispensing system |
| US3975931A (en) * | 1972-10-26 | 1976-08-24 | Siemens Electrogerate Gmbh | Flush-in device for an appliance such as a laundry or dishwashing machine |
| US3950277A (en) * | 1973-07-25 | 1976-04-13 | The Procter & Gamble Company | Laundry pre-soak compositions |
| US4365853A (en) * | 1974-05-15 | 1982-12-28 | Colgate-Palmolive Company | Article for storing and dispensing detergent compositions utilizing separate tablets of components |
| US4093417A (en) * | 1974-06-01 | 1978-06-06 | Karl Hans Heinlein | Method for processing textile material |
| US3942341A (en) * | 1974-08-30 | 1976-03-09 | General Electric Company | Additive dispensing system |
| US4107065A (en) * | 1975-11-05 | 1978-08-15 | Colgate-Palmolive Company | Activated peroxy compound bleaching compositions and bleaching detergent compositions |
| FR2574097B1 (fr) * | 1984-11-30 | 1987-01-23 | Amiens Const Electro Mec | Machine a laver le lige possedant une boite a produits de lavage a double usage |
| US4846992A (en) * | 1987-06-17 | 1989-07-11 | Colgate-Palmolive Company | Built thickened stable non-aqueous cleaning composition and method of use, and package therefor |
| US4745021A (en) * | 1986-12-19 | 1988-05-17 | The Procter & Gamble Company | Nonpilling fibrous substrate for pouched laundry products |
| US4756844A (en) | 1986-12-29 | 1988-07-12 | The Dow Chemical Company | Controlled-release composition having a membrane comprising submicron particles |
| US4777682A (en) * | 1987-04-23 | 1988-10-18 | Washex Machinery Corporation | Integral water and heat reclaim system for a washing machine |
| US5078301A (en) * | 1987-10-02 | 1992-01-07 | Ecolab Inc. | Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use |
| FR2660455A1 (fr) * | 1990-04-03 | 1991-10-04 | Chabard Paul | Procede et dispositif d'alimentation d'un compartiment en produits de traitement notamment d'une machine a laver le linge. |
| US5133892A (en) * | 1990-10-17 | 1992-07-28 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing detergent tablets |
| US5388298A (en) * | 1990-11-30 | 1995-02-14 | The Procter & Gamble Company | Device for the machine washing of clothes and the method of utilizing said device |
| GB9103743D0 (en) | 1991-02-22 | 1991-04-10 | Unilever Plc | Laundry treatment product |
| US5589448A (en) * | 1993-02-17 | 1996-12-31 | The Clorox Company | High water liquid enzyme prewash composition |
| DE4324106C1 (de) | 1993-05-25 | 1994-09-15 | Henkel Ecolab Gmbh & Co Ohg | Verfahren und Vorrichtung zur Zudosierung von Wirkstoffen zu einer Spülmaschine |
| US5887753A (en) * | 1994-04-27 | 1999-03-30 | The Procter & Gamble Company | Pretreating dispensing device having a freely rotating ball capable of rotating in all directions |
| IT1270257B (it) * | 1994-06-20 | 1997-04-29 | Tecnoplastica Prealpina Spa | Un complesso valvola di distribuzione-cassetto di miscelazione per la fornitura selettiva di detersivi o altre sostanze alla vasca di lavaglavaggio di una macchina lavatrice o similare |
| US5768917A (en) * | 1996-09-17 | 1998-06-23 | Freida; Leu Shiow Jiuan | Laundry ball |
| WO2001005928A1 (fr) * | 1999-07-14 | 2001-01-25 | Johnsondiversey, Inc. | Composition detergente et procede de lavage du linge |
| EP1072717A1 (fr) | 1999-07-19 | 2001-01-31 | The Procter & Gamble Company | Distributeur de détergent en pastilles |
-
2000
- 2000-10-27 DE DE10053416A patent/DE10053416A1/de not_active Withdrawn
-
2001
- 2001-10-25 WO PCT/EP2001/012365 patent/WO2002034873A1/fr not_active Ceased
- 2001-10-25 EP EP01988757.9A patent/EP1332204B2/fr not_active Expired - Lifetime
- 2001-10-25 DE DE50114603T patent/DE50114603D1/de not_active Expired - Lifetime
- 2001-10-25 AT AT01988757T patent/ATE418598T1/de not_active IP Right Cessation
- 2001-10-25 KR KR1020037003483A patent/KR100819656B1/ko not_active Expired - Fee Related
-
2003
- 2003-04-24 US US10/422,210 patent/US20030233710A1/en not_active Abandoned
-
2007
- 2007-03-02 US US11/713,339 patent/US8101562B2/en not_active Expired - Fee Related
- 2007-03-02 US US11/713,338 patent/US7977295B2/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4219620A1 (de) † | 1992-06-16 | 1993-12-23 | Licentia Gmbh | Verfahren zur Reinigungsmittelzugabe bei Haushalt-Geschirrspülmaschinen |
| WO1996015710A1 (fr) † | 1994-11-24 | 1996-05-30 | Unilever N.V. | Procede et composition destines au lavage industriel de vaisselle sans agent de blanchiment |
| DE19907764A1 (de) † | 1998-02-26 | 1999-11-04 | Il Yang Pharm Co Ltd | Verfahren zur Herstellung von magensaftresistentem Pankreatingranulat |
| EP0976819A1 (fr) † | 1998-07-17 | 2000-02-02 | The Procter & Gamble Company | Comprimé détergent |
| EP0979866A1 (fr) † | 1998-07-17 | 2000-02-16 | The Procter & Gamble Company | Comprimé détergent |
| WO2000050557A1 (fr) † | 1999-02-25 | 2000-08-31 | Henkel Kommanditgesellschaft Auf Aktien | Corps moules de produits de lavage et de nettoyage stables au stockage |
| WO2001025527A1 (fr) † | 1999-10-01 | 2001-04-12 | The Procter & Gamble Company | Distributeur de dose intelligent |
| WO2002029150A1 (fr) † | 2000-10-04 | 2002-04-11 | The Procter & Gamble Company | Dispositif de dosage intelligent |
Non-Patent Citations (1)
| Title |
|---|
| ANDREE H. DR. ET AL: "Waschmittelchemie", 1976, DR. ALFRED HÜTHIG VERLAG, HEIDELBERG, pages: 166 - 167 † |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100819656B1 (ko) | 2008-04-04 |
| US8101562B2 (en) | 2012-01-24 |
| KR20040007394A (ko) | 2004-01-24 |
| EP1332204A1 (fr) | 2003-08-06 |
| DE50114603D1 (de) | 2009-02-05 |
| EP1332204B1 (fr) | 2008-12-24 |
| ATE418598T1 (de) | 2009-01-15 |
| US7977295B2 (en) | 2011-07-12 |
| DE10053416A1 (de) | 2002-05-08 |
| US20070155642A1 (en) | 2007-07-05 |
| WO2002034873A1 (fr) | 2002-05-02 |
| US20070155643A1 (en) | 2007-07-05 |
| US20030233710A1 (en) | 2003-12-25 |
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