EP1405948A1 - Procédé d'impression textile - Google Patents

Procédé d'impression textile Download PDF

Info

Publication number
EP1405948A1
EP1405948A1 EP03019726A EP03019726A EP1405948A1 EP 1405948 A1 EP1405948 A1 EP 1405948A1 EP 03019726 A EP03019726 A EP 03019726A EP 03019726 A EP03019726 A EP 03019726A EP 1405948 A1 EP1405948 A1 EP 1405948A1
Authority
EP
European Patent Office
Prior art keywords
reserve
ink
etching
printing
etching ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03019726A
Other languages
German (de)
English (en)
Inventor
Gerhard Prof. Dr. Schulz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHT Germany GmbH
Original Assignee
Reinhold-Beitlich-Stiftung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reinhold-Beitlich-Stiftung filed Critical Reinhold-Beitlich-Stiftung
Publication of EP1405948A1 publication Critical patent/EP1405948A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/15Locally discharging the dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/12Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/15Locally discharging the dyes
    • D06P5/155Locally discharging the dyes with reductants
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22Effecting variation of dye affinity on textile material by chemical means that react with the fibre
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30Ink jet printing

Definitions

  • the invention relates to a textile printing method in which a textile fabric preferably colored dark with a basic dye and in a pattern area is provided with a printed pattern.
  • the invention further relates to a reserve or etching ink for application to a textile Sheet.
  • the invention is based on the object in the state the disadvantages of the technology to avoid and the textile printing of Motifs on a dark or colored background largely without design To enable restrictions with the least possible production effort.
  • the invention is based on the idea of controlling inkjet printing Do not color or keep the motif free of the basic color. Accordingly, it is proposed according to the invention that the Reserve ink applied to sample area by inkjet printing with the reserve ink being permanently fixed in the pattern area of the basic dye prevented. Alternatively, it is provided that the pattern area an etching ink is applied by ink jet printing, wherein the etching ink in the pattern area destroys the basic dye.
  • the reserve ink Reserving agents based on sulfites, sulfite adducts, thiourea or Preparations thereof.
  • the etching ink contains a suitable reducing agent, in particular sulfoxylates.
  • the basic dye is formed by a vinyl sulfone dye.
  • the full coloring of the fabric with the basic dye can by a block process before or after the reserve or Etching ink done. This allows brilliant colorations with high color strength receive.
  • the textile fabric is preferred subjected to a fixation treatment by the action of saturated steam.
  • a pH regulator can preferably be selected from the group soda, hydrogen carbonate, Sodium hydroxide solution, water glass or potassium carbonate can be activated.
  • An embodiment of the invention provides that the print pattern as a white reserve or white etching is formed.
  • colored dyes alternatively, preferably based on monochlorotriazines, it is possible that the print pattern is formed as a color reserve or color sets.
  • the print head is working line by line, with a large number of parallel channels or pressure nozzles are present to different colors printed closely side by side Print dots additively a halftone dot as the pixel of a digital image or to create a motif.
  • the reserve or etching ink a viscosity regulator based on glycols, especially polyethylene glycol or contains polyacrylates
  • a viscosity in the range from 2 to 10 mPas is favorable for the formation of drops at the nozzle.
  • the reserve or etching ink may contain a preferably nonionic surfactant.
  • the reserve or etching ink hygroscopic additives such as urea or Contains glycerin. Biodegradation, for example, by bacteria delayed because the reserve or caustic ink is a preservative like contains formaldehyde.
  • the reserve or etching ink advantageously contains demineralized water as a carrier.
  • the conductivity of the Reserve or etching ink is less than 60 mS / cm.
  • Another aspect of the invention resides in a reserve ink for application on a textile fabric by inkjet printing, preferably containing one Reserving agent based on sulfites or sulfite adducts to inhibit the fixation of a basic dye.
  • Yet another object of the invention is an etching ink to be applied to a textile fabric by inkjet printing, containing a reducing agent, in particular Sulfoxylates to destroy a basic dye.
  • a preferred use of a reserve or etching ink according to the invention lies in digital textile printing on a dark background using inkjet technology.
  • a suitable etching ink contains a reducing agent instead of the reservation agent, especially sulfoxilates to destroy the base dye.
  • the ink Before use, the ink should be degassed using ultrasound to ensure an undisturbed flow through the ink channels.
  • the textile is pre-padded with a thickener solution based on natural alginates or based on synthetic thickener systems and then dried.
  • the pre-block fleet is composed as follows: 5 - 50 g / kg Na alginate as a thickener; 0-150 g / kg Urea to increase depth of color; 3 g / kg Complexing agents, for example based on polyphosphates; x g / kg Water demineralized.
  • the squeezing effect should be around 80%.
  • the padded goods are, as described above, with the inkjet printer the reserve ink and possibly additionally monochlorotriazine colored dyes printed.
  • the squeezing effect should be approx. 80%.
  • the fixation takes place under saturated steam conditions or with superheated steam in 2 up to 10 minutes. Then the prints, as with reactive dyes usual, washed to the boil.
  • the goods are padded with a padding liquor that contains an alkali dispenser (sodium trichloroacetate or sodium hydrogen carbonate) and the vinyl sulfone dye intended for the fund as well as an anti-migration aid, according to the following recipe example: 10 - 80 g / kg Vinylsulfonfarbstoff; 0-150 g / kg Urea; 3 - 20 g / kg Phosphate; 5 - 50 g / kg alginate; 10 - 100 g / kg Alkalis; x g / kg Water.
  • an alkali dispenser sodium trichloroacetate or sodium hydrogen carbonate
  • vinyl sulfone dye intended for the fund as well as an anti-migration aid
  • the product comes with a fund dye and alginate or synthetic Block liquor containing thickener and then dried.
  • Recipe example for the pre-block fleet 10 - 80 g / kg Vinylsulfonfarbstoff; 0-150 g / kg Urea; 0-10 g / kg Ludigol; 5 - 50 g / kg alginate; 2 g / kg Monosodium phosphate (pH 6-7) as a buffer; x g / kg Water.
  • the padded goods are printed with the inkjet printer as described.
  • the prints are fixed with an alkaline and saline padding liquor padded and then fixed in saturated steam.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)
EP03019726A 2002-09-10 2003-08-29 Procédé d'impression textile Withdrawn EP1405948A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10242216 2002-09-10
DE2002142216 DE10242216A1 (de) 2002-09-10 2002-09-10 Textildruckverfahren

Publications (1)

Publication Number Publication Date
EP1405948A1 true EP1405948A1 (fr) 2004-04-07

Family

ID=31724665

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03019726A Withdrawn EP1405948A1 (fr) 2002-09-10 2003-08-29 Procédé d'impression textile

Country Status (2)

Country Link
EP (1) EP1405948A1 (fr)
DE (1) DE10242216A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108474162A (zh) * 2015-11-09 2018-08-31 扣尼数字有限公司 用于喷墨组合物的拔染试剂

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0107016A2 (fr) * 1982-09-24 1984-05-02 Hoechst Aktiengesellschaft Procédé pour l'impression de matière textile
JPS62232473A (ja) * 1986-04-03 1987-10-12 Canon Inc インクジエツト着色抜染インク
JPS62257486A (ja) * 1986-04-28 1987-11-10 キヤノン株式会社 インクジエツト防染方法
DE19743759A1 (de) * 1997-10-02 1999-04-08 Brueggemann L Kg Sulfinsäurederivate und deren Herstellung und Verwendung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0107016A2 (fr) * 1982-09-24 1984-05-02 Hoechst Aktiengesellschaft Procédé pour l'impression de matière textile
JPS62232473A (ja) * 1986-04-03 1987-10-12 Canon Inc インクジエツト着色抜染インク
JPS62257486A (ja) * 1986-04-28 1987-11-10 キヤノン株式会社 インクジエツト防染方法
DE19743759A1 (de) * 1997-10-02 1999-04-08 Brueggemann L Kg Sulfinsäurederivate und deren Herstellung und Verwendung

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 198750, Derwent World Patents Index; Class A87, AN 1987-353040, XP002268234 *
PATENT ABSTRACTS OF JAPAN vol. 012, no. 103 (C - 485) 5 April 1988 (1988-04-05) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108474162A (zh) * 2015-11-09 2018-08-31 扣尼数字有限公司 用于喷墨组合物的拔染试剂
EP3374561A4 (fr) * 2015-11-09 2019-07-03 Kornit Digital Ltd. Réactif de décoloration pour compositions à jet d'encre

Also Published As

Publication number Publication date
DE10242216A1 (de) 2004-03-18

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