EP1436128A1 - Mat de fibres, piece moulee obtenue a partir dudit mat et procede permettant de le produire - Google Patents
Mat de fibres, piece moulee obtenue a partir dudit mat et procede permettant de le produireInfo
- Publication number
- EP1436128A1 EP1436128A1 EP02782946A EP02782946A EP1436128A1 EP 1436128 A1 EP1436128 A1 EP 1436128A1 EP 02782946 A EP02782946 A EP 02782946A EP 02782946 A EP02782946 A EP 02782946A EP 1436128 A1 EP1436128 A1 EP 1436128A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fiber mat
- fibers
- cellulose fibers
- mat according
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 81
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 19
- 239000004033 plastic Substances 0.000 claims abstract description 16
- 229920003023 plastic Polymers 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 244000198134 Agave sisalana Species 0.000 claims abstract description 3
- 244000025254 Cannabis sativa Species 0.000 claims abstract description 3
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims abstract description 3
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims abstract description 3
- 240000000797 Hibiscus cannabinus Species 0.000 claims abstract description 3
- 240000006240 Linum usitatissimum Species 0.000 claims abstract description 3
- 235000004431 Linum usitatissimum Nutrition 0.000 claims abstract description 3
- 229920000297 Rayon Polymers 0.000 claims abstract description 3
- 235000009120 camo Nutrition 0.000 claims abstract description 3
- 235000005607 chanvre indien Nutrition 0.000 claims abstract description 3
- 239000011487 hemp Substances 0.000 claims abstract description 3
- 239000008240 homogeneous mixture Substances 0.000 claims abstract description 3
- 239000004627 regenerated cellulose Substances 0.000 claims abstract 2
- 238000000465 moulding Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- -1 polypropylene Polymers 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 239000002318 adhesion promoter Substances 0.000 claims description 4
- 239000003063 flame retardant Substances 0.000 claims description 4
- 239000005871 repellent Substances 0.000 claims description 4
- 230000002940 repellent Effects 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims description 2
- 238000007906 compression Methods 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 abstract description 10
- 239000001913 cellulose Substances 0.000 abstract description 10
- 239000002023 wood Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 238000003475 lamination Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 241001417494 Sciaenidae Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000010897 cardboard waste Substances 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/007—Manufacture of substantially flat articles, e.g. boards, from particles or fibres and at least partly composed of recycled material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/002—Manufacture of substantially flat articles, e.g. boards, from particles or fibres characterised by the type of binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/10—Moulding of mats
- B27N3/12—Moulding of mats from fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/18—Auxiliary operations, e.g. preheating, humidifying, cutting-off
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
Definitions
- the invention relates to a fiber mat according to the preamble of claim 1, a molded part produced from this fiber mat and a method for its production.
- DE 2845117 A1 already discloses a process for the production of plate material which can be pressed into molded parts from cellulose-containing material and at least one thermoplastic binder, in which the cellulose-containing material and the thermoplastic binder are mixed and the mixture is formed into plate material in the heated state.
- the cellulose-containing material is defibrated into fiber and mixed with the thermoplastic binders, a fleece is formed from the mixture and the fleece is compressed to the plate material by the action of heat and pressure.
- Waste of cellulose materials such as paper, Cardboard, textiles, etc., however, may also be used, possibly even in a predominant proportion of peat, bark and, in a particularly preferred manner, dried plant parts of annual plants such as straw or the like.
- pulp-containing material such as paper and cardboard waste is broken down into particles with dimensions of approximately 5 ⁇ 5 mm and then fiberized, so that the maximum fiber length is approximately 5 mm.
- a dry powder of fibrous particle nature made of polyethylene is used as the thermoplastic binder. No lengths are given for these particles.
- the molded parts made from this sheet material have a limited strength, so that they usually also contain thermosetting binders.
- the plastic is in the form of fibers with a length in the range of 30-100 mm and the cellulose fibers have a length of 10-100 mm, a relatively dimensionally stable fiber mat can be obtained, in particular after needling, which can be handled without problems until further processing ,
- the molded part obtained from this is given the great length of the cellulose fibers, great strength and impact resistance, especially at very low temperatures.
- the fact that no thermosetting binders are required means that the molded parts can be produced inexpensively, are light in weight and are largely free of emissions and odors and are easily recyclable.
- Preferred cellulose fibers are those which have a length in the range of 50-100 mm, and in particular those whose average length is 70 mm +/- 20%. Their share in the total weight of the fiber mat can be between 10 and 90%.
- the cellulose fibers advantageously consist of natural fibers from annual plants, such as hemp, flax, sisal or kenaf or technical viscose fibers, and also from cellulose regenerate, that is to say synthetic cellulose, which is preferably obtained from wood but does not contain its lignin components. Mixtures of the aforementioned various cellulose fibers can also be used.
- the cellulose fibers Before the formation of the fiber mat, the cellulose fibers can have been chemically, chemically-physically or physically pretreated in a known manner, for example bleached, mercerized, alkalized, ace- ethylated or provided with an adhesion promoter, flame retardant or water repellent.
- Polypropylene is preferably used for the plastic fibers. However, they generally consist of textile fibers, ribbon fibers or fibrous film chips made of polyolyphins, engineering plastics and / or copolymers, as well as mixtures of several polymers (e.g. as bico fibers). In order to obtain a homogeneous fiber mixture, the plastic fibers should have a fineness in the range of 3.3-25 dtex.
- auxiliaries in particular processing aids such as antistatic agents or adhesion promoters, but also water repellents, flame retardants and additives can be added during the manufacture of the mat. However, their total amount should not exceed 10% of the total weight of the mat.
- the fiber mat can be covered on at least one side with a light fleece made of e.g. polypropylene / polyester and with a basis weight of up to 300 g / m 2 are covered.
- the connection between the fiber mat and light fleece is expediently made by needling.
- the manufacture of the fiber mat basically takes place in a known manner, as is known for example from DE 2845117 AI.
- the main steps in mat formation are as follows:
- the corresponding fiber components are delivered in bale form to a processing plant and fed via a bale opener with metering devices, pre-opener, fine opener, fiber finisher, mixing chamber and box storage as a fiber mixture to the fleece system.
- the bale opener releases the cellulose and plastic fibers from the respective bales.
- a weighing device doses the desired mixing ratio of the fibers on a collecting belt.
- the material is transported from the collecting belt to a mixer opener (pre-opener) in which the fiber components are roughly mixed.
- a mixer opener pre-opener
- the following fine opener is used to shorten, refine and clean bast fibers.
- This device is equipped with a trough feed and a sawtooth barrel. Cockroaches and other contaminants are separated by means of expanded metal gratings arranged on the circumference of the tambour.
- the fibers are treated with a spray system with liquid additives such as water repellents, lubricants, flame retardants, antistatic agents, adhesion promoters and the like.
- a stationary rotary separator in the bunker ceiling ensures an even layering of the fibers and the formation of a fiber sandwich.
- This fiber sandwich is milled vertically by an emptying machine.
- the box feeder doses the fiber mixture into a volumetric filler shaft using a flat cloth belt. This doses the fiber cake into the fleece system via a dosing scale.
- the fleece system consists of a pre-fleece and an end fleece.
- a pre-web is produced in the pre-web former either by a carding system or an aerodynamic system.
- the fibers are placed in an oriented manner.
- the homogeneously premixed fiber components in the form of the preliminary nonwoven are broken down from a high-speed sawtooth turret to individual fibers. Due to the centrifugal force, the fibers detach themselves from the tambour and are blown onto the screen surface by the pleasure flow of a cross-flow fan. The simultaneous suction by vacuum fans causes the formation of tangled fleece on the screen surface.
- the subsequent needling of the fiber mats is a mechanical consolidation, which is based on a weaving of the fibers and the increase in friction between the fibers caused by the compaction of the fleece.
- the fleece is first pre-compacted by rolling or a press belt and then fed to the needle machine.
- the endlessly produced needle felt is then cut to mat dimensions for pallet stacking or rolled goods by means of a cross-cut and a longitudinal cut device.
- the mats will stored on pallets via an automatic stacking device.
- the needle fleece is wound onto carrier sleeves.
- the production of the molded parts can take place spatially and temporally separately from the fiber mat production. It is possible to produce the molded part together with a lamination from a fabric, a decorative film or the like in the so-called one-shot process. This can significantly reduce production costs.
- the fiber mat is first fed to a preheating station, in which it is heated to approximately 180 degrees Celsius. At the same time, pre-compression takes place. At this temperature, the plastic fibers melt so that they lose their fiber structure.
- the heated fiber mat is then introduced together with the lamination into a molding press, in which the molding receives its shape and at the same time the lamination is connected to the molding by the molten plastic.
- the molding press has a temperature of less than 80 degrees Celsius, so that the molded part is cooled and the molten plastic solidifies, as a result of which a dimensionally stable molded part can be removed from the molding press.
- Such a molded part which was made from 50 percent by weight of cellulose fibers and 50 percent by weight of polypropylene fibers, has, for example, a density of 1.0 g / cm 3 , a water absorption of 4.5 percent by weight, a flexural modulus of 3500 N / mm 2 and a bending strength of 65-70 N / mm 2 .
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Nonwoven Fabrics (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
L'invention concerne un mat de fibres servant de produit intermédiaire pour produire des pièces moulées d'épaisseur de paroi de préférence identique, consistant en fibres essentiellement à base de cellulose, comprimées avec une matière plastique en mélange homogène. La matière plastique se présente sous forme de fibres d'une longueur de l'ordre de 30 à 100 mm et les fibres de cellulose présentent une longueur de l'ordre de 10 à 100 mm. Les fibres de cellulose se composent de préférence de fibres naturelles obtenues à partir de lin, de sisal, de chanvre, de kenaf, de fibres de viscose techniques ou de mélanges de ces constituants, ou bien à partir de régénérat de cellulose, en d'autres termes notamment de cellulose synthétique issue du bois.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10151368 | 2001-10-17 | ||
| DE2001151368 DE10151368A1 (de) | 2001-10-17 | 2001-10-17 | Fasermatte, daraus hergestelltes Formteil und Verfahren zu dessen Herstellung |
| PCT/EP2002/011653 WO2003033226A1 (fr) | 2001-10-17 | 2002-10-17 | Mat de fibres, piece moulee obtenue a partir dudit mat et procede permettant de le produire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1436128A1 true EP1436128A1 (fr) | 2004-07-14 |
Family
ID=7702872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02782946A Withdrawn EP1436128A1 (fr) | 2001-10-17 | 2002-10-17 | Mat de fibres, piece moulee obtenue a partir dudit mat et procede permettant de le produire |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20040266292A1 (fr) |
| EP (1) | EP1436128A1 (fr) |
| JP (1) | JP2005505445A (fr) |
| DE (1) | DE10151368A1 (fr) |
| WO (1) | WO2003033226A1 (fr) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10326181B4 (de) | 2003-06-06 | 2008-04-30 | Cvp Clean Value Plastics Gmbh | Holzwerkstoffplatte und Verfahren zu ihrer Herstellung |
| US20050253031A1 (en) * | 2004-04-22 | 2005-11-17 | Bushey Richard D | Formed felt device and method of making the same |
| DE102004022464B4 (de) * | 2004-05-06 | 2011-08-18 | Techtex GmbH Vliesstoffe, 09648 | Formteil für die Innenausstattung von Fahrzeugen |
| US7609638B2 (en) * | 2004-10-04 | 2009-10-27 | Lg Electronics Inc. | Message transmission in wireless access system |
| DE102004053131A1 (de) * | 2004-10-29 | 2006-05-11 | Faurecia Innenraum Systeme Gmbh | Flächiges Halbzeug aus einem Faserverbundwerkstoff und Verfahren zur Herstellung eines Formteils |
| US7996235B2 (en) * | 2005-08-10 | 2011-08-09 | General Motors Llc | Telematics marketing information acquisition triggering method and system |
| FI122418B (fi) * | 2007-12-13 | 2012-01-13 | Valtion Teknillinen | Luonnonkuitupohjainen komposiittimateriaali |
| FR2960937B1 (fr) * | 2010-06-07 | 2013-05-17 | Cavac Biomateriaux | Materiau isolant |
| BE1020055A5 (nl) * | 2011-07-08 | 2013-04-02 | Oosterlynck Lin Luc | Constructie-eenheid uit plaatvormig materiaal en werkwijze voor de vervaardiging ervan. |
| DE102013007283A1 (de) * | 2013-04-27 | 2014-03-06 | Volkswagen Ag | Innenverkleidungsbauteil aus naturfaserverstärktem Kunststoff |
| DE102013111459A1 (de) * | 2013-10-17 | 2015-04-23 | Elringklinger Ag | Akustisch wirksame Abschirmteile und Abdeckungen |
| DE202016002946U1 (de) * | 2016-05-03 | 2017-08-04 | Spengler Technology GmbH | Verbundwerkstoff |
| DE102021004823A1 (de) * | 2021-09-26 | 2023-03-30 | Dieffenbacher GmbH Maschinen- und Anlagenbau | Windstreukammer und Verfahren zum Streuen und Formen eines rieselfähigen Materials auf einem Formband |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2845117C2 (de) * | 1978-10-17 | 1985-03-07 | Casimir Kast Gmbh & Co Kg, 7562 Gernsbach | Verfahren und Anlage zur Herstellung von zu Formteilen verpreßbarem Plattenmaterial |
| US4418031A (en) * | 1981-04-06 | 1983-11-29 | Van Dresser Corporation | Moldable fibrous mat and method of making the same |
| GB2209352A (en) * | 1987-09-04 | 1989-05-10 | Wilkie J & D Ltd | Non-woven sheet material which includes jute fibres and thermoplastic material |
| AT387798B (de) * | 1987-12-11 | 1989-03-10 | Kuehnsdorfer Gmbh | Verfahren zur herstellung einer lagerfaehigen, handhabbaren fasermatte und nach dem verfahren hergestellte fasermatte |
| DK162535C (da) * | 1989-11-30 | 1992-03-30 | Dansk Hoerindustri As | Hoerfiberfiltplade |
| FI94325C (fi) * | 1992-05-27 | 1995-08-25 | Valmet Paper Machinery Inc | Menetelmä ja laitteisto kuitutuotteen valmistamiseksi |
| DE19535559C1 (de) * | 1995-09-12 | 1997-05-15 | Lignotock Gmbh | Flexible, in der Wärme verpreßbare Holzwerkstoffmatte |
| DE19602551C1 (de) * | 1996-01-25 | 1997-08-07 | Asglawo Gmbh Stoffe Zum Daemme | Matte für die Herstellung selbsttragender Formteile durch Warmumformung |
| JPH10273859A (ja) * | 1997-03-28 | 1998-10-13 | Ikeda Bussan Co Ltd | 内装基材原反 |
-
2001
- 2001-10-17 DE DE2001151368 patent/DE10151368A1/de not_active Withdrawn
-
2002
- 2002-10-17 WO PCT/EP2002/011653 patent/WO2003033226A1/fr not_active Ceased
- 2002-10-17 US US10/492,579 patent/US20040266292A1/en not_active Abandoned
- 2002-10-17 JP JP2003536000A patent/JP2005505445A/ja active Pending
- 2002-10-17 EP EP02782946A patent/EP1436128A1/fr not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| See references of WO03033226A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20040266292A1 (en) | 2004-12-30 |
| DE10151368A1 (de) | 2003-05-08 |
| WO2003033226A1 (fr) | 2003-04-24 |
| JP2005505445A (ja) | 2005-02-24 |
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Legal Events
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