EP1525060A1 - Verfahren und vorrichtung zur kontinuierlichen herstellung metallischer bänder - Google Patents
Verfahren und vorrichtung zur kontinuierlichen herstellung metallischer bänderInfo
- Publication number
- EP1525060A1 EP1525060A1 EP03766145A EP03766145A EP1525060A1 EP 1525060 A1 EP1525060 A1 EP 1525060A1 EP 03766145 A EP03766145 A EP 03766145A EP 03766145 A EP03766145 A EP 03766145A EP 1525060 A1 EP1525060 A1 EP 1525060A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strip
- rolling
- chemical treatment
- heating
- rolling process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000010924 continuous production Methods 0.000 title claims abstract description 7
- 238000005096 rolling process Methods 0.000 claims abstract description 53
- 238000010438 heat treatment Methods 0.000 claims abstract description 21
- 239000000126 substance Substances 0.000 claims abstract description 19
- 238000005554 pickling Methods 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 5
- 238000009966 trimming Methods 0.000 claims description 5
- 238000005238 degreasing Methods 0.000 claims description 4
- 238000005097 cold rolling Methods 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 abstract description 5
- 239000010959 steel Substances 0.000 abstract description 5
- 238000000137 annealing Methods 0.000 description 19
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 238000005422 blasting Methods 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000013980 iron oxide Nutrition 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
- B21B1/28—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by cold-rolling, e.g. Steckel cold mill
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B15/0035—Forging or pressing devices as units
- B21B15/005—Lubricating, cooling or heating means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B3/02—Rolling special iron alloys, e.g. stainless steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/28—Control of flatness or profile during rolling of strip, sheets or plates
- B21B37/44—Control of flatness or profile during rolling of strip, sheets or plates using heating, lubricating or water-spray cooling of the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/04—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing
- B21B45/06—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing of strip material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/004—Heating the product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49988—Metal casting
- Y10T29/49991—Combined with rolling
Definitions
- the invention relates to a process for the continuous production of a metallic, preferably cold-rolled strip, in particular a stainless steel strip, the strip to be produced being passed in a conveying direction through a device in which the strip is subjected to a rolling process, heating and chemical treatment. Furthermore, the invention relates to a device, in particular for performing the method.
- a metal strip passes through a production device in which various processes are carried out on the strip.
- the strip is reduced in thickness in a rolling process. It can also be followed by heat treatment, which gives the strip special material properties.
- the strip must have a scale-free surface, which is why it passes a pickling line in which the scale is removed by means of a chemical treatment.
- the hot-rolled steel strip For further processing - e.g. B. by cold rolling, for a metallic coating or direct processing into an end product - the hot-rolled steel strip must have a scale-free surface. Therefore, the scale created during hot rolling and during the subsequent cooling must be removed completely. This is usually done by a pickling process, with the scale consisting of the various iron oxides (FeO, Fe 3 O 4 , Fe 2 O 3 ) or, in the case of stainless steels, also of chromium-rich iron oxides, depending on the steel quality, using various acids (e.g. hydrochloric acid, sulfuric acid) , Nitric acid or mixed acid) is dissolved at elevated temperatures by chemical reaction with the acid.
- various acids e.g. hydrochloric acid, sulfuric acid
- Nitric acid Nitric acid
- a method or a device of the generic type is known from DE 100 22 045 C1. It is disclosed there that a strip is guided through a pickling device, a rolling unit being arranged in front of and behind the pickling device. In the conveying direction of the strip behind the second rolling unit, the strip passes through an annealing furnace and then a pickling tank in which the scale is removed from the surface of the strip. Before winding the finished strip to this extent, it can still be processed in a skin pass mill.
- WO 00/37189 and WO 00/37190 disclose a device for producing a metal strip, in which the strip is first reduced in thickness in a multi-stand rolling mill. The strip then goes into an annealing furnace; in the further course the strip is led through a pickling device. Before the strip is wound up, a rolling operation can also follow here, but this only makes a slight reduction in thickness on the strip.
- US 2001/0037667 A1 discloses a similar device for producing a metal strip. However, there is no heating of the belt here. The strip is only passed through a rolling mill in a pickling line after descaling.
- the equipment downstream of the rolling mill and here in particular the annealing furnace and the pickling line, is adapted in its dimensions to the strip thickness typically reduced by 30 to 40% by the rolling process Need to become; As the strip is already thinner but longer, the annealing furnace and pickling line must also be designed to be long enough, which leads to high system costs.
- the invention is therefore based on the object of creating a method and an associated device of the type mentioned at the outset with which it is possible to avoid the disadvantages mentioned, which in particular means greater productivity and economy in the production of a Tape to be achieved; the surface quality of the finished strip is also to be improved.
- this object is achieved in that the rolling process is carried out only after the strip has been heated and after the chemical treatment.
- the heating of the strip, the chemical treatment of the strip and the rolling process are preferably carried out in this order.
- the rolling process is preferably a tandem rolling process.
- the rolling process here means that the thickness of the strip is reduced significantly, preferably by at least 20%.
- the chemical treatment of the strip is preferably a pickling process.
- the inventive device for the continuous production of a metallic, cold-rolled strip has a device for heating, i. H. in particular for annealing the strip, a device for chemically treating the strip and a device for rolling the strip.
- the device for rolling the strip in the conveying direction is arranged behind the device for heating the strip and the device for chemically treating the strip, the device for rolling the strip having at least one tandem rolling train.
- This consists of several rolling stands, which can be designed as a 6-high rolling mill or as a Z-high rolling mill. Apart from this rolling device, no further device is required to reduce the thickness of the strip.
- a stretch-leveling unit can also be arranged between the device for heating the strip (annealing furnace) and the device for chemical treatment of the strip (pickling line). Furthermore, a metal grain blasting unit can be arranged between the annealing furnace and the pickling line. A trimming unit can also be arranged in the conveying direction behind the device for chemical treatment of the tape in order to cut the tape laterally.
- the device has at least one, preferably three, belt stores.
- the manufacturing device explained can also be operated as a combined hot and cold strip annealing and pickling line with an integrated rolling mill (tandem mill).
- a degreasing device can additionally be arranged in the conveying direction in front of the device for heating the belt, in particular in front of the infeed belt store.
- FIG. 1 An embodiment of the invention is shown.
- the single figure shows schematically a device for producing a stainless steel strip.
- the figure shows a device 2 on which a metal strip 1 (metal strand) is processed.
- the belt 1 is in the conveying direction R - d. H. in the figure from left to right - guided by the device 2, a continuous passage of the belt 1 (passage with a largely constant belt speed) being sought.
- the belt 1 is fed to the device 2 in an inlet section 13, not shown in detail.
- the tape 1 is unwound from an unwinding unit, not shown, and passed into the device 2.
- a degreasing device 12 follows in the conveying direction R, in which the belt surface is cleaned.
- the strip 1 then arrives in a strip store 9 (inlet store) which is positioned below a device 3 for heating the strip 1 (annealing furnace). It can be achieved via the tape store 9 that Continuous running of the belt is achieved even with minor external disturbances in the belt feed.
- the strip 1 is subjected to a heat treatment in the annealing furnace 3. Then there is a stretch leveling unit 6, in which the strip 1 is smoothed. A metal grain blasting unit 7 is arranged downstream of the stretch-leveling unit 6.
- a device 4 for the chemical treatment of the strip 1 is arranged, namely a pickling line, in which the strip 1 is guided through pools which are filled with acid.
- a strip store 11 (intermediate store) is arranged below the pickling line 4. From this the tape 1 runs into a trimming unit 8 in which the sides of the tape 1 are cut. The strip 1 passes from the trimming unit 8 via a further strip store 10 (outlet store) to the device 5 for rolling the strip 1.
- This device 5 is designed as a tandem rolling mill. There are three rolling stands 5a, 5b and 5c arranged one behind the other, in which the strip 1 is rolled and its thickness is thereby reduced.
- An outlet section 14 is arranged behind the tandem rolling mill 5 and has a winding unit (not shown) with which the finished strip 1 can be wound up.
- the tandem rolling mill 5 has three roll stands 5a, 5b and 5c, which can be designed in the form of a multi-roll cold rolling mill, a 6-high rolling mill or a Z-high rolling mill.
- the fact that the thickness of the strip 1 is only reduced in the only device 5 for rolling the strip 1 at the end of the device 2 shows the strip 1 in front of the tandem mill 5 a relatively large thickness, namely the thickness with which the strip 1 enters the device 2.
- the consequence of this is that the overall length of both the annealing furnace 3 and the pickling line 4 can be kept relatively short.
- Both the annealing furnace 3 and the pickling line 4 can thus be designed for the original thickness of the strip 1 with which the strip 1 enters the device 2.
- the thickness can be reduced without prior annealing, which leads to a smaller maximum thickness reduction of a maximum of 30 to 40%.
- the maximum thickness reduction of the strip 1 per pass through the device 2 depends only on the materials and the performance of the tandem rolling mill 5; no consideration has to be given to the unannealed strip.
- a roll stand of the tandem rolling mill 5 can be designed such that the strip 1 can be treated during a final annealing.
- the descaled and preferably already trimmed strip - following the device 2 - can run continuously into a downstream device (hot-dip galvanizing system, etc.) without intermediate storage and with uniform strip tension.
- the finished strip can be alternately wound up with two reels behind the downstream device and divided with scissors. LIST OF REFERENCE NUMBERS
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metal Rolling (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Winding, Rewinding, Material Storage Devices (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Manufacturing Of Electric Cables (AREA)
- Coating With Molten Metal (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10234109A DE10234109A1 (de) | 2002-07-26 | 2002-07-26 | Verfahren und Vorrichtung zur kontinuierlichen Herstellung metallischer Bänder |
| DE10234109 | 2002-07-26 | ||
| PCT/EP2003/007464 WO2004012878A1 (de) | 2002-07-26 | 2003-07-10 | Verfahren und vorrichtung zur kontinuierlichen herstellung metallischer bänder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1525060A1 true EP1525060A1 (de) | 2005-04-27 |
| EP1525060B1 EP1525060B1 (de) | 2006-08-30 |
Family
ID=30010423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP03766145A Expired - Lifetime EP1525060B1 (de) | 2002-07-26 | 2003-07-10 | Verfahren und anlage zur kontinuierlichen herstellung metallischer bänder |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20060053617A1 (de) |
| EP (1) | EP1525060B1 (de) |
| JP (1) | JP2006502003A (de) |
| KR (1) | KR100990865B1 (de) |
| CN (1) | CN1671490A (de) |
| AT (1) | ATE337862T1 (de) |
| AU (1) | AU2003250025B2 (de) |
| BR (1) | BR0312756B1 (de) |
| DE (2) | DE10234109A1 (de) |
| ES (1) | ES2271651T3 (de) |
| MX (1) | MXPA05001083A (de) |
| RU (1) | RU2350415C2 (de) |
| TW (1) | TWI273929B (de) |
| WO (1) | WO2004012878A1 (de) |
| ZA (1) | ZA200500458B (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI389747B (zh) * | 2007-10-16 | 2013-03-21 | Ihi Metaltech Co Ltd | 鎂合金板之重捲設備 |
| KR101103346B1 (ko) * | 2009-07-14 | 2012-01-11 | 주식회사 동방플랜텍 | 냉연 강판의 프로세싱 라인장치 |
| RU2499640C1 (ru) * | 2012-06-14 | 2013-11-27 | Открытое акционерное общество "Северсталь" (ОАО "Северсталь") | Способ производства холоднокатаного проката для упаковочной ленты |
| RU2592609C1 (ru) * | 2015-04-21 | 2016-07-27 | Публичное акционерное общество "Северсталь" (ПАО "Северсталь") | Способ производства холоднокатаного проката для упаковочной ленты |
| TWI625172B (zh) * | 2016-09-19 | 2018-06-01 | 複合式冷軋線 | |
| RU2769149C1 (ru) * | 2018-09-28 | 2022-03-28 | ДжФЕ СТИЛ КОРПОРЕЙШН | Способ изготовления листа из текстурированной электротехнической стали и стан холодной прокатки |
| CN116851490A (zh) * | 2023-06-06 | 2023-10-10 | 中铝瑞闽股份有限公司 | 一种可消除铝板带碱液痕方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05161901A (ja) * | 1991-12-12 | 1993-06-29 | Sumitomo Metal Ind Ltd | 表面光沢の良好な冷延金属帯の製造方法 |
| JPH07164008A (ja) * | 1993-12-15 | 1995-06-27 | Nkk Corp | 酸洗−冷間圧延設備 |
| JPH0824936A (ja) * | 1994-07-15 | 1996-01-30 | Nisshin Steel Co Ltd | 金属帯の圧延方法および設備 |
| JPH08246060A (ja) * | 1995-03-10 | 1996-09-24 | Kawasaki Steel Corp | 缶用鋼板の製造方法 |
| DE19532278B4 (de) * | 1995-09-01 | 2006-07-27 | Bwg Bergwerk- Und Walzwerk-Maschinenbau Gmbh | Verfahren zur Herstellung eines kaltgewalzten Bandes in einem Durchlauf |
| FR2775205B1 (fr) * | 1998-02-25 | 2000-03-24 | Usinor | Installation de fabrication de bandes d'acier inoxydable laminees a froid |
| BR9916306A (pt) * | 1998-12-18 | 2001-11-20 | Avesta Sheffield Ab | Método para fabricação de tiras e linha delaminação |
| JP3460612B2 (ja) * | 1999-03-04 | 2003-10-27 | Jfeスチール株式会社 | 表面欠陥計を備えるプロセスライン |
| JP3695212B2 (ja) * | 1999-03-30 | 2005-09-14 | Jfeスチール株式会社 | ステンレス鋼帯の冷間圧延方法 |
| DE10022045C1 (de) * | 2000-02-22 | 2001-07-19 | Sundwig Gmbh | Fertigungslinie und Verfahren zum kontinuierlichen Herstellen von kaltgewalzten metallischen Bändern |
| JP2001262232A (ja) * | 2000-03-15 | 2001-09-26 | Kawasaki Steel Corp | ステンレス鋼帯の製造方法 |
| FR2807957B1 (fr) * | 2000-04-21 | 2002-08-02 | Vai Clecim | Procede et installation de laminage a froid |
| JP2001340905A (ja) * | 2000-05-31 | 2001-12-11 | Kawasaki Steel Corp | 黒皮鋼板の圧延方法 |
-
2002
- 2002-07-26 DE DE10234109A patent/DE10234109A1/de not_active Withdrawn
-
2003
- 2003-07-03 TW TW092118181A patent/TWI273929B/zh active
- 2003-07-10 DE DE50304876T patent/DE50304876D1/de not_active Expired - Fee Related
- 2003-07-10 AT AT03766145T patent/ATE337862T1/de not_active IP Right Cessation
- 2003-07-10 US US10/522,484 patent/US20060053617A1/en not_active Abandoned
- 2003-07-10 BR BRPI0312756-7A patent/BR0312756B1/pt not_active IP Right Cessation
- 2003-07-10 CN CNA03817975XA patent/CN1671490A/zh active Pending
- 2003-07-10 EP EP03766145A patent/EP1525060B1/de not_active Expired - Lifetime
- 2003-07-10 ES ES03766145T patent/ES2271651T3/es not_active Expired - Lifetime
- 2003-07-10 MX MXPA05001083A patent/MXPA05001083A/es active IP Right Grant
- 2003-07-10 RU RU2005105314/02A patent/RU2350415C2/ru not_active IP Right Cessation
- 2003-07-10 JP JP2004525173A patent/JP2006502003A/ja active Pending
- 2003-07-10 WO PCT/EP2003/007464 patent/WO2004012878A1/de not_active Ceased
- 2003-07-10 KR KR1020057001351A patent/KR100990865B1/ko not_active Expired - Fee Related
- 2003-07-10 AU AU2003250025A patent/AU2003250025B2/en not_active Ceased
-
2005
- 2005-01-18 ZA ZA200500458A patent/ZA200500458B/en unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2004012878A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200414942A (en) | 2004-08-16 |
| KR20050021565A (ko) | 2005-03-07 |
| AU2003250025A1 (en) | 2004-02-23 |
| WO2004012878A1 (de) | 2004-02-12 |
| CN1671490A (zh) | 2005-09-21 |
| AU2003250025B2 (en) | 2008-08-28 |
| DE50304876D1 (de) | 2006-10-12 |
| DE10234109A1 (de) | 2004-02-05 |
| KR100990865B1 (ko) | 2010-10-29 |
| BR0312756A (pt) | 2005-04-26 |
| RU2005105314A (ru) | 2005-07-20 |
| MXPA05001083A (es) | 2005-06-06 |
| ZA200500458B (en) | 2006-04-26 |
| US20060053617A1 (en) | 2006-03-16 |
| ES2271651T3 (es) | 2007-04-16 |
| RU2350415C2 (ru) | 2009-03-27 |
| EP1525060B1 (de) | 2006-08-30 |
| TWI273929B (en) | 2007-02-21 |
| BR0312756B1 (pt) | 2011-05-31 |
| JP2006502003A (ja) | 2006-01-19 |
| ATE337862T1 (de) | 2006-09-15 |
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