Classifications

• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
  • G02F1/166—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
  • G02F1/167—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
  • G02F1/1675—Constructional details
  • G02F1/16757—Microcapsules
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
  • G02F1/1675—Constructional details
  • G02F1/1677—Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• • E—FIXED CONSTRUCTIONS
  • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
  • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
  • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
  • E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
  • E06B2009/2464—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
  • G02F1/1675—Constructional details
  • G02F1/1679—Gaskets; Spacers; Sealing of cells; Filling or closing of cells
  • G02F1/1681—Gaskets; Spacers; Sealing of cells; Filling or closing of cells having two or more microcells partitioned by walls, e.g. of microcup type
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
  • G02F1/1675—Constructional details
  • G02F2001/1678—Constructional details characterised by the composition or particle type
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F2201/00—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
  • G02F2201/12—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00 electrode

Definitions

• LIGHT MODULATORS This invention relates to light modulators, that is to say to variable transmission windows, mirrors and similar devices designed to modulate the amount of light or other electro-magnetic radiation passing therethrough; for convenience, the term "light” will normally be used herein, but this term should be understood in a broad sense to include electro-magnetic radiation at non-visible wavelengths.
• the present invention may be applied to provide windows which can modulate infra-red radiation for controlling temperatures within buildings. More specifically, this invention relates to light modulators which use particle-based electrophoretic media to control light modulation.
• Particle-based electrophoretic displays in which a plurality of charged particles move through a suspending fluid under the influence of an electric field, have been the subject of intense research and development for a number of years.
• Such displays can have attributes of good brightness and contrast, wide viewing angles, state bistability, and low power consumption when compared with liquid, crystal displays.
• bistable and “bistability” are used herein in their conventional meaning in the art to refer to displays comprising display elements having first and second display states differing in at least one optical property, and such that after any given element has been driven, by means of an addressing pulse of finite duration, to assume either its first or second display state, after the addressing pulse has terminated, that state will persist for at least several times, for example at least four times, the minimum duration of the addressing pulse required to change the state of the display element. It is shown in published U.S. Patent Application No. 2002/0180687 that some particle-based electrophoretic displays capable of gray scale are stable not only in their extreme black and white states but also in their intermediate gray states, and the same is true of some other types of electro-optic displays.
• bistable This type of display is properly called “multi-stable” rather than bistable, although for convenience the term “bistable” may be used herein to cover both bistable and multi-stable displays. Nevertheless, problems with the long-term image quality of these displays have prevented their widespread usage. For example, particles that make up electrophoretic displays tend to settle, resulting in inadequate service-life for these displays. As noted above, electrophoretic media require the presence of a suspending fluid.
• this suspending fluid is a liquid, but electrophoretic media can be produced using gaseous suspending fluids; see, for example, Kitamura, T., et al, "Electrical toner movement for electronic paper-like display", IDW Japan, 2001, Paper HCSl-1, and Yamaguchi, Y., et al., "Toner display using insulative particles charged triboelectrically", IDW Japan,
• encapsulated electrophoretic media comprise numerous small capsules, each of which itself comprises an internal phase containing electrophoretically-mobile particles suspended in a liquid suspending medium, and a capsule wall surrounding the internal phase.
• the capsules are themselves held within a polymeric binder to form a coherent layer positioned between two electrodes.
• Encapsulated media of this type are described, for example, in U.S. Patents Nos. 5,930,026; 5,961,804; 6,017,584; 6,067,185
• a single particle medium has only a single type of electrophoretic particle suspended in a suspending medium, at least one optical characteristic of which differs from that of the particles. (In referring to a single type of particle, we do not imply that all particles of the type are absolutely identical.
• the medium can display the optical characteristic of the particles (when the particles are adjacent the electrode closer to the observer, hereinafter called the "front” electrode) or the optical characteristic of the suspending medium (when the particles are adjacent the electrode remote from the observer, hereinafter called the "rear” electrode (so that the particles are hidden by the suspending medium).
• a dual particle medium has two different types of particles differing in at least one optical characteristic and a suspending fluid which may be uncolored or colored, but which is typically uncolored.
• the two types of particles differ in electrophoretic mobility; this difference in mobility may be in polarity (this type may hereinafter be referred to as an "opposite charge dual particle" medium) and/or magnitude.
• the medium can display the optical characteristic of either set of particles, although the exact manner in which this is achieved differs depending upon whether the difference in mobility is in polarity or only in magnitude. For ease of illustration, consider an electrophoretic medium in which one type of particles is black and the other type white.
• the two types of particles differ in polarity (if, for example, the black particles are positively charged and the white particles negatively charged), the particles will be attracted to the two different electrodes, so that if, for example, the front electrode is negative relative to the rear electrode, the black particles will be attracted to the front electrode and the white particles to the rear electrode, so that the medium will appear black to the observer. Conversely, if the front electrode is positive relative to the rear electrode, the white particles will be attracted to the front electrode and the black particles to the rear electrode, so that the medium will appear white to the observer.
• both types of particles have charges of the same polarity, but differ in electrophoretic mobility (this type of medium may hereinafter to referred to as a "same polarity dual particle" medium), both types of particles will be attracted to the same electrode, but one type will reach the electrode before the other, so that the type facing the observer differs depending upon the electrode to which the particles are attracted. For example suppose the previous illustration is modified so that both the black and white particles are positively charged, but the black particles have the higher electrophoretic mobility.
• both the black and white particles will be attracted to the front electrode, but the black particles, because of their higher mobility will reach it first, so that a layer of black particles will coat the front electrode and the medium will appear black to the observer.
• both the black and white particles will be attracted to the rear electrode, but the black particles, because of their higher mobility will reach it first, so that a layer of black particles will coat the rear electrode, leaving a layer of white particles remote from the rear electrode and facing the observer, so that the medium will appear white to the observer: note that this type of dual particle medium requires that the suspending fluid be sufficiently transparent to allow the layer of white particles remote from the rear electrode to be readily visible to the observer.
• the suspending fluid in such a display is not colored at all, but some color may be incorporated for the purpose of correcting any undesirable tint in the white particles seen therethrough.
• Both single and dual particle electrophoretic displays may be capable of intermediate gray states having optical characteristics intermediate the two extreme optical states already described.
• Some of the aforementioned patents and published applications disclose encapsulated electrophoretic media having three or more different types of particles within each capsule. For purposes of the present application, such multi- particle media are regarded as sub-species of dual particle media.
• the walls surrounding the discrete microcapsules in an encapsulated electrophoretic medium could be replaced by a continuous phase, thus producing a so-called polymer-dispersed electrophoretic display, in which the electrophoretic medium comprises a plurality of discrete droplets of an electrophoretic fluid and a continuous phase of a polymeric material, and that the discrete droplets of electrophoretic fluid within such a polymer-dispersed electrophoretic display may be regarded as capsules or microcapsules even though no discrete capsule membrane is associated with each individual droplet; see for example, the aforementioned 2002/0131147.
• microcell electrophoretic display In a microcell electrophoretic display, the charged particles and the suspending fluid are not encapsulated within microcapsules but instead are retained within a plurality of cavities formed within a carrier medium, typically a polymeric film. See, for example, International Application Publication No. WO 02/01281, and published US Application No. 2002/0075556, both assigned to Sipix Imaging, Inc.
• electrophoretic media are often opaque (since, for example, in many electrophoretic media, the particles substantially block transmission of visible light through the display) and operate in a reflective mode
• many electrophoretic displays can be made to operate in a so-called "shutter mode" in which one display state is substantially opaque and one is light-transmissive.
• Shutter mode in which one display state is substantially opaque and one is light-transmissive.
• Dielectrophoretic displays which are similar to electrophoretic displays but rely upon variations in electric field strength, can operate in a similar mode; see U.S. Patent No.
• An encapsulated or microcell elecfrophoretic display typically does not suffer from the clustering and settling failure mode of traditional electrophoretic devices and provides further advantages, such as the ability to print or coat the display on a wide variety of flexible and rigid substrates.
• the word “printing” is intended to include all forms of printing and coating, including, but without limitation: pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating; roll coating such as knife over roll coating, forward and reverse roll coating; gravure coating; dip coating; spray coating; meniscus coating; spin coating; brush coating; air knife coating; silk screen printing processes; electrostatic printing processes; thermal printing processes; ink jet printing processes; electrophoretic deposition; and other similar techniques.
• pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating
• roll coating such as knife over roll coating, forward and reverse roll coating
• gravure coating dip coating
• spray coating meniscus coating
• spin coating spin coating
• brush coating air knife coating
• silk screen printing processes electrostatic printing processes
• thermal printing processes ink jet printing processes
• electrophoretic deposition electrophoretic deposition
• electrophoretic deposition and other similar techniques.
• electrophoretic media could be used as coatings on windows to enable the proportion of incident radiation transmitted through the windows to be electronically controlled by varying the optical state of the electrophoretic media.
• Effective implementation of such "variable- transmissivity" (“NT") technology in buildings is expected to provide (1) reduction of unwanted heating effects during hot weather, thus reducing the amount of energy needed for cooling, the size of air conditioning plants, and peak electricity demand; (2) increased use of natural daylight, thus reducing energy used for lighting and peak electricity demand; and (3) increased occupant comfort by increasing both thermal and visual comfort. Even greater benefits would be expected to accrue in an automobile, where the ratio of glazed surface to enclosed volume is significantly larger than in a typical building.
• NT technology in automobiles is expected to provide not only the aforementioned benefits but also (1) increased motoring safety, (2) reduced glare, (3) enhanced mirror performance (by using an electro-optic coating on the mirror), and (4) increased ability to use heads-up displays.
• Other potential applications include of
• NT technology include privacy glass and glare-guards in electronic devices.
• the present invention relates to adapting particle-based electrophoretic media, which may be encapsulated or unencapsulated, for use in light modulators.
• this invention provides an electrophoretic medium comprising a suspending fluid and a plurality of electrically charged particles disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the suspending fluid, the suspending fluid and electrically charged particles being present as a plurality of discrete droplets, the electrophoretic medium further comprising a continuous phase surrounding the droplets, wherein the difference between the refractive index of the suspending fluid and the continuous phase is not greater than 0.07.
• the index matched suspending fluid medium of the invention for convenience be called the "index matched suspending fluid" medium of the invention.
• the difference between the refractive index of the suspending fluid and the continuous phase is not greater than 0.05, preferably less than 0.03, and the smaller this difference can be made the better, the ideal being of course to have the two refractive indices exactly the same, although in practice this may be difficult to achieve given the other limitations on the materials to be used.
• the index matched suspending fluid medium of the invention can be of several different types.
• the elecfrophoretic medium may be an encapsulated electrophoretic medium in which the continuous phase comprises a plurality of capsule walls surrounding the droplets.
• the electrophoretic medium may be a polymer-dispersed electrophoretic medium in which a polymeric binder is in direct contact with the suspending fluid.
• the electrophoretic medium may also be of the microcell type with a continuous phase comprising a carrier medium having a plurality of closed cavities from therein, with the droplets being confined within the cavities.
• the suspending fluid comprises a mixture of a hydrocarbon and chloronaphthalene.
• This invention extends to an electrophoretic display comprising a layer of an index matched suspending fluid medium of the invention and elecfrode means arranged to apply an electric field to the electrophoretic medium, the electrode means being arranged to drive the electrophoretic medium to a non-light- fransmissive state, in which the particles occupy a major proportion of the area of the layer, thereby rendering the layer substantially non-light-transmissive, and a fransmissive state, in which the particles occupy only a minor proportion of the area of the layer, thereby rendering the layer substantially light-transmissive.
• this invention provides an electrophoretic medium comprising a suspending fluid and a plurality of electrically charged particles disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the suspending fluid, the suspending fluid and electrically charged particles being present as a plurality of discrete droplets, each droplet being surrounded by a capsule wall, the electrophoretic medium further comprising a polymeric binder phase surrounding the capsule walls, wherein the difference between the refractive index of the capsule walls and the polymeric binder is not greater than 0.07.
• This aspect of the invention may hereinafter for convenience be called the "index matched binder" medium of the invention.
• the difference between the refractive index of the capsule walls and the polymeric binder is not greater than 0.05, preferably less than 0.03, and the smaller this difference can be made the better, the ideal being of course to have the two refractive indices exactly the same, although in practice this may be difficult to achieve given the other limitations on the materials to be used.
• This invention extends to an electrophoretic display comprising a layer of an index matched binder electrophoretic medium of the invention and electrode means arranged to apply an electric field to the electrophoretic medium, the electrode means being arranged to drive the electrophoretic medium to a non- light-transmissive state, in which the particles occupy a major proportion of the area of the layer, thereby rendering the layer substantially non-light-transmissive, and a fransmissive state, in which the particles occupy only a minor proportion of the area of the layer, thereby rendering the layer substantially light-transmissive.
• this invention provides an improvement in a process for forming an electrophoretic medium, which process comprises: (a) providing a substrate; (b) applying to the substrate a coating material comprising a plurality of capsules in a liquid phase, each of the capsules comprising a suspending fluid and a plurality of electrically charged particles disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the capsule, and subjecting the coating material to conditions effective to cause formation of a coherent solid layer containing the capsules on the substrate; and (c) applying an adhesive layer over the capsule-containing layer on the substrate.
• the improvement comprises planarizing the capsule-containing layer on the substrate after step (b) but before step (c).
• planarized capsule layer This aspect of the invention may hereinafter for convenience be called the "planarized capsule layer " process of the invention.
• the planarization may be effected by coating the capsule-containing layer with a material having a refractive index which does not differ from that of the capsule layer by more than 0.1.
• the planarization may be effected by mechanical pressure on the capsule-containing layer.
• this invention provides an electrophoretic display comprising a layer of an electrophoretic medium comprising a suspending fluid and a plurality of electrically charged particles disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the suspending fluid, and elecfrode means arranged to apply an electric field to the electrophoretic medium, the elecfrode means being arranged to drive the electrophoretic medium to a non-light-transmissive state, in which the particles occupy a major proportion of the area of the layer, thereby rendering the layer substantially non-light-transmissive, and a fransmissive state, in which the particles occupy only a minor proportion of the area of the layer, thereby rendering the layer substantially light-transmissive, wherein the suspending fluid and electrically charged particles are present as a plurality of discrete droplets, the electrophoretic medium further comprising a continuous phase within which the droplets are confined, the droplets having an aspect ratio of at least 2.
• the electrophoretic medium used in such as display may be of various types, including the encapsulated elecfrophoretic medium, polymer-dispersed electrophoretic medium and microcell electrophoretic medium mentioned above.
• this invention provides a method of driving an elecfrophoretic display, the display comprising a layer of an elecfrophoretic medium having first and second surfaces on opposed sides thereof, and elecfrode means arranged to apply an electric field to the electrophoretic medium, the electrode means being arranged to drive the elecfrophoretic medium to a non-light- fransmissive state, in which the particles occupy a major proportion of the area of the layer, thereby rendering the layer substantially non-light-transmissive, and a fransmissive state, in which the particles occupy only a minor proportion of the area of the layer, thereby rendering the layer substantially light-transmissive, wherein the elecfrophoretic medium comprises a suspending fluid and a plurality of electrically charged particles disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the suspending fluid, the suspending fluid and electrically charged particles being present as a plurality of discrete droplets, the electrophoretic medium further comprising a continuous phase within
• the elecfrophoretic medium used in such a method may be of various types, including the encapsulated elecfrophoretic medium, polymer-dispersed electrophoretic medium and microcell electrophoretic medium mentioned above.
• this invention provides an elecfrophoretic display comprising a laminar carrier medium having end walls and side walls defining a plurality of closed cavities formed therein, the sidewalls extending substantially normal to the thickness of the laminar carrier medium, each of the cavities having confined therein a suspending fluid and a plurality of electrically charged particles disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the suspending fluid, wherein at least a portion of each side wall is electrically conductive.
• this aspect of the invention may hereinafter be called the "conductive sidewall microcell display" of the invention.
• the display may further comprise a light-transmissive front electrode provided at or adjacent one major surface of the laminar medium and at least one rear electrode at or adjacent the other major surface of the laminar medium, and therein the conductive side walls are electrically connected to at least one of the rear electrodes but are insulated from the front elecfrode.
• this invention provides a light modulator comprising two light-transmissive panels spaced from one another and an electrophoretic medium disposed between the two panels, the elecfrophoretic medium having a light-transmissive state and a dark state in which its light transmission is lower than in its light-transmissive date, wherein the electrophoretic medium is sensitive to at least one wavelength of electromagnetic radiation, and at least one of the light-transmissive panels comprises an absorber for electromagnetic radiation of this wavelength.
• this aspect of the invention may hereinafter be called the "radiation-absorbing panel light modulator" of the invention.
• this invention provides an elecfrophoretic display comprising a layer of an electrophoretic medium comprising a suspending fluid and a plurality of first particles, which are electrically charged and colored, and disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the suspending fluid, and electrode means arranged to apply an electric field to the electrophoretic medium, the electrode means being arranged to drive the electrophoretic medium to a non-light-transmissive state, in which the fist particles occupy a major proportion of the area of the layer, thereby rendering the layer substantially non-light-transmissive, and a fransmissive state, in which the first particles occupy only a minor proportion of the area of the layer, thereby rendering the layer substantially light-fransmissive, wherein the elecfrophoretic medium also comprises a plurality of second particles, which are electrically charged and substantially transparent, disposed in the suspending fluid and capable of moving therethrough on application of an electric field to the suspending fluid.
• this aspect of the invention may hereinafter be called the "transparent particle electrophoretic display" of the invention.
• the electrophoretic medium used in such a display may be of various types, including the encapsulated electrophoretic medium, polymer-dispersed electrophoretic medium and microcell electrophoretic medium mentioned above.
• the sole Figure of the accompanying drawing is a graph showing the variation in optical density with applied field frequency for an electrophoretic medium of the present invention. As already indicated, this invention provides a variety of improvements in electrophoretic media and displays intended for use in light modulators.
• the electro-optic properties of most electrophoretic media have been optimized to ensure good optical density when the media are being used in an opaque or substantially opaque state, and relatively little consideration has been given to improving light transmission in the "transparent" state when such media are used in a shutter or variable transmission mode.
• a number of techniques are available for improving such light transmission. Firstly, in an elecfrophoretic medium, one major source of light scattering, and hence lack of transparency in a fransmissive state, is the boundary between the droplets of the internal phase (the suspending fluid and the electrophoretic particles therein) and the continuous phase which surrounds the droplets.
• the continuous phase material has a substantially higher refractive index than the aliphatic hydrocarbon solvents used as the suspending fluid, and to increase the refractive index of the latter, aromatic and polyhalide solvents (and possibly also silicones) may be used in the suspending fluid to increase its refractive index.
• Isopar Registered Trade Mark
• methoxynaphthalene 1.69
• polybromoaromatics or polybromoalkanes.
• the electrophoretic medium may be an encapsulated electrophoretic medium, in which case the relevant boundary is that between the suspending fluid and the plurality of capsule walls surrounding the droplets.
• the electrophoretic medium may be a polymer-dispersed elecfrophoretic medium, in which case the relevant boundary is that between the suspending fluid and the polymeric binder which is in direct contact with the suspending fluid.
• the medium may also be of the microcell type, in which case the relevant boundary is that between the suspending fluid and the walls defining the microcells.
• the "continuous phase" of the elecfrophoretic medium itself comprises two separate phases, namely the capsule walls and the binder, and a major source of light scattering and lack of transparency is the boundary between the capsule wall and the binder, and it is desirable to index match the capsule wall and the binder as closely as possible, again within (say) 0.07, desirably 0.05, and preferably 0.03.
• the gelatin-based capsule walls described in many of the E Ink and MIT patents and applications mentioned above have a refractive index of about 1.53, and the polyurethane-based binders with which such capsule walls have hitherto typically been used are not well index matched to the gelatin- based capsule walls.
• Another location where light scattering occurs in a typical electrophoretic display is the interface between the electrophoretic medium layer itself and the lamination adhesive which is normally used to secure this layer to another layer of the finil display, for example a backplane or other electrode assembly.
• the interface is typically not planar; the capsules within the capsule/binder layer cause "bumps" on the surface of the layer, resulting in a non-planar interface, and it is well known to those skilled in optics that a non-planar index mismatched interface results in more light scattering than a similar planar interface.
• the same interface in a polymer-dispersed electrophoretic medium may also be non-planar for similar reasons, although the extent of non- planarity is likely to be less than in the case of an encapsulated electrophoretic medium.
• the light scattering at this interface may be substantially reduced by accurate index matching of the binder, capsule wall and lamination adhesive, but given the large number of mechanical and electrical constraints placed upon lamination adhesives for use with electrophoretic media (see especially U.S. Patent Publication 2003/0025855), it may be difficult to find a lamination adhesive which achieves accurate index matching and still satisfies all the other constraints.
• planarization may be effected by coating the exposed surface of the capsule/binder layer with a solution of an index-matching material, preferably gelatin, and drying prior to contacting the capsule/binder layer with the lamination adhesive.
• planarization may be effected mechanically by calendaring, i.e. by subjecting the capsule/binder layer to pressure, and optionally heat, typically by contacting it with a roller. If mechanical planarization is used, care should of course be taken to choose planarization conditions which will not cause excessive capsule bursting.
• Droplet aspect ratio and material considerations It may be desirable to use relatively large droplets (often in the form of large capsules or microcells) in light modulators, at least when it is not possible to achieve accurate index matching of the various components of the electrophoretic medium.
• electrophoretic media are used in a non-transmissive mode, small droplets and thin, preferably monolayer, media are generally preferred since for a given operating voltage and internal phase, smaller droplets result in greater switching speeds, which are desirable when images are being changed, and many of the aforementioned E Ink and MIT patents and applications show use of small droplets in the form of capsules having diameters in the range of about 20-50 ⁇ m.
• capsule wall or other continuous phases are a major source of light scattering, it is desirable to reduce the amount of capsule wall or continuous phase per unit area of the modulator.
• the perimeter of capsule wall or microcell wall in the areal cross-section of the electrophoretic layer is roughly inversely proportional to the diameter of the capsules or microcell size (and a similar effect is found for polymer-dispersed electrophoretic media).
• the capsule or microcell wall, or the boundary between the droplet and the continuous phase in the case of a polymer-dispersed electrophoretic medium is expected to be the principal source of scattering
• increasing the capsule diameter to about 100-150 ⁇ m should reduce scattering by a factor of 3.
• the electrophoretic layer thickness will typically be substantially less than the capsules diameter (say around 40-50 ⁇ m) so that the large capsules will be flattened into a "pancake" shape, with the droplet within the capsule having an aspect ratio (height/width) not greater than 0.5, and desirably not greater than 0.35.
• Such a pancake shape may be best achieved by using highly flexible or conformal capsules having a lower degree of cross-linking that that typically used in the aforementioned E Ink and MIT patents and applications; however, it should be noted that gelatin capsules which are not cross-linked are highly susceptible to bursting.
• gelatin capsules which are not cross-linked are highly susceptible to bursting.
• polymer-dispersed electrophoretic media with droplets having similar aspect ratios, and microcells having similar aspect ratios.
• the electrophoretic particle size and volume fraction should be optimized to achieve maximal clarity in the transparent (“open") state and adequate opacity in the opaque (“closed”) state.
• a light modulator of the present invention When a light modulator of the present invention is to used in window or similar glass to control heat transmission, electrophoretic particles with high infra-red reflectivity are desirable; example of IR-reflective pigments include titania and zinc sulfide.
• the light modulators of the present invention should typically have high bistability, up to several hours or more. Their bistability can be increased by addition of rheological addenda of any kind, including polyisobutylene (PIB) or
• carbon particles may represent the optimal choice, by reason of their low cost, metallic, or semi-conductive particles may have advantages.
• the dielecfrophoretic effect depends on the conductivity, since it is the result of an induced dipolar interaction with the field. Higher conductivity should result in particles that respond more readily.
• Semiconductive particles particularly those with such high doping levels that they have relatively high conductivities, may also be used; the polarizability of the particle is important for the dielecfrophoretic performance, so elements low in the periodic table may be better (e.g. cadmium sulfide, selenide or telluride).
• This effect i.e., the dependence of the response on frequency, may afford a method of causing the display to close (see below regarding the scrubbing bubble effect).
• Smaller elecfrophoretic particles are likely to give a faster response to a polarizing field.
• secondary, substantially transparent electrophoretic particles may also be advantageous to incorporate into the electrophoretic medium of a light modulator, in addition to the primary colored elecfrophoretic particles.
• These second electrophoretic particles (“scrubbing bubbles”) may bear a charge of either polarity (i.e., the same as or opposite to the charges on the primary electrophoretic particles) and may be moved by a low frequency waveform to stir up the electrophoretic medium.
• Such transparent particles could be, for example very small (20-50 ⁇ m) particles of silica, or another colloid, that are too small to scatter light appreciably.
• the transparent particles could be index-matched (to the suspending fluid) polymer particles, either a . non-swelling latex particle with the correct refractive index or a swellable, but insoluble, particle, possibly comprising a cross- linked microgel; such a microgel latex might be particularly beneficial because in its swollen form it would comprise a majority of solvent, and therefore be easier to index-match with the medium, resulting in low scattering.
• the transparent state is brought about by field dependent aggregation of the electrophoretic particles; such field dependent aggregation may take the form of dielecfrophoretic movement of elecfrophoretic particles to the lateral walls of a droplet (whether that droplet is present in a polymer-dispersed medium, or within a capsule or microcell), or "chaining", i.e., formation of strands of electrophoretic particles within the droplet, or possibly in other ways.
• such field dependent aggregation of the electrophoretic particles causes the particles to occupy only a small proportion of the viewable area of each droplet, as seen in a direction looking perpendicular to the viewing surface through which an observer views the electrophoretic medium.
• the major part of the viewable area of each droplet is free from electrophoretic particles and light can pass freely therethrough.
• the elecfrophoretic particles are distributed throughout the whole viewable area of each droplet (the particles may be uniformly distributed throughout the volume of the suspending fluid or concentrated in a layer adjacent one major surface of the electrophoretic layer), so that no light can pass therethrough.
• a stranding display i.e., one in which the particles aggregate as in an electrorheological fluid
• These changes in waveform can be coupled with either patterned electrodes or with the semiconductive particles described above to optimize the response in both directions.
• the Figure shows the variation of optical density of the medium with the frequency of the applied field, and it will be seen that the optical density could be adjusted from about 0.9 to about 0.3 (corresponding to optical transmissivities of about 10 and 50 per cent respectively) simply by adjusting the frequency of the applied field.
• the medium displayed slight hysteresis, so the results for opening (black to transparent) and closing (transparent to black) transitions of the medium are plotted separately in the Figure.
• the optical density of the medium was not history-dependent (i.e., the optical density obtained was not a function of the prior states of the medium). This greatly simplified driving the medium.
• the optical density of an electrophoretic medium of the present invention is a function of the fraction of the viewable area occupied by the electrophoretic particles, and to produce the best transparent state, this fraction should be as small as possible.
• the appearance of the transparent state of the medium when viewed off-axis i.e., when viewed in a direction at an acute angle to the thickness of the elecfrophoretic layer
• the appearance of the transparent state of the medium when viewed off-axis is a function not only of the fraction of the viewable area occupied by the electrophoretic particles, but also of the distribution of the electrophoretic particles through the thickness of the electrophoretic layer.
• the particles form structures extending through the whole thickness of the electrophoretic layer (for example, if the particles occupy the entire sidewalls of droplets, or form strands extending throughout the thickness of the layer), these structures will be visible when the medium is viewed off-axis, and may occupy a substantial proportion of the visible area, thus reducing the off-axis transparency of the medium. If, however, the particles form structures extending through only part of the thickness of the electrophoretic layer, when the medium is viewed off-axis these structures will occupy a smaller proportion of the visible area, thus improving the off-axis transparency of the medium.
• the electrophoretic layer may be advantageous to keep the electrophoretic layer as thin as possible, thus reducing the size of any particle structures extending through the thickness of the electrophoretic layer; however, as noted above, a thin electrophoretic layer requires a corresponding increase in the volume fraction of elecfrophoretic particles to achieve adequate opacity in the closed state of the display. Accordingly, there is likely to be an optimum thickness of the electrophoretic layer for any given selection of materials for use in a light modulator.
• the structures are of a type which occupy the sidewalls of a droplet, it is advantageous to use wide droplets, since this reduces the number of sidewalls on which the particle structures form, and hence the proportion of the visible area occupied by the structures when the elecfrophoretic layer is viewed off-axis.
• the transparency of such an elecfrophoretic layer viewed off-axis is a function of the aspect ratio (height to maximum lateral dimension) of the droplets. Off-axis transparency can also be improved by controlling the particle structures so that they do not occupy the whole sidewalls of a droplet.
• Such particle structures may be produced in accordance with the DC/AC drive method of the present invention by first bringing all the particles within a droplet adjacent one major surface of the electrophoretic layer by applying a DC field to the layer, and then driving the particles to the sidewalls using an AC field of appropriate frequency.
• Such conductive sidewalls may or may not be insulated from the electrodes used to drive the elecfrophoretic medium.
• the conductive sidewalls are insulated from the drive electrodes, as the medium is driven, such conductive sidewalls will become polarized by induction, and the electric field experienced by the electrophoretic internal phase within the microcells will be concentrated in the areas between the conductive sidewalls and the driving electrodes, so that any particle structures formed will be concentrated adjacent these areas and will not spread over the whole of the sidewalls.
• the conductive sidewalls may be in electrical contact with the backplane of the display, but isolated from the front electrode(s), thereby concentrating electric field strength near the "tops" of the sidewalls (i.e., in the portions of the sidewalls adjacent the front electrode(s)), so that, in the open state of the display, the elecfrophoretic particles would become concentrated adjacent these portions of the sidewalls.
• the electro-optic performance of the light modulators of the present invention may also be substantially affected by the geometry of the electrodes used to drive the display.
• Electrode width should be small relative to the gap between the electrodes, and the electrophoretic layer should be as thin as possible, in order to maximize the lateral component of the field.
• a top plane with a different polarity to the patterned backplane also helps to maximize the lateral field gradient, and concenfrate the particles in regions of highest field.
• patterned electrodes may also be advantageous for displays using this technique.
• Strong local field gradients may be produced by, for example, an inter-digitated electrode (i.e., an electrode arrangement having two sets of alternating elongate tines, with the tines of each set being held at the same voltage) with the tines at different voltages, perhaps in conjunction with a top plane electrode. If the tines are then placed at the same potential, the device could be used to effect electrophoretic, front-back switching, which should enhance the rate of closing of an (open) transparent display.
• Segmented, patterned electrodes on glass allow for signage based on a clear/opaque contrast (rather than a color-based, reflective contrast as in most prior art elecfrophoretic displays) in addition to general clear/opaque transition.
• the patterned electrodes would be placed so as to spell out letters or an image, and could be arranged to be addressed separately from the background.
• the elecfrophoretic media used in the modulators of the present invention can be produced economically. Since uniform droplet size is not required, polymer-dispersed and/or unclassified (i.e., not selected for size) encapsulated media, possibly prepared by a limited coalescence procedure (see copending
• the internal phase may contain, in addition to the electrophoretic particles and suspending fluid, only a surfactant/dispersing aid/charging agent. It may be possible to use bare carbon dispersions directly from the manufacturer, without synthetic preparation of any kind. It should be noted that, since the desired contrast in the present light modulators is between a closed state in which light is blocked by the electrophoretic particles, and an open state in which the light is not blocked, the electrophoretic medium used will typically be single particle, since there is no need for more than one type of elecfrophoretic particle to be present. Furthermore, the suspending fluid in such a single particle medium will normally be undyed to provide maximum fransparency in the open state.
• the electrophoretic medium may be in the form of a multi-layer (as opposed to a monolayer) coating; and still give satisfactory results. If the system is adequately index-matched as a result of the appropriate choice of both internal phase materials and binder, and is otherwise optimized as described above, the trade-off between decreased cost and decreased transparency/increased haze (scattering) in a multi-layer coating may be favorable.
• the preferred multi-level/multi-frequency waveforms for use in the present light modulators have already been discussed above.
• Control of the pulse shape of the waveform may also be desirable; for example, as between square and sine wave pulse shapes, the sine wave may give better closing behavior because polarization of particles builds more slowly and under conditions where less hydrodynamic mixing of the system occurs.
• electrophoretic media are often sensitive to various wavelengths of electromagnetic radiation, which tend, inter alia, to decrease the working lifetime of the media. Hence it is often desirable to provide filter layers to screen the media from radiation to which they are sensitive.
• a variable transmission window of the present invention will typically have the form of an electrophoretic medium sandwiched between two panes of glass, and, in accordance with the radiation- absorbing panel aspect of the present invention, in this structure cost savings can be achieved by providing the necessary filtering, for example ultra-violet and/or infra- red filtering, in one or both of the glass panes (or other similar panels used), rather than providing separate filter layers in the elecfrophoretic medium.
• the necessary filtering for example ultra-violet and/or infra- red filtering

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