EP1754010A1 - Four a etages - Google Patents
Four a etagesInfo
- Publication number
- EP1754010A1 EP1754010A1 EP05742828A EP05742828A EP1754010A1 EP 1754010 A1 EP1754010 A1 EP 1754010A1 EP 05742828 A EP05742828 A EP 05742828A EP 05742828 A EP05742828 A EP 05742828A EP 1754010 A1 EP1754010 A1 EP 1754010A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- wall
- furnace according
- furnace
- scraped area
- area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007790 scraping Methods 0.000 claims abstract description 17
- 238000004140 cleaning Methods 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 26
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 230000000149 penetrating effect Effects 0.000 claims description 3
- 239000011819 refractory material Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 230000035939 shock Effects 0.000 abstract 1
- 230000002093 peripheral effect Effects 0.000 description 17
- 206010039509 Scab Diseases 0.000 description 9
- 238000007789 sealing Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 208000028659 discharge Diseases 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000036461 convulsion Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B9/00—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
- F27B9/14—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment
- F27B9/16—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a circular or arcuate path
- F27B9/18—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a circular or arcuate path under the action of scrapers or pushers
- F27B9/185—Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a circular or arcuate path under the action of scrapers or pushers multiple hearth type furnaces
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D25/00—Devices or methods for removing incrustations, e.g. slag, metal deposits, dust; Devices or methods for preventing the adherence of slag
- F27D25/001—Devices or methods for removing incrustations, e.g. slag, metal deposits, dust; Devices or methods for preventing the adherence of slag comprising breaking tools, e.g. hammers, drills, scrapers
Definitions
- the present invention relates to a multi-storey oven.
- a multi-storey oven comprises a furnace wall delimiting a cylindrical space with a vertical axis.
- a plurality of superimposed soles delimit the stages of the furnace within this space.
- At each sole are provided scraper arms driven in rotation by a central shaft coaxial with the vertical axis of the furnace. These scraping arms are equipped with scrapers which return the material to be treated on the sole and move it on a first type of sole towards the periphery and on a second type of sole towards the center of the sole.
- the first type of hearth is provided with peripheral drop openings through which the material to be treated falls on a second type hearth in the floor below.
- the second type of hearth is provided with a central drop opening through which the material to be treated falls on a first type hearth in the floor below. It is further known to equip in each stage of the furnace at least one of the scraping arm of a wall scraper.
- the function of this wall scraper is to take up the material accumulating in the immediate vicinity of the furnace wall to push it on the first type of hearth in the peripheral chute openings and on the second type of hearth to redirect it into the flow of material moved to the center of the oven.
- a radial clearance remains between the wall scraper and the inner surface of the furnace wall. During operation of the oven, this functional game is however quickly clogged by the material to be treated.
- a layer of material is formed on the inner surface of the wall that the wall scraper progressively compacts by "spreading", to finally obtain a very hard crust which adheres to the inner surface of the wall.
- the wall scraper rubs on this peripheral crust, which generates a significant additional braking moment on the scraping arm. It will be noted that the situation is aggravated by the fact that the hardness and the resistance of the peripheral crust are not generally uniform.
- the module of the braking force exerted on the wall scraper therefore varies in jerks, which causes jolts in the scraping arm. This results in dynamic stresses generating fatigue phenomena which are at the origin of many ruptures of the scraping arms.
- the object of the present invention is to provide a stepped furnace which reduces the aforementioned phenomena. According to the invention, this objective is achieved by a multi-stage furnace according to claim 1.
- a multistage furnace comprises, in a manner known per se, an oven wall delimiting a cylindrical space with a vertical axis, a plurality of soles delimiting the stages inside this cylindrical space and at least one scraping arm. with a wall scraper.
- This scraping arm is associated with one of the soles where it is rotated about the vertical axis of the furnace.
- its wall scraper defines a scraped area on the inner surface of the furnace wall.
- the furnace wall comprises a plurality of wall cavities which form a succession of access openings in the scraped area by the wall scraper.
- the furnace wall generally includes an outer shield and an inner refractory liner.
- the aforementioned wall cavities are provided in the refractory lining and, in a preferred embodiment, the shield is provided with cleaning apertures for reaching the wall cavities.
- the cleaning opening associated with a wall cavity has a substantially smaller cross-section than the access opening formed by the cavity of the furnace wall. wall in the scraped area.
- the cross section of the wall cavity preferably decreases progressively towards the cleaning opening.
- the circumferential extent of the residual area between two successive access openings is smaller than the circumferential extent of such an access opening.
- the ideal case would be to separate two successive access openings by a sharp edge, but for reasons of wear and stability will generally provide a residual area between two access openings.
- the circumferential extent of this residual area is preferably less than 50% of the circumferential extent of one of the access openings that it separates. In the vertical direction, the access openings extend slightly beyond the upper limit of said scraped area. Through the cleaning openings in the outer shield, the wall cavities can be easily cleaned by workers with special tools.
- a device for injecting a fluid with one, more or all of the wall cavities, so as to be able to drive the material accumulated in the wall cavity on the hearth with the aid of injected fluid.
- a mechanical pusher can be integrated in one, several or all of the wall cavities, so as to be able to push accumulated matter back into a wall cavity on the floor.
- Each of the cleaning openings is advantageously associated with a closure device which comprises a steel closure flange fixed on a counter flange of said outer shield and a central core of refractory material penetrating into the cleaning opening.
- FIG. 1 a cross-section of the multistage furnace at a first type of hearth
- FIG. 2 a cross-section of the multistage furnace at a second type of hearth
- FIG. 3 a vertical section marked by section line 3-3 'in FIG. 2;
- FIG. 4 a vertical section marked by section line 4-4 'in FIG. 1;
- FIG. 5 a three-dimensional view of an annular element of a furnace wall of a multi-storey furnace according to the invention.
- FIG.6 a vertical section of the furnace wall at a wall cavity with a cleaning opening equipped with a closure device.
- Fig. 1 shows a first cross section through a multi-storey furnace according to the invention.
- An oven wall 10 delimits radially a cylindrical space with a vertical axis 11 (perpendicular to the plane of the figure). Inside this space, a plurality of superimposed soles vertically delimit the stages of the furnace.
- a first type of sole 12 It is a sole 12 with peripheral drop openings 14. At this sole 12 are associated two scraping arms 16, 16 ', which are rotated about the vertical axis 11 by a drive shaft 17.
- Each scraper arm 16, 16' supports a series of scrapers 18, 18 'which are oriented to return the material to be treated on the hearth 12 and to move it towards the periphery of the hearth 12, where it falls through the peripheral fall openings 14 on a peripheral surface of a lower hearth.
- References 20, 20 ' indicate wall scrapers which function to take up the accumulating material in close proximity to the furnace wall 10 and push it into the peripheral drop openings 14.
- FIG. 2 shows a second type of hearth 22. It is a hearth 22 with a central drop opening 24 surrounding the drive shaft 17. At this sole 22 are associated two scraping arms 26, 26 ', which are also rotated by the drive shaft 17.
- Each scraper arm 26, 26 ' supports a series of scrapers 30, 30' which are this time oriented so as to return the material to be treated on the sole 22 and move it into the central region of the hearth 22, where it falls through the central fall opening 24 in the central region of a lower hearth.
- the reference 32 indicates a wall scraper of the scraper arm 26 which aims to take up the material accumulating in the immediate vicinity of the furnace wall 10 and to push it back into the flow of material displaced towards the center of the hearth 22
- the soles of the stack furnace are alternatively of the first type shown in FIG. 1 or the second type shown in FIG. 2.
- FIG. 3 shows a vertical section through the furnace wall 10 at veal of sole 22 of FIG. 2, the reference 42 identifying the inner surface and the reference 44 the outer surface of the furnace wall 10.
- This furnace wall 10 comprises in known manner an outer shield 46 of steel and an inner refractory lining 48.
- FIG. . 3 is also shown the end of the scraping arm 26 with its wall scraper 32, which has an end edge 50.
- the end edge 50 passes to a distance "x" in front of the inner surface 42 of the furnace wall 10. This distance "x" must be dimensioned so as to avoid direct contact between the wall scraper 32 and the inner refractory lining 48, even when the scraper arm 26 and the furnace wall 10 undergo thermal expansions or retractions of different magnitude.
- the furnace wall 10 comprises a plurality of wall cavities 54 which form a succession of access openings. 56 in the scraped area 52. It will be appreciated that these wall cavities 54, which are provided in the inner refractory liner 48, greatly reduce the risk of forming a crust of hardened material, which adheres to the inner surface 42 of the furnace wall 10 and opposes a resistance to the passage of the wall scraper 32.
- the wall cavities 54 in the wall 10 are filled as and when material.
- a compaction phenomenon by "spreading" which in the furnaces of the state of the art is at the origin of a very hard peripheral crust and adhering to the inner surface of the furnace wall, does not occur almost not.
- the material that accumulates in the wall cavities 54 is almost not compacted by the passage of the wall scraper 32. It remains relatively soft and therefore produces no significant braking jolts.
- Cleaning apertures 58 in the outer shield 46 allow the wall cavities 54 to be reached. Through these cleaning apertures 58, bars, lances or other devices can easily be introduced from outside.
- the cleaning opening associated with a wall cavity 54 has a cross section substantially smaller than the access opening 56 formed by said wall cavity in said scraped area 52. The cross section of the wall cavity 54 then gradually decreases towards the cleaning opening.
- the wall cavities 54 are for example of pyramidal shape, and the cleaning openings are of cylindrical shape and are arranged in the top axis of the pyramid (see Fig. 2 and 3). ).
- the pyramidal wall cavities 54 will most often have a rectangular cross section, even square. However, their cross-section may also be triangular or polygonal and, in general, have a shape conforming to the shape of other objects integrated in the furnace wall (for example openings for burners, gas pipes, probes, etc. .). It is also possible to give the wall cavities a shape of a cone of revolution and then to arrange the cleaning opening 58 in the vertex axis of this cone of revolution. In FIG.
- the circumferential extent of the residual surface 60 between two successive access openings 56 ⁇ , 56 2 in the scraped area 52 is much smaller than the circumferential extent of such an access opening 56.
- the circumferential extent of the residual surface 60 between two successive access openings 56 ⁇ , 56 2 in the scraped area 52 represents for example only 20% of the circumferential extent of an access opening 56.
- FIG. 4 shows a vertical section through furnace wall 10 at hearth 12 of FIG. 1.
- the reference 52 ' identifies the extent of the "scraped area" of the furnace wall 10 at this sole 12.
- the scraped area 52' is also subdivided by a succession of access openings 56 'formed by wall cavities 54' in the refractory lining 48.
- the hatched rectangles 74 indicate the locations of support bases for a hearth of the type of FIG. 1, that is to say a sole with peripheral discharge openings 14. It is very clear the wall depressions 70 between the support bases 74.
- a hearth with central discharge opening will be arranged directly below the lower edge of the annular element shown.
- the upper row of access openings 56 ' is therefore the succession of access openings associated with a hearth 12 with peripheral discharge openings 14, whereas the lower row of access openings 56 is the succession of access openings 56. access openings associated with a sole 22 with central discharge opening 24.
- FIG. 6 shows in a vertical section a detail of a wall cavity 54 with a cleaning opening sealingly closed by means of a sealing device 90.
- the cleaning opening itself comprises a hole 92 in the outer shield 46.
- This hole 92 opens into a metal sleeve 94 which extends for a distance in the refractory lining 48.
- the sealing device 90 comprises a closure flange 96 of steel fixed on a counter-flange 98 of the outer shield 46, and a central core 100 of refractory material penetrating into the metal sleeve 94.
- a refractory ring 102 surrounds the central core 100.
- the closure flange 96 is fixed on the counter-flange 98 with the aid of keys mounted on pivots, which allows a quick disassembly and reassembly of the closure flange 96.
- a handle 104 allows easy handling of the sealing device 90.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Tunnel Furnaces (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Furnace Charging Or Discharging (AREA)
Abstract
Description
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL05742828T PL1754010T3 (pl) | 2004-06-02 | 2005-04-13 | Piec piętrowy |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU91080A LU91080B1 (fr) | 2004-06-02 | 2004-06-02 | Four à étages. |
| PCT/EP2005/051628 WO2005119153A1 (fr) | 2004-06-02 | 2005-04-13 | Four a etages |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1754010A1 true EP1754010A1 (fr) | 2007-02-21 |
| EP1754010B1 EP1754010B1 (fr) | 2007-10-17 |
Family
ID=34955592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP05742828A Expired - Lifetime EP1754010B1 (fr) | 2004-06-02 | 2005-04-13 | Four a etages |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7735434B2 (fr) |
| EP (1) | EP1754010B1 (fr) |
| JP (1) | JP4662560B2 (fr) |
| CN (1) | CN100465563C (fr) |
| AU (1) | AU2005250591B2 (fr) |
| BR (1) | BRPI0511653A (fr) |
| CA (1) | CA2567508C (fr) |
| DE (1) | DE602005002952T2 (fr) |
| ES (1) | ES2296172T3 (fr) |
| LU (1) | LU91080B1 (fr) |
| PL (1) | PL1754010T3 (fr) |
| RU (1) | RU2365841C2 (fr) |
| TW (1) | TWI314638B (fr) |
| WO (1) | WO2005119153A1 (fr) |
| ZA (1) | ZA200609602B (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2730061A1 (fr) * | 2008-08-15 | 2010-02-18 | Wayne/Scott Fetzer Company | Systeme de four a combustible de biomasse et procedes relatifs |
| CN103528371B (zh) * | 2012-07-06 | 2016-03-16 | 攀钢集团攀枝花钢铁研究院有限公司 | 具有破拱装置的转底炉 |
| US9702022B2 (en) | 2014-08-13 | 2017-07-11 | Industrial Furnace Company | Process and system for de-coating of aluminum scrap contaminated with organic coatings |
| BE1024249B1 (nl) | 2016-05-27 | 2018-01-08 | Sadaci N.V. | Roostoven, gebruik ervan en werkwijze voor het verwerken van ertsen of concentraten |
| CN114018039B (zh) * | 2021-12-14 | 2024-05-03 | 苏州中材非金属矿工业设计研究院有限公司 | 一种回转焙烧炉体内壁结圈处理装置及其处理方法 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US393387A (en) * | 1888-11-27 | Velocipede | ||
| GB393387A (en) * | 1932-03-21 | 1933-06-08 | Nicolas Ivanovitsch Ivanovsky | Arrangement for removing soot, coal dust, ashes and the like from flues in operation |
| US2317941A (en) * | 1941-03-24 | 1943-04-27 | Nichols Eng & Res Corp | Incineration of liquid sludge or the like |
| US2488115A (en) * | 1946-04-23 | 1949-11-15 | Nickolas K Benos | Roaster furnace |
| US2471882A (en) * | 1946-05-07 | 1949-05-31 | Warren S Martin | Means for converting material |
| US2676006A (en) * | 1951-01-10 | 1954-04-20 | Warren S Martin | Continuous furnace for converting material |
| US2969960A (en) * | 1957-06-05 | 1961-01-31 | Mobay Chemical Corp | Mixing apparatus |
| US3175809A (en) * | 1962-03-06 | 1965-03-30 | American Metal Climax Inc | Rabble tooth |
| US3361419A (en) * | 1966-05-10 | 1968-01-02 | Selas Corp Of America | Air preheating burner with furnace preheating passage cleaner means |
| US3430928A (en) * | 1967-04-03 | 1969-03-04 | Chemetron Corp | Scraping apparatus |
| US3497190A (en) | 1968-04-15 | 1970-02-24 | James E Moore | System for hot de-oiling and hot briquetting |
| US3658309A (en) * | 1970-08-03 | 1972-04-25 | Sherritt Gordon Mines Ltd | Temperature control of ore in multiple hearth furnace |
| US3874644A (en) * | 1974-03-07 | 1975-04-01 | Amax Inc | Rabble cleaning device |
| JPS5149761U (fr) * | 1974-10-09 | 1976-04-15 | ||
| JPS6054590B2 (ja) * | 1976-06-25 | 1985-11-30 | 日立金属株式会社 | 立形多段炉 |
| US4046086A (en) * | 1976-07-19 | 1977-09-06 | Nichols Engineering & Research Corporation | Treatment of waste material containing alkali metals in a controlled atmosphere furnace |
| JPS53117774U (fr) * | 1977-02-26 | 1978-09-19 | ||
| JPS54144408A (en) * | 1978-05-02 | 1979-11-10 | Sumitomo Jukikai Envirotech Kk | Multiistage furnace for treating clinker product |
| JPS5553686A (en) * | 1978-10-18 | 1980-04-19 | Hitachi Metals Ltd | Stirrer for vertical furnace |
| JPS5934877Y2 (ja) * | 1979-07-09 | 1984-09-27 | 日立金属株式会社 | 立型多段炉 |
| US4391208A (en) * | 1980-09-29 | 1983-07-05 | Sterling Drug, Inc. | Method for controlling temperatures in the afterburner and combustion hearths of a multiple hearth furnace |
| DE3101308C2 (de) * | 1980-12-30 | 1986-05-22 | Linnhoff & Thesenfitz Maschinenbau GmbH, 2090 Winsen | Zylindrischer Erhitzungskessel |
| JPS5960175A (ja) * | 1982-09-30 | 1984-04-06 | 株式会社新潟鐵工所 | 多段炉 |
| US4728339A (en) * | 1984-12-19 | 1988-03-01 | K-Fuel Partnership | Multiple hearth apparatus and process for thermal treatment of carbonaceous materials |
| JPS63201483A (ja) * | 1987-02-16 | 1988-08-19 | 川崎重工業株式会社 | 立型多段炉 |
| JP2877162B2 (ja) * | 1989-10-09 | 1999-03-31 | 三菱化学株式会社 | 堅型多段床炉 |
| JP3321224B2 (ja) * | 1992-03-13 | 2002-09-03 | ティーディーケイ株式会社 | 移動物体検出装置 |
| NL9401622A (nl) * | 1994-10-03 | 1996-05-01 | Tabo Inex Holding Bv | Crematieoven-belader. |
| RU2100701C1 (ru) | 1995-11-17 | 1997-12-27 | Товарищество с ограниченной ответственностью Научно-производственная фирма "Термоэкология" | Топочное устройство |
| US5720855A (en) * | 1996-05-14 | 1998-02-24 | Saturn Machine & Welding Co. Inc. | Coke oven door |
| US5752452A (en) * | 1996-10-25 | 1998-05-19 | Praxair Technology, Inc. | Apparatus and method for oxygen lancing in a multiple hearth furnace |
| WO1999029910A1 (fr) * | 1997-12-10 | 1999-06-17 | Paul Wurth S.A. | Procede de production de fer directement reduit dans un four a etages |
| LU90282B1 (de) * | 1998-09-02 | 2000-03-03 | Wurth Paul Sa | Verfahren zur thermischen Behandlung oel-und eisenoxidhaltiger Reststoffe |
| LU90766B1 (en) * | 2001-04-25 | 2002-10-28 | Wurth Paul Sa | Method of operating a multiple hearth furnace |
| LU90793B1 (en) * | 2001-06-26 | 2002-12-27 | Wurth Paul Sa | Multiple heath furnace |
-
2004
- 2004-06-02 LU LU91080A patent/LU91080B1/fr active
-
2005
- 2005-04-06 TW TW094110846A patent/TWI314638B/zh not_active IP Right Cessation
- 2005-04-13 ES ES05742828T patent/ES2296172T3/es not_active Expired - Lifetime
- 2005-04-13 US US11/570,031 patent/US7735434B2/en not_active Expired - Fee Related
- 2005-04-13 DE DE602005002952T patent/DE602005002952T2/de not_active Expired - Lifetime
- 2005-04-13 CN CNB2005800178770A patent/CN100465563C/zh not_active Expired - Fee Related
- 2005-04-13 JP JP2007513893A patent/JP4662560B2/ja not_active Expired - Fee Related
- 2005-04-13 PL PL05742828T patent/PL1754010T3/pl unknown
- 2005-04-13 CA CA2567508A patent/CA2567508C/fr not_active Expired - Fee Related
- 2005-04-13 BR BRPI0511653-8A patent/BRPI0511653A/pt not_active IP Right Cessation
- 2005-04-13 RU RU2006146614/03A patent/RU2365841C2/ru not_active IP Right Cessation
- 2005-04-13 EP EP05742828A patent/EP1754010B1/fr not_active Expired - Lifetime
- 2005-04-13 AU AU2005250591A patent/AU2005250591B2/en not_active Ceased
- 2005-04-13 WO PCT/EP2005/051628 patent/WO2005119153A1/fr not_active Ceased
-
2006
- 2006-11-17 ZA ZA200609602A patent/ZA200609602B/en unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2005119153A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2005250591A1 (en) | 2005-12-15 |
| US7735434B2 (en) | 2010-06-15 |
| CA2567508A1 (fr) | 2005-12-15 |
| ES2296172T3 (es) | 2008-04-16 |
| JP2008501924A (ja) | 2008-01-24 |
| CA2567508C (fr) | 2012-06-05 |
| US20070209563A1 (en) | 2007-09-13 |
| BRPI0511653A (pt) | 2008-01-02 |
| TW200540385A (en) | 2005-12-16 |
| AU2005250591B2 (en) | 2009-08-06 |
| LU91080B1 (fr) | 2005-12-05 |
| PL1754010T3 (pl) | 2008-02-29 |
| EP1754010B1 (fr) | 2007-10-17 |
| CN1961189A (zh) | 2007-05-09 |
| CN100465563C (zh) | 2009-03-04 |
| DE602005002952D1 (de) | 2007-11-29 |
| RU2006146614A (ru) | 2008-07-27 |
| ZA200609602B (en) | 2008-01-30 |
| JP4662560B2 (ja) | 2011-03-30 |
| TWI314638B (en) | 2009-09-11 |
| DE602005002952T2 (de) | 2008-07-24 |
| WO2005119153A1 (fr) | 2005-12-15 |
| RU2365841C2 (ru) | 2009-08-27 |
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