EP1819877A1 - Procede pour produire du papier, du carton, du carton blanchi presentant une resistance elevee a sec - Google Patents

Procede pour produire du papier, du carton, du carton blanchi presentant une resistance elevee a sec

Info

Publication number
EP1819877A1
EP1819877A1 EP05811227A EP05811227A EP1819877A1 EP 1819877 A1 EP1819877 A1 EP 1819877A1 EP 05811227 A EP05811227 A EP 05811227A EP 05811227 A EP05811227 A EP 05811227A EP 1819877 A1 EP1819877 A1 EP 1819877A1
Authority
EP
European Patent Office
Prior art keywords
mol
units
monoethylenically unsaturated
monomers
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP05811227A
Other languages
German (de)
English (en)
Other versions
EP1819877B1 (fr
Inventor
Anton Esser
Hans-Joachim HÄHNLE
Martin Rübenacker
Norbert Schall
Jacques Dupuis
Josef Neutzner
Manfred Niessner
Berthold Sturm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to PL05811227T priority Critical patent/PL1819877T3/pl
Publication of EP1819877A1 publication Critical patent/EP1819877A1/fr
Application granted granted Critical
Publication of EP1819877B1 publication Critical patent/EP1819877B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/56—Polyamines; Polyimines; Polyester-imides

Definitions

  • the invention relates to a process for the production of paper, paperboard and cardboard with high dry strength by separate addition of a vinylamine units containing polymer and a polymeric anionic compound to a pulp, dewatering of the pulp and drying of the paper products.
  • a process for the production of paper with high dry strength is known in which the paper stock is first a water-soluble cationic polymer, z. Polyethyleneimine, and thereafter adding a water-soluble anionic polymer, e.g. a hydrolyzed polyacrylamide, added and the Textil ⁇ material on the paper machine with sheet formation dewatered.
  • the anionic polymers contain up to 30 mol% of copolymerized acrylic acid.
  • a process for the production of paper with high dry strength in which the paper stock is first added a water-soluble cationic polymer and then a water-soluble anionic polymer sat.
  • Suitable anionic polymers are, for example, homopolymers or copolymers of ethylenically unsaturated C 3 -C 5 -carboxylic acids.
  • the copolymers contain at least 35% by weight of an ethylenically unsaturated C 3 -C 5 -carboxylic acid (for example acrylic acid) in copolymerized form.
  • the cationic polymers described in the examples are polyethyleneimine, polyvinylamine, polydiallyldimethylammonium chloride and epichlorohydrin-crosslinked condensation products of adipic acid and diethylenetriamine.
  • the use of partially hydrolyzed homo- and Copolymers of N-vinylformamide have been considered.
  • the degree of hydrolysis of the N-vinylformamide polymers is at least 30 mol% and is preferably from 50 to 100 mol%.
  • a paper product with improved strength properties is known, which is obtainable by applying to the surface of a paper product a polyvinylamine and a polymeric anionic compound which can form a polyelectrolyte complex with polyvinylamine, or a polymer compound with Alde ⁇ hydfunktionen such as aldehyde-containing polysaccharides applies.
  • a polyvinylamine and a polymeric anionic compound which can form a polyelectrolyte complex with polyvinylamine, or a polymer compound with Alde ⁇ hydfunktionen such as aldehyde-containing polysaccharides applies.
  • the paper improve its dry and wet strength, it also observes a sizing effect of the treating agents.
  • WO 04/061235 a process for the production of paper, in particular tissue, with particularly high wet and / or dry strengths is known in which the paper material is first added a water-soluble cationic polymer, that min ⁇ least 1, 5meq / g polymer contains primary amino functionalities and has a Molekularwicht of at least 10,000 daltons. Particular emphasis is placed here partially and fully hydrolyzed homopolymers of N-vinylformamide. Subsequently, a water-soluble anionic polymer is added which contains anionic and / or aldehydic groups.
  • the advantage of this method is, above all, the variability of the described two-component systems with regard to various paper properties, including wet and dry strength.
  • EP-A 438 744 is the use of copolymers of, for example, N-vinylformamide and acrylic acid, methacrylic acid and / or maleic acid having a K value of 8 to 50 (determined according to H. Fikentscher in 1% aqueous solution at pH 7 and 25 ° C) and the resulting from partial or complete elimination of formyl groups from the polymerized vinyl formamide to form vinylamine units available polymers as anti-scale agents in water-bearing systems such as boilers or pipes known.
  • copolymers obtainable by copolymerizing N-vinylcarboxamides, monoethylenically unsaturated carboxylic acids and, if appropriate, other ethylenically unsaturated monomers and subsequent hydrolysis of the vinylcarboxylic acid units in the copolymers to the corresponding amine or ammonium units are obtainable papermaking can be used as an additive to the paper stock to increase the rate of dewatering and the retention and the dry and wet strength of the paper, cf. EP-B 672 212.
  • the object of the present invention is to provide a further process for the production of paper with high dry strength and the lowest possible wet strength.
  • the increase in dry strength, in particular in packaging papers (for example testliner) should be further improved compared to the processes known hitherto.
  • the wet strength or the ratio of wet to dry strength should be further minimized.
  • the object is achieved according to the invention by a process for the production of paper, paperboard and cardboard with high dry strength by separately adding a polymer containing vinylamine units and a polymeric anionic compound to a pulp, dewatering the pulp and drying the paper products, if polymeric anionic compound at least one copolymer obtainable by copolymerizing
  • R 1 , R 2 H or C 1 - to C 6 -alkyl
  • (d) compounds having at least two ethylenically unsaturated double bonds in the molecule are (d) compounds having at least two ethylenically unsaturated double bonds in the molecule.
  • the polymeric anionic compound is a copolymer obtainable by copolymerizing
  • N-vinylformamide (b) acrylic acid, methacrylic acid and / or their alkali metal or ammonium salts and optionally (c) other monoethylenically unsaturated monomers.
  • the polymeric anionic compound contains, for example
  • These compounds may be modified in such a way that they additionally contain at least one compound with at least two ethylenically unsaturated double bonds in copolymerized form in the molecule.
  • branched copolymers are obtained.
  • the proportions and reaction conditions are to be chosen such that water-soluble polymers are still obtained.
  • polymerization regulators Use can be made of all known regulators, such as e.g. Thiols, sec. Alcohols, sulfites, phosphites, hypophosphites, thioacids, aldehydes, etc. (further details can be found, for example, in EP-A 438 744, page 5, lines 7-12).
  • the branched copolymers contain, for example
  • Examples of monomers of group (a) are N-vinylformamide, N-vinyl-N-methylformamide, N-vinylacetamide, N-vinyl-N-methylacetamide, N-vinyl-N-ethylacetamide, N-vinyl-N-methylpropionamide and N -Vinylpropionamid.
  • the monomers of group (a) can be used alone or in a mixture in the copolymerization with the monomers of the other groups.
  • Suitable monomers of group (b) are, in particular, monoethylenically unsaturated carboxylic acids having 3 to 8 carbon atoms and the water-soluble salts of these carboxylic acids.
  • This group of monomers includes, for example, acrylic acid, methacrylic acid, dimethacrylic acid, ethacrylic acid, maleic acid, fumaric acid, itoconic acid, mesaconic acid, citraconic acid, methylenemalonic acid, allylacetic acid, vinylacetic acid and crotonic acid.
  • Suitable monomers of group (b) are also monomers containing sulfo groups, such as vinylsulfonic acid, acrylamido-2-methylpropanesulfonic acid and styrenesulfonic acid, and also vinylphosphonic acid.
  • the monomers of this group can be used alone or in mixture with one another, in partially or completely neutralized form in the copolymerization.
  • neutralization use is made, for example, of alkali metal or alkaline earth metal bases, ammonia, amines and / or alkanolamines.
  • Examples thereof are sodium hydroxide solution, potassium hydroxide solution, sodium hydroxide, potassium carbonate, sodium bicarbonate, magnesium oxide, calcium hydroxide, calcium oxide, triethanolamine, ethanolamine, morpholine, diethylenetriamine or tetraethylenepentamine.
  • the monomers of group (b) are preferably used in the copolymerization in partially neutralized form.
  • the copolymers may optionally contain monomers of group (c) in copolymerized form, for example esters of ethylenically unsaturated C 3 - to C 5 -carboxylic acids, such as methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, isobutyl methacrylate, methyl methacrylate, ethyl methacrylate and vinyl esters, for example vinyl acetate. acetate or vinyl propionate, or other monomers such as N-vinylpyrrolidone, N-vinylimidazole, acrylamide and / or methacrylamide.
  • monomers of group (c) in copolymerized form for example esters of ethylenically unsaturated C 3 - to C 5 -carboxylic acids, such as methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl
  • copolymers (d) which contain at least two double bonds in the molecule, for example methylene bisacrylamide, glycol diacrylate, glycol dimethacrylate, glyceryl triacrylate, triallylamine, pentaerythritol triallyl ether, at least two times with acrylic acid and or methacrylic acid esterified polyalkylene glycols or polyols such as pentaerythritol, Sobit or glucose. If at least one monomer of group (d) is used in the copolymerization, the amounts used are up to 2 mol / o, for example 0.001 to 1 mol%.
  • copolymerization of the monomers takes place in a known manner in the presence of free-radical polymerization initiators and if appropriate in the presence of polymerization regulators, cf. EP-B 672 212, page 4, lines 13-37 or EP-A 438 744, page 2, line 26 to page 8, line 18.
  • Suitable polymeric anionic compounds are also amphoteric copolymers obtainable by copolymerizing
  • R 1 , R 2 H or C 1 - to C 6 -alkyl
  • amphoteric compounds thus obtained contain, for example
  • (e) contains 0 to 42 mol% of vinylamine units in copolymerized form, wherein the content of amino groups in the copolymer is at least 5 mol% below the content of copolymerized acid group-containing monomer (b).
  • the hydrolysis of the anionic copolymers can be carried out in the presence of acids or bases or else enzymatically.
  • the vinylamine groups formed from the vinylcarboxamide units are in salt form.
  • the hydrolysis of vinylcarboxylic acid amide copolymers is described in U.S. Pat
  • polymeric anionic compound is preferably used a copolymer which
  • the average molecular weights M.sub.w of the anionic or amphoteric polymers are, for example, 30,000 D to 10 million D, preferably 100,000 D to 1 million D.
  • These polymers have, for example, K values (determined according to H. Fikentscher in 5% aqueous sodium chloride solution pH 7, a polymer concentration of 0.5% by weight and a temperature of 25 ° C) in the range of 20 to 250, preferably 50 to 150.
  • a polymeric cationic component is added to the paper stock, which is exclusively polymers containing vinylamine units.
  • all polymers are suitable, which are spielnem in the cited in the prior art WO 04/061235, page 12, line 28 to page 13, line 21 and in Figure 1 are given.
  • the molar mass M w of the polymers containing vinylamine units is, for example, 1000 to 5 million and is usually in the range from 5 000 to 500 000, preferably 40 000 D to 400 000 D.
  • the other group of polymers, namely polymers containing vinylamine units are obtainable, for example, by polymerizing at least one monomer of the formula
  • R 1 , R 2 H or C 1 - to C 6 -alkyl
  • amide units can be formed in a secondary reaction from vinylamine units and adjacent vinylformamide units.
  • the indication of vinylamine units comprises the sum of vinylamine and amidine units in the polymer.
  • polymer containing vinylamine units for example, a homopolymer of N-vinylformamide hydrolyzed to at least 10 mol% is used. Polyvinylamine and / or at least 50 mol% of hydrolyzed homopolymers of N-vinylformamide are preferably used in the inventive method as katio ⁇ African component.
  • amphoteric copolymers as the cationic component, provided that they have at least 10 mol% more cationic groups than anionic groups.
  • amphoteric polymers are spielnem available by copolymerization
  • R 1 , R 2 H or C 1 - to C 6 -alkyl
  • This group of polymers contains, for example, up to a maximum of 35 mol%, preferably up to a maximum of 10 mol%, of at least one acid group-containing monomer of group (b).
  • Wood pulp includes, for example, groundwood, thermomechanical pulp (TMP), chemo-thermo-mechanical pulp (CTMP), pressure pulp, semi-pulp, high yield pulp and refiner mechanical pulp (RMP).
  • TMP thermomechanical pulp
  • CMP chemo-thermo-mechanical pulp
  • RMP refiner mechanical pulp
  • pulp for example, sulphate, sulphite and soda pulps come into consideration.
  • unbleached pulp which is also referred to as unbleached kraft pulp.
  • Suitable annual plants for the production of pulps are, for example, rice, wheat, sugar cane and kenaf.
  • waste paper is usually used, which is used either alone or in admixture with other pulps or one starts from fiber blends of a primary material and recycled coated broke, e.g. Bleached pine sulfate in admixture with reclaimed coated broke.
  • the inventive method has particular significance for the production of paper and cardboard from waste paper, because it significantly increases the strength properties of the recycled fibers.
  • the pH of the stock suspension is, for example, in the range of 4.5 to 8, most 6 to 7.5.
  • an acid such as sulfuric acid or aluminum sulphate.
  • the polymers comprising vinylamine units, ie the cationic component of the polymers to be metered into the paper stock, are added to the thick stock or preferably to a thin stock in the method according to the invention.
  • the point of addition is preferably in front of the screens, but may also be between a shearing stage and a screen or afterwards.
  • the anionic component is usually only after addition of the cationic component added to the pulp, but can also be dispensed simultaneously but separately from the cationic component to the pulp. Furthermore, it is also possible first to add the anionic and subsequently the cationic component.
  • the vinylamine units-containing polymer and the polymeric anionic compound are used, for example, in each case in an amount of 0.1 to 2.0% by weight, preferably 0.3 to 1% by weight, based on dry paper stock.
  • the ratio of vinylamine-containing polymer to polymeric anionic compound is for example 5: 1 to 1: 5 and is preferably in the range of 2: 1 to 1: 2.
  • the process according to the invention gives paper products which, compared with the processes of the prior art, have a higher level of dry strength with simultaneously low wet strength.
  • the parts given in the following examples are parts by weight, the percentages relate to the weight of the substances.
  • the K value of the polymers was determined according to Fikentscher, Cellulose-Chemie, Volume 13, 58-64 and 71-74 (1932) strength at a temperature of 2O 0 C in 5 wt .-% aqueous saline solutions at a pH of 7 and a polymer concentration of 0.5%.
  • K k * 1000.
  • the amounts of a polyvinylamine (PVAm 1) with a K value of 110 (prepared by hydrolysis of polyvinylformamide, degree of hydrolysis 95%), based on dry fiber, were first given in Table 1. and after a residence time of 5 minutes, the amounts of a copolymer of 60% of acrylic acid and 40% of acrylonitrile (copolymer 1) also shown in Table 1 are added. The copolymer was in the form of the sodium salt and had a K value of 130. After an exposure time of 1 minute, the paper stock thus treated in each case was dewatered to form a sheet.
  • PVAm 1 polyvinylamine
  • X Amount of cationic component used
  • Y Amount of anionic component used
  • TRL Dry breaking length
  • NRL Wet breaking length ReI.
  • NRL relative wet tear length

Landscapes

  • Paper (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un procédé pour produire du papier, du carton ou du carton blanchi présentant une résistance élevée à sec, comprenant l'ajout séparé d'un polymère contenant des unités d'amine vinylique et d'un composé anionique polymère à la pulpe de papier, le drainage de la pulpe de papier et le séchage des produits en papier. Le procédé de l'invention est caractérisé par l'utilisation d'au moins un copolymère en tant que composé anionique polymère, obtenu par copolymérisation (a) d'au moins un amide d'acide N-propénoïque de formule (I), dans laquelle R<SUP>1</SUP>, R<SUP>2</SUP>= H ou alkyle C<SUB>1</SUB>-C<SUB>6</SUB>, (b) au moins un monomère non saturé par du monoéthylène contenant un groupe d'acides et/ou des sels de métaux alcalins, des sels d'alcalino-terreux ou leurs sels d'ammonium, et éventuellement (c) d'autres monomères non saturés par du monoéthylène, et éventuellement (d) des composés qui comprennent au moins deux liaisons doubles non saturées par du monoéthylène dans la molécule.
EP05811227A 2004-11-23 2005-11-21 Procede pour produire du papier, du carton, du carton blanchi presentant une resistance elevee a sec Expired - Lifetime EP1819877B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL05811227T PL1819877T3 (pl) 2004-11-23 2005-11-21 Sposób wytwarzania papieru, tektury i kartonu o dużej wytrzymałości w stanie suchym

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004056551A DE102004056551A1 (de) 2004-11-23 2004-11-23 Verfahren zur Herstellung von Papier, Pappe und Karton mit hoher Trockenfestigkeit
PCT/EP2005/012429 WO2006056381A1 (fr) 2004-11-23 2005-11-21 Procede pour produire du papier, du carton, du carton blanchi presentant une resistance elevee a sec

Publications (2)

Publication Number Publication Date
EP1819877A1 true EP1819877A1 (fr) 2007-08-22
EP1819877B1 EP1819877B1 (fr) 2013-01-09

Family

ID=35911124

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05811227A Expired - Lifetime EP1819877B1 (fr) 2004-11-23 2005-11-21 Procede pour produire du papier, du carton, du carton blanchi presentant une resistance elevee a sec

Country Status (11)

Country Link
US (1) US8349134B2 (fr)
EP (1) EP1819877B1 (fr)
JP (1) JP4778521B2 (fr)
CN (1) CN101065538B (fr)
BR (1) BRPI0518485B1 (fr)
CA (1) CA2586076C (fr)
DE (1) DE102004056551A1 (fr)
ES (1) ES2400189T3 (fr)
PL (1) PL1819877T3 (fr)
PT (1) PT1819877E (fr)
WO (1) WO2006056381A1 (fr)

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DE102004052957A1 (de) * 2004-10-29 2006-05-04 Basf Ag Verfahren zur Herstellung von gekrepptem Papier
DE102005029010A1 (de) * 2005-06-21 2006-12-28 Basf Ag Verfahren zur Herstellung von Papier, Pappe und Karton
ES2625622T3 (es) 2006-03-16 2017-07-20 Basf Se Procedimiento para la fabricación de papel, cartulina y cartón con alta resistencia en seco
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PT2288750E (pt) 2008-05-15 2012-09-26 Basf Se Processo para a produção de papel, de papelão e de cartão com elevada resistência a seco
US8404083B2 (en) 2008-08-18 2013-03-26 Basf Se Process for increasing the dry strength of paper, board and cardboard
WO2010089334A1 (fr) 2009-02-05 2010-08-12 Basf Se Procédé de fabrication de papier, de carton-pâte et de carton présentant une grande résistance à sec
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CN104452463B (zh) 2013-09-12 2017-01-04 艺康美国股份有限公司 造纸方法以及组合物
CN104452455B (zh) 2013-09-12 2019-04-05 艺康美国股份有限公司 造纸助剂组合物以及增加成纸灰分保留的方法
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MX2018015283A (es) 2016-06-10 2019-04-09 Ecolab Usa Inc Polimero de polvo seco de bajo peso molecular para usar como agente de resistencia en estado seco que fabrica papel.
BR112020001752B1 (pt) 2017-07-31 2024-01-09 Ecolab Usa Inc Método para incorporar um auxiliar de resistência de polímero de baixo peso molecular em um processo de fabricação de papel
CN115162044B (zh) * 2017-10-11 2024-02-23 索理思科技开曼公司 用于生产纸或纸板的方法
WO2019118675A1 (fr) 2017-12-13 2019-06-20 Ecolab Usa Inc. Solution comprenant un polymère associatif et un polymère de cyclodextrine
WO2020053393A1 (fr) 2018-09-14 2020-03-19 Solenis Technologies Cayman, L.P. Procédé d'hydrolyse d'un polymère
KR20230116829A (ko) 2020-12-04 2023-08-04 에이지씨 케미컬스 아메리카스 인코포레이티드 처리된 물품, 처리된 물품을 제조하는 방법, 및 처리된 물품을 제조하는 데 이용하기 위한 분산액

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WO2006056381A1 (fr) 2006-06-01
BRPI0518485B1 (pt) 2015-08-04
PL1819877T3 (pl) 2013-05-31
EP1819877B1 (fr) 2013-01-09
DE102004056551A1 (de) 2006-05-24
JP2008520844A (ja) 2008-06-19
JP4778521B2 (ja) 2011-09-21
CN101065538A (zh) 2007-10-31
US8349134B2 (en) 2013-01-08
BRPI0518485A2 (pt) 2008-11-18
CA2586076C (fr) 2016-03-15
CA2586076A1 (fr) 2006-06-01
ES2400189T3 (es) 2013-04-08
US20090145566A1 (en) 2009-06-11
PT1819877E (pt) 2013-03-12
CN101065538B (zh) 2011-10-12

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