EP1843865A1 - Verfahren zum herstellen einer behälterdrehverschluss-kappe und behälterdrehverschluss-kappe - Google Patents
Verfahren zum herstellen einer behälterdrehverschluss-kappe und behälterdrehverschluss-kappeInfo
- Publication number
- EP1843865A1 EP1843865A1 EP06700491A EP06700491A EP1843865A1 EP 1843865 A1 EP1843865 A1 EP 1843865A1 EP 06700491 A EP06700491 A EP 06700491A EP 06700491 A EP06700491 A EP 06700491A EP 1843865 A1 EP1843865 A1 EP 1843865A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cap
- seal
- container
- film
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 238000007789 sealing Methods 0.000 claims abstract description 45
- 229910052751 metal Inorganic materials 0.000 claims abstract description 39
- 239000002184 metal Substances 0.000 claims abstract description 39
- 230000002093 peripheral effect Effects 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 238000004080 punching Methods 0.000 claims description 9
- 239000011888 foil Substances 0.000 claims description 8
- 230000004888 barrier function Effects 0.000 claims description 6
- 238000010030 laminating Methods 0.000 description 12
- 239000011521 glass Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000012939 laminating adhesive Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 239000000565 sealant Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000006399 behavior Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 235000008452 baby food Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000009928 pasteurization Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000021058 soft food Nutrition 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000028838 turning behavior Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D43/00—Lids or covers for rigid or semi-rigid containers
- B65D43/02—Removable lids or covers
- B65D43/0202—Removable lids or covers without integral tamper element
- B65D43/0225—Removable lids or covers without integral tamper element secured by rotation
- B65D43/0231—Removable lids or covers without integral tamper element secured by rotation only on the outside, or a part turned to the outside, of the mouth of the container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D51/00—Making hollow objects
- B21D51/16—Making hollow objects characterised by the use of the objects
- B21D51/38—Making inlet or outlet arrangements of cans, tins, baths, bottles, or other vessels; Making can ends; Making closures
- B21D51/44—Making closures, e.g. caps
- B21D51/46—Placing sealings or sealing material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D51/00—Making hollow objects
- B21D51/16—Making hollow objects characterised by the use of the objects
- B21D51/52—Making hollow objects characterised by the use of the objects boxes, cigarette cases, or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00018—Overall construction of the lid
- B65D2543/00064—Shape of the outer periphery
- B65D2543/00074—Shape of the outer periphery curved
- B65D2543/00092—Shape of the outer periphery curved circular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2543/00—Lids or covers essentially for box-like containers
- B65D2543/00009—Details of lids or covers for rigid or semi-rigid containers
- B65D2543/00953—Sealing means
- B65D2543/00962—Sealing means inserted
Definitions
- the invention relates to a method for producing a container twist-lock cap, in which the container twist-lock cap is punched out of sheet metal and a peripheral wall with a rolled edge is formed on a bottom and a seal is attached. Furthermore, the invention relates to a container rotary closure cap with a bottom, a peripheral wall adjoining the bottom and angled relative to the bottom, which has a rolled-up edge at its free end and surrounds an inside, and a seal.
- the capsule is formed from a sheet of metal.
- a blank required to form the capsule is punched out of a sheet which is in the form of a sheet.
- the peripheral wall can also be bent during punching. In further operations, the free end of the peripheral wall is then rolled up.
- the cap is provided with a seal when it is finished.
- the sealing material is partially applied on the inside of the bottom in the container mouth area up to the transition area between the bottom and the peripheral wall. In some cases, the seal is only applied over part of the surface.
- the seal is made of elastic material, which can put on the mouth of the container to be sealed for sealing.
- the invention has for its object to be able to produce a rotary container cap inexpensively.
- this object is achieved in that the seal is applied to the sheet metal before it is formed, the seal being arranged in such a way that it extends into the rolled edge.
- the seal is preferably applied before punching out. So you can apply the seal when the sheet is still in sheet or strip form. This significantly simplifies handling.
- the seal is preferably laminated in the form of a sealing film onto a sheet-like or band-shaped blank.
- the sealing film can be pulled off a roll, for example.
- For lamination it is basically only necessary to pass the metal sheet or the metal strip together with the sealing film through the nip of a pair of rollers and to apply an increased pressure and possibly an increased temperature there.
- a stamp-like press is also suitable for laminating or laminating a sealing film onto a metal sheet. If the cap is then punched out of this composite material and shaped, then it has on its inside the seal, which not only extends into the rolled edge, but practically ends with the peripheral edge of the cap. This has other advantages.
- a fully laminated cap on the inside is also gentle on the mouth of a glass container.
- the risk of glass splintering when closing is significantly minimized.
- the seal lies in another area at the mouth of the container.
- the risk of rust formation on the inside of the cap, also on the edge, is greatly minimized.
- the cap is also more suitable for PET bottles because the flat elastic layer allows it to adapt to the mouth of the container. Manufacturing becomes safer since it can practically no longer happen that a cap has no seal. So there is less committee.
- a multilayer film is preferably used as the sealing film. If you use a film as a seal, you can adapt to different requirements by selecting the sealing film. In the case of a multilayer film, the construction of individual layers can meet various requirements. In the case of a multilayer film, the individual layers do not have to be clearly separated from one another. Accordingly, relatively inexpensive sealing films can be used.
- an outer coating is applied in the form of a film on the side of the sheet metal opposite the seal, which extends into the rolled edge.
- a film can be applied on the outside, which is then a replacement for the previously used printing on the cap.
- the film on the outside can then shape the outer appearance of the cap. For example, the name of the manufacturer or the type of goods contained in the container can be printed there. If the film on the outside is also in the rolled area W
- the object is achieved in a container rotary closure cap 0 of the type mentioned in that the seal extends into the rolled edge.
- the sealing properties are improved because the seal lies in a larger area at the mouth of the container, for example a beverage bottle, a jam jar, a preserving jar or a baby soft food container.
- the enlargement of the expansion of the seal is gentle on the mouth of the glass container.
- the risk of glass splintering when closing is significantly minimized.
- the corrosion behavior of the cap is improved compared to the paint layer previously present on the inside.
- the seal is preferably formed by a sealing film which is applied to a blank from which the cap is formed.
- the application of the seal can be simplified considerably. You only have to apply the sealing film to a sheet of metal or a metal strip. On the one hand, such a process can be automated well. On the other hand, it can be accomplished with relatively simple devices. Basically, you only have to run the sealing film together with the board or the tape through a press.
- the waste that arises after punching will also be covered with a film. However, this can easily be accepted.
- the seal is also held by the rolled edge, i.e. H . there is no area where you can freely access the seal from the outside to remove it.
- the sealing film is preferably designed as a multilayer film.
- the individual layers can be adapted to different requirements.
- the sealing film is formed at least in part of its thickness by a foam-like material.
- a foam-like material for example in the form of a foam core
- good flexibility of the sealing film is achieved. This improves the contact of the sealing film with the container mouth.
- the sealing film preferably has a metallized barrier layer on its side facing away from the floor.
- Such a barrier layer improves the seal against the container.
- such a barrier layer prevents oxygen from the air from diffusing through the plastic, which is a major component of the film, into the interior of the container.
- the turning behavior for example when opening, can be influenced favorably. (If the outer coating overlaps the rolled edge, you can favorably influence the friction behavior between the lid and the container by choosing the appropriate material.
- the cap has an outer coating on an outer side separated from the inside by the floor, which overlaps the rolled edge.
- Such an outer coating can replace the paint used previously. '' Because the outer coating overlaps the edge up to its invisible edge, i.e. covers the entire surface of the sheet, there is little risk that the outer coating will be accidentally detached [ ⁇ You can already apply the desired outer coating to the cap Provide optical design, for example printing. It is much easier to print a flat coating than a three-dimensional cap. This also helps keep costs down.
- an aluminum foil can be used as the barrier layer.
- the outer coating is preferably formed by a film which is applied to the blank. For example, such a film can also be laminated or laminated onto the metal sheet or the metal strip on the outside. The outer coating is then punched out together with the inner coating and the material of the cap and at the same time formed into the cap.
- Fig. 1 shows a first embodiment of a container rotary closure cap, partly in section
- Fig. 2 shows a second embodiment of a container screw cap, partly in section
- Fig. 3 shows a detail X of the cap of a first embodiment
- Fig. 5 shows the detail X of the cap of a third embodiment
- Fig. 6 shows a schematic illustration to explain the manufacture of the cap.
- Fig. 1 shows a first embodiment of a container rotary closure cap 1, partly in section.
- the containers termosverschluß cap 1 is also abbreviated in the following with "cap 1".
- the cap 1 has a base 2 which merges into a peripheral wall 3.
- the peripheral wall 3 is angled relative to the floor 2 by approximately 90 °.
- the transition between the floor 2 and the peripheral wall 3 takes place here via an inclined surface 4. In one of the 2 alternative embodiment shown, the transition can also take place via a curvature 4 '.
- the peripheral wall 3 is at its free, ie. H . in Fig. 1 lower end curled, d. H . it has a rolled-up edge 5.
- the edge 5 surrounds a circumferential cavity 6 which is enclosed by the peripheral wall 3.
- the cavity 6 can be open towards the bottom 2, as is the case with the embodiment in FIG. 1 is the case. However, the cavity 6 can also be closed, as is the case in the embodiment of FIG. 2 is shown.
- the edge 5 has a plurality of radially inward projections 7 which can engage in a thread on a container (not shown in more detail).
- a container not shown in more detail.
- projections 7 are unnecessary if the container neck is designed accordingly.
- the cap 1 can be loosened in any case by turning the container neck.
- the peripheral wall 3 surrounds an inside 8 of the cap 1. Accordingly, an outside 9 is formed on the outside of the cap 1.
- inside and outside side refer not only to the bottom 2, but to the complete cap 1.
- a seal 10 is arranged on the inside 8. As shown in Fig. 3 to 5 can be seen, this seal can have 10 different designs. Common to all of the embodiments, however, is that the seal 10 is not limited to the base 2, but rather via the inclined surface 4 or. the curvature 4 'into the peripheral wall 3 and there is continued into the rolled edge 5, so that the seal 10 practically ends with the edge of the rolled edge. This means that the seal 10 is formed together with the edge 5. This means that there is no area at any point where one could engage in the contact area between the seal 10 and the sheet metal of the cap 1 in order to detach the cap. In the configuration according to Fig. 2, the edge 5 is even bent back on itself, that is, it additionally clamps the seal 10.
- the outer side 9 of the cap 1 is provided with an outer coating 11.
- the outer coating 11 also extends over the entire outside 9 of the cap 1, that is to say over the rolled-up edge 5, and covers the entire outside 9 of the cap 1 over the entire area.
- a metal sheet 12 or a metal strip is passed through a laminating device 13.
- the laminating device is shown here schematically with two rollers 14, 15
- the laminating device can, however, also be formed in another way, for example by a press which works with stamps.
- a roll 17 is arranged in front of the laminating device 13, from which the seal 10 in the form of a sealing film 18 is pulled off.
- the sealing film 18 passes through the laminating device 13 together with the metal sheet 12 and is laminated there onto the metal sheet 12.
- a roller 19 is arranged in front of the laminating device 13 on the side of the metal sheet 12 opposite the roller 17 of the sealing foil 18, from which a foil 20 is pulled off, which forms the outer coating 11 of the cap 1.
- the sealing film 18 and the film 20 are thus laminated onto the metal sheet 12 in one operation.
- the composite material formed in this way from sheet metal sheet 12, sealing sheet 18 and sheet 20 is passed through a punch 21 which, in one working step, stamps out both the material required for the manufacture of cap 1 from sheet metal sheet 12 and cap 1 in a preliminary stage of the one shown in FIG . 1 brings shape. Not only is the sheet metal of the sheet metal plate 12 formed, but also the sealing film 18 and the film 20 laminated onto the sheet metal plate 12. The film 20 may be unnecessary.
- the punch 21 immediately follows the laminating device. As a rule, however, the laminated metal sheet will be used for a predetermined time, e.g. 24 hours, let it rest between the Foils and the laminating adhesive arranged in the sheet metal reaches its final strength.
- a further machine 31 connects to the punch 21 and ultimately rolls the edge 5.
- This machine 31 is shown here as a single machine. However, it can also be integrated into the punch 21 or be formed from several individual forming machines.
- the sealing film 18 and the film 20 are formed together with the sheet metal, which ultimately forms the cap 1.
- FIGS. 1, 2 and 6 show different designs of caps in a detail X.
- the same parts have the same reference numerals as in FIGS. 1, 2 and 6 provided.
- the section of the base 2 which is mainly formed from a sheet 22 as a load-bearing element.
- the in Fig. the stratification shown in FIG. 3 continues over the entire material of the cap 1, that is also in the edge 5.
- the sheet 22 has the film 20 on its outside and the sealing film 18 on its inside.
- the film 20 can bear any print. It can be formed by a relatively thin plastic film.
- the sealing film 18 is suitable for sealing. Accordingly, it has a thickness of, for example, min. at least 250 ⁇ m and a suitable elasticity. Both the sealing film 18 and the film 20 can be connected to the sheet 22 using suitable laminating adhesives. When using laminating adhesives, the possible. After filling and closing a container, the required heat processes, for example pasteurization, are carried out.
- the sealing film 18 can be compact or foamed. The foaming does not have to go through the entire thickness of the sealing film 18.
- Fig. 3 shows the sealing film 18 with one layer.
- Fig. 4 shows an embodiment in which the film 18 a
- Has carrier region 23 with a greater thickness which can be foamed, for example, and a metal layer 24, for example an aluminum foil, or a metallized layer, for example an evaporated foil.
- the metallized layer prevents, for example, oxygen from the air from getting through the carrier layer 23 into the interior of the container closed with the cap 1.
- Fig. 5 shows a film 18 which is composed of three layers, namely the mentioned carrier layer 23, the metal layer 24 and a fastening layer 25.
- the person skilled in the art will select a suitable construction of the sealing film 18 with one or more layers.
- the sealing film 18 and optionally also the film 20 can be produced as an outer coating by laminating a sheet metal sheet 12 flat on high-performance tape or sheet laminating systems 13.
- a laminating system 13 of this type can handle the same throughput as the downstream punch 21. Accordingly, less mechanical effort is required.
- cap 1 There is no need for complex production facilities for introducing a seal into a single cap 1. A larger selection of materials is obtained for the seal 10. The cap 1 can thus be better adapted to individual requirements. The manufacturing process for the cap 1 is reduced to a minimum. The result is a very small space requirement and a considerably lower energy requirement. A cap 1, which is fully laminated on the inside, is also gentle on the mouth for the container, for example a glass container. The risk of glass splintering when closing is significantly minimized.
- the seal lies in a wide area on the mouth of the container.
- the risk of rust formation on the inside is greatly minimized.
- a film 20 is used as the outer coating, this also applies to the outer coating.
- the film 20 can punch even on the cutting edge that is created during punching. Even if the film 20 only partially covers this cut edge, it improves the corrosion protection.
- the cap 1 is also more suitable for PET bottles, since it can adapt to the mouth of such a container through the flat elastic seal 10.
- the formation of the outer coating 11 as a film 20 saves energy and time. Only two work steps are required, namely the production of the film and the application of the film 20 to the metal sheet 12. So far, far more processes have been required, namely priming, printing and silver coating the cap, with thermal aftertreatment being necessary which is correspondingly energy-intensive.
- Sealing film 18 and film 20 only have to be applied to the sheet and, if necessary, glued there. A thermal aftertreatment is not necessary or only necessary to harden the laminating adhesive between the foils 18, 20 and the sheet 22.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Closures For Containers (AREA)
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005005003A DE102005005003B3 (de) | 2005-02-03 | 2005-02-03 | Verfahren zum Herstellen einer Behälterdrehverschluß-Kappe und Behälterdrehverschluß-Kappe |
| PCT/EP2006/000387 WO2006081943A1 (de) | 2005-02-03 | 2006-01-18 | Verfahren zum herstellen einer behälterdrehverschluss-kappe und behälterdrehverschluss-kappe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1843865A1 true EP1843865A1 (de) | 2007-10-17 |
| EP1843865B1 EP1843865B1 (de) | 2008-12-24 |
Family
ID=36013453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06700491A Expired - Lifetime EP1843865B1 (de) | 2005-02-03 | 2006-01-18 | Verfahren zum herstellen einer behälterdrehverschluss-kappe und behälterdrehverschluss-kappe |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1843865B1 (de) |
| AT (1) | ATE418403T1 (de) |
| DE (1) | DE102005005003B3 (de) |
| ES (1) | ES2318718T3 (de) |
| WO (1) | WO2006081943A1 (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015050755A1 (en) | 2013-10-02 | 2015-04-09 | Valspar Corporation | Removable closure and coating system |
| PL2996954T3 (pl) | 2013-10-02 | 2023-05-29 | Swimc Llc | Wymienny system zamknięcia i powlekania |
| EP3194286A1 (de) | 2014-08-20 | 2017-07-26 | Crown Packaging Technology, Inc. | Laschenverschluss |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1600676A (de) * | 1968-12-31 | 1970-09-04 | ||
| ES237022U (es) * | 1978-06-30 | 1978-09-16 | Vem De Tapas Metalicas, S. A. | Tapa metalica para envase. |
| DE19503031A1 (de) * | 1995-01-31 | 1996-08-08 | Schmalbach Lubeca | Dichtungs-Print-Verfahren für Metalldeckel |
-
2005
- 2005-02-03 DE DE102005005003A patent/DE102005005003B3/de not_active Expired - Fee Related
-
2006
- 2006-01-18 WO PCT/EP2006/000387 patent/WO2006081943A1/de not_active Ceased
- 2006-01-18 AT AT06700491T patent/ATE418403T1/de not_active IP Right Cessation
- 2006-01-18 EP EP06700491A patent/EP1843865B1/de not_active Expired - Lifetime
- 2006-01-18 ES ES06700491T patent/ES2318718T3/es not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2006081943A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2318718T3 (es) | 2009-05-01 |
| EP1843865B1 (de) | 2008-12-24 |
| DE102005005003B3 (de) | 2006-09-28 |
| ATE418403T1 (de) | 2009-01-15 |
| WO2006081943A1 (de) | 2006-08-10 |
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