EP1925339A1 - Mittel zur Beseitigung von schlechten Gerüchen und von Pestiziden und Verfahren zu dessen Herstellung - Google Patents

Mittel zur Beseitigung von schlechten Gerüchen und von Pestiziden und Verfahren zu dessen Herstellung Download PDF

Info

Publication number: EP1925339A1
Authority: EP; European Patent Office
Prior art keywords: group; agent; pesticide; malodor; counteractant
Prior art date: 2006-11-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP06023459A

Other languages

English (en)

French (fr)

Inventor

Jih-Ru Hwu

Cheng-Mei Jseng

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Well-being Biochemical Corp

Well being Biochemical Corp

Original Assignee

Well-being Biochemical Corp

Well being Biochemical Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-11-10

Filing date

2006-11-10

Publication date

2008-05-28

2006-11-10 Application filed by Well-being Biochemical Corp, Well being Biochemical Corp filed Critical Well-being Biochemical Corp

2006-11-10 Priority to EP06023459A priority Critical patent/EP1925339A1/de

2008-05-28 Publication of EP1925339A1 publication Critical patent/EP1925339A1/de

Status Withdrawn legal-status Critical Current

Links

239000000575 pesticide Substances 0.000 title claims abstract description 81
239000003795 chemical substances by application Substances 0.000 title claims abstract description 80
238000004519 manufacturing process Methods 0.000 title claims abstract description 17
238000000034 method Methods 0.000 title claims abstract description 17
239000000470 constituent Substances 0.000 claims abstract description 31
150000008040 ionic compounds Chemical class 0.000 claims abstract description 23
239000000443 aerosol Substances 0.000 claims abstract description 20
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 15
239000005515 coenzyme Substances 0.000 claims abstract description 14
239000007800 oxidant agent Substances 0.000 claims abstract description 13
239000003599 detergent Substances 0.000 claims abstract description 11
239000006172 buffering agent Substances 0.000 claims abstract description 10
230000003197 catalytic effect Effects 0.000 claims abstract description 10
239000000203 mixture Substances 0.000 claims abstract description 9
239000000654 additive Substances 0.000 claims abstract description 6
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238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910000403 monosodium phosphate Inorganic materials 0.000 description 1
235000019799 monosodium phosphate Nutrition 0.000 description 1
210000000214 mouth Anatomy 0.000 description 1
230000035772 mutation Effects 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
230000007170 pathology Effects 0.000 description 1
OGYFATSSENRIKG-UHFFFAOYSA-N pencycuron Chemical compound C1=CC(Cl)=CC=C1CN(C(=O)NC=1C=CC=CC=1)C1CCCC1 OGYFATSSENRIKG-UHFFFAOYSA-N 0.000 description 1
LMNZTLDVJIUSHT-UHFFFAOYSA-N phosmet Chemical compound C1=CC=C2C(=O)N(CSP(=S)(OC)OC)C(=O)C2=C1 LMNZTLDVJIUSHT-UHFFFAOYSA-N 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
239000011736 potassium bicarbonate Substances 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 1
DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 1
150000004059 quinone derivatives Chemical class 0.000 description 1
230000001850 reproductive effect Effects 0.000 description 1
238000001223 reverse osmosis Methods 0.000 description 1
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
239000007921 spray Substances 0.000 description 1
235000021012 strawberries Nutrition 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
230000008685 targeting Effects 0.000 description 1
235000013616 tea Nutrition 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000004308 thiabendazole Substances 0.000 description 1
235000010296 thiabendazole Nutrition 0.000 description 1
WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
229960004546 thiabendazole Drugs 0.000 description 1
QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1
210000004916 vomit Anatomy 0.000 description 1
230000008673 vomiting Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1

Images

Classifications

- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/02—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by biological methods, i.e. processes using enzymes or microorganisms
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/38—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by oxidation; by combustion
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/04—Combined processes involving two or more non-distinct steps covered by groups A62D3/10 - A62D3/40

Definitions

the present invention relates to a malodor and pesticide counteractant agent and the fabrication method thereof, particularly to a counteractant agent including its fabrication method that can effectively decompose pesticides, malodors, and smokes.
pesticides on crops, such as vegetables, fruits, and tea trees.
pesticides such as Malathion, Iprodine (an organonitrogen/heterocyclic pesticide widely used for strawberries), and Pyridaben (widely used for tea trees) are hazardous toward human health. Because pesticides are often organic compounds and water insoluble, it is difficult to remove them with water. As a result, a portion of pesticide residues usually remains on the surface of the vegetables, fruits, and tea leaves. Overdose of pesticide makes farmers sick, vomit, or harmful to their cranial nerve. The pesticides accumulated in the body induce genetic mutations and could lead to cancer. The phenomenon of "Cancer Village" appearing in venue China results from the residual pesticides in the foods, which were eaten by the villagers over a long period of time.
Unpleasant smells often come from malodors and smokes.
the sources of malodors are usually nitrogen- or sulfur-containing compounds, such as amine (body odor and perspiration odor), trimethylamine (fish odor), hydrogen sulfide (rotten egg smell), and methyl mercaptan (kitchen garbage odor).
the smoke often comes from cigarette.
the deodorants on the market generally function on the basis of the principles of covering malodor with good odor, absorbing malodor, or neutralizing the acidic/basic molecules of malodors.
the odor-covering type deodorants can cover malodors, but they cannot decompose malodor molecules; therefore, the malodor still remains partially.
the absorption type deodorants are limited by their absorption capacity.
deodorants When malodor is too intense or after the deodorants have been used for a long period of time, the absorption capability of deodorants may be exhausted.
the acid-base neutralizing type deodorants can only be applied to the compounds that possess acidic or basic property.
Smoke pollution includes cigarette, barbecue, kitchen smokes, etc.
the primary constituent for cigarette smoke is nicotine
for barbecue smoke is acrylamide, imidazole, and quinoline as well as for kitchen smoke is usually indene, naphthalene, and phenanthrene.
Borgerding M.; Klus, H. Experimental and Toxicologic Pathology 2005, 57, 43-73 ; Brage, C.; Yu, Q.; Chen, G.; Sjostrom, K. Biomass and Bioenergy 2000, 18, 87-91 ; Preuss, R.; Angerer, H.; Drexler, H. Int. Arch. Occup. Environ. Health 2003, 76, 556-576 .
All of the smokes mentioned above are hazardous to human body; however, so far on the market, there is no appropriate agent that can effectively decompose the primary constituents of smokes.
the present invention discloses a malodor and pesticide counteractant agent and a fabrication method thereof, whereby the molecules of pesticides, malodors, and smokes can be decomposed as soon as those molecules contact the agent of the present invention.
the primary objective of the present invention is to provide a malodor and pesticide counteractant agent and a fabrication method thereof, wherein the agent of the present invention can be fabricated into an aerosol, a detergent, or an additive and used to decompose pesticides, malodors, and smokes.
Another objective of the present invention is to provide a malodor and pesticide counteractant agent and a fabrication method thereof, wherein the detergent fabricated according to the present invention can be used to clean the residual pesticides on crops, particularly vegetables and unpeeled fruits.
the other objective of the present invention is to provide a malodor and pesticide counteractant agent and a fabrication method thereof, wherein the aerosol fabricated according to the present invention can effectively decompose the residual pesticides on crops.
the aerosol of the present invention can be used to eliminate body odors, such as underarm odor, perspiration odor, sole odor, bad breath, hair odor, menstrual odor as well as odors of animals and pets.
the aerosol of the present invention can be applied directly on daily necessities, air filters, clothes, respirators, masks, gloves, protective clothes, condoms, and medical devices.
the aerosol can also be applied to the spaces polluted by odors or smokes, such as the interior and exterior of living rooms, vehicle compartments, fish bowls, bathrooms, restaurants, hotels, kitchens, barbecues, cybercafés, and smoking areas.
the malodor and pesticide counteractant agent of the present invention comprises: a catalytic ionic compound, a buffering agent, and a mixture of a reducing coenzyme and an oxidizing agent/an ionic compound/a sulfide, and the proportion of these constituents by weight is 1: 40 ⁇ 4,000 : 2 ⁇ 200.
the reducing coenzyme is selected from the group consisting of FMNH 2 (reduced flavin mononucleotide), FADH 2 (reduced flavin adenine dinucleotide), NADH (reduced nicotinamide adenine dinucleotide), and NADPH (reduced nicotinamide adenine dinucleotide phosphate);
the oxidizing agent is selected from the group consisting of hydrogen peroxide and quinone-based compounds, such as azulenequinone and its derivatives.
the general formula of the ionic compound is NX, wherein N is selected from the group consisting of Li, Na, and K, and X is selected from the group consisting of chloride, bromide, iodide, sulfite, acetate, succinate, pyrophosphate, perchlorate,
the present invention discloses a malodor and pesticide counteractant agent and a fabrication method thereof.
the agent of the present invention may be fabricated into an aerosol, a detergent, or an additive for decomposing pesticides, malodors, and smokes.
a detergent it can be used to remove the pesticide residues on the surface of fruits and vegetables.
an aerosol it can be sprayed on the unharvested crops to decompose the residual pesticides.
the aerosol can be applied on daily usage products, air filters, clothes, respirators, masks, gloves, protective clothes, condoms, and medical devices.
the aerosol can be sprayed on various areas of the human body to eliminate body odors, such as the hands, feet, head, underarms, reproductive organ, and oral cavity.
the aerosol is also able to eliminate the odors of animals and pets.
the malodor and pesticide counteractant agent is prepared by use of three primary constituents, which are mixed in different concentrations and proportions and then fabricated into different forms.
the constituents of the malodor and pesticide counteractant agents of the present invention include: (A) a catalytic ionic compound, (B) a buffering agent, and (C) a mixture of a reducing coenzyme and an oxidizing agent/an ionic compound/a sulfide.
Those constituents are to be described in detail below.
the malodor and pesticide counteractant agent of the present invention can be used to decompose the molecules of pesticides, odors, and smokes.
the agent of the present invention can be fabricated into an aerosol and sprayed onto the surface of the objects or to the air of the surroundings, and the agent can instantly react with oxygen and then decompose the chemical components contained in pesticides, odors, and smokes.
the agent of the present invention can be fabricated into a detergent or an additive and used to decompose the molecules of pesticides or odors in solutions.
the active time of the agent of the present invention correlates closely with the proportion, concentration, and dosage of the agent.
the active time of the agent sprayed on the surface of crops lasts as long as 3 ⁇ 7 days.
the active time of the agent sprayed on the objects or to the air of the surroundings depends on the characteristics of the surroundings and may reach to 12 ⁇ 72 hours.
the active time is 6 ⁇ 12 hours.
the agent is used to eliminate the underarm odor, perspiration odor, sole odor, bad breath, hair odor, or menstrual odor of the human body, the active time is 4 ⁇ 8 hours.
the fabrication method of the present invention includes the following steps:
Experiment 1 is to verify the efficacy of the agent fabricated according to the abovementioned embodiment in decomposing pesticides; tap water and a 10% salt solution are used for comparison of the decomposing rate in the this experiment.
the pesticides tested in this experiment include seven groups of pesticides with the total number thereof amounting to 17 compounds.
the pesticides tested in this experiment include: organophosphorous pesticides, such as Diazinon, Terbufos, Acephate, Glyphosate, Phosmet, and Mevinphos; organonitrogen/heterocyclic pesticides, such as Benomyl, Metalaxyl, and Pymetrozine; carbamate pesticides, such as Methomyl, Fenobucard, and Carbendazim; urea-type pesticides (herbicides), such as Pencycuron; triazole pesticides, such as Hexaconazole; dithiocarbamates pesticides (germicides), such as Thiophanate-methyl and Cartap; and other type pesticides, such as Thiabendazole.
organophosphorous pesticides such as Diazinon, Terbufos, Acephate, Glyphosate, Phosmet, and Mevinphos
organonitrogen/heterocyclic pesticides such as Benomyl, Metal
Fig. 1 and Table 1 indicate that the agent of the present invention can indeed decompose pesticides.
the agent of the present invention exhibits the best decomposition results on Terbufos, Acephate, and Hexaconazole.
Table 1 The experimental results of the agent of the present invention decomposing Terbufos, Acephate, and Hexaconazole.
Experiment 2 is to verify efficacy of the agent fabricated according to the abovementioned embodiment in destroying the molecules of malodors.
the decomposing rates are compared in this experiment.
the nitrogen- and sulfur-containing compounds, which have strong odor, are used as targeting samples, such as Terbufos, Diazinon, Hexaconazole, and Fenobucard.
the structural formula of these odor compounds are shown below:
Fig. 2 shows that the agent of the present invention can effectively decompose the nitrogen- or sulfur-containing odor molecules of Terbufos, Diazinon, Hexaconazole, and Fenobucard in 1.0 min, 3.0 min, and 5.0 min, respectively.
the agent of the present invention destroyed 91% of Terbufos, 87% of Diazinon, 85% of Hexaconazole, and 76% of Fenobucard. Therefore, the agent of the present invention can indeed decompose odor molecules in an efficient way.
Experiment 3 is to verify the efficiency of the agent fabricated according to the abovementioned embodiment in destroying the primary molecules of smokes, and the decomposing rates are compared.
nicotine, indene, and naphthalene are used as the testing samples. They respectively represent the major components in cigarette smoke, barbecue smoke, and kitchen smoke.
the solutions with different concentrations of the agent of the present invention are used to react with nicotine-the primary constituent of cigarette-in order to obtain the destruction rates of different concentrations of the agent.
Fig. 3 shows that the agent of the present invention decomposed the primary constituents of cigarette smoke (i.e., nicotine), barbecue smoke (i.e., indene), and kitchen smoke (i.e., naphthalene).
the twenty times dilution of the agent of the present invention destroyed >90% the primary constituents of the abovementioned smokes in 3.0 min; especially, the destruction extent of the primary constituent of cigarette smoke-nicotine-was as high as 99%.
Fig. 4 indicates that the agent of the present invention effectively decomposed nicotine in 2.0 min when the concentration of the agent of the present invention is twenty times diluted. Its destruction extent is >99%. Therefore, the agent of the present invention can indeed decompose the molecules of smokes efficiently.
the present invention achieves the objectives of eliminating pesticides, malodors, and smokes.

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Business, Economics & Management (AREA)
General Health & Medical Sciences (AREA)
Emergency Management (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Toxicology (AREA)
Microbiology (AREA)
Molecular Biology (AREA)
Engineering & Computer Science (AREA)
Biomedical Technology (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

EP06023459A 2006-11-10 2006-11-10 Mittel zur Beseitigung von schlechten Gerüchen und von Pestiziden und Verfahren zu dessen Herstellung Withdrawn EP1925339A1 (de)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
EP06023459A EP1925339A1 (de)	2006-11-10	2006-11-10	Mittel zur Beseitigung von schlechten Gerüchen und von Pestiziden und Verfahren zu dessen Herstellung

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Application Number	Priority Date	Filing Date	Title
EP06023459A EP1925339A1 (de)	2006-11-10	2006-11-10	Mittel zur Beseitigung von schlechten Gerüchen und von Pestiziden und Verfahren zu dessen Herstellung

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN101869845A (zh) *	2010-06-21	2010-10-27	浙江新和成股份有限公司	一种用于去氢异植物醇选择性加氢合成异植物醇的催化剂
US11988601B2 (en)	2020-06-08	2024-05-21	Kimberly-Clark Worldwide, Inc.	Method for determining residual carbamate compounds on an elastomeric article

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US11988601B2 (en)	2020-06-08	2024-05-21	Kimberly-Clark Worldwide, Inc.	Method for determining residual carbamate compounds on an elastomeric article

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EP1925339A1 - Mittel zur Beseitigung von schlechten Gerüchen und von Pestiziden und Verfahren zu dessen Herstellung - Google Patents

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Citations (7)

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