EP2041026A2 - Kryogenes flüssigkeitsinjektionssystem zur massenverarbeitung von produkten sowie kühlverfahren mit diesem system - Google Patents

Kryogenes flüssigkeitsinjektionssystem zur massenverarbeitung von produkten sowie kühlverfahren mit diesem system

Info

Publication number
EP2041026A2
EP2041026A2 EP07803959A EP07803959A EP2041026A2 EP 2041026 A2 EP2041026 A2 EP 2041026A2 EP 07803959 A EP07803959 A EP 07803959A EP 07803959 A EP07803959 A EP 07803959A EP 2041026 A2 EP2041026 A2 EP 2041026A2
Authority
EP
European Patent Office
Prior art keywords
valve
injection device
cryogenic fluid
enclosure
channel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07803959A
Other languages
English (en)
French (fr)
Other versions
EP2041026B1 (de
EP2041026B2 (de
Inventor
Hervé Flamant
Olivier Pouchain
Jacques Fouche
Jo Algoet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=37928620&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2041026(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to PL07803959.1T priority Critical patent/PL2041026T5/pl
Publication of EP2041026A2 publication Critical patent/EP2041026A2/de
Publication of EP2041026B1 publication Critical patent/EP2041026B1/de
Application granted granted Critical
Publication of EP2041026B2 publication Critical patent/EP2041026B2/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • F25D3/12Devices using other cold materials; Devices using cold-storage bodies using solidified gases, e.g. carbon-dioxide snow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/90Heating or cooling systems
    • B01F35/91Heating or cooling systems using gas or liquid injected into the material, e.g. using liquefied carbon dioxide or steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/30Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages
    • B05B1/3033Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head
    • B05B1/3073Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head the controlling element being a deflector acting as a valve in co-operation with the outlet orifice
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B15/00Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
    • B05B15/60Arrangements for mounting, supporting or holding spraying apparatus
    • B05B15/65Mounting arrangements for fluid connection of the spraying apparatus or its outlets to flow conduits
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/90Heating or cooling systems
    • B01F2035/98Cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/30Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages
    • B05B1/32Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages in which a valve member forms part of the outlet opening
    • B05B1/323Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages in which a valve member forms part of the outlet opening the valve member being actuated by the pressure of the fluid to be sprayed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • F25D3/10Devices using other cold materials; Devices using cold-storage bodies using liquefied gases, e.g. liquid air

Definitions

  • the present invention relates to a device for injecting, in a chamber, a cryogenic fluid under a pressure greater than that prevailing in the chamber.
  • a known device for the implementation of this method comprises several injection devices, arranged in the bottom of the tank, and supplied with liquid CO2 by a set of pipes, this assembly being provided with a single common control valve. .
  • the liquid CO2 in the pipes downstream of this valve can not be evacuated very quickly by the injection devices, and when the pressure falls below 5.18 bar approximately in the pipes, it turns into dry ice in these pipes which are thus obstructed. It is therefore impossible to resume the injection until the snow has disappeared by turning into gas by heating.
  • the pipes connecting the valve to the injection devices are flexible, which allows disassembly, and therefore accelerates the restart of the system. This disassembly is however a relatively long and painful operation.
  • Patent EP-744 578 describes an injection device making it possible to avoid the disadvantages caused by the incidents of capping under normal conditions of use.
  • This device is such that the connection between the shut-off valve and the injection nozzle is calculated so that a plug possibly formed in said connection and said nozzle following a closure of the injection valve can be expelled to the chamber by the pressurized liquid during the reopening of the injection valve.
  • the device does not have means to prevent plug formation, but the expulsion of this plug is possible from the restart, so that it is possible to proceed to a new injection to any time after the end of an earlier period of injection.
  • this device can be plugged by the entry of the material to be cooled in the injection device, and therefore the use of this device is limited to the cooling of solid product.
  • the present invention relates to an injection device intended to be fixed on the lower part of a container containing a product to be cooled in bulk, said injection device comprising a hollow cylindrical body into which is inserted a valve forced by a spring, said injection device comprising a through channel substantially parallel to said valve to be supplied with cryogenic fluid under pressure, one end of said through channel being connected to the cryogenic fluid supply system and the opposite end opening at the seat of the valve.
  • the spring is calibrated so that the valve can not slide without being subjected to a pressure of the cryogenic fluid at least equal to a threshold pressure.
  • the device according to the invention it is impossible for the material contained in the enclosure can be introduced into the device and create fillings requiring disassembly and cleaning, whatever the physical state of this material.
  • the device according to the invention is therefore suitable for cooling product both in liquid form, pasty, solid or granular.
  • pasty product any product whose viscosity is between liquid and solid.
  • the device may advantageously replace the cooling devices from the top of the tanks containing liquid or powdery products for which the systems of the prior art cooling down were not suitable.
  • the cryogenic fluid used is liquid nitrogen or liquid CO2, especially when the product to be cooled is a food product.
  • the device according to the invention can be implemented with any type of cryogenic fluid.
  • the device may comprise several transverse channels, one of whose ends opens at the seat of the valve.
  • the device comprises n through channels, n being between 1 and 20, an even number, their number increases when the pressure of use of the cryogenic fluid decreases, said channels being arranged symmetrically with respect to the longitudinal axis of the valve.
  • two channels are arranged symmetrically with respect to the longitudinal axis of the valve.
  • the device of the invention is subject to very large temperature differences. Indeed, the wall of the enclosure to which the device is attached is generally at room temperature, while the opposite portion of the device which receives the cryogenic fluid supply is at a temperature of -196 ° C. Icing phenomena on the external surface of the enclosure are therefore inevitable. There may therefore be sticking on the frosted wall of the enclosure of the material to be cooled. The icing points become hooked points of the product contained in the enclosure. These points become larger and end up closing the valve, no longer allowing the injection of cryogenic fluid.
  • the thermal break may be made of any insulating material, in particular polymer resin or any other insulating plastic material.
  • the device according to the invention comprises: a lower element, which in the operating position is furthest from the wall of the enclosure and which is connected to the cryogenic fluid supply system,
  • a central element whose lower end bears on the lower element, a valve slidably disposed in a through-hole formed axially in the central element, the seat of the valve being in sealing engagement against the beveled upper portion of said through hole, a thermal bridge surrounding the central element and the end of which lower is in support on the lower element,
  • said lower element comprising:
  • At least one supply channel whose one end is in connection with the supply system and the other end is in connection with an end of a through channel present in the central element, said through channel being substantially parallel to the axis of the valve, its other end opening at the seat of the valve,
  • said through hole of the central portion having at its lower end an upper diameter such that in the mounting position, the setting spring is held against said shoulder in the central hole of larger diameter and in the central recess of the lower element.
  • the various constituent elements are made of steel, preferably of steel stainless steel with the exception of the thermal bridge which is made of an insulating material.
  • the various constituent elements are held together by means of a quick disassembly coupling or screw-type or bayonet type or the like.
  • the device according to the invention must be able to be disassembled with a view in particular to calibrating the spring forcing the valve, or cleaning which is obligatory in the case of food products and which may be made necessary by abnormal operation or else by pollution. accidental.
  • the device is connected to the cryogenic fluid supply via a flexible fluid conduit. This is to allow quick disassembly. Indeed, the flexible conduit does not have to be removed for cleaning.
  • the cleaning is further facilitated by the maintenance of the various component parts using a rapid mechanical maintenance system ("quick" connection).
  • a rapid mechanical maintenance system (“quick" connection).
  • the device of the invention being intended to be used under pressure, means are provided so that only authorized personnel can disassemble the device.
  • the component parts of the device are fixed to each other by means of tamperproof screws and an anti-whiplash cable is fixed on the one hand to the flexible hose, on the other hand on both sides of the hose. "quick" connection, on the lower part of the device and on the upper part of it. The withdrawal of the whiplash antibody cable is only possible by using a specific key whose use is reserved for authorized persons.
  • the device according to the invention is fixed tangentially on the previously perforated wall of the enclosure.
  • the enclosure is a kneader
  • the devices at about 45 ° of the kneading arms in a sector between an angle of 0 ° (that is to say vertical) to 50 ° with respect to an angle of 90 ° (that is to say horizontal to the kneading arms) so that the cryogenic fluid is injected into the core of the material to be cooled.
  • part of the cryogenic fluid is already converted into a solid before coming into contact with the mass to be cooled.
  • the cryogenic solid is formed as soon as the fluid hits the seat of the valve in the space between the seat and the support.
  • the product can of course be in motion in the enclosure, which promotes heat exchange and thus the cooling of the contents.
  • the device according to the invention is fixed on the lower part of the mixing tank.
  • FIG. 1 is a sectional view of an installation comprising an enclosure and devices according to one invention
  • Figure 2 is an elevational view of a device according to the invention
  • FIG. 3 is a view, in section, along the plane III-III of FIG. 2, and
  • FIG. 4 is a view, in section, along the plane IV-IV of FIG. 2.
  • FIG. 1 shows the lower part of an enclosure 1 on the wall of which are fixed, preferably by welding, two devices. 3 of cryogenic fluid injection according to the invention.
  • the devices 3 are connected by a flexible pipe 4 and a heat-insulating pipe 5 to a solenoid valve 6 allowing the opening and closing of the cryogenic fluid supply.
  • FIG. 2 shows in more detail an injection device 3, comprising an upper part 7 whose free end 8 is intended to be fixed on the outer wall of an enclosure, and a lower part 9, the two parts being connected together. by a quick connector 10.
  • a flexible hose 4 At the lower part 9 of said device 3 is connected a flexible hose 4.
  • a whiplash antibody cable 11 connecting the hose 4, the lower part 9 and the upper part 7. This cable is attached to the using safety hooks 12 so that only authorized persons can undo for example for disassembly.
  • the injection device 3 comprises a body composed of two parts made integral, the lower part 9 and the upper part 7.
  • the upper part itself consists of 3 elements, one substantially cylindrical outer wall 14 made of stainless steel, one end of which bears indirectly on the lower part 9 and the other end of which is intended to be fixed on the wall of the enclosure.
  • a complementary shaped piece, called thermal bridge, also hollow, insulating inside which is disposed a third element 16 made of stainless steel crossed at its center by the valve 17 and by two channels
  • the central through opening of the part 16 comprises three zones, a central zone 19a of diameter substantially equal to that of the valve so that the valve can be slidably placed in this zone and a lower zone 19b of greater diameter, of so that it can receive around the axis of the valve spring 19 forcing it.
  • This spring 19 being maintained by the shoulder 20 formed between the zones 19a and 19b.
  • the zone 19c is of beveled shape, of larger diameter at its free end, the shape of the bevel being adapted to sealingly receive the seat of the valve when the valve is forced by the spring.
  • the lower part 9 is in turn made of a single element made of stainless steel, generally cylindrical.
  • This part comprises a central blind recess 21 which when the device is mounted coincides with the opening 19b of the upper part.
  • This recess is intended to receive the end of the valve held by the spring 19 and the setting nut 22 of the spring. It also comprises on both sides of the blind recess two vertical channels 23, 24 which in the mounting position open at one end each on a through channel 18 and the other end in a channel perpendicular 25 which one of the ends opens on the channel 23 and the other is intended to be connected to the cryogenic fluid supply system through the connector 26.
  • the lower part 9 is fixed to the central piece 16 by screws 27 and 28.
  • the screw 28 is an anti-disassembly screw allowing compliance with the safety standards of the devices under pressure.
  • the parts 14 and 15 are secured to the part 9 by the connector 10 (shown in Figure 2).
  • the connector 10 is a quick disconnect fitting. It could also be screw-type or bayonet type or the like.
  • the valve 6 is open, and the cryogenic fluid is sent by the pipes 5 and the hose 4 into the interior of the device 3, through the channel 25 and each of the channels 18.
  • the pressurized fluid then exerts a pressure on the seat of the valve, a space is then formed between the portion 19c and the seat of the valve.
  • the cryogenic solid begins to form in this space by the shock between the fluid and the seat of the valve, and is forced inside the enclosure.
  • the valve 6 is closed.
  • the invention also relates to the use of an injection device as described above for the cooling of bulk product. It also relates to a method of cooling bulk material contained in an enclosure, wherein a cryogenic fluid is injected into the core of the material to be cooled using at least one injection device, preferably m devices. injection symmetrically distributed in the lower part of the enclosure, m being an integer between 2 and 20, preferably an even number.
  • the enclosure is a mixer.
  • the method is particularly well suited for cooling any type of material regardless of its physical state, especially for products, liquid, pasty, solid or powdery.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
EP07803959.1A 2006-07-10 2007-06-28 Kryogenes flüssigkeitsinjektionssystem zur massenverarbeitung von produkten sowie kühlverfahren mit diesem system Active EP2041026B2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07803959.1T PL2041026T5 (pl) 2006-07-10 2007-06-28 Układ wtryskiwania płynu kriogenicznego umożliwiający przetwarzanie produktów sypkich i sposób chłodzenia z jego wykorzystaniem

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0652885A FR2903482B1 (fr) 2006-07-10 2006-07-10 Systeme d'injection de fluide cryogenique permettant le traitement de produits en vrac
PCT/FR2007/051549 WO2008007000A2 (fr) 2006-07-10 2007-06-28 Systeme d'injection de fluide cryogenique permettant le traitement de produits en vrac et procede de refroidissement le mettant en oeuvre

Publications (3)

Publication Number Publication Date
EP2041026A2 true EP2041026A2 (de) 2009-04-01
EP2041026B1 EP2041026B1 (de) 2018-03-14
EP2041026B2 EP2041026B2 (de) 2024-04-24

Family

ID=37928620

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07803959.1A Active EP2041026B2 (de) 2006-07-10 2007-06-28 Kryogenes flüssigkeitsinjektionssystem zur massenverarbeitung von produkten sowie kühlverfahren mit diesem system

Country Status (12)

Country Link
US (1) US8621878B2 (de)
EP (1) EP2041026B2 (de)
CN (1) CN101489929B (de)
AU (1) AU2007274158B2 (de)
BR (1) BRPI0714376B1 (de)
DK (1) DK2041026T3 (de)
ES (1) ES2665876T5 (de)
FR (1) FR2903482B1 (de)
PL (1) PL2041026T5 (de)
PT (1) PT2041026T (de)
WO (1) WO2008007000A2 (de)
ZA (1) ZA200900079B (de)

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WO2011070283A1 (fr) 2009-12-08 2011-06-16 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procede et installation de refroidissement et/ou surgelation de produits, mettant en oeuvre l'injection de deux liquides cryogeniques

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FR2949647B1 (fr) * 2009-09-10 2011-10-21 Air Liquide Procede et installation de refroidissement du contenu d'une enceinte mettant en oeuvre un systeme de convection forcee dans la partie haute de l'enceinte
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FR3064198B1 (fr) 2017-03-23 2021-10-01 Air Liquide France Ind Dispositif d'injection d'un fluide cryogenique par le bas d'un melangeur
CN109114336B (zh) * 2017-06-26 2020-10-30 中航光电科技股份有限公司 一种流体连接器、连接器组件及液冷系统
DE102018006575A1 (de) * 2018-08-21 2020-02-27 Willmes GmbH Vorrichtung und Verfahren zur Reinigung des Innenraums einer Presse zum Auspressen von flüssigkeitshaltigen Stoffen
CN109279604B (zh) * 2018-11-30 2020-04-10 厦门理工学院 一种高密度二氧化碳成型设备
JP7276958B2 (ja) * 2019-07-05 2023-05-18 日本エア・リキード合同会社 冷凍撹拌装置
CN110959745A (zh) * 2019-12-17 2020-04-07 内蒙古蒙牛乳业(集团)股份有限公司 脆筒类冷饮巧克力凝冻装置及保持巧克力脆筒脆性的方法
FR3106036B1 (fr) 2020-01-10 2024-06-14 Air Liquide France Ind Procédé et Installation de transformation d’un produit liquide ou pâteux en particules surgelées dans un appareil de hachage rotatif (« cutter »)
DE102023109505A1 (de) 2023-04-14 2024-10-17 Messer France S.A.S Vorrichtung zum Eindosieren eines kryogenen Mediums
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FR3162644A1 (fr) 2024-05-31 2025-12-05 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Dispositif d’injection d’un fluide cryogénique par le bas d’un mélangeur

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011070283A1 (fr) 2009-12-08 2011-06-16 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procede et installation de refroidissement et/ou surgelation de produits, mettant en oeuvre l'injection de deux liquides cryogeniques

Also Published As

Publication number Publication date
BRPI0714376A2 (pt) 2013-04-02
US8621878B2 (en) 2014-01-07
ES2665876T3 (es) 2018-04-30
FR2903482A1 (fr) 2008-01-11
BRPI0714376B1 (pt) 2018-06-19
WO2008007000A3 (fr) 2008-03-13
ES2665876T5 (es) 2024-11-15
CN101489929B (zh) 2012-01-18
CN101489929A (zh) 2009-07-22
FR2903482B1 (fr) 2008-08-22
EP2041026B1 (de) 2018-03-14
WO2008007000A2 (fr) 2008-01-17
ZA200900079B (en) 2009-12-30
PL2041026T5 (pl) 2024-09-09
AU2007274158B2 (en) 2012-07-26
DK2041026T3 (en) 2018-05-22
AU2007274158A1 (en) 2008-01-17
EP2041026B2 (de) 2024-04-24
PT2041026T (pt) 2018-05-14
PL2041026T3 (pl) 2018-08-31
US20090314010A1 (en) 2009-12-24

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