EP2093276A1 - Billes parfumées et filtre à cigarette - Google Patents

Billes parfumées et filtre à cigarette Download PDF

Info

Publication number
EP2093276A1
EP2093276A1 EP07850428A EP07850428A EP2093276A1 EP 2093276 A1 EP2093276 A1 EP 2093276A1 EP 07850428 A EP07850428 A EP 07850428A EP 07850428 A EP07850428 A EP 07850428A EP 2093276 A1 EP2093276 A1 EP 2093276A1
Authority
EP
European Patent Office
Prior art keywords
flavorant
flavor
film
glucan
flavor bead
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07850428A
Other languages
German (de)
English (en)
Other versions
EP2093276A4 (fr
EP2093276B1 (fr
Inventor
Masahiro Chida
Yasuhiro Nakagawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Tobacco Inc
Original Assignee
Japan Tobacco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Tobacco Inc filed Critical Japan Tobacco Inc
Publication of EP2093276A1 publication Critical patent/EP2093276A1/fr
Publication of EP2093276A4 publication Critical patent/EP2093276A4/fr
Application granted granted Critical
Publication of EP2093276B1 publication Critical patent/EP2093276B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes

Definitions

  • the present invention relates to a flavor bead and a cigarette filter containing the same.
  • Flavorants added to cut tobacco include a primary flavorant as a casing sauce, and a secondary flavorant as a top flavor.
  • the components of the secondary flavorant are relatively highly volatile, and are susceptible to pyrolysis. Therefore, the secondary flavorant contained in a cigarette evaporates during storage, which results in a decrease of the flavor during smoking.
  • the secondary flavorant migrates to and is adsorbed on the charcoal filter, which results in a further decrease of the flavor.
  • the charcoal filter having the second flavorant adsorbed has decreased capability to remove the components of tobacco mainstream smoke.
  • Japanese Patent No. 2709077 discloses microcapsulating a secondary flavorant with a natural polysaccharide, and adding the microcapsules to a tobacco filter by a so-called cavity filling process. Since the flavorant is encapsulated in the microcapsules composed of the natural polysaccharide, it will not cause the migration or evaporation of the flavorant during storage, and thus will not deteriorate the capability of the charcoal filter to remove the components of tobacco mainstream smoke.
  • the flavor can be tasted only by crushing or grating them by fingers (application of external force) when smoking.
  • the application of external force is bothersome.
  • the flavor released by the application of external force will not uniformly spread over the filter, which results in erratic taste during smoking.
  • the present invention is intended to provide a flavor bead and a cigarette filter which can suppress the evaporation and migration of a flavorant during non-smoking stages, and allow for stable tasting of the flavor during smoking stages without requiring the application of external force.
  • a flavor bead comprising a particulate carrier, a glucan film supported by the particulate carrier, and a flavorant, wherein the flavorant is supported by the flavor bead such that release of flavor from the flavorant is suppressed by the glucan film, but the flavor is released by the glucan film being at least partially dissolved when the glucan film contacts with tobacco mainstream smoke.
  • a cigarette filter including the flavor beads of the present invention.
  • a flavor bead according to the present invention includes a particulate carrier, a glucan film supported by the particulate carrier, and a flavorant.
  • the flavorant is supported by the flavor bead such that release of flavor from the flavorant is suppressed by the glucan film, but the flavor is released by the glucan film being at least partially dissolved when the glucan film contacts with tobacco mainstream smoke.
  • the glucan film contains the flavorant, and directly covers the surface of the particulate carrier.
  • the flavor bead according to the first embodiment includes the particulate carrier, and the glucan film covering the surface of the particulate carrier and holding the flavorant.
  • the flavorant is a solid flavorant which directly covers the surface of the particulate carrier, and the glucan film covers the solid flavorant film.
  • the flavor beads according to the second embodiment each include the particulate carrier, the menthol film covering the surface of the carrier, and the glucan film covering the surface of the menthol film.
  • the particulate carrier used in the present invention may be composed of particles of calcium carbonate, activated carbon, sugar crystals (for example, granulated sugar), or coffee beans.
  • particles having an average particle size of 75 ⁇ m to 2000 ⁇ m, e.g., 75 ⁇ m to 350 ⁇ m may be suitably used.
  • the glucan film is composed of, for example, pullulan, maltodextrin or hydroxypropyl cellulose, and is water-soluble.
  • the flavorant may be one for food or tobacco use.
  • examples of such flavorant include lavender, cinnamon, cardamom, celery, clove, cascarilla, nutmeg, sandalwood, bergamot, geranium, honey essence, rose oil, vanilla, lemon, orange, mint, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cassia, ylang ylang, sage, spearmint, fennel, pimento, ginger, anise, coriander, and coffee essential oils.
  • FIG. 1 is an enlarged schematic cross sectional view of a flavor bead 10 according to the first embodiment of the present invention.
  • the flavor bead 10 includes a particulate carrier (core) 12, whose surface is covered by a glucan film 14.
  • the glucan film 14 contains the flavorant.
  • the glucan film 14 containing the flavorant may be formed from an aqueous solution or dispersion of the flavorant and glucan.
  • the flavorant is preferably used in an amount corresponding to 20% or less (but more than 0%) of the weight of the glucan.
  • the glucan film 14 is not particularly limited in its thickness. However, in view of releaseability of the flavor during smoking, the glucan film is preferably formed with glucan in an amount corresponding to 0.25% to 5% of the weight of the finished flavor bead.
  • the flavor bead according to the first embodiment may be produced, for example, by the following method. Namely, the particulate carriers composed of calcium carbonate or the like are charged into a fluidized-bed granulation drier, and an aqueous glucan solution or dispersion containing the flavorant is continuously or intermittently sprayed onto the surface of the particulate carriers while blowing, e.g., warm air at 80°C or lower into the granulation drier, followed by drying. In this case, the carriers are immediately cooled depending on the type of the flavorant or the composition of the glucan solution. In this manner, a glucan film holding the flavorant is formed on the surface of the particulate carrier.
  • the flavorant is contained within the glucan film, which has a low gas permeability, the evaporation and degradation of the flavorant during storage can be suppressed. Only after contact with tobacco mainstream smoke during smoking, the glucan film is partially dissolved mainly by highly polar components (for example, water) in the tobacco mainstream smoke, and releases the flavorant component which disperses into the mainstream smoke, thus allowing stable tasting of the flavor of the flavorant.
  • the flavor bead of the present invention does not require the application of external force to taste the flavor as done in the case of microcapsules.
  • FIG. 2 is an enlarged schematic cross sectional view of a flavor bead 20 according to the second embodiment of the present invention.
  • the entire surface of a particulate carrier (core) 22 is covered by a film 24 of a solid flavorant such as menthol, and the entire surface of the solid flavorant film 24 is covered by a glucan film 26.
  • the solid flavorant film 24 may be formed by finely pulverizing crystals of the solid flavorant such as menthol, mixing the resultant solid flavorant fine particles with the particulate carrier 12, thereby adhering the solid flavorant fine particles to the particulate carrier 22, melting the solid flavorant fine particles on the particulate carrier 22 by heating, and then recrystallizing the solid flavorant by cooling.
  • a crystal growth inhibitor such as a fatty acid, glycerol or propylene glycol be added to the solid flavorant.
  • the crystal growth inhibitor may be used in an amount corresponding to 0.1 to 1.0% of the weight of the solid flavorant such as menthol.
  • the solid flavorant film 14 may contain a flavorant other than the solid flavorant.
  • the solid flavorant film 24 is not particularly limited in its thickness. However, the solid flavorant film 24 is preferably formed with the solid flavorant in an amount corresponding to 1 to 20% of the weight of the finished flavor bead.
  • the glucan film 26 may be formed from an aqueous solution or dispersion of glucan.
  • the glucan film 26 is not particularly limited in its thickness. However, in view of holdability of the flavor of the solid flavorant at non-smoking stages and of releaseability of menthol during smoking, the glucan film 26 is preferably formed with glucan in an amount corresponding to 0.25% to 5% of the weight of the finished flavor bead.
  • the flavor bead according to the second embodiment may be produced by, for example, the following method. Namely, the particulate carriers and fine particles of the solid flavorant crystals, and as necessary, the crystal growth inhibitor and other flavorant are mixed and heated in a ribbon mixer. During the early stages of the mixing, the fine particles of the solid flavorant crystals adhere to the surfaces of the particulate carriers, and the fine particles of the solid flavorant crystals begin melting when the heating temperature reaches the melting point of the solid flavorant (for example, about 42°C for menthol). Stirring and mixing are further continued thereby uniformly applying the molten solid flavorant to the surfaces of the particulate carriers.
  • the melting point of the solid flavorant for example, about 42°C for menthol
  • the particulate carriers are immediately cooled by, for example, cooling the can body of the ribbon mixer, or blowing cold air into the ribbon mixer.
  • the molten solid flavorant is recrystallized by the cooling treatment to cover the surfaces of the particulate carriers as a film.
  • the particulate carriers covered with the solid flavorant films are charged into a fluidized-bed granulation drier, and an aqueous solution or dispersion of glucan is intermittently sprayed onto the particulate carriers while blowing, for example, warm air at 40°C or lower into the granulation drier, followed by cooling. In this manner, a glucan film is formed on the surface of the solid flavorant film formed on the surface of the particulate carrier.
  • the flavor bead according to the second embodiment may also be produced by forming a solid flavorant film on the surfaces of the particulate carriers as described above, and spraying an aqueous solution or dispersion of glucan onto the particulate carriers having the solid flavorant films in a ribbon mixer or a rolling granulator, thereby covering the solid flavorant film with the glucan film, followed by cooling.
  • the solid flavorant film formed on the surface of the particulate carrier is covered by the glucan film, which has a low gas permeability, menthol is prevented from evaporating or adhering to charcoal during storage under ordinary conditions.
  • the glucan film contacts with the hydrophilic components such as water contained in mainstream smoke emitted during smoking of the cigarette, the glucan film is partially deformed and dissolved, whereby the flavor is released from the underlying solid flavorant film and can be tasted.
  • the flavor bead of the present invention does not require the application of external force to taste the flavor as done in the case of microcapsules.
  • a cigarette filter according to the present invention contains the flavor beads of the present invention.
  • FIGS. 3 and 4 A cigarette provided the filter of the present invention will be described below with reference to FIGS. 3 and 4 .
  • similar elements are designated by the same reference numerals.
  • FIG. 3 is a schematic cross sectional view of a cigarette (filter-tipped cigarette) 30 provided with a cigarette filter according to one embodiment of the present invention.
  • the filter-tipped cigarette 30 includes a cigarette portion 32 composed of a tobacco filler 321 such as cut tobacco wrapped with a cigarette paper 322.
  • the cigarette portion 32 is similar to that included in an ordinary cigarette.
  • a filter portion 34 is attached to one end of the cigarette portion 32.
  • the filter portion 34 is composed of a charcoal filter section 341 provided directly adjacent to one end of the cigarette portion 32, and another filter section 342 containing the flavor beads provided at the downstream end of the charcoal filter section, viewed in the flow direction of mainstream smoke.
  • the charcoal filter section 341 is formed by wrapping, e.g., cellulose acetate fibers 341a, in which charcoal particles 341b are dispersed, with a filter wrapping paper 341c.
  • the charcoal filter section 341 is similar to that included in an ordinary charcoal filter.
  • the filter section 342 containing the flavor beads is formed by wrapping, e.g., cellulose acetate fibers 342a, in which flavor beads FB of the present invention are dispersed, with a filter wrapping paper 342b.
  • the filter portion 34 composed of the filter sections 321 and 322 is attached to the cigarette portion 32 with a tipping paper 36.
  • FIG. 4 is a schematic cross sectional view of a cigarette (filter-tipped cigarette) 40 provided with a cigarette filter according to another embodiment of the present invention.
  • a filter portion 42 attached to the cigarette portion 32 with the tipping paper 36 is composed of a charcoal filter section 341 which is directly attached to one end of the cigarette portion 32, and a plain filter section 422 which is provided spaced apart from the charcoal filter section 341.
  • the filter portion 42 is entirely wrapped with a filter wrapping paper 46.
  • the plain filter section 422 is composed of, for example, tow of cellulose acetate fibers 422a.
  • the flavor beads (FB) of the present invention are filled in a cavity 44 between the charcoal filter section 341 and the plain filter section 422.
  • Filter-tipped cigarettes as shown in FIG. 3 were made using the flavor beads obtained in Examples 1 to 3, respectively.
  • the amount of the flavor beads added to the filter section 342 was 100 mg at maximum for 10 mm of the filter length. These cigarettes did not emit the flavor of the flavorant during storage. However, the flavor could be stably tasted when these cigarettes were smoked.
  • the calcium carbonate particles having the menthol films were charged into a fluidized-bed granulator, and immediately a 5% by weight aqueous solution of pullulan was intermittently sprayed on the particles while blowing warm air at 40°C into the granulator at a flow rate of 1.0 m/second, thereby spraying 15 g in total of the pullulan aqueous solution onto the calcium carbonate particles. Thereafter, the particles were cooled to 25°C, thus obtaining desired menthol-flavor beads.
  • the filter-tipped cigarettes as shown in FIG. 3 were made using the menthol-flavor beads obtained in Example 5.
  • the amount of the menthol-flavor beads added to the filter section 342 was 3 mg in terms of menthol per cigarette.
  • the cigarettes did not emit the flavor of menthol under ordinary storage conditions. However, the menthol flavor could be stably tasted when these cigarettes were smoked.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Fats And Perfumes (AREA)
  • Manufacture Of Tobacco Products (AREA)
EP07850428A 2006-12-13 2007-12-11 Billes parfumées et filtre à cigarette Active EP2093276B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2006336180 2006-12-13
JP2007075371 2007-03-22
PCT/JP2007/073866 WO2008072627A1 (fr) 2006-12-13 2007-12-11 Billes parfumées et filtre à cigarette

Publications (3)

Publication Number Publication Date
EP2093276A1 true EP2093276A1 (fr) 2009-08-26
EP2093276A4 EP2093276A4 (fr) 2010-02-17
EP2093276B1 EP2093276B1 (fr) 2012-11-21

Family

ID=39511648

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07850428A Active EP2093276B1 (fr) 2006-12-13 2007-12-11 Billes parfumées et filtre à cigarette

Country Status (11)

Country Link
US (1) US20090235941A1 (fr)
EP (1) EP2093276B1 (fr)
JP (1) JP4876296B2 (fr)
KR (1) KR101148254B1 (fr)
CN (1) CN101558143B (fr)
CA (1) CA2671004C (fr)
ES (1) ES2396593T3 (fr)
MY (1) MY157908A (fr)
RU (1) RU2405810C1 (fr)
TW (1) TWI384063B (fr)
WO (1) WO2008072627A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2253232A4 (fr) * 2008-03-18 2012-07-25 Japan Tobacco Inc Adsorbant pour composants principaux de fumée de cigarette et filtre de cigarette
GB2516104A (en) * 2013-07-12 2015-01-14 British American Tobacco Co Material for inclusion in a smoking article

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009157240A1 (fr) * 2008-06-25 2009-12-30 日本たばこ産業株式会社 Article à fumer
TW201032739A (en) * 2009-01-08 2010-09-16 Japan Tobacco Inc Filter for cigarette
GB2469842A (en) * 2009-04-29 2010-11-03 British American Tobacco Co Aerosol generating material for a smoking article
GB0910373D0 (en) * 2009-06-16 2009-07-29 Filtrona Int Ltd Tabacco smoke filter
KR101720739B1 (ko) * 2009-11-30 2017-04-11 (주)아모레퍼시픽 항산화 효과를 갖는 천연 향료 조성물
AR081808A1 (es) * 2010-03-26 2012-10-24 Philip Morris Prod Procedimiento para producir una estructura continua de un material encapsulado
JP2011205914A (ja) * 2010-03-29 2011-10-20 British American Tobacco (Investments) Ltd 喫煙品
US20110271968A1 (en) * 2010-05-07 2011-11-10 Carolyn Rierson Carpenter Filtered Cigarette With Modifiable Sensory Characteristics
EP2401929A1 (fr) * 2010-06-30 2012-01-04 Philip Morris Products S.A. Filtre pour article à fumer
JP5422748B2 (ja) * 2010-10-18 2014-02-19 日本たばこ産業株式会社 フレーバー放出性顆粒の製造方法、フレーバー放出性顆粒およびフレーバー放出性顆粒を含むシガレット用フィルタ
EP2462822A1 (fr) * 2010-12-13 2012-06-13 Philip Morris Products S.A. Article à fumer incluant des granules aromatiques
CN102068038A (zh) * 2010-12-31 2011-05-25 贵州中烟工业有限责任公司 一种卷烟热敏性保润中线滤棒的制备方法
RU2435500C1 (ru) * 2011-01-11 2011-12-10 Олег Иванович Квасенков Способ производства некурительного изделия из махорки
RU2441431C1 (ru) * 2011-01-20 2012-02-10 Олег Иванович Квасенков Способ получения некурительного изделия из махорки
RU2448589C1 (ru) * 2011-01-21 2012-04-27 Олег Иванович Квасенков Способ получения некурительного изделия из махорки
IT1404015B1 (it) * 2011-02-04 2013-11-08 Hsd Holding Smart Device S R L Uso di un polimero di destrano reticolato come filtro contro l'inalazione di sostanze nocive per la salute
GB201110369D0 (en) 2011-06-17 2011-08-03 Filtrona Filter Prod Dev Co Tobacco smoke filter with activated carbon
GB201110863D0 (en) 2011-06-27 2011-08-10 British American Tobacco Co Smoking article filter and insertable filter unit thereof
JP5719931B2 (ja) * 2011-07-15 2015-05-20 日本たばこ産業株式会社 香料担持吸着剤粒子、シガレット用フィルタ、フィルタ付きシガレットおよび香料担持吸着剤粒子の製造方法
CN107034015B (zh) * 2011-07-15 2021-04-06 日本烟草产业株式会社 香料担载低吸附性粒子的制造方法
EP2554060A1 (fr) * 2011-08-01 2013-02-06 JT International S.A. Élément filtrant intégrant une capsule cassable, procédé de fabrication d'une cigarette dotée d'un élément filtrant intégrant une capsule cassable et appareil pour fabriquer une cigarette dotée d'un élément filtrant intégrant une capsule cassable
CN102432921B (zh) * 2011-09-16 2013-04-17 中国烟草总公司郑州烟草研究院 普鲁兰多糖添加剂及其在卷烟中的应用
UA112328C2 (uk) * 2011-11-07 2016-08-25 Філіп Морріс Продактс С.А. Ментолвмісний курильний виріб
CN102533445B (zh) * 2012-02-05 2013-09-18 云南正邦生物技术有限公司 一种卷烟主动释放型补香颗粒的制备方法
CN104540403B (zh) * 2012-08-02 2019-06-25 菲利普·莫里斯产品股份有限公司 带有薄荷滤嘴的吸烟制品
CN102823945A (zh) * 2012-09-17 2012-12-19 川渝中烟工业有限责任公司 一种香精粒子添加剂及其制备方法和应用
CN103054184A (zh) * 2012-11-28 2013-04-24 红塔烟草(集团)有限责任公司 一种含薰衣草香味的卷烟纸质滤材
CN102987563A (zh) * 2012-11-28 2013-03-27 红塔烟草(集团)有限责任公司 一种含兰花香味的卷烟纸质滤材
US10849358B2 (en) * 2014-10-29 2020-12-01 Altria Client Services Llc E-vaping cartridge
EP3212017B1 (fr) 2014-10-29 2021-06-16 Altria Client Services LLC Cartouche de formulation de gel sans éthanol pour dispositif de vapotage
CN104856223B (zh) * 2015-04-29 2019-05-10 湖北中烟工业有限责任公司 一种烟用固体加香珠及其制备方法
CN104997158B (zh) * 2015-05-29 2017-01-18 湖北中烟工业有限责任公司 辛香型烟用香料提取物的制备方法及其应用
CN105029700A (zh) * 2015-06-17 2015-11-11 云南中烟工业有限责任公司 一种植物组合三醋酸甘油酯提取物及其在卷烟中的应用
CN104939307B (zh) * 2015-07-17 2019-08-09 云南中烟工业有限责任公司 一种烟用极性香料载核及应用
CN105001988B (zh) * 2015-07-17 2018-07-24 云南中烟工业有限责任公司 一种三层夹心结构香料缓释滤嘴添加剂的制备装置及其应用方法
CN105105327B (zh) * 2015-07-21 2019-07-23 中国烟草总公司广东省公司 一种含有全组分烟草提取物的香薰烟及其制备方法
CN105231480B (zh) * 2015-11-10 2017-07-04 江苏中烟工业有限责任公司 一种碳酸钙作为加香载体在再造烟叶涂布液中应用的方法
US20170265517A1 (en) * 2016-03-15 2017-09-21 Rai Strategic Holdings, Inc. Multi-Layered Micro-Beads for Electronic Cigarettes
ITUA20162010A1 (it) * 2016-03-24 2017-09-24 Gd Spa Articolo da fumo e metodo per la sua realizzazione.
GB201608943D0 (en) * 2016-05-20 2016-07-06 British American Tobacco Co Capsule for tobacco industry product
JP6831384B2 (ja) * 2016-08-17 2021-02-17 日本たばこ産業株式会社 フィルタ及びたばこ製品
CN106590931A (zh) * 2016-12-14 2017-04-26 江西中烟工业有限责任公司 一种烟用蛋白质‑多糖复合乳液载体体系的制备方法及在卷烟中的应用
CN107022414A (zh) * 2017-04-27 2017-08-08 河南中烟工业有限责任公司 一种卷烟爆珠用香草味香精及其在卷烟中的应用
US10492522B2 (en) 2017-05-03 2019-12-03 R.J. Reynolds Tobacco Company Flavored menthol-containing objects for application to smoking article components
CN107419593A (zh) * 2017-10-11 2017-12-01 云南中烟工业有限责任公司 一种蜜甜香型卷烟纸及其制备方法
CN107629876A (zh) * 2017-10-31 2018-01-26 鹰潭中投科技有限公司 提高再造烟叶卷烟品质的烟用香精及其制备和应用
CN110574961A (zh) * 2018-06-08 2019-12-17 湖南中烟工业有限责任公司 一种烟用柠檬香精的制备方法及烟用爆珠和爆珠烟
CN108523217A (zh) * 2018-06-08 2018-09-14 滁州卷烟材料厂 一种具有降焦增香性能的卷烟滤棒
CN108851214B (zh) * 2018-08-06 2020-06-30 江西中烟工业有限责任公司 一种含有单固态香珠颗粒的细支烟嘴棒及其制备方法
JP7295225B2 (ja) * 2019-05-13 2023-06-20 日本たばこ産業株式会社 非燃焼加熱型香味吸引物品、及び、電気加熱型香味吸引システム
CN110629590A (zh) * 2019-09-20 2019-12-31 河南中烟工业有限责任公司 一种雪茄风味香精、雪茄风味光油及卷烟用接装纸
CN110801049B (zh) * 2019-11-07 2022-02-01 云南中烟工业有限责任公司 一种烟用滤嘴香气缓释颗粒及其制备方法
CN110934333A (zh) * 2019-12-27 2020-03-31 山东中烟工业有限责任公司 一种基于纳米纤维结构的香烟滤嘴及香烟
JP7362891B2 (ja) * 2020-03-04 2023-10-17 日本たばこ産業株式会社 たばこ製品の香料担持構成部材、たばこ製品およびこれらの製造方法
RU2767511C2 (ru) * 2020-07-13 2022-03-17 Бритиш Америкэн Тобэкко (Инвестментс) Лимитед Вставной фильтрующий элемент для нагреваемого без горения продукта
KR102571393B1 (ko) * 2020-08-28 2023-08-25 주식회사 케이티앤지 향 지속성이 개선된 필터 및 이를 포함하는 흡연 물품
CN112914144B (zh) * 2020-12-31 2022-10-21 中国农业科学院烟草研究所 一种加热卷烟烟草基段及其制作方法
JP2023008482A (ja) * 2021-07-06 2023-01-19 日本たばこ産業株式会社 たばこ製品の香味料担持構成部材及びこの製造方法
CN114775333B (zh) * 2022-04-13 2023-09-19 江苏卫星新材料股份有限公司 一种甜味剂接装纸及其制备方法
WO2025257950A1 (fr) * 2024-06-11 2025-12-18 日本たばこ産業株式会社 Composant vecteur d'arôme pour article générateur d'arôme, article générateur d'arôme et liquide pour enrobage

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3297041A (en) * 1965-03-15 1967-01-10 American Filtrona Corp Tobacco smoke filter or the like
JPS5932108B2 (ja) * 1977-04-20 1984-08-06 日本たばこ産業株式会社 香料を芯物質としたマイクロカプセルおよびこれを含有するたばこ製品
JPS55102385A (en) * 1979-01-30 1980-08-05 Japan Tobacco & Salt Public Tobacco product with filter impregnated by solid flavor
US5060676A (en) * 1982-12-16 1991-10-29 Philip Morris Incorporated Process for making a carbon heat source and smoking article including the heat source and a flavor generator
JP2709077B2 (ja) 1987-05-29 1998-02-04 日本たばこ産業株式会社 煙草用フィルター
US5070891A (en) * 1989-07-12 1991-12-10 International Flavors & Fragrances, Inc. Method for imparting flavors and aromas, flavor-imparting articles, and methods for preparation and use thereof
US5258185A (en) * 1989-08-23 1993-11-02 Bauer Kurt H Highly active, rapidly absorbable formulations of glibenclamide, processes for the production thereof and their use
US5144964A (en) * 1991-03-14 1992-09-08 Philip Morris Incorporated Smoking compositions containing a flavorant-release additive
TR28670A (tr) * 1993-06-02 1996-12-17 Procter & Gamble Zeolitleri iceren parfüm birakma sistemi.
US5396909A (en) * 1993-12-16 1995-03-14 R. J. Reynolds Tobacco Company Smoking article filter
US5845649A (en) * 1994-01-26 1998-12-08 Japan Tobacco Inc. Flavor-tasting article
ATE174478T1 (de) * 1994-01-26 1999-01-15 Japan Tobacco Inc Aromaerzeugende artikel
JPH0928366A (ja) * 1995-07-24 1997-02-04 Japan Tobacco Inc シガレット
MY135471A (en) * 2002-01-09 2008-04-30 Philip Morris Prod Cigarette filter with beaded carbon
US20050100640A1 (en) * 2002-02-11 2005-05-12 Pearce Tony M. Microcapsule edibles
CA2489139C (fr) * 2002-06-12 2012-01-10 Traptek, Llc Particules actives encapsulees et procedes de fabrication et d'utilisation desdites particules
US20050172976A1 (en) * 2002-10-31 2005-08-11 Newman Deborah J. Electrically heated cigarette including controlled-release flavoring
US7381277B2 (en) * 2004-07-29 2008-06-03 R.U. Reynolds Tobacco Company Flavoring a cigarette by using a flavored filter plug wrap
US20060144410A1 (en) * 2004-12-30 2006-07-06 Philip Morris Usa Inc. Surface-modified activated carbon in smoking articles
UA87192C2 (en) * 2005-02-04 2009-06-25 Филип Моррис Продактс С.А. Cigarette
CN101258140A (zh) * 2005-04-19 2008-09-03 佛莱克特瑞尔公司 苯并(b)环丙(d)吡喃-2-(1h)-酮衍生物
AU2006271321B2 (en) * 2005-06-21 2012-04-26 V. Mane Fils Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule
US20070231387A1 (en) * 2006-04-04 2007-10-04 Luigi Levi Film-coated solid dosage forms
US8356606B2 (en) * 2007-06-01 2013-01-22 Philip Morris Usa Inc. Production of micronized encapsulated tobacco particles for tobacco flavor delivery from an oral pouch
RU2447819C1 (ru) * 2008-03-18 2012-04-20 Джапан Тобакко Инк. Адсорбент компонентов основного потока сигаретного дыма и сигаретный фильтр

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2253232A4 (fr) * 2008-03-18 2012-07-25 Japan Tobacco Inc Adsorbant pour composants principaux de fumée de cigarette et filtre de cigarette
US9486011B2 (en) 2008-03-18 2016-11-08 Japan Tobacco Inc. Cigarette mainstream smoke component adsorbent and cigarette filter
GB2516104A (en) * 2013-07-12 2015-01-14 British American Tobacco Co Material for inclusion in a smoking article

Also Published As

Publication number Publication date
WO2008072627A1 (fr) 2008-06-19
TWI384063B (zh) 2013-02-01
TW200848505A (en) 2008-12-16
KR20090089357A (ko) 2009-08-21
CA2671004C (fr) 2013-03-12
RU2405810C1 (ru) 2010-12-10
EP2093276A4 (fr) 2010-02-17
US20090235941A1 (en) 2009-09-24
ES2396593T3 (es) 2013-02-22
KR101148254B1 (ko) 2012-05-25
HK1133034A1 (en) 2010-03-12
CN101558143A (zh) 2009-10-14
JP4876296B2 (ja) 2012-02-15
JPWO2008072627A1 (ja) 2010-04-02
CN101558143B (zh) 2012-09-26
EP2093276B1 (fr) 2012-11-21
MY157908A (en) 2016-08-15
CA2671004A1 (fr) 2008-06-19

Similar Documents

Publication Publication Date Title
EP2093276B1 (fr) Billes parfumées et filtre à cigarette
US12349726B2 (en) Application of a flavorant particle in a filter of a smoking article for delivering flavor
US4889144A (en) Filter for tobacco smoking
EP3299084B1 (fr) Procédé de fabrication de capsules utilisées dans des produits de tabac
RU2587073C2 (ru) Регулирование профиля затяжек
US20200268036A1 (en) Smokeless tobacco product
KR20180078232A (ko) 용융 가능한 지질이 있는 균질화 담배 물질
EP3082480A1 (fr) Système de distribution d'arôme encapsulé dans de la cire pour du tabac
EP4051021B1 (fr) Composition génératrice d'aérosol contenant du tabac comprenant des triglycérides à chaîne moyenne
US4715388A (en) Cigarettes having minimized loose ends and a process for preparing same
HK1133034B (en) Perfumed beads and filter for cigarette
EA046136B1 (ru) Табакосодержащий состав, генерирующий аэрозоль, содержащий триглицерид средней цепи

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20090602

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

A4 Supplementary search report drawn up and despatched

Effective date: 20100114

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20100408

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: A24D 3/06 20060101ALI20120316BHEP

Ipc: C11B 9/00 20060101AFI20120316BHEP

Ipc: A24D 3/14 20060101ALI20120316BHEP

Ipc: A24D 3/16 20060101ALI20120316BHEP

Ipc: A24B 15/28 20060101ALI20120316BHEP

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIN1 Information on inventor provided before grant (corrected)

Inventor name: CHIDA, MASAHIRO

Inventor name: NAKAGAWA, YASUHIRO

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: CH

Ref legal event code: NV

Representative=s name: NOVAGRAAF INTERNATIONAL SA, CH

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 585096

Country of ref document: AT

Kind code of ref document: T

Effective date: 20121215

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602007026899

Country of ref document: DE

Effective date: 20130117

REG Reference to a national code

Ref country code: RO

Ref legal event code: EPE

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2396593

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20130222

REG Reference to a national code

Ref country code: GR

Ref legal event code: EP

Ref document number: 20120402707

Country of ref document: GR

Effective date: 20130122

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130321

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130221

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121231

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20130822

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602007026899

Country of ref document: DE

Effective date: 20130822

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121211

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071211

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121121

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20211221

Year of fee payment: 15

Ref country code: TR

Payment date: 20211209

Year of fee payment: 15

Ref country code: RO

Payment date: 20211202

Year of fee payment: 15

Ref country code: AT

Payment date: 20211222

Year of fee payment: 15

Ref country code: IE

Payment date: 20211222

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GR

Payment date: 20211223

Year of fee payment: 15

Ref country code: CH

Payment date: 20211221

Year of fee payment: 15

Ref country code: BE

Payment date: 20211221

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20211221

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20220218

Year of fee payment: 15

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230530

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221211

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20230101

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 585096

Country of ref document: AT

Kind code of ref document: T

Effective date: 20221211

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20221231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221212

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221231

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221211

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221231

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221211

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230705

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221231

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20240126

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221212

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221212

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221211

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20241210

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20241224

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20241223

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20241227

Year of fee payment: 18