EP2245201A1 - Acier haute résistance et faiblement allié pour tubes sans soudure particulièrement apte à la soudure et résistant à la corrosion - Google Patents

Acier haute résistance et faiblement allié pour tubes sans soudure particulièrement apte à la soudure et résistant à la corrosion

Info

Publication number
EP2245201A1
EP2245201A1 EP09716073A EP09716073A EP2245201A1 EP 2245201 A1 EP2245201 A1 EP 2245201A1 EP 09716073 A EP09716073 A EP 09716073A EP 09716073 A EP09716073 A EP 09716073A EP 2245201 A1 EP2245201 A1 EP 2245201A1
Authority
EP
European Patent Office
Prior art keywords
steel
max
strength
mpa
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09716073A
Other languages
German (de)
English (en)
Other versions
EP2245201B1 (fr
Inventor
André Schneider
Tanja Schmidt
Christina Wintermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vallourec Deutschland GmbH
Original Assignee
V&M Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by V&M Deutschland GmbH filed Critical V&M Deutschland GmbH
Publication of EP2245201A1 publication Critical patent/EP2245201A1/fr
Application granted granted Critical
Publication of EP2245201B1 publication Critical patent/EP2245201B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper

Definitions

  • the invention relates to a high-strength low-alloy steel for seamless steel pipes with excellent weldability and resistance to stress corrosion cracking according to claim 1.
  • Seamless tubes made of high-strength steels are z. B. used for pipes for the transport of oil or gas, which are laid both onshore and offshore.
  • Alloys commonly used for seamless conduits are defined for steels up to 80 ksi (X80) in standards such as API 5L, DNV-OS-F101 and EN 10208. For high strength grades above 80 ksi, these standards do not specify the limits for the alloying elements. When developing higher-strength grades, it must be borne in mind that the steel tubes produced from them are weldable and must possess good strength and toughness properties. While to date standard for steel pipes good to X80 (R min p02 551 MPa, R m min 620 MPa according to API 5L were used, there is now an increasing need for
  • the strength-increasing mechanism which at the same time leads to an increase in toughness, is known to be the reduction of the grain size. This can be achieved, inter alia, by alloying nickel and molybdenum and the associated reduction in the transformation temperature
  • molybdenum improves tempering resistance at higher tempering temperatures and throughput.
  • nickel significantly deteriorates the surface quality of the hot-rolled tubes above a certain alloy content
  • titanium, niobium and vanadium are used. Titanium precipitates as high-coarse titanium nitride at high temperatures. Niobium forms at lower temperatures Niobkarbonit ⁇ d precipitates With further decreasing temperature, vanadium additionally accumulates in carbonitrides , ie it is to be expected with the excretion of VC-Te ⁇ lchen
  • a high strength, low alloy steel for hot rolled seamless steel tubing that meets the requirements of an X100 API 5L for welded tubes is from WO 2007/017161 A1 known
  • This known steel alloy has an alloy concept with C 0 03 - 0.13%, Mn 0.90 - 1, 80%, Si ⁇ 0.40%, P ⁇ 0.020%, S ⁇ 0.005%, Ni 0 , 10 - 1, 00%, Cr 0,20 - 1, 20%, Mo 0,15 - 0,80%, Ca ⁇ 0,040%, V ⁇ 0,10%, Nb ⁇ 0,040%, Ti ⁇ 0,020%, N ⁇ 0.011% and a mixture consisting of bainite and martensite
  • the N ⁇ contents are up to 1% in the known steel very high, which can in the formation of adhesive scale on the surface during hot rolling of the tubes, eg hot pilots, Rohrkontivon, etc, impact, and the surface quality of the pipes strong and would require extensive surface finishing
  • the object of the invention is to provide a low-cost low-alloy steel for the production of high-strength weldable seamless steel tubes, which satisfies the stated requirements for yield strength, tensile strength and impact energy and also ensures good general weldability and sufficient corrosion resistance in sour gas use and after hot rolling has a perfect surface
  • This object is achieved with the features of claim 1.
  • Remaining iron with impurities caused by melting with optional addition of Ti and the proviso that the sum of the contents of Ti + Nb + V is ⁇ 0.04 to ⁇ 0.15% and the ratio Cu / Ni is a value of ⁇ 1 having.
  • the steel alloy according to the invention is based on the development of the pipe steels according to API 5L, ISO 3183, DNV-OS-F101 and EN 10208.
  • copper In addition to nickel, copper also has a positive effect on acid gas resistance. Copper alloyed alone adversely affects hot workability and damages the material Grain boundaries. By alloying Ni with an additionally adjusted with respect to sour gas resistance Cu / Ni ratio (Cu / Ni ⁇ 1), this is compensated.
  • the Ni content is max. 0.60% low enough to produce a sufficiently good surface quality for the tube manufacturing processes mainly used for this steel grade.
  • the seamless steel tubes produced from an operating melt with the steel alloy of the invention listed below have excellent strength and toughness properties.
  • the values are the mean values of three tensile specimens each, or three notched-bar impact specimens.
  • the samples were taken as longitudinal samples from heat-treated tubes made in-house.
  • OD outer diameter
  • WD wall thickness

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Articles (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

1. L’invention se rapporte à un acier haute résistance ainsi qu’à un tube en acier haute résistance et apte à la soudure. 2.1. L’invention se rapporte à un acier haute résistance ainsi qu’à un tube en acier haute résistance et apte à la soudure. 2.2. L’acier haute résistance et faiblement allié pour tubes sans soudure est particulièrement apte à la soudure et résistant à la corrosion fissurante sous contrainte et a une limite élastique d'au moins 620 MPa et une résistance à la rupture en traction d'au moins 690 MPa. Ledit acier est caractérisé par la composition donnée à la revendication 1.
EP09716073.3A 2008-02-28 2009-02-02 Acier haute résistance et faiblement allié pour tubes sans soudure particulièrement apte à la soudure et résistant à la corrosion Not-in-force EP2245201B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008011856A DE102008011856A1 (de) 2008-02-28 2008-02-28 Hochfester niedriglegierter Stahl für nahtlose Rohre mit hervorragender Schweißbarkeit und Korrosionsbeständigkeit
PCT/DE2009/000158 WO2009106033A1 (fr) 2008-02-28 2009-02-02 Acier haute résistance et faiblement allié pour tubes sans soudure particulièrement apte à la soudure et résistant à la corrosion

Publications (2)

Publication Number Publication Date
EP2245201A1 true EP2245201A1 (fr) 2010-11-03
EP2245201B1 EP2245201B1 (fr) 2017-09-13

Family

ID=40637863

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09716073.3A Not-in-force EP2245201B1 (fr) 2008-02-28 2009-02-02 Acier haute résistance et faiblement allié pour tubes sans soudure particulièrement apte à la soudure et résistant à la corrosion

Country Status (8)

Country Link
US (1) US20110259478A1 (fr)
EP (1) EP2245201B1 (fr)
JP (1) JP5715826B2 (fr)
AR (1) AR070624A1 (fr)
BR (1) BRPI0908484A8 (fr)
DE (1) DE102008011856A1 (fr)
MX (1) MX2010009446A (fr)
WO (1) WO2009106033A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9040865B2 (en) 2007-02-27 2015-05-26 Exxonmobil Upstream Research Company Corrosion resistant alloy weldments in carbon steel structures and pipelines to accommodate high axial plastic strains
CN102154593B (zh) * 2011-05-26 2013-01-16 天津钢管集团股份有限公司 X80钢级抗腐蚀低温无缝管线管
CN102900897A (zh) * 2011-07-28 2013-01-30 锐迈管业有限公司 一种混凝土泵车弯管及其加工工艺
CN104404368A (zh) * 2014-10-22 2015-03-11 苏州莱特复合材料有限公司 耐腐蚀性不锈钢合金及其制备方法
BR102016001063B1 (pt) 2016-01-18 2021-06-08 Amsted Maxion Fundição E Equipamentos Ferroviários S/A liga de aço para componentes ferroviários, e processo de obtenção de uma liga de aço para componentes ferroviários
CN105543705A (zh) * 2016-01-19 2016-05-04 天津钢管集团股份有限公司 海洋环境R-Lay铺设用抗大应变抗腐蚀无缝管线管的制造方法
CN105543690A (zh) * 2016-01-19 2016-05-04 天津钢管集团股份有限公司 具有抗大应变的415spdf以上钢级海底无缝管线管
EP3269837B1 (fr) * 2016-07-13 2020-11-04 Vallourec Deutschland GmbH Acier micro allié et procédé de production dudit acier

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56166324A (en) * 1980-05-23 1981-12-21 Kawasaki Steel Corp Production of high-strength seamless steel pipe of good weldability for middle temperature region
JPS5837120A (ja) * 1981-08-28 1983-03-04 Kawasaki Steel Corp 脆性破壊の伝播停止特性にすぐれたパイプライン用厚肉鋼管の製造方法
JPS62151545A (ja) * 1985-12-25 1987-07-06 Kawasaki Steel Corp 厚肉高強度低PcM曲管とその製造方法
JPH01139740A (ja) * 1987-11-27 1989-06-01 Kawasaki Steel Corp 耐食二重管
DE3832014C2 (de) * 1988-09-16 1994-11-24 Mannesmann Ag Verfahren zur Herstellung hochfester nahtloser Stahlrohre
JPH06172855A (ja) * 1992-12-10 1994-06-21 Nippon Steel Corp 低降伏比高靭性シームレス鋼管の製造法
JPH09287027A (ja) * 1996-04-19 1997-11-04 Sumitomo Metal Ind Ltd 高強度高靱性継目無鋼管の製造方法
JPH1017986A (ja) * 1996-06-28 1998-01-20 Nippon Steel Corp パイプラインの耐外面scc特性に優れた鋼
JP2004176172A (ja) * 2002-10-01 2004-06-24 Sumitomo Metal Ind Ltd 耐水素誘起割れ性に優れた高強度継目無鋼管およびその製造方法
CN100564567C (zh) * 2003-10-20 2009-12-02 杰富意钢铁株式会社 扩管用无缝油井钢管及其制造方法
JP4475023B2 (ja) * 2004-06-10 2010-06-09 住友金属工業株式会社 低温靱性に優れた超高強度ベンド管
MXPA05008339A (es) 2005-08-04 2007-02-05 Tenaris Connections Ag Acero de alta resistencia para tubos de acero soldables y sin costura.

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2009106033A1 *

Also Published As

Publication number Publication date
JP5715826B2 (ja) 2015-05-13
AR070624A1 (es) 2010-04-21
JP2011513584A (ja) 2011-04-28
BRPI0908484A8 (pt) 2017-05-16
WO2009106033A1 (fr) 2009-09-03
US20110259478A1 (en) 2011-10-27
MX2010009446A (es) 2010-09-30
EP2245201B1 (fr) 2017-09-13
BRPI0908484A2 (pt) 2015-08-18
DE102008011856A1 (de) 2009-09-10

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