EP2488691A2 - Revêtement en matière adhésive hydrosoluble pour des doublures hydrosolubles - Google Patents

Revêtement en matière adhésive hydrosoluble pour des doublures hydrosolubles

Info

Publication number
EP2488691A2
EP2488691A2 EP10771328A EP10771328A EP2488691A2 EP 2488691 A2 EP2488691 A2 EP 2488691A2 EP 10771328 A EP10771328 A EP 10771328A EP 10771328 A EP10771328 A EP 10771328A EP 2488691 A2 EP2488691 A2 EP 2488691A2
Authority
EP
European Patent Office
Prior art keywords
water
soluble
adhesive
adhesive composition
carrier material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP10771328A
Other languages
German (de)
English (en)
Inventor
Peter Grynaeus
Holger KÖHNLEIN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carl Freudenberg KG
Original Assignee
Carl Freudenberg KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carl Freudenberg KG filed Critical Carl Freudenberg KG
Publication of EP2488691A2 publication Critical patent/EP2488691A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266—Natural fibres not provided for in group D04H1/425
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4309—Polyvinyl alcohol
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/641—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions characterised by the chemical composition of the bonding agent
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • D—TEXTILES; PAPER
    • D05—SEWING; EMBROIDERING; TUFTING
    • D05C—EMBROIDERING; TUFTING
    • D05C17/00—Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D06M17/06—Polymers of vinyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/716—Degradable
    • B32B2307/7166—Water-soluble, water-dispersible
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/06—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals

Definitions

  • the invention relates to an insert for use as an embroidery fixation insert, consisting of a textile carrier material which is coated with an adhesive mass, wherein the adhesive composition comprises a water-soluble, thermoplastic polymer.
  • lining fabrics or nonwovens are laminated together with a textile layer configured as an outer material in a fixing press. Subsequently, reinforced and unreinforced parts are joined together, sewn and shaped if necessary by shaping.
  • the polymers known from DE 100 32 769 A1 for adhesive compositions based on (co) polyamides, polyvinyl alcohols and / or (co) polyesters can not be imprinted on water-soluble nonwovens in the form of an aqueous dispersion by a rotary screen printing method, since the water in the Adhesive mass leads to selective dissolution of the water-soluble nonwoven fabric. Triggered or printed areas of the water soluble nonwoven result in an unsightly, rough surface of the adhesive coated nonwoven fabric.
  • the invention is therefore based on the object to design the adhesive compositions known from the prior art in such a way and further that they can be easily used for water-soluble deposits, especially for nonwovens.
  • the aforementioned insert is characterized in that the adhesive composition is designed as an aqueous polymer dispersion and / or as a polymer solution.
  • Nonwovens is imprintable. This is under cold water, a water
  • a stencil size of CP 5 - CP 250 can be used.
  • the adhesive mass could have a solids content of more than 50%. This or a higher concentration swells the
  • the adhesive composition could have vinylpyrrolidone or modified vinylpyrrolidone.
  • Polymer solution have in particular polyvinylpyrrolidone and
  • Vinylpyrrolidones with polyvinyl acetate moieties are less hygroscopic at room temperature than unmodified vinylpyrrolidones. Therefore, the coated deposits do not stick when rolled up.
  • the adhesive composition could comprise polyols or polyglycols.
  • polyols and / or polyglycols By adding polyols and / or polyglycols, the melting range of a polymer, in particular the vinylpyrrolidones, can be changed, in particular lowered, or the melt flow of the polymer can be adapted to the respective applications.
  • the water-soluble adhesive is softened by polyglycols.
  • Polyethylene glycol (PEG) is preferably used as plasticizer.
  • PEG 400 in a concentration of 0-20%, particularly preferably in a concentration of 2-10%.
  • the adhesive mass could be admixed with 0-10% by weight of printing auxiliaries, such as dispersants or thickeners.
  • the textile carrier material could be water-soluble. As a result, the carrier material can be dissolved.
  • the textile carrier material could be made of polyvinyl alcohol.
  • the polyvinyl alcohol of the carrier material could be modified by ethoxylation of the polymers or by saponification with a degree of saponification greater than 95%. Modified polyvinyl alcohols dissolve well in cold water, namely water at a temperature of 10 to 40 ° C.
  • the textile carrier material could be designed as a nonwoven fabric.
  • the nonwoven fabric could have a basis weight of 20 to 120 g / m 2 .
  • Temperatures of 10 to 40 ° C be water-soluble.
  • Solved coating of a textile substrate is also suitable for printing on not
  • the solids content of the adhesive mass could be less than 50%.
  • the deposits described here are fixable, that is, they can be easily connected in a thermal process with textile materials of any kind.
  • the thermal process namely fixation or lamination, is carried out at temperatures of 80 to 140 ° C.
  • the adhesive compositions described here are preferably usable for nonwoven insert fabrics, in particular for water-soluble inlay and / or embroidery nonwovens.
  • a method of making a liner of the type described herein could include the steps of providing a textile substrate and coating the polymeric substrate with an adhesive comprising an aqueous polymer dispersion and / or a polymer solution.
  • an insert is first produced as an intermediate, with a aqueous polymer dispersion and / or a polymer solution is coated. This intermediate then loses the water of the aqueous
  • Table 1 below shows the change in melting range and melt flow.
  • Table 1 Preference is given to using a mixture of Luvitec VA 64 with 0-20% PEG 400, more preferably 3-15% PEG 400. Other PEGs can also be used. embodiments
  • Basis weight of 80 g / m 2 was printed with an adhesive mass of an aqueous polymer dispersion having a solids content of 45%.
  • the polymer dispersion consisted of 400 g / l Luvitec VA 64, 40 g / l PEG 400 and 5 g / l of a mixture of dispersants, thickeners and
  • the printing was carried out by means of a rotary screen printing technique. It was applied with a printing template CP 110, which corresponds to an open area of 20%, a coating of adhesive mass of 25 g / m 2 . The drying took place at 145.degree.
  • Embodiment 2 is a diagrammatic representation of Embodiment 1:
  • the carrier material for an embroidery fixation insert was a thermally bonded nonwoven fabric produced from cold-water-soluble polyvinyl alcohol (PVAL) staple fibers having a weight per unit area of about 40 g / m 2 .
  • PVAL cold-water-soluble polyvinyl alcohol
  • the polyvinyl alcohol staple fibers were prepared in a gel spinning process and had a strength of 4 g / denier.
  • This nonwoven fabric was printed with an adhesive mass, namely a dispersion or solution, with 60% solids content.
  • the adhesive consisted of 600 g / l Luvitec VA 64, 45 g / l PEG 400 and 5 g / l of a mixture of dispersants, thickeners and paste flow aids.
  • the printing was carried out by means of a rotary screen printing technique. A coating of adhesive mass of 15 g / m 2 was applied using a CP 52 printing stencil, which corresponds to an open area of 15%. The drying took place at 145.degree.
  • the printing with the above adhesives prepared surprisingly no problems. After drying, no sticking of the layers was observed.
  • Table 2 The modified (mod.) PA (polyamide) mentioned in table 2 corresponds to the polyamide according to example 1 from DE 100 32 769 A1.
  • VA stands for vinyl acetate, using the product Luvitec VA 64.
  • PEG stands for polyethylene glycol.
  • This polymer mixture can be used as a hot-melt or in the ground state as
  • Powder point to be applied This additional operation makes the process more expensive, the discoloration representing an undesired additional property.
  • the method described here is easy to implement because the components can be stirred together. After venting creates a slightly whitish dispersion or a clear solution. With 1 - 3% modified cellulosic thickener, the necessary viscosity of the mixture can be achieved Print to be set. Depending on requirements, further printing auxiliaries can be added in small amounts.
  • the printable adhesive mass should have a solids content of more than 50% in order to print good cold water-soluble carrier materials can.
  • Solids greater than 75% provide a high viscosity blend that is relatively difficult to use for printing. It is also possible to print on mixtures with lower solids contents on non-water-soluble carrier materials.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Details Of Garments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)
  • Automatic Embroidering For Embroidered Or Tufted Products (AREA)

Abstract

L'invention concerne une doublure destinée à être utilisée comme doublure de fixation de broderie et comprenant un matériau support textile recouvert d'une matière adhésive qui présente un polymère thermoplastique hydrosoluble. L'invention vise à confectionner et à perfectionner les matières adhésives connues de l'art antérieur de façon qu'elles puissent être utilisées sans problème pour des doublures hydrosolubles, notamment des non-tissés. A cet effet, la matière adhésive est une dispersion polymère aqueuse et/ou une solution polymère.
EP10771328A 2009-10-16 2010-10-12 Revêtement en matière adhésive hydrosoluble pour des doublures hydrosolubles Withdrawn EP2488691A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009049802A DE102009049802A1 (de) 2009-10-16 2009-10-16 Wasserlösliche Haftmassenbeschichtung für wasserlösliche Einlagestoffe
PCT/EP2010/006206 WO2011045017A2 (fr) 2009-10-16 2010-10-12 Revêtement en matière adhésive hydrosoluble pour des doublures hydrosolubles

Publications (1)

Publication Number Publication Date
EP2488691A2 true EP2488691A2 (fr) 2012-08-22

Family

ID=43733985

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10771328A Withdrawn EP2488691A2 (fr) 2009-10-16 2010-10-12 Revêtement en matière adhésive hydrosoluble pour des doublures hydrosolubles

Country Status (9)

Country Link
EP (1) EP2488691A2 (fr)
JP (1) JP5625204B2 (fr)
KR (1) KR101482948B1 (fr)
CN (1) CN102575417B (fr)
AR (1) AR078642A1 (fr)
BR (1) BR112012008738A2 (fr)
DE (1) DE102009049802A1 (fr)
TW (1) TWI424110B (fr)
WO (1) WO2011045017A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010046386A1 (de) * 2010-09-24 2012-03-29 Carl Freudenberg Kg Thermisch fixierbarer Einlagestoff und Verwendung
CN104073999B (zh) * 2014-06-27 2016-04-06 昆山胜昱无纺布有限公司 水溶布的复合材料及水溶布流水线
CN104074000B (zh) * 2014-06-27 2017-01-11 昆山胜昱无纺布有限公司 一种水溶布流水线
CN104088102A (zh) * 2014-07-02 2014-10-08 苏州市叶绣工艺厂 适用于大众的刺绣布
US20230002966A1 (en) * 2021-06-30 2023-01-05 CreateMe Technologies LLC Stabilizer coating for machine embroidering
WO2024135718A1 (fr) * 2022-12-20 2024-06-27 株式会社クラレ Fibres modifiées en surface, leur procédé de production et article moulé utilisant des fibres modifiées en surface

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Publication number Priority date Publication date Assignee Title
US3961125A (en) * 1972-12-18 1976-06-01 Kurashiki Boseki Kabushiki Kaisha Temporary interlining coated with foamed adhesive
JPS5898464A (ja) * 1981-12-07 1983-06-11 日本バイリ−ン株式会社 ケミカルレ−ス用基布の製造方法
JPS60162850A (ja) * 1984-01-30 1985-08-24 金井　宏之 水溶性繊維シ−ト
GB2188566A (en) * 1986-04-02 1987-10-07 Clark & Sons Ltd William Interlining materials
JPH03146759A (ja) * 1989-10-30 1991-06-21 Reiko Co Ltd 立体的刺繍製品及び立体的刺繍方法
JP3128326B2 (ja) * 1992-05-11 2001-01-29 株式会社クラレ 水溶性シート及びその製造方法
MX9800069A (es) * 1995-06-30 1998-03-31 Kimberly Clark Co Compuestos coform no tejidos fibrosos dispersables en agua.
DE59911115D1 (de) * 1999-08-26 2004-12-23 Siber Hegner & Co Ltd Verfahren zur herstellung einer trägerbahn für nachmaliges besticken
DE10032769C2 (de) 2000-07-05 2003-12-04 Freudenberg Carl Kg Wasserlösliche Stickerei-Fixiereinlage und Verfahren zu desen Herstellung
US6443081B1 (en) * 2000-10-13 2002-09-03 Laura J. Quint Applique art kit assembly and method of creating an applique art object
DE10344573A1 (de) * 2002-10-01 2004-04-15 Textilforschungsinstitut Thüringen-Vogtland e.V. Verfahren zum Besticken von elastischen textilen oder nichttextilen Materialien auf Industrie-Großstickmaschinen
US20090064424A1 (en) * 2005-06-03 2009-03-12 Kuraray Co. Ltd. Ground fabric for masking for use in method of transfer piece dyeing of embroidered part

Non-Patent Citations (2)

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Title
None *
See also references of WO2011045017A2 *

Also Published As

Publication number Publication date
AR078642A1 (es) 2011-11-23
TW201120276A (en) 2011-06-16
CN102575417B (zh) 2015-04-08
JP2013507538A (ja) 2013-03-04
WO2011045017A2 (fr) 2011-04-21
TWI424110B (zh) 2014-01-21
DE102009049802A1 (de) 2011-04-21
KR101482948B1 (ko) 2015-01-15
JP5625204B2 (ja) 2014-11-19
BR112012008738A2 (pt) 2016-05-10
KR20120089724A (ko) 2012-08-13
WO2011045017A3 (fr) 2011-07-14
CN102575417A (zh) 2012-07-11

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