EP2494020A1 - Lavage au moyen de corps polymères - Google Patents

Lavage au moyen de corps polymères

Info

Publication number
EP2494020A1
EP2494020A1 EP10766061A EP10766061A EP2494020A1 EP 2494020 A1 EP2494020 A1 EP 2494020A1 EP 10766061 A EP10766061 A EP 10766061A EP 10766061 A EP10766061 A EP 10766061A EP 2494020 A1 EP2494020 A1 EP 2494020A1
Authority
EP
European Patent Office
Prior art keywords
polymer
polymer body
acid
detergent composition
hexamethylenediamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10766061A
Other languages
German (de)
English (en)
Other versions
EP2494020B1 (fr
Inventor
Susanne Schneider
Dirk Weinrich
Helga Werner
Noelle Wrubbel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=43466500&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2494020(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL10766061T priority Critical patent/PL2494020T3/pl
Publication of EP2494020A1 publication Critical patent/EP2494020A1/fr
Application granted granted Critical
Publication of EP2494020B1 publication Critical patent/EP2494020B1/fr
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/01—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using only solid or pasty agents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • the invention relates to a method for cleaning and / or conditioning of textile
  • the invention also relates to a kit comprising ingredients of the formulation.
  • WO 2007/128962 A1 discloses a washing method which comprises the treatment of soiled laundry by contacting the laundry with a formulation comprising a multiplicity of polymer particles.
  • This object is achieved by a method for cleaning and / or conditioning of textile fabrics, wherein the moist, to be cleaned and / or conditioned fabrics with a formulation containing
  • Conditioning process is less heavily colored or dirty on its surface. Due to the much cleaner appearance of the polymer body, the consumer has significantly fewer inhibitions to use the polymer body multiple times.
  • the polymer body is a polymer selected from the group of
  • Polyalkylenes polyesters, polyurethanes, polyamides and mixtures thereof. These polymers are suitable for use in such a low-water washing process and, above all, are also compatible with H 2 O 2 .
  • the polymer body contains a polyamide which is selected from the group comprising PA 6 (polymer of ⁇ -caprolactam), PA 1 1 (polymer of 1 1-aminoundecanoic acid), PA 12 (polymer of ⁇ - Laurolactam), PA 66 (polymer of hexamethylenediamine and adipic acid), PA 69 (polymer of hexamethylenediamine and azelaic acid), PA 612 (polymer of hexamethylenediamine and dodecanedioic acid), PA 46 (polymer of tetramethylenediamine and adipic acid), PA 610 (polymer of hexane) 1, 6-diamine and sebacic acid) PA 612 (polymer of hexane-1, 6-diamine and dodecanedioic acid), PA 66/610
  • Polyamides are preferably used in the polymer body since they are effective on a variety of different stains.
  • the polymer body contains a polyalkylene which is selected from the group of polyethylenes, polypropylenes and mixtures thereof.
  • Polymer bodies of polyalkylenes are particularly suitable for the removal of oil-based stains.
  • the detergent composition may be free of enzymes.
  • the polymer body is in the form of a chip, a sphere, a cube, an ice, a cylinder, a disk, a cuboid or a truncated cone. It is further preferred that the maximum spatial extent of the polymer body is in the range of 1 to 10 mm. A polymer body of this size and shape has a good flow or
  • the hydrogen peroxide can be incorporated separately, incorporated into the detergent composition, applied to the polymer body, and / or absorbed by the polymer body in the process.
  • the detergent composition may be applied separately, applied to the polymer body and / or absorbed by the polymer body in the process.
  • H 2 O 2 which is an inexpensive bleaching agent compared with other bleaching agents such as percarbonates or perborates, can be used in the process.
  • hydrogen peroxide is used in aqueous solution, so that the bleaching agent does not have to dissolve during the washing process. It also distributes it more evenly in the formulation.
  • the invention also relates to a kit for cleaning and / or conditioning textile
  • the method according to the invention can be applied to a large number of textile fabrics. It can be used for example in all natural and synthetic
  • Tissue fibers are used, although it is particularly advantageously applied to fabrics of PA 66, polyester and cotton.
  • the tissues to be treated are moistened with water, in particular to improve the transport of dirt particles to the polymer body. If the H 2 0 2 and / or the detergent composition applied to the polymer body and / or absorbed by the polymer body, by wetting the fabrics also the transport of H 2 0 2 and / or the ingredients of the detergent composition of
  • Fabric may be made, for example, by wetting with water or an aqueous solution of the detergent composition.
  • the weight ratio of fabric to water be from 1: 0, 1 to 1: 5, and more preferably from 1: 0.2 to 1: 2.
  • At least one polymer body is used in the process. However, it is preferred for reasons of process efficiency if a variety of polymer bodies are used in the process.
  • the weight ratio of polymer body to textile fabrics is preferably from 30: 1 to 1: 1, more preferably from 15: 1 to 2: 1, and most preferably from 8: 1 to 3: 1.
  • the polymer body may include a polymer selected from the group of polyalkylenes, polyesters, polyurethanes, polyamides, and mixtures thereof, with polyamides and polyalkylenes being preferred.
  • Preferred polyalkylenes include polyethylenes, polypropylenes or mixtures thereof.
  • the polymer body contains a polyamide.
  • the polyamide may be selected from the group comprising PA 6 (polymer of ⁇ -caprolactam), PA 1 1 (polymer of 1 1 -aminoundecanoic acid), PA 12 (polymer of ⁇ -laurolactam), PA 66 (polymer of
  • PA 69 polymer of hexamethylenediamine
  • PA 612 polymer of hexamethylenediamine and dodecanedioic acid
  • PA 46 polymer of tetramethylenediamine and adipic acid
  • PA 610 polymer of hexane-1, 6-diamine and
  • PA 612 polymer of hexane-1, 6-diamine and dodecanedioic acid
  • the polymer body may be of any shape, but is preferably in the form of a chip, sphere, cube, ice, cylinder, disk, cuboid or truncated cone. These forms ensure good mobility of the
  • the maximum spatial extent of the polymer body is preferably in the range of 1 to 10 mm, and more preferably in the range of 2 to 6 mm.
  • maximum spatial extent of the polymer body is preferably in the range of 1 to 10 mm, and more preferably in the range of 2 to 6 mm.
  • Expansion in this context refers to the distance between the two farthest points on the polymer body.
  • the polymer body is in the form of a cloth, for example a microfiber cloth.
  • the microfiber cloth is attached to the fabrics, and more preferably to the patches located there.
  • the attachment should be such that as much as possible of the surface of the textile fabrics is in contact with the surface of the fabric. It is advantageous if the cloth used has as much surface as possible, so that
  • Looped goods, velvet, terry cloth or nonwoven fabrics are preferably used.
  • the cloth has a surface area (in one side) of from 40 cm 2 to 800 cm 2, and more preferably from 100 cm 2 to 400 cm 2 .
  • the formulation contains, in addition to the molding, a detergent composition.
  • the detergent composition contains surfactant (s) wherein anionic, nonionic, zwitterionic and / or amphoteric surfactants can be used. Preference is given to
  • the total surfactant content of a liquid detergent is preferably below 40% by weight and more preferably below 35% by weight, based on the total, preferably liquid, detergent composition.
  • Suitable nonionic surfactants include alkoxylated fatty alcohols, alkoxylated
  • Fatty acid alkyl esters Fatty acid alkyl esters, fatty acid amides, alkoxylated fatty acid amides, polyhydroxy fatty acid amides, alkylphenol polyglycol ethers, amine oxides, alkyl polyglucosides and mixtures thereof.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • Preferred ethoxylated alcohols include, for example, C 12 -14 alcohols containing 3 EO, 7 EO or 4 EO, C 9 n-alcohol with 7 EO, C 13 -i 5 alcohols containing 3 EO, 5 EO, 7 EO or 8 EO, Ci 2 -i8 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as
  • Ci 2 -i4-alcohol with 3 EO Ci 2 -i8-alcohol with 7 EO.
  • Levels of ethoxylation represent statistical averages, which may be an integer or a fractional number for a particular product.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention.
  • a mixture of a (more) branched ethoxylated fatty alcohol and an unbranched ethoxylated fatty alcohol such as a mixture of a C16-18 fatty alcohol with 7 EO and 2-propylheptanol with 7 EO.
  • the washing, cleaning, post-treatment or washing aid containing a C 2 -i8 fatty alcohol with 7 EO, or C-i3-i5-oxo-alcohol with 7 EO as non-ionic surfactant.
  • the content of nonionic surfactants in the detergent composition is preferably 3 to 40 wt .-%, preferably 5 to 30 wt .-% and in particular 7 to 20 wt .-%, each based on the total detergent composition.
  • the detergent composition may also contain anionic surfactants.
  • the anionic surfactant used is preferably sulfonates, sulfates, soaps, alkyl phosphates, anionic silicone surfactants and mixtures thereof.
  • Suitable surfactants of the sulfonate type are preferably C 9 .i 3 -alkylbenzenesulfonates and olefinsulfonates. Also suitable are C 2 -i 8-alkanesulfonates and the esters of a-sulfofatty acids (ester sulfonates), for example, the ⁇ -sulfonated Methylester of hydrogenated coconut, palm kernel or tallow fatty acids.
  • Alk (en) ylsulfates are the alkali metal and in particular the sodium salts of
  • Sulfuric acid semi-esters of Ci 2 -C 8 fatty alcohols for example from coconut fatty alcohol,
  • Tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the Ci 0 -C 2 o-oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred.
  • the Ci 2 -Ci 6 alkyl sulfates and Ci 2 -Ci 5 alkyl sulfates and Ci 4 -Ci 5 alkyl sulfates are preferred.
  • 2,3-alkyl sulfates are also suitable anionic surfactants.
  • sulfuric acid monoesters of straight-chain or branched C 7 ethoxylated with 1 to 6 moles of ethylene oxide are suitable.
  • 2 i-alcohols such as 2-methyl-branched Cg-n-alcohols having on average 3.5 mol of ethylene oxide (EO) or Ci 2 _i 8 -Fettalkohole with 1 to 4 EO, are suitable.
  • anionic surfactants are soaps.
  • Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants including the soaps may be in the form of their sodium, potassium or magnesium or ammonium salts.
  • the anionic surfactants are in the form of their sodium salts.
  • Further preferred counterions for the anionic surfactants are also the protonated forms of choline, triethylamine or methylethylamine.
  • the content of anionic surfactants in a washing or cleaning agent may be from 1 to 40% by weight, preferably from 5 to 30% by weight and most preferably from 10 to 25% by weight, based in each case on the total washing or cleaning agent ,
  • the detergent composition may contain other ingredients which have the performance and / or aesthetic properties of the surfactants.
  • Detergent composition further improve.
  • preferred detergent compositions additionally comprise one or more substances from the group of builders, bleaching agents, bleach activators, bleach catalysts, enzymes, electrolytes, nonaqueous solvents, pH adjusters, perfumes, perfume carriers, Fluorescent agents, dyes, hydrotopes, foam inhibitors, silicone oils, soil release polymers, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents,
  • Color transfer inhibitors antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, thickeners, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents and UV absorbers.
  • the detergent composition contain no ingredients which, when in contact with skin, contain an ingredient
  • the detergent composition may be free of enzymes.
  • the detergent composition itself may be solid, liquid, gel, waxy or pasty, with liquid detergents being particularly preferred due to the improved quenching properties.
  • the detergent composition can be applied separately and / or on the polymer body and / or absorbed by the polymer body in the process. It may be preferred that the polymer body is coated with the detergent composition. When the detergent composition is applied to the polymer body and / or absorbed by the polymer body used in the process, this facilitates the operation of the process for the user since he does not yet have to dose the detergent composition separately.
  • the formulation contains hydrogen peroxide. Hydrogen peroxide is a cheap bleaching agent and does not leave any residue on the treated textile fabrics.
  • the hydrogen peroxide may be incorporated separately and / or in the detergent composition and / or applied to the polymer body and / or absorbed by the polymer body in the process. If the hydrogen peroxide is already incorporated into detergent composition or is applied to the polymer body and / or absorbed by the polymer body in the process, this avoids the user coming into direct contact with the hydrogen peroxide.
  • the amount of H 2 O 2 is preferably 0.5 to 10 g, and more preferably 0.5 to 3 g per
  • the process can be carried out in specially designed washing machines.
  • the polymer bodies used can either be introduced separately into the washing drum by the user of the method or, in an alternative embodiment, stored in a storage chamber within the washing machine and then to the wash cycle in the washing machine Wash drum automatically dosed.
  • the polymer bodies may be either removed along with the cleaned fabrics after completion of the washing process or returned to the pantry for other applications.
  • a refreshing step When using a polymer body several times, it may be preferable to subject it to a refreshing step. This can be done, for example, by rinsing the
  • this refreshing step may be automatically executed in a dedicated one
  • the process can be carried out in a commercially available dryer.
  • the moist textiles to be cleaned together with the polymer body (s), the detergent composition and the hydrogen peroxide are placed in an air, water and water vapor-tight bag and this is then placed sealed in a dryer. After completion of the drying program, the bag is removed and the cleaned fabrics are removed and dried.
  • the process according to the invention is preferably carried out at a temperature of less than 100.degree
  • the process is carried out. Particularly preferably, the process is carried out at temperatures between 30 and 90 ° C.
  • the duration of the process is preferably between 15 and 240 minutes and more preferably between 20 and 90 minutes.
  • An autoclave pouch was charged with 550 g nylon PA 66 (Zytel® 101 from DuPont) polyamide chips having a length of about 4 mm, a width of 3 mm and a weight of 30 to 40 mg per chip.
  • 150 g of white barley grain towels on which standard cotton test cloths were attached with test spots were moistened with an aqueous solution of 290.7 g of water, 1 g of H 2 O 2 (active ingredient) and 11, 81 g of Detergent A.
  • the bag was then closed and transferred to the drum of a dryer (Miele Novotronic T 7644 C).
  • Example 2 The procedure was analogous to Example 1, with the difference that the terry towels were moistened with an aqueous solution of 290.7 g of water and 1 1, 81 g of detergent A.
  • the detergent A contained 21, 1 wt .-% surfactants (nonionic and anionic surfactants), and other conventional ingredients of liquid detergents such as the sodium salt of citric acid, sodium metaborate, defoamers, Acrylatverdicker, water-miscible solvents, optical brightener, dyes, perfume and water.
  • Detergent A was free of enzymes.
  • Standard color value Y (DIN 5033). These were the Y values of the stained, untreated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un procédé de nettoyage et/ou de conditionnement de surfaces textiles, selon lequel les surfaces textiles humides à nettoyer et/ou à conditionner sont mises en contact avec une formulation contenant a) au moins un corps polymère, b) une composition détergente et c) du peroxyde d'hydrogène (H2O2).
EP10766061.5A 2009-10-29 2010-10-19 Lavage au moyen de corps polymères Revoked EP2494020B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10766061T PL2494020T3 (pl) 2009-10-29 2010-10-19 Zmywanie za pomocą bryłek polimerycznych

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009046170A DE102009046170A1 (de) 2009-10-29 2009-10-29 Waschen mit Polymerkörpern
PCT/EP2010/065737 WO2011051140A1 (fr) 2009-10-29 2010-10-19 Lavage au moyen de corps polymères

Publications (2)

Publication Number Publication Date
EP2494020A1 true EP2494020A1 (fr) 2012-09-05
EP2494020B1 EP2494020B1 (fr) 2016-03-02

Family

ID=43466500

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10766061.5A Revoked EP2494020B1 (fr) 2009-10-29 2010-10-19 Lavage au moyen de corps polymères

Country Status (5)

Country Link
EP (1) EP2494020B1 (fr)
DE (1) DE102009046170A1 (fr)
ES (1) ES2565478T3 (fr)
PL (1) PL2494020T3 (fr)
WO (1) WO2011051140A1 (fr)

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US9315766B2 (en) 2011-06-09 2016-04-19 Haier Group Corporation Solid particle for washing and washing method using the same

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GB201006076D0 (en) 2010-04-12 2010-05-26 Xeros Ltd Novel cleaning apparatus and method
GB201015277D0 (en) 2010-09-14 2010-10-27 Xeros Ltd Novel cleaning method
GB201015276D0 (en) * 2010-09-14 2010-10-27 Xeros Ltd Polymer treatment method
GB201100627D0 (en) 2011-01-14 2011-03-02 Xeros Ltd Improved cleaning method
GB201100918D0 (en) 2011-01-19 2011-03-02 Xeros Ltd Improved drying method
GB201117421D0 (en) * 2011-10-10 2011-11-23 Reckitt & Colman Overseas Product
GB201117425D0 (en) * 2011-10-10 2011-11-23 Reckitt & Colman Overseas Product
DE102012003342A1 (de) * 2012-02-21 2013-08-22 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Waschen mit Fasern
GB201204071D0 (en) * 2012-03-08 2012-04-18 Reckitt & Colman Overseas Polymer treatment method
GB201204074D0 (en) * 2012-03-08 2012-04-18 Reckitt & Colman Overseas Novel cleaning method
GB201212098D0 (en) * 2012-07-06 2012-08-22 Xeros Ltd New cleaning material
DE102012222263A1 (de) 2012-12-05 2014-06-05 Henkel Ag & Co. Kgaa Entfernung fettiger Anschmutzungen
GB201319782D0 (en) 2013-11-08 2013-12-25 Xeros Ltd Cleaning method and apparatus
GB201320784D0 (en) 2013-11-25 2014-01-08 Xeros Ltd Improved cleaning Apparatus and method
DE102014213312A1 (de) * 2014-07-09 2016-01-14 Henkel Ag & Co. Kgaa Waschmaschine mit Entfärbungseinrichtung und Reservoir für wasserunlösliche feste Teilchen
DE102014213313A1 (de) * 2014-07-09 2016-01-14 Henkel Ag & Co. Kgaa Waschmaschine mit Entfärbungseinrichtung und Reservoir für wasserunlösliche feste Teilchen
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Also Published As

Publication number Publication date
WO2011051140A1 (fr) 2011-05-05
PL2494020T3 (pl) 2016-08-31
EP2494020B1 (fr) 2016-03-02
DE102009046170A1 (de) 2011-05-05
ES2565478T3 (es) 2016-04-05

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