EP2548982A1 - Raffinierte Titanlegierung - Google Patents
Raffinierte Titanlegierung Download PDFInfo
- Publication number
- EP2548982A1 EP2548982A1 EP12175562A EP12175562A EP2548982A1 EP 2548982 A1 EP2548982 A1 EP 2548982A1 EP 12175562 A EP12175562 A EP 12175562A EP 12175562 A EP12175562 A EP 12175562A EP 2548982 A1 EP2548982 A1 EP 2548982A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- titanium
- alloy
- precious metal
- alloy according
- alloyed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910001069 Ti alloy Inorganic materials 0.000 title abstract description 3
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 30
- 239000000956 alloy Substances 0.000 claims abstract description 30
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000010936 titanium Substances 0.000 claims abstract description 29
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 28
- 239000010970 precious metal Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 239000010931 gold Substances 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 238000004320 controlled atmosphere Methods 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 229910000923 precious metal alloy Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000447437 Gerreidae Species 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003353 gold alloy Substances 0.000 description 1
- ZNKMCMOJCDFGFT-UHFFFAOYSA-N gold titanium Chemical compound [Ti].[Au] ZNKMCMOJCDFGFT-UHFFFAOYSA-N 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 229910001258 titanium gold Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
Definitions
- This invention refers to the technical field of metallurgy, in particular to the technical field of alloys consisting of titanium and at least one other material.
- titanium possesses in particular a high specific mechanical strength and a very high resistance to corrosion in different aggressive environments.
- strength of titanium can be further improved by adding alloying elements such as aluminum and vanadium.
- the density of titanium is 40% lower than that of carbon steels, making it particularly suitable for different applications where the relationship between weight and strength of materials play an important role.
- titanium The corrosion resistance of titanium is accompanied by resistance to erosion by fluids loaded with abrasive products (eg sand in seawater), fire and chemical attack. These properties are mainly due to the ability of titanium to passivate by the formation of an oxide protective film. Titanium thus resists perfectly all natural environments (atmosphere, seawater, ...) and many chemicals, especially those containing chlorine.
- titanium Another remarkable property of titanium is its good biocompatibility, so essentially the property of a material not to induce negative reactions when it is brought into contact with biological tissues (eg skin, bone, blood, etc.). Indeed, a large part of Surgical instruments and medical implants are today made of a suitable titanium alloy.
- titanium in the fields of jewelery, jewelery or watchmaking remains rather symbolic.
- the aesthetic aspects of titanium make it rather uninteresting for those areas in which the appearance and dollar value of the products still play a vital role.
- the most used metals in the fields of jewelery, jewelery and high-end watchmaking are precious metals, in particular gold, silver, platinum or palladium. These metals are particularly appreciated for the aesthetic properties, but also for the economic value.
- the present invention therefore aims to provide a new material, especially for the production of timepieces and / or jewelry, to overcome the limitations of the state of the art mentioned above, also reducing significantly the production costs of the parts.
- the advantage of this invention over all known solutions in the state of the art is that the resulting alloy has a very advantageous combination of properties.
- the proposed new material has the mechanical properties of titanium, namely a very good resistance to corrosion and other chemical attacks, as well as a high mechanical hardness and strength.
- this new alloy also has properties inherited from precious metals, including excellent polishability, good gloss, and a specific color with different reflections depending on the precious metal content.
- this new material can also be easily colored, thanks to the completely preserved titanium coloring properties.
- the objectives of the present invention are effectively achieved by using an alloy which is made of titanium and at least one other material, containing between 50% and 99% titanium and between 1% and 50% of the other material, and wherein the other material is a precious metal.
- the hardness and color of the alloy, as well as its monetary value depend essentially on the amount of precious metals used in the alloy.
- the variety of colors of the alloy according to the invention can range from green or blue to gray, via pink or pale yellow, depending on the specific needs.
- the precious metal used in the alloy may be any one between gold, silver, platinum or palladium.
- the precious metal used in the alloy may be any one between gold, silver, platinum or palladium.
- other materials metal or non-metals
- titanium and the precious metal are alloyed under controlled atmosphere and / or under pressure. Titanium and precious metal are alloyed in a closed enclosure to obtain conditions of pressure and controlled atmosphere. Indeed, it is important given the avidity of titanium to oxygen to work under a neutral atmosphere free of oxygen. To do this a relatively high vacuum is made in the enclosure of the machine after introduction of the alloying elements. Only when oxygen is removed or replaced by a neutral gas such as argon are the elements melted and alloyed by electrical discharge. This gives alloys with properties perfectly mastered.
- the parts in question being notably watchmaking elements intended to be polished.
- the piece in question can notably be a watch case, a bracelet, a crown, certain elements of a movement, such as a platinum, bridges, etc. Of course, other pieces are absolutely possible.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Adornments (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH11492011 | 2011-07-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2548982A1 true EP2548982A1 (de) | 2013-01-23 |
Family
ID=46583854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP12175562A Withdrawn EP2548982A1 (de) | 2011-07-08 | 2012-07-09 | Raffinierte Titanlegierung |
Country Status (1)
| Country | Link |
|---|---|
| EP (1) | EP2548982A1 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3067755A1 (de) * | 2015-03-12 | 2016-09-14 | Ynsendia AG | Federhaus für einen zeitmesser |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB733882A (en) * | 1952-03-08 | 1955-07-20 | Brevets D Etudes Et De Rech S | An alloy of which the base metal is titanium |
| US4568398A (en) * | 1984-04-06 | 1986-02-04 | National Research Development Corp. | Titanium alloys |
| WO2008018109A1 (en) * | 2006-08-11 | 2008-02-14 | Consiglio Nazionale Delle Ricerche | Precious metal alloys based on the nitiau system, with phase transformations in solid state and methods for the production and transformation thereof |
-
2012
- 2012-07-09 EP EP12175562A patent/EP2548982A1/de not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB733882A (en) * | 1952-03-08 | 1955-07-20 | Brevets D Etudes Et De Rech S | An alloy of which the base metal is titanium |
| US4568398A (en) * | 1984-04-06 | 1986-02-04 | National Research Development Corp. | Titanium alloys |
| WO2008018109A1 (en) * | 2006-08-11 | 2008-02-14 | Consiglio Nazionale Delle Ricerche | Precious metal alloys based on the nitiau system, with phase transformations in solid state and methods for the production and transformation thereof |
Non-Patent Citations (1)
| Title |
|---|
| KEUN-TAEK OH ET AL: "Cytocompatibility and electrochemical properties of Ti-Au alloys for biomedical applications", JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B: APPLIED BIOMATERIALS, vol. 83B, no. 2, 1 November 2007 (2007-11-01), pages 320 - 326, XP055047686, ISSN: 1552-4973, DOI: 10.1002/jbm.b.30798 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3067755A1 (de) * | 2015-03-12 | 2016-09-14 | Ynsendia AG | Federhaus für einen zeitmesser |
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| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
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| AX | Request for extension of the european patent |
Extension state: BA ME |
|
| 17P | Request for examination filed |
Effective date: 20130723 |
|
| RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
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| 17Q | First examination report despatched |
Effective date: 20140620 |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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| 18D | Application deemed to be withdrawn |
Effective date: 20141031 |