EP2809994A2 - Élément écran thermique pour une dérivation d'air de compresseur autour de la chambre de combustion - Google Patents
Élément écran thermique pour une dérivation d'air de compresseur autour de la chambre de combustionInfo
- Publication number
- EP2809994A2 EP2809994A2 EP13712711.4A EP13712711A EP2809994A2 EP 2809994 A2 EP2809994 A2 EP 2809994A2 EP 13712711 A EP13712711 A EP 13712711A EP 2809994 A2 EP2809994 A2 EP 2809994A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- combustion chamber
- wall
- heat shield
- height
- shield element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 58
- 238000001816 cooling Methods 0.000 claims description 13
- 230000002093 peripheral effect Effects 0.000 claims description 7
- 239000002826 coolant Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
- F23R3/04—Air inlet arrangements
- F23R3/06—Arrangement of apertures along the flame tube
- F23R3/08—Arrangement of apertures along the flame tube between annular flame tube sections, e.g. flame tubes with telescopic sections
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/005—Combined with pressure or heat exchangers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/007—Continuous combustion chambers using liquid or gaseous fuel constructed mainly of ceramic components
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/42—Continuous combustion chambers using liquid or gaseous fuel characterised by the arrangement or form of the flame tubes or combustion chambers
- F23R3/50—Combustion chambers comprising an annular flame tube within an annular casing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/42—Continuous combustion chambers using liquid or gaseous fuel characterised by the arrangement or form of the flame tubes or combustion chambers
- F23R3/60—Support structures; Attaching or mounting means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R2900/00—Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
- F23R2900/03042—Film cooled combustion chamber walls or domes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
- F23R3/04—Air inlet arrangements
- F23R3/06—Arrangement of apertures along the flame tube
Definitions
- the invention relates to a heat shield element of a Brennkam ⁇ mer, in particular an annular combustion chamber of a gas turbine plant, and refers to the bypass of compressor air to the combustion chamber at part load.
- the invention further relates to a combustion chamber and a corresponding gas turbine plant.
- Object of the present invention is to expand by indicating a bypass the carbon monoxide compliant driving range of the gas turbine as far as possible in the direction of low power.
- Another object of the present invention is to provide an improved combustor. Finally, it is an object of the present invention to provide an improved gas turbine.
- the first object is achieved by a heat shield element according to claim 1, the second object by a combustion chamber according to claim 6 and the third object by a gas turbine according to claim 10.
- a heat shield element in particular for lining a combustion chamber wall, comprising a first wall with a hot side to be acted upon by a hot medium, a cold side facing the hot side and a peripheral edge located at a first, a second and a third narrow side of the first wall on the cold side, in substance up to a first elevation extends, the environmentally running edge at a fourth narrow side up to a two ⁇ th height extends that is smaller than the first height, and in that a second wall of the cold side is located substantially opposite the second height and is adjacent over the width of the fourth narrow side from the fourth narrow side over a part of the length of the fourth narrow side
- Narrow sides extends, wherein the second wall has at its end facing away from the fourth narrow side end an edge which extends to the first height.
- the invention is based on the idea that, in an annular combustion chamber, which is largely lined with ceramic Hitzeschildele ⁇ elements and only the inlet is lined in the turbine with metallic heat shield elements, shield elements, the supply of the bypass air in the region of the metallic heat the combustion chamber wall is to be done, because the supply ⁇ as far as possible behind the combustion to prevent cooling of the flame, but in front of the turbine to achieve the highest possible gas turbine efficiency, suc- should be.
- a new design of the metallic heat shield elements is needed. This design is the subject of this invention.
- the heat shield element is subdivided into two superimposed regions which are dense to one another and form chambers in the installed state, ie with the combustion chamber wall.
- a first chamber extends over the entire surface of the heat shield element and is used for normal cooling of the metallic heat shield.
- a second chamber is located in the turbine facing portion of the heat shield element above the first chamber.
- a heat shield element of a high temperature resistant metal or a high temperature resistant metal alloy since these materials have a lower brittleness than, for example, ceramic and a comparatively ⁇ as good heat and Temperaturleit .
- a plurality of spaced circumferential edge cooling air openings from which the pre-cooling to the heat shield element provided ⁇ compressor discharge air can escape into the combustion chamber.
- the cooling air openings are arranged at least in the region of the second wall between the first and the second wall.
- thedeöffnun ⁇ gene in the region of the first chamber for the cooling of the heat shield element.
- the heat shield element further comprises a mounting opening, the enclosure of which extends from the first wall to the first height.
- the heat shield element is used to protect against overheating ei ⁇ ner hot gas component, in particular a combustion chamber, preferably an annular combustion chamber of a gas turbine, which has a combustion chamber wall, with a burner side and a turbine end, wherein the combustion chamber wall has a circumferential direction.
- a number of heat shield elements is preferably arranged at the turbine end of the combustion chamber wall to form two chambers in the circumferential direction, wherein the fourth
- Narrow side is aligned towards the turbine end.
- the heat shield elements are preferably fixed with Fixed To ⁇ fixing bolts on the combustion chamber wall.
- bores are introduced in the combustion chamber wall so that coolant can be supplied to the heat shield elements.
- at least one supply channel per heat shield element is arranged in the region of the respective second wall in the combustion chamber wall, which opens into a plenum which revolves at least partially around the combustion chamber.
- the combustion chamber to which heat shield elements are attached is preferably part of a gas turbine.
- This gas turbine comprises at least one discharge for compressor air, which opens into the plenum via at least one line with a valve.
- the invention enables the supply of bypass air in the hot gas path without far-reaching modifications to H synthgasbond ⁇ generating components.
- the implementation is therefore likely to be comparatively inexpensive. It ensures that no hot gas is drawn in even when the bypass is switched off, since the second chamber is constantly purged and its outlet streamlined between heat shield element and turbine vane 1 is located.
- FIG. 2 shows a metallic heat shield element according to the invention
- FIG. 3 shows a section through an annular combustion chamber according to the invention with removal system for the compressor Lucasby- pass.
- 1 shows schematically and exemplarily the Burn ⁇ recognition system 1 an annular combustion chamber according to the prior art in a housing 2.
- the annular combustion chamber 1 is disposed about a rotor axis 3 of a closed ring.
- Burner 4 are arranged in the upper region of the combustion chamber 1 in inlet openings 5. There, the mixing of the fuel 6 with the compressor air 7 takes place. In the combustion chamber 1, the actual combustion takes place. Through the outlet at the turbine end 8 of the annular combustion chamber 1, the hot combustion gases enter the turbine 9, where they meet the first stationary vane 10.
- the annular combustion chamber 1 is lined with ceramic heat shield elements 11 and metallic heat shield elements 12, which are fastened to the combustion chamber wall 13.
- FIG. 2 shows a metallic heat shield element 14 according to the invention which is to be fastened to the combustion chamber wall 13 and forms with it a first chamber 15 and a second chamber 16 open in the direction of the turbine, which are sealed against each other.
- the metallic heat shield member 14 itself includes a first wall 17 with a with a hot medium beaufschlag ⁇ cash hot side 18, one of the hot side 18 opposite the cold side 19, and four intermediate narrow sides 20,
- a peripheral edge 24 extends from each narrow side 20, 21, 22, 23 beyond the cold side 19. At the first 20, the second 21 and the third narrow side 22, the edge 24 extends substantially to a first height 25 with respect to the cold side 19 of the first wall 17 and on the fourth narrow side 23 only to a smaller second height 26. This is the built-me ⁇ -metallic heat shield member 14 at the edges of three narrow ⁇ pages 20, 21, 22 on the combustion chamber wall 13 at.
- a second wall 27 is located substantially opposite to the second height 26 of the cold side 19. It extends over the width of the fourth narrow side 23 and the fourth narrow ⁇ page 23 from a portion of the length of the fourth narrow side 23 adjacent narrow sides 20, 22. Furthermore, the second wall 27 at its fourth narrow side 23 make ⁇ turned end 28 on an edge 29, which extends from the second height 26 to the first height 25.
- a plurality of cooling air openings 30 are provided in the peripheral edge 24 in the region of the first chamber 15.
- the first chamber 15 is supplied as in heat shield elements 12 of the prior art via holes through the combustion chamber wall 13 with Ver Whyrend Kunststoff for cooling, which escapes from the metallic heat shield element 14 via these cooling air ⁇ openings 30.
- the metallic heat shield element 14 has a Fixed To ⁇ restriction opening 31, the skirt 32 extends from the first wall 17 to the first height 25th By this Befes- actuating opening 31, the heat shield member 14 is secured by means of fastening bolts Be ⁇ on the combustion chamber wall. 13
- the supply of open in the direction of the turbine 9 second chamber 16 with compressor air consists of two components. On the one hand, the second chamber 16 becomes permanent over some
- the second chamber 16 can be actuated switchably with a bypass mass flow. This is done over comparatively large holes, i. compared to the holes for the flushing, fed in the combustion chamber wall 13.
- the bypass mass flow then escapes via the opening at the trailing edge, i. the combustion chamber facing side of the heat shield element 14, on which the peripheral edge 24 extends only to the second height 26, in the gap between the metallic heat shield element 14 and the first stationary vane 10th
- FIG. 3 shows how compressor air is first led out of the gas turbine via a removal 33 for the bypass. Outside of the gas turbine, the circuit via a Ven ⁇ til 34. Thereafter, the air is carried via a line 35 is recirculated to the gas turbine ⁇ and inputted in a ring around the combustion chamber 1 in order ⁇ running Plenum 36th From there lead stub lines 37 or tap holes to the respective second chamber 16 of the respective metallic heat shield element 14.
- a valve 34, a line 35 and a plenum 36 are shown. However, solutions with more withdrawals, valves, pipes and plenums are also possible.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Supercharger (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102012204103A DE102012204103A1 (de) | 2012-03-15 | 2012-03-15 | Hitzeschildelement für einen Verdichterluftbypass um die Brennkammer |
| PCT/EP2013/055007 WO2013135702A2 (fr) | 2012-03-15 | 2013-03-12 | Élément écran thermique pour une dérivation d'air de compresseur autour de la chambre de combustion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2809994A2 true EP2809994A2 (fr) | 2014-12-10 |
| EP2809994B1 EP2809994B1 (fr) | 2016-05-04 |
Family
ID=48013936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13712711.4A Not-in-force EP2809994B1 (fr) | 2012-03-15 | 2013-03-12 | Élément écran thermique pour une dérivation d'air de compresseur autour de la chambre de combustion |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20150027128A1 (fr) |
| EP (1) | EP2809994B1 (fr) |
| CN (1) | CN104169648B (fr) |
| DE (1) | DE102012204103A1 (fr) |
| RU (1) | RU2622590C2 (fr) |
| WO (1) | WO2013135702A2 (fr) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012204162A1 (de) * | 2012-03-16 | 2013-09-19 | Siemens Aktiengesellschaft | Ringbrennkammer-Bypass |
| US10408451B2 (en) | 2013-09-11 | 2019-09-10 | Siemens Aktiengesellschaft | Wedge-shaped ceramic heat shield of a gas turbine combustion chamber |
| EP3084310A4 (fr) * | 2013-12-19 | 2017-01-04 | United Technologies Corporation | Ensemble paroi de moteur à turbine à gaz présentant une architecture de rails circonférentiels associés à des tiges filetées |
| US10645404B2 (en) | 2014-03-24 | 2020-05-05 | Qualcomm Incorporated | Generic use of HEVC SEI messages for multi-layer codecs |
| DE102014206018A1 (de) * | 2014-03-31 | 2015-10-01 | Siemens Aktiengesellschaft | Gasturbinenanlage |
| DE102014214981B3 (de) * | 2014-07-30 | 2015-12-24 | Siemens Aktiengesellschaft | Seitenbeschichtetes Hitzeschildelement mit Prallkühlung an Freiflächen |
| DE102014221225A1 (de) * | 2014-10-20 | 2016-04-21 | Siemens Aktiengesellschaft | Hitzeschildelement und Verfahren zu seiner Herstellung |
| DE102015202097A1 (de) * | 2015-02-06 | 2016-08-11 | Siemens Aktiengesellschaft | Ringbrennkammer mit Bypasssegment |
| CN104654359B (zh) * | 2015-02-13 | 2017-12-19 | 北京华清燃气轮机与煤气化联合循环工程技术有限公司 | 一种燃烧室预混合燃料喷嘴的引流结构 |
| CN104654358B (zh) * | 2015-02-13 | 2017-09-15 | 北京华清燃气轮机与煤气化联合循环工程技术有限公司 | 一种带有引流结构的燃烧室预混合燃料喷嘴 |
| DE102015205975A1 (de) * | 2015-04-02 | 2016-10-06 | Siemens Aktiengesellschaft | Umführungs-Hitzeschildelement |
| DE102015215207A1 (de) * | 2015-08-10 | 2017-02-16 | Siemens Aktiengesellschaft | Brennkammer für eine Gasturbine und Hitzeschildelement zum Auskleiden einer derartigen Brennkammer |
| WO2017032424A1 (fr) * | 2015-08-27 | 2017-03-02 | Siemens Aktiengesellschaft | Élément d'écran thermique métallique à circulation d'air de refroidissement optimisée |
| DE102015224524A1 (de) * | 2015-12-08 | 2017-06-08 | Siemens Aktiengesellschaft | Brennkammer mit Resonatoren |
| US10237339B2 (en) * | 2016-08-19 | 2019-03-19 | Microsoft Technology Licensing, Llc | Statistical resource balancing of constrained microservices in cloud PAAS environments |
| DE102018204453B4 (de) * | 2018-03-22 | 2024-01-18 | Rolls-Royce Deutschland Ltd & Co Kg | Brennkammerbaugruppe mit unterschiedlichen Krümmungen für eine Brennkammerwand und eine hieran fixierte Brennkammerschindel |
| DE102020116245B4 (de) * | 2020-06-19 | 2024-03-07 | Man Energy Solutions Se | Baugruppe einer Gasturbine mit Brennkammerluftbypass |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2312654A1 (fr) * | 1975-05-28 | 1976-12-24 | Snecma | Perfectionnements aux chambres de combustion pour moteurs a turbine a gaz |
| US4573865A (en) * | 1981-08-31 | 1986-03-04 | General Electric Company | Multiple-impingement cooled structure |
| US4896510A (en) * | 1987-02-06 | 1990-01-30 | General Electric Company | Combustor liner cooling arrangement |
| GB9018014D0 (en) * | 1990-08-16 | 1990-10-03 | Rolls Royce Plc | Gas turbine engine combustor |
| DE19730751A1 (de) * | 1996-07-24 | 1998-01-29 | Siemens Ag | Keramisches Bauteil für eine Wärmeschutzschicht sowie Wärmeschutzschicht |
| FR2752916B1 (fr) * | 1996-09-05 | 1998-10-02 | Snecma | Chemise de protection thermique pour chambre de combustion de turboreacteur |
| US6358041B1 (en) * | 2000-04-21 | 2002-03-19 | Eastman Chemical Company | Threaded heat shield for burner nozzle face |
| JP2002317650A (ja) * | 2001-04-24 | 2002-10-31 | Mitsubishi Heavy Ind Ltd | ガスタービン燃焼器 |
| EP1284390A1 (fr) * | 2001-06-27 | 2003-02-19 | Siemens Aktiengesellschaft | Ensemble bouclier thermique pour un composant acheminant un gaz chaud, notamment pour des pièces de structure de turbines à gaz |
| JP2003201863A (ja) * | 2001-10-29 | 2003-07-18 | Mitsubishi Heavy Ind Ltd | 燃焼器及びこれを備えたガスタービン |
| RU2243448C2 (ru) * | 2002-12-18 | 2004-12-27 | Федеральное государственное унитарное предприятие "Центральный институт авиационного моторостроения им. П.И. Баранова" | Камера сгорания |
| EP1482246A1 (fr) * | 2003-05-30 | 2004-12-01 | Siemens Aktiengesellschaft | Chambre de combustion |
| EP1486730A1 (fr) * | 2003-06-11 | 2004-12-15 | Siemens Aktiengesellschaft | Elément de bouclier thermique |
| EP1507116A1 (fr) * | 2003-08-13 | 2005-02-16 | Siemens Aktiengesellschaft | Ensemble bouclier thermique pour un composant acheminant un gaz chaud, notamment pour une chambre de combustion de turbine à gaz |
| US7363763B2 (en) * | 2003-10-23 | 2008-04-29 | United Technologies Corporation | Combustor |
| GB0425794D0 (en) * | 2004-11-24 | 2004-12-22 | Rolls Royce Plc | Acoustic damper |
| EP1715249A1 (fr) * | 2005-04-19 | 2006-10-25 | Siemens Aktiengesellschaft | Elément de bouclier thermique et chambre de combustion avec un bouclier thermique |
| ATE509236T1 (de) * | 2007-10-26 | 2011-05-15 | Siemens Ag | Stützring für hitzeschildelemente eines flammenrohrs und eine brennkammeranordnung mit einem derartigen stützring |
| EP2182285A1 (fr) * | 2008-10-29 | 2010-05-05 | Siemens Aktiengesellschaft | Pièce du brûleur pour une chambre de combustion d'une turbine à gaz et turbine à gaz |
| US8281601B2 (en) * | 2009-03-20 | 2012-10-09 | General Electric Company | Systems and methods for reintroducing gas turbine combustion bypass flow |
| US9416970B2 (en) * | 2009-11-30 | 2016-08-16 | United Technologies Corporation | Combustor heat panel arrangement having holes offset from seams of a radially opposing heat panel |
| US8499566B2 (en) * | 2010-08-12 | 2013-08-06 | General Electric Company | Combustor liner cooling system |
| EP2960436B1 (fr) * | 2014-06-27 | 2017-08-09 | Ansaldo Energia Switzerland AG | Structure de refroidissement pour un conduit de transition d'une turbine à gaz |
| DE102015205975A1 (de) * | 2015-04-02 | 2016-10-06 | Siemens Aktiengesellschaft | Umführungs-Hitzeschildelement |
-
2012
- 2012-03-15 DE DE102012204103A patent/DE102012204103A1/de not_active Ceased
-
2013
- 2013-03-12 US US14/384,257 patent/US20150027128A1/en not_active Abandoned
- 2013-03-12 EP EP13712711.4A patent/EP2809994B1/fr not_active Not-in-force
- 2013-03-12 CN CN201380013709.9A patent/CN104169648B/zh not_active Expired - Fee Related
- 2013-03-12 WO PCT/EP2013/055007 patent/WO2013135702A2/fr not_active Ceased
- 2013-03-12 RU RU2014141355A patent/RU2622590C2/ru not_active IP Right Cessation
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2013135702A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013135702A3 (fr) | 2013-11-14 |
| RU2014141355A (ru) | 2016-05-10 |
| EP2809994B1 (fr) | 2016-05-04 |
| WO2013135702A2 (fr) | 2013-09-19 |
| US20150027128A1 (en) | 2015-01-29 |
| CN104169648A (zh) | 2014-11-26 |
| DE102012204103A1 (de) | 2013-09-19 |
| RU2622590C2 (ru) | 2017-06-16 |
| CN104169648B (zh) | 2016-03-02 |
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Legal Events
| Date | Code | Title | Description |
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