EP2873523B1 - Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication - Google Patents

Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication Download PDF

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Publication number
EP2873523B1
EP2873523B1 EP13192704.8A EP13192704A EP2873523B1 EP 2873523 B1 EP2873523 B1 EP 2873523B1 EP 13192704 A EP13192704 A EP 13192704A EP 2873523 B1 EP2873523 B1 EP 2873523B1
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Prior art keywords
group
substituted
layer
board according
wooden board
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German (de)
English (en)
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EP2873523A1 (fr
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Norbert Dr. Kalwa
Andreas Dr. Gier
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Flooring Technologies Ltd
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Flooring Technologies Ltd
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Priority to PL13192704T priority Critical patent/PL2873523T3/pl
Priority to ES13192704.8T priority patent/ES2625704T3/es
Priority to PT131927048T priority patent/PT2873523T/pt
Priority to EP13192704.8A priority patent/EP2873523B1/fr
Publication of EP2873523A1 publication Critical patent/EP2873523A1/fr
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Publication of EP2873523B1 publication Critical patent/EP2873523B1/fr
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/24Pressing or stamping ornamental designs on surfaces

Definitions

  • the present invention relates to a wood-based panel according to the preamble of claim 1 and a method for its production according to claim 14.
  • Laminate flooring has become established in the global flooring market over the past twenty years, although there is still no saturation in many submarkets. This success and the high acceptance of laminate flooring is based above all on the good property profile and the possibility of imitation of wooden floors. Another positive aspect is that the covering is predominantly made of wood and thus has ecological advantages over many other floor coverings.
  • laminate floors also have some drawbacks that relate in part to the backing plate and partly to the surface.
  • the surface of laminate floors usually consists of a cured synthetic resin.
  • This resin is typically a melamine-formaldehyde resin from which, among other things, utensils such as crockery and cutlery are made.
  • a surface of melamine resin is particularly criticized that it feels hard and cold when walking or when touching. This phenomenon is caused by other plastics - high thermal conductivity.
  • the present invention is therefore based on the object to provide a provided with a resin layer wood material panel, in particular in the form of a laminate floor, with a user-improved feel. In doing so, previous positive product characteristics should be changed as little as possible and no significant technical or financial expenditures should be necessary.
  • a mixture of silanes of the general formula (I) can also be used.
  • the radical X is advantageously selected from a group comprising fluorine, chlorine, bromine, iodine, C 1-6 -alkoxy, in particular methoxy, ethoxy, n-propoxy and butoxy, C 6-10 -aryloxy, in particular phenoxy, C 2-7 -Acyloxy, in particular acetoxy or propionoxy, C 2-7 alkylcarbonyl, in particular acetyl, monoalkylamino or dialkylamino with C 1 to C 12 , in particular C 1 to C 6 .
  • Particularly preferred hydrolyzable groups are C 1-4 alkoxy groups, especially methoxy and ethoxy.
  • non-hydrolyzable organic radical is to be understood as meaning an organic radical which does not lead to the formation of an OH group or NH 2 group linked to the Si atom in the presence of water.
  • the nonhydrolyzable radical R 1 is preferably selected from a group comprising substituted C 1 -C 30 -alkyl, in particular C 5 -C 25 -alkyl, and substituted C 3 -C 8 -cycloalkyl.
  • radical R 1 is selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, s-butyl, t-butyl, pentyl, hexyl and cyclohexyl, preferably methyl, ethyl or propyl.
  • the at least one functional group Q 1 which may be contained in the organic non-hydrolyzable group, preferably includes an amino group, a monoalkylamino group or substituted or unsubstituted silyl group, an aryl group, especially a phenyl group, and a hydroxy group.
  • Typical compounds of general formula (I) which can be used in the primer layer are e.g. Bis (3-trimethoxysilylpropyl) amine, aminopropyltrimethoxysilane, aminopropyltriethoxysilane, 3-aminopropylmethyldimethoxysilane, 3-aminopropylmethyldiethoxysilane, N- (n-butyl) -3-aminopropyltrimethoxysilane, N- (n-butyl) - 3-aminopropyltriethoxysilane, aminoethylaminopropyltrimethoxysilane or aminoethylaminopropyltriethoxysilane.
  • Bis (3-trimethoxysilylpropyl) amine aminopropyltrimethoxysilane, aminopropyltriethoxysilane, 3-aminopropylmethyldimethoxysilane, 3-aminopropylmethyldiethoxysi
  • the primer layer is preferably applied to a resin layer of a conventionally produced wood-based panel.
  • the resin layer can - but does not necessarily have to be sanded - before applying the primer layer; this depends on the nature of the resin layer.
  • the advantage of sanding the resin layer prior to application of the primer layer is improved adhesion of the primer layer to the resin layer.
  • the resin layer is composed of a formaldehyde resin as a polycondensate, in particular a melamine-formaldehyde resin, a melamine-urea-formaldehyde resin or urea-formaldehyde resin.
  • the resin layer can be arranged directly or directly on the surface of the carrier plate.
  • the resin layer can also be applied to a decor paper, which in turn is arranged on the support plate. It is also conceivable that the resin layer is applied to a directly on the support plate printed decor layer.
  • the resin layer may have various additives such as natural or synthetic fibers, flame retardants, dyes or abrasion-resistant particles. In general, various variants of the resin layer provided on the carrier plate are conceivable.
  • a particularly good adhesion of the primer layer to the resin layer is effected, which is particularly caused by the specific substituents.
  • the OH group may undergo a preferential interaction with the matrix of the resin layer.
  • a mixture of silanes of the general formula (II) can also be used.
  • the non-hydrolyzable radical R 2 is preferably selected from a group comprising substituted C 1 -C 30 -alkyl, in particular C 5 -C 25 -alkyl, substituted-substituted C 2 -C 6 -alkenyl, substituted C 3 -C 8 -cycloalkyl and substituted substituted C 3 -C 8 cycloalkenyl.
  • nonhydrolyzable R 2 is selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, s-butyl, t-butyl, pentyl, hexyl, cyclohexyl, vinyl, 1 Propenyl, 2-propenyl, butenyl, acetylenyl, propargyl, substituted substituted butadienyl or substituted cyclohexadienyl, preferably methyl, ethyl, propyl or vinyl.
  • the at least one functional group Q 2 which may be contained in the radical R 2 , advantageously comprises an acrylic group, acryloxy group, methacrylic group or a methacryloxy group, an epoxide, preferably a 1,2-epoxyethyl group, a glycidyl or glycidyloxy group , and / or an isocyano group.
  • the functional group Q 2 accordingly advantageously has a radical with a double bond or an epoxide group which can be activated and polymerized by means of UV radiation. This allows hardening of the topcoat layer by means of UV irradiation.
  • Typical compounds of general formula (II) which may be used in the topcoat layer are methacryloxypropyltrimethoxysilane (MPTS), aminoethylaminopropyltrimethoxysilane, silanes having an epoxy functionalization such as glycidyloxypropyltriethoxysilane, or silanes having a vinylfunctionalization such as e.g. Vinyltrimethoxysilane.
  • MPTS methacryloxypropyltrimethoxysilane
  • aminoethylaminopropyltrimethoxysilane silanes having an epoxy functionalization such as glycidyloxypropyltriethoxysilane
  • silanes having a vinylfunctionalization such as e.g. Vinyltrimethoxysilane.
  • mixtures of silane compounds of the general formula (II) are used in a topcoat layer.
  • nonhydrolyzable groups R 1 and R 2 each have at least one functional group Q 1 or Q 2 .
  • the radicals R 1 and R 2 may also be substituted by further radicals.
  • substituted when used with “alkyl”, “alkenyl”, “aryl”, etc., refers to the substitution of one or more atoms, usually H atoms, by one or more of the following substituents, preferably by one or two of the following substituents: halogen, hydroxy, protected hydroxy, oxo, protected oxo, C 3 -C 7 cycloalkyl, bicyclic alkyl, phenyl, naphthyl, amino, protected amino, monosubstituted amino, protected monosubstituted amino, disubstituted amino, guanidino, protected guanidino, a heterocyclic ring, a substituted heterocyclic ring, imidazolyl, indolyl, pyrrolidinyl, C 1 -C 12 alkoxy, C 1 -C 12 acyl, C 1 -C 12 acyloxy, acryloyloxy, nitro, carboxy, protected carboxy
  • alkynyl as used herein preferably denotes a radical of the formula RC ⁇ C-, in particular a "C 2 -C 6 -alkynyl".
  • C 2 -C 6 alkynyls include ethynyl, propynyl, 2-butynyl, 2-pentynyl, 3-pentynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, vinyl and di- and tri- ines of straight ones and branched alkyl chains.
  • aryl as used herein preferably refers to aromatic hydrocarbons, for example, phenyl, benzyl, naphthyl, or anthryl. Substituted aryl groups are aryl groups which are substituted with one or more substituents as defined above.
  • cycloalkyl preferably includes the groups cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl.
  • cycloalkenyl preferably includes substituted or unsubstituted cyclic groups such as cyclopentenyl or cyclohexenyl. Also, the term “cycloalkenyl” covers cyclic groups having conjugated double bonds such as cyclohexadienes.
  • alkenyl in the context of the present applications comprises groups having one or more double bonds, wherein the double bonds may also be present in conjugated form, such as e.g. Butadiene.
  • the present wood-based panel has no so-called polishing effects, which typically occur in the production or use of very matt surfaces.
  • Polishing effects for example in the form of shiny spots, occur, for example, when cleaning conventional matt surfaces with a soft cloth (polishing) or when sliding furniture with felt glides over a floor covering with a corresponding surface.
  • These glossy spots can no longer be removed and, in addition to the matte surface of the surface of the utility object, are particularly easily recognizable, as a result of which the visual impression of the product is very damaged.
  • conventional matte surfaces have not been able to secure any relevant market share in the past, although the surface has been found to be haptic as well as soft general impression is perceived as very pleasant. It is all the more surprising that such polishing effects do not occur in the case of the present wood-based panel.
  • the preferably used particles have a size between 2 and 400 nm, preferably between 2 to 100 nm, particularly preferably between 2 to 50 nm.
  • the particles can be of oxidic, hydroxidic or oxihydroxide nature, which can be produced by different processes, for example ion exchange process, plasma process, sol-gel process, grinding or also flame deposition.
  • particles based on SiO 2 , Al 2 O 3 , ZrO 2 , TiO 2 , SnO are used, with SiO 2 particles being very particularly preferred.
  • the nanoparticles used in the present case may have a specific surface area of from 50 to 500 m 2 / g, preferably from 100 to 400 m 2 / g, particularly preferably from 200 to 300 m 2 / g.
  • the specific surface area was determined by adsorption of nitrogen by the BET method of Brunauer, Emmett and Teller.
  • wear-inhibiting particles can also be added to the paint. These can u. a. consist of alumina (corundum), carbides, etc. It is important that the size of the particles is matched to the order quantity of the topcoat.
  • the size of the anti-wear particles may be in the range between 1 and 20 microns, preferably 5 and 15 microns, more preferably between 7 and 12 microns. and at a layer thickness of the topcoat of z. B. 10 - 12 microns, the anti-wear materials should not exceed particle sizes of 8 - 10 microns. Accordingly, nanoparticles and / or larger abrasion-resistant particles can be contained in the topcoat layer.
  • hydrolysis products of the at least one compound of the general formula (I) in the primer layer and / or the at least one compound of the general formula (II) may be present in the topcoat layer both in the primer layer and in the topcoat layer.
  • Such hydrolysis products are preferably obtainable in the presence of at least one hydrolytically active compound, in particular an acidic compound.
  • the acid-reacting compounds may be selected from the group consisting of saturated or unsaturated mono- and polycarboxylic acids, in particular octadecanoic acid, acrylic acid, methacrylic acid or crotonic acid, dicarbonyl compounds, in particular acetylacetone, or amino acids, organic derivatives of sulfuric acid such as alkyl sulfates or fatty alcohol sulfates, esters of sulfonic acids such as alkylsulfonic acids and alkylsulfonates, p-toluenesulfonic acid, organic phosphates such as (alkyl) ethoxylated phosphoric acids or lecithin, polyacids, in particular polyhydroxyaspartic acid and polyhydroxystearic acid.
  • saturated or unsaturated mono- and polycarboxylic acids in particular octadecanoic acid, acrylic acid, methacrylic acid or crotonic acid, dicarbonyl compounds, in particular acety
  • an alkaline reacting compound is preferably selected from the group consisting of mono- and polyamines, in particular methylamine, or ethylenediamine, ammonia, alkali metal and alkaline earth metal hydroxides, in particular NaOH or KOH.
  • hydrolytically active compound in one embodiment, more than one hydrolytically active compound is employed, with the use of two acids being preferred.
  • a carrier plate a plate made of a wood material or plastic or a wood-plastic mixture can be used, in particular a chip, medium-density fiber (MDF), high-density fiber (HDF) - or coarse chip (OSB) - or plywood panels, a Cement fiber board and / or gypsum fiber board.
  • MDF medium-density fiber
  • HDF high-density fiber
  • OSB coarse chip
  • the material plate may comprise at least one decorative layer and / or at least one sound-insulating layer.
  • the decorative layer is preferably provided between the carrier plate and the resin layer.
  • the decors for the upper surfaces of the carrier plates can be printed on a paper layer or directly on the plate-shaped base. Such decors are for example wood or stone imitations. Fantasy decors are also possible. These can result, for example, from modifications of natural materials.
  • the sound insulating layer is preferably disposed on the underside of the support plate opposite to the resin layer.
  • sound-insulating layers come networked PE mats with thicknesses of 1.0 mm or 0.3 to 3 mm thick filled heavy foils, but also foamed PE or PU foils for use.
  • pigments such as color pigment or the like, are contained in the topcoat layer.
  • a further modification of the topcoat layer may consist in introducing structures such as depressions or elevations into the topcoat layer.
  • Such structures can be produced with structured application rollers in the topcoat layer, which can be adapted to the decors used if necessary and / or desired.
  • Such methods for structuring surfaces are, for example, from EP 2 251 501 B1 known.
  • the wood-based panel according to the present invention can be used as a floor panel but also as a wall panel, ceiling panel or furniture panel due to the improved feel.
  • the resin layer arranged on the carrier plate is ground before the application of the primer layer.
  • the sanding can be done using a sanding machine with e.g. an 80 grit take place.
  • the grain of the grinding machine is dependent on the properties (thickness, composition) of the resin layer and adjusted accordingly.
  • the cleaning of the ground resin layer can be carried out by conventional methods, e.g. done with a brush.
  • Solvents are especially suitable alcohols such as methanol, ethanol, propanol and butanol.
  • the application of the primer layer can be done with a roll coater or by any other known method.
  • the primer layer is then dried or flashed off at room temperature. This process can be assisted by using an IR emitter.
  • the topcoat layer containing at least one of the silane compounds of the general formula (II) is then applied to the primer layer in an amount of 5 to 30 g / m 2 , preferably 10 to 20 g / m 2 , particularly preferably 10 to 15 g / m 2 .
  • solvents such as methanol, ethanol, propanol and butanol.
  • the application of the topcoat can also be done with the aid of a roll coater or other known application methods.
  • the topcoat nanoparticles may be blended into the topcoat layer to adjust the level of gloss.
  • the nanoparticles can be mixed in an amount of 5 to 30% by weight, preferably 10 to 20% by weight, particularly preferably 15% by weight, based on the topcoat layer.
  • the subsequent hardening or curing of the topcoat layer in the next process step takes place by UV irradiation, e.g. with a gallium radiator.
  • the present material plate has a number of advantages over the conventional material plates.
  • the primer used contains a small amount of solvent, which is acceptable due to the low application rate.
  • the topcoat is a UV system which can be adjusted to different gloss levels by adding matting agents.
  • Another key benefit of the present process is that products with slightly defective resin surfaces or non-salable surfaces can be inexpensively converted into new products.
  • FIG. 1 shows the cross section through an embodiment of the present wood-based panel consisting of a support plate 1 with a provided on top of the support plate 1 resin layer 2.
  • the resin layer 2 may be, for example, a melamine-formaldehyde resin layer, directly on the support plate or on one on the support plate glued decorative paper is applied. It is also possible for a sound-absorbing layer to be applied to the underside of the carrier plate 1 (not shown).
  • a primer layer 3 containing at least one silane compound of the general formula (I) is applied followed by a topcoat layer 4 containing at least one silane compound of the general formula (II).
  • a topcoat layer 4 containing at least one silane compound of the general formula (II) In the topcoat layer 4 structures 5 can be embossed.
  • a primer (Inosil HP17 from Inomat GmbH) was applied in an amount of about 5 g / m 2 (liquid).
  • This primer contains an acidolysis product of bis (3-trimethoxysilyl-propyl) amine and p-toluenesulfonic acid.
  • This UV varnish consists essentially of a reaction or hydrolysis product of methacryloxypropyltrimethoxysilane (MPTS) and aminoethylaminopropyltrimethoxysilane.
  • a matting agent (Siloid 244) in an amount of about 15% by weight, based on the paint, was added.
  • the paint is cured by means of a UV lamp (gallium radiator, power: 80 watts / cm).
  • a crosshatch test (DIN EN ISO 2409) was carried out on the surface painted and cured in this way. In this case, the level 0 was reached which represents the best result according to this test.
  • a gloss measurement (DIN EN ISO 2813, measuring angle: 85 °) averaged a value of 3.5. By varying the amount of matting agent in the topcoat also other gloss levels are possible.

Landscapes

  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Claims (15)

  1. Panneau en matériau à base de bois présentant une surface matte, qui ne présente pas d'effets de repolissage, comprenant au moins un panneau support (1) et au moins une couche de résine (2) disposée sur au moins une face du panneau support, caractérisé en ce qu'au moins une couche d'apprêt (3) est disposée sur ladite au moins une couche de résine (2), ladite au moins une couche d'apprêt (3) présentant au moins un composé de formule générale (I)

            R1 aSiX(4-a)     (I),

    et/ou son produit d'hydrolyse, dans laquelle
    - X représente H, OH ou un radical hydrolysable, choisi dans le groupe comprenant halogène, alcoxy, carboxy, amino, monoalkylamino ou dialkylamino, aryloxy, acyloxy, alkylcarbonyle,
    - R1 représente un radical organique non hydrolysable, R1 étant choisi dans le groupe comprenant alkyle substitué, cycloalkyle substitué, qui peuvent être interrompus par -O- ou -NH-, et
    - R1 présentant au moins un groupe fonctionnel Q1, qui est choisi dans un groupe contenant les groupes silyle, aryle, hydroxy, éther, amino, monoalkylamino, dialkylamino, anilino substitué et non substitué, amide, carboxy, mercapto, alcoxy, aldéhyde et alkylcarbonyle, et
    - a = 1, 2, 3, en particulier 1 ou 2, et
    au moins une couche en laque de recouvrement (4) étant disposée sur ladite au moins une couche d'apprêt (3), ladite au moins une laque de recouvrement (4) présentant au moins un composé de formule générale (II)

            R2 aSiX(4-a)     (II),

    et/ou son produit d'hydrolyse, dans laquelle
    - X représente H, OH ou un radical hydrolysable, choisi dans le groupe comprenant halogène, alcoxy, carboxy, amino, monoalkylamino ou dialkylamino, aryloxy, acyloxy, alkylcarbonyle,
    - R2 représente un radical organique non hydrolysable, R2 étant choisi dans le groupe comprenant alkyle substitué, aryle substitué, alcényle substitué et, alcynyle substitué, cycloalkyle substitué, cycloalcényle substitué, qui peuvent être interrompus par -O- ou -NH-, et
    - R2 présentant au moins un groupe fonctionnel Q2 qui est choisi dans un groupe contenant les groupes époxyde, alcényle, alcynyle, acryle, acryloxy, méthacryle, méthacryloxy, cyano et isocyano et
    - a = 1, 2, 3, en particulier 1 ou 2.
  2. Panneau en matériau à base de bois selon la revendication 1, caractérisé en ce que X est choisi dans le groupe contenant fluor, chlore, brome, iode, C1-6-alcoxy, en particulier méthoxy, éthoxy, n-propoxy et butoxy, C6-10-aryloxy, en particulier phénoxy, C2-7-acyloxy, en particulier acétoxy ou propionoxy, C2-7-alkylcarbonyle, en particulier acétyle, monoalkylamino ou dialkylamino en C1 à C12, en particulier en C1 à C6.
  3. Panneau en matériau à base de bois selon la revendication 1 ou 2, caractérisé en ce que R1 est choisi dans un groupe comprenant C1-C30-alkyle substitué, en particulier C5-C25-alkyle, et C3-C8-cycloalkyle substitué.
  4. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que R1 est choisi dans le groupe contenant méthyle, éthyle, n-propyle, isopropyle, n-butyle, s-butyle, t-butyle, pentyle, hexyle et cyclohexyle, de préférence méthyle, éthyle ou propyle.
  5. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que le groupe fonctionnel Q1 est un groupe amino, un groupe monoalkylamino, de préférence un groupe propylamino, un groupe butylamino, un groupe aminoéthylamino ou un groupe silylpropylamino, un groupe aryle, en particulier un groupe phényle, et un groupe hydroxy.
  6. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que R2 est choisi dans un groupe comprenant C1-C30-alkyle substitué, en particulier C5-C25-alkyle, C2-C6-alcényle substitué, C3-C8-cycloalkyle substitué et C3-C8-cycloalcényle substitué.
  7. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que R2 est choisi dans le groupe contenant méthyle, éthyle, n-propyle, isopropyle, n-butyle, s-butyle, t-butyle, pentyle, hexyle, cyclohexyle, vinyle, 1-propényle, 2-propényle, butényle, acétylényle, propargyle, butadiényle substitué ou cyclohexadiényle substitué, de préférence méthyle, éthyle, propyle ou vinyle.
  8. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que le groupe fonctionnel Q2 est un groupe acryle, un groupe acryloxy, un groupe méthacryle ou un groupe méthacryloxy, un groupe époxyde, de préférence un groupe 1,2-époxyéthyle, un groupe glycidyle ou un groupe glycidyloxy et/ou un groupe isocyano.
  9. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que ladite au moins une couche de laque de recouvrement (4) peut contenir des nanoparticules présentant une grosseur entre 2 et 400 nm, de préférence entre 2 à 100 nm, en particulier de préférence entre 2 à 50 nm.
  10. Panneau en matériau à base de bois selon la revendication 9, caractérisé en ce que les nanoparticules sont des nanoparticules oxydes, hydroxydes ou oxyhydroxydes, en particulier à base de SiO2, Al2O3, ZrO2, TiO2, SnO.
  11. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que le produit d'hydrolyse dudit au moins un composé de formule générale (I) dans la couche d'apprêt (3) et/ou dudit au moins un composé de formule générale (II) dans la couche de laque de recouvrement (4) peut être obtenu en présence d'au moins un composé à effet hydrolytique, en particulier d'un composé à réaction acide.
  12. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que la couche de résine (2) est constituée par une résine de formaldéhyde, en particulier par une résine de mélamine-formaldéhyde, par une résine de mélamine-urée-formaldéhyde ou par une résine de urée-formaldéhyde.
  13. Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce qu'au moins une couche décorative est prévue entre le panneau support (1) et la couche de résine (2).
  14. Procédé pour la préparation d'un panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, comprenant les étapes de :
    - application de ladite au moins une couche d'apprêt (3) sur la couche de résine (2) durcie disposée sur au moins une face du panneau support ;
    - application de ladite au moins une couche de laque de recouvrement (4) sur la couche d'apprêt (4) ;
    - addition de nanoparticules à la couche de laque de recouvrement pour le réglage d'un degré de brillance, et
    - durcissement de la couche de laque de recouvrement par irradiation aux UV.
  15. Procédé selon la revendication 14, caractérisé en ce que la couche de résine (2) est poncée avant l'application de la couche d'apprêt (3).
EP13192704.8A 2013-11-13 2013-11-13 Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication Active EP2873523B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PL13192704T PL2873523T3 (pl) 2013-11-13 2013-11-13 Płyta z tworzywa drzewnego o zmodyfikowanej powierzchni i sposób jej produkcji
ES13192704.8T ES2625704T3 (es) 2013-11-13 2013-11-13 Placa de material derivado de la madera con superficie modificada y procedimiento para su fabricación
PT131927048T PT2873523T (pt) 2013-11-13 2013-11-13 Placa de material à base de madeira com superfície modificada e processo para a sua preparação
EP13192704.8A EP2873523B1 (fr) 2013-11-13 2013-11-13 Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication

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EP13192704.8A EP2873523B1 (fr) 2013-11-13 2013-11-13 Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication

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EP2873523A1 EP2873523A1 (fr) 2015-05-20
EP2873523B1 true EP2873523B1 (fr) 2017-04-12

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
US11292926B2 (en) 2019-04-02 2022-04-05 Flooring Technologies Ltd. Impregnate with antistatic properties
US11597188B2 (en) * 2019-04-02 2023-03-07 Flooring Technologies Ltd. Wooden composite board with antistatic properties

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL3231596T3 (pl) * 2016-04-12 2019-04-30 SWISS KRONO Tec AG Materiał nośny ze zmodyfikowaną warstwą żywicy i jego produkcja
EP3231597B1 (fr) * 2016-04-12 2018-08-22 Flooring Technologies Ltd. Panneau en bois, particulièrement du type planchéiage, et un procédé pour sa production.
PT3878648T (pt) 2020-03-11 2022-06-07 Flooring Technologies Ltd Material laminado com uma película termoplástica para utilização num painel de pavimento e um processo para a sua produção
EP3964553B1 (fr) * 2020-09-03 2023-06-07 SWISS KRONO Tec AG Procédé de fabrication d'un support pourvu d'un revêtement antiviral

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DE3721071C1 (de) * 1987-06-26 1989-01-19 Benecke Gmbh J Verfahren und Vorrichtung zur Herstellung matter Lackoberflaechen
EP2147956A2 (fr) * 2008-07-23 2010-01-27 Flooring Technologies Ltd. Procédé de fabrication de surfaces de laque au moins enclines aux salissures sur des objets, comme des plaques de matière dérivée du bois

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Publication number Priority date Publication date Assignee Title
DE102006002417A1 (de) * 2006-01-18 2007-07-19 Kaindl Flooring Gmbh Verfahren zur Herstellung eines Verkleidungselements
PL2251501T3 (pl) 2009-05-14 2014-02-28 Flooring Technologies Ltd Sposób nanoszenia struktury na powierzchnię wykładziny

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3721071C1 (de) * 1987-06-26 1989-01-19 Benecke Gmbh J Verfahren und Vorrichtung zur Herstellung matter Lackoberflaechen
EP2147956A2 (fr) * 2008-07-23 2010-01-27 Flooring Technologies Ltd. Procédé de fabrication de surfaces de laque au moins enclines aux salissures sur des objets, comme des plaques de matière dérivée du bois

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11292926B2 (en) 2019-04-02 2022-04-05 Flooring Technologies Ltd. Impregnate with antistatic properties
US11597188B2 (en) * 2019-04-02 2023-03-07 Flooring Technologies Ltd. Wooden composite board with antistatic properties
US11623995B2 (en) 2019-04-02 2023-04-11 Flooring Technologies Ltd. Impregnate with antistatic properties

Also Published As

Publication number Publication date
PL2873523T3 (pl) 2017-09-29
EP2873523A1 (fr) 2015-05-20
PT2873523T (pt) 2017-07-06
ES2625704T3 (es) 2017-07-20

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