EP2873523B1 - Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication - Google Patents
Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication Download PDFInfo
- Publication number
- EP2873523B1 EP2873523B1 EP13192704.8A EP13192704A EP2873523B1 EP 2873523 B1 EP2873523 B1 EP 2873523B1 EP 13192704 A EP13192704 A EP 13192704A EP 2873523 B1 EP2873523 B1 EP 2873523B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- group
- substituted
- layer
- board according
- wooden board
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000002023 wood Substances 0.000 title description 20
- 239000002131 composite material Substances 0.000 title 1
- -1 carboxy, amino Chemical group 0.000 claims description 55
- 229920005989 resin Polymers 0.000 claims description 39
- 239000011347 resin Substances 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 18
- 229920000877 Melamine resin Polymers 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 125000000524 functional group Chemical group 0.000 claims description 10
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 125000004663 dialkyl amino group Chemical group 0.000 claims description 9
- 230000007062 hydrolysis Effects 0.000 claims description 9
- 238000006460 hydrolysis reaction Methods 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 125000004423 acyloxy group Chemical group 0.000 claims description 5
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- 125000004104 aryloxy group Chemical group 0.000 claims description 4
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000002462 isocyano group Chemical group *[N+]#[C-] 0.000 claims description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- 125000005346 substituted cycloalkyl group Chemical group 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 4
- 125000000304 alkynyl group Chemical group 0.000 claims description 3
- 125000003107 substituted aryl group Chemical group 0.000 claims description 3
- 125000006017 1-propenyl group Chemical group 0.000 claims description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 claims description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000003678 cyclohexadienyl group Chemical group C1(=CC=CCC1)* 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- HANVTCGOAROXMV-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine;urea Chemical compound O=C.NC(N)=O.NC1=NC(N)=NC(N)=N1 HANVTCGOAROXMV-UHFFFAOYSA-N 0.000 claims description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 2
- 230000003301 hydrolyzing effect Effects 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical class NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000004426 substituted alkynyl group Chemical group 0.000 claims description 2
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004922 lacquer Substances 0.000 claims 7
- 230000003319 supportive effect Effects 0.000 claims 4
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- 229910052681 coesite Inorganic materials 0.000 claims 1
- 229910052906 cristobalite Inorganic materials 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 229910052682 stishovite Inorganic materials 0.000 claims 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(II) oxide Inorganic materials [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 claims 1
- 229910052905 tridymite Inorganic materials 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 239000010410 layer Substances 0.000 description 86
- 239000000463 material Substances 0.000 description 11
- 239000003973 paint Substances 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 239000004640 Melamine resin Substances 0.000 description 9
- 150000004756 silanes Chemical class 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000009408 flooring Methods 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 150000002118 epoxides Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000006224 matting agent Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
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- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- TZZGHGKTHXIOMN-UHFFFAOYSA-N 3-trimethoxysilyl-n-(3-trimethoxysilylpropyl)propan-1-amine Chemical compound CO[Si](OC)(OC)CCCNCCC[Si](OC)(OC)OC TZZGHGKTHXIOMN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 description 1
- KFOZMMAXUUCIKU-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)butan-1-amine Chemical compound CCCCNCCC[Si](OCC)(OCC)OCC KFOZMMAXUUCIKU-UHFFFAOYSA-N 0.000 description 1
- XCOASYLMDUQBHW-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)butan-1-amine Chemical compound CCCCNCCC[Si](OC)(OC)OC XCOASYLMDUQBHW-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 description 1
- 125000000719 pyrrolidinyl group Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000005017 substituted alkenyl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 125000003396 thiol group Chemical class [H]S* 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/24—Pressing or stamping ornamental designs on surfaces
Definitions
- the present invention relates to a wood-based panel according to the preamble of claim 1 and a method for its production according to claim 14.
- Laminate flooring has become established in the global flooring market over the past twenty years, although there is still no saturation in many submarkets. This success and the high acceptance of laminate flooring is based above all on the good property profile and the possibility of imitation of wooden floors. Another positive aspect is that the covering is predominantly made of wood and thus has ecological advantages over many other floor coverings.
- laminate floors also have some drawbacks that relate in part to the backing plate and partly to the surface.
- the surface of laminate floors usually consists of a cured synthetic resin.
- This resin is typically a melamine-formaldehyde resin from which, among other things, utensils such as crockery and cutlery are made.
- a surface of melamine resin is particularly criticized that it feels hard and cold when walking or when touching. This phenomenon is caused by other plastics - high thermal conductivity.
- the present invention is therefore based on the object to provide a provided with a resin layer wood material panel, in particular in the form of a laminate floor, with a user-improved feel. In doing so, previous positive product characteristics should be changed as little as possible and no significant technical or financial expenditures should be necessary.
- a mixture of silanes of the general formula (I) can also be used.
- the radical X is advantageously selected from a group comprising fluorine, chlorine, bromine, iodine, C 1-6 -alkoxy, in particular methoxy, ethoxy, n-propoxy and butoxy, C 6-10 -aryloxy, in particular phenoxy, C 2-7 -Acyloxy, in particular acetoxy or propionoxy, C 2-7 alkylcarbonyl, in particular acetyl, monoalkylamino or dialkylamino with C 1 to C 12 , in particular C 1 to C 6 .
- Particularly preferred hydrolyzable groups are C 1-4 alkoxy groups, especially methoxy and ethoxy.
- non-hydrolyzable organic radical is to be understood as meaning an organic radical which does not lead to the formation of an OH group or NH 2 group linked to the Si atom in the presence of water.
- the nonhydrolyzable radical R 1 is preferably selected from a group comprising substituted C 1 -C 30 -alkyl, in particular C 5 -C 25 -alkyl, and substituted C 3 -C 8 -cycloalkyl.
- radical R 1 is selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, s-butyl, t-butyl, pentyl, hexyl and cyclohexyl, preferably methyl, ethyl or propyl.
- the at least one functional group Q 1 which may be contained in the organic non-hydrolyzable group, preferably includes an amino group, a monoalkylamino group or substituted or unsubstituted silyl group, an aryl group, especially a phenyl group, and a hydroxy group.
- Typical compounds of general formula (I) which can be used in the primer layer are e.g. Bis (3-trimethoxysilylpropyl) amine, aminopropyltrimethoxysilane, aminopropyltriethoxysilane, 3-aminopropylmethyldimethoxysilane, 3-aminopropylmethyldiethoxysilane, N- (n-butyl) -3-aminopropyltrimethoxysilane, N- (n-butyl) - 3-aminopropyltriethoxysilane, aminoethylaminopropyltrimethoxysilane or aminoethylaminopropyltriethoxysilane.
- Bis (3-trimethoxysilylpropyl) amine aminopropyltrimethoxysilane, aminopropyltriethoxysilane, 3-aminopropylmethyldimethoxysilane, 3-aminopropylmethyldiethoxysi
- the primer layer is preferably applied to a resin layer of a conventionally produced wood-based panel.
- the resin layer can - but does not necessarily have to be sanded - before applying the primer layer; this depends on the nature of the resin layer.
- the advantage of sanding the resin layer prior to application of the primer layer is improved adhesion of the primer layer to the resin layer.
- the resin layer is composed of a formaldehyde resin as a polycondensate, in particular a melamine-formaldehyde resin, a melamine-urea-formaldehyde resin or urea-formaldehyde resin.
- the resin layer can be arranged directly or directly on the surface of the carrier plate.
- the resin layer can also be applied to a decor paper, which in turn is arranged on the support plate. It is also conceivable that the resin layer is applied to a directly on the support plate printed decor layer.
- the resin layer may have various additives such as natural or synthetic fibers, flame retardants, dyes or abrasion-resistant particles. In general, various variants of the resin layer provided on the carrier plate are conceivable.
- a particularly good adhesion of the primer layer to the resin layer is effected, which is particularly caused by the specific substituents.
- the OH group may undergo a preferential interaction with the matrix of the resin layer.
- a mixture of silanes of the general formula (II) can also be used.
- the non-hydrolyzable radical R 2 is preferably selected from a group comprising substituted C 1 -C 30 -alkyl, in particular C 5 -C 25 -alkyl, substituted-substituted C 2 -C 6 -alkenyl, substituted C 3 -C 8 -cycloalkyl and substituted substituted C 3 -C 8 cycloalkenyl.
- nonhydrolyzable R 2 is selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, s-butyl, t-butyl, pentyl, hexyl, cyclohexyl, vinyl, 1 Propenyl, 2-propenyl, butenyl, acetylenyl, propargyl, substituted substituted butadienyl or substituted cyclohexadienyl, preferably methyl, ethyl, propyl or vinyl.
- the at least one functional group Q 2 which may be contained in the radical R 2 , advantageously comprises an acrylic group, acryloxy group, methacrylic group or a methacryloxy group, an epoxide, preferably a 1,2-epoxyethyl group, a glycidyl or glycidyloxy group , and / or an isocyano group.
- the functional group Q 2 accordingly advantageously has a radical with a double bond or an epoxide group which can be activated and polymerized by means of UV radiation. This allows hardening of the topcoat layer by means of UV irradiation.
- Typical compounds of general formula (II) which may be used in the topcoat layer are methacryloxypropyltrimethoxysilane (MPTS), aminoethylaminopropyltrimethoxysilane, silanes having an epoxy functionalization such as glycidyloxypropyltriethoxysilane, or silanes having a vinylfunctionalization such as e.g. Vinyltrimethoxysilane.
- MPTS methacryloxypropyltrimethoxysilane
- aminoethylaminopropyltrimethoxysilane silanes having an epoxy functionalization such as glycidyloxypropyltriethoxysilane
- silanes having a vinylfunctionalization such as e.g. Vinyltrimethoxysilane.
- mixtures of silane compounds of the general formula (II) are used in a topcoat layer.
- nonhydrolyzable groups R 1 and R 2 each have at least one functional group Q 1 or Q 2 .
- the radicals R 1 and R 2 may also be substituted by further radicals.
- substituted when used with “alkyl”, “alkenyl”, “aryl”, etc., refers to the substitution of one or more atoms, usually H atoms, by one or more of the following substituents, preferably by one or two of the following substituents: halogen, hydroxy, protected hydroxy, oxo, protected oxo, C 3 -C 7 cycloalkyl, bicyclic alkyl, phenyl, naphthyl, amino, protected amino, monosubstituted amino, protected monosubstituted amino, disubstituted amino, guanidino, protected guanidino, a heterocyclic ring, a substituted heterocyclic ring, imidazolyl, indolyl, pyrrolidinyl, C 1 -C 12 alkoxy, C 1 -C 12 acyl, C 1 -C 12 acyloxy, acryloyloxy, nitro, carboxy, protected carboxy
- alkynyl as used herein preferably denotes a radical of the formula RC ⁇ C-, in particular a "C 2 -C 6 -alkynyl".
- C 2 -C 6 alkynyls include ethynyl, propynyl, 2-butynyl, 2-pentynyl, 3-pentynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, vinyl and di- and tri- ines of straight ones and branched alkyl chains.
- aryl as used herein preferably refers to aromatic hydrocarbons, for example, phenyl, benzyl, naphthyl, or anthryl. Substituted aryl groups are aryl groups which are substituted with one or more substituents as defined above.
- cycloalkyl preferably includes the groups cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl.
- cycloalkenyl preferably includes substituted or unsubstituted cyclic groups such as cyclopentenyl or cyclohexenyl. Also, the term “cycloalkenyl” covers cyclic groups having conjugated double bonds such as cyclohexadienes.
- alkenyl in the context of the present applications comprises groups having one or more double bonds, wherein the double bonds may also be present in conjugated form, such as e.g. Butadiene.
- the present wood-based panel has no so-called polishing effects, which typically occur in the production or use of very matt surfaces.
- Polishing effects for example in the form of shiny spots, occur, for example, when cleaning conventional matt surfaces with a soft cloth (polishing) or when sliding furniture with felt glides over a floor covering with a corresponding surface.
- These glossy spots can no longer be removed and, in addition to the matte surface of the surface of the utility object, are particularly easily recognizable, as a result of which the visual impression of the product is very damaged.
- conventional matte surfaces have not been able to secure any relevant market share in the past, although the surface has been found to be haptic as well as soft general impression is perceived as very pleasant. It is all the more surprising that such polishing effects do not occur in the case of the present wood-based panel.
- the preferably used particles have a size between 2 and 400 nm, preferably between 2 to 100 nm, particularly preferably between 2 to 50 nm.
- the particles can be of oxidic, hydroxidic or oxihydroxide nature, which can be produced by different processes, for example ion exchange process, plasma process, sol-gel process, grinding or also flame deposition.
- particles based on SiO 2 , Al 2 O 3 , ZrO 2 , TiO 2 , SnO are used, with SiO 2 particles being very particularly preferred.
- the nanoparticles used in the present case may have a specific surface area of from 50 to 500 m 2 / g, preferably from 100 to 400 m 2 / g, particularly preferably from 200 to 300 m 2 / g.
- the specific surface area was determined by adsorption of nitrogen by the BET method of Brunauer, Emmett and Teller.
- wear-inhibiting particles can also be added to the paint. These can u. a. consist of alumina (corundum), carbides, etc. It is important that the size of the particles is matched to the order quantity of the topcoat.
- the size of the anti-wear particles may be in the range between 1 and 20 microns, preferably 5 and 15 microns, more preferably between 7 and 12 microns. and at a layer thickness of the topcoat of z. B. 10 - 12 microns, the anti-wear materials should not exceed particle sizes of 8 - 10 microns. Accordingly, nanoparticles and / or larger abrasion-resistant particles can be contained in the topcoat layer.
- hydrolysis products of the at least one compound of the general formula (I) in the primer layer and / or the at least one compound of the general formula (II) may be present in the topcoat layer both in the primer layer and in the topcoat layer.
- Such hydrolysis products are preferably obtainable in the presence of at least one hydrolytically active compound, in particular an acidic compound.
- the acid-reacting compounds may be selected from the group consisting of saturated or unsaturated mono- and polycarboxylic acids, in particular octadecanoic acid, acrylic acid, methacrylic acid or crotonic acid, dicarbonyl compounds, in particular acetylacetone, or amino acids, organic derivatives of sulfuric acid such as alkyl sulfates or fatty alcohol sulfates, esters of sulfonic acids such as alkylsulfonic acids and alkylsulfonates, p-toluenesulfonic acid, organic phosphates such as (alkyl) ethoxylated phosphoric acids or lecithin, polyacids, in particular polyhydroxyaspartic acid and polyhydroxystearic acid.
- saturated or unsaturated mono- and polycarboxylic acids in particular octadecanoic acid, acrylic acid, methacrylic acid or crotonic acid, dicarbonyl compounds, in particular acety
- an alkaline reacting compound is preferably selected from the group consisting of mono- and polyamines, in particular methylamine, or ethylenediamine, ammonia, alkali metal and alkaline earth metal hydroxides, in particular NaOH or KOH.
- hydrolytically active compound in one embodiment, more than one hydrolytically active compound is employed, with the use of two acids being preferred.
- a carrier plate a plate made of a wood material or plastic or a wood-plastic mixture can be used, in particular a chip, medium-density fiber (MDF), high-density fiber (HDF) - or coarse chip (OSB) - or plywood panels, a Cement fiber board and / or gypsum fiber board.
- MDF medium-density fiber
- HDF high-density fiber
- OSB coarse chip
- the material plate may comprise at least one decorative layer and / or at least one sound-insulating layer.
- the decorative layer is preferably provided between the carrier plate and the resin layer.
- the decors for the upper surfaces of the carrier plates can be printed on a paper layer or directly on the plate-shaped base. Such decors are for example wood or stone imitations. Fantasy decors are also possible. These can result, for example, from modifications of natural materials.
- the sound insulating layer is preferably disposed on the underside of the support plate opposite to the resin layer.
- sound-insulating layers come networked PE mats with thicknesses of 1.0 mm or 0.3 to 3 mm thick filled heavy foils, but also foamed PE or PU foils for use.
- pigments such as color pigment or the like, are contained in the topcoat layer.
- a further modification of the topcoat layer may consist in introducing structures such as depressions or elevations into the topcoat layer.
- Such structures can be produced with structured application rollers in the topcoat layer, which can be adapted to the decors used if necessary and / or desired.
- Such methods for structuring surfaces are, for example, from EP 2 251 501 B1 known.
- the wood-based panel according to the present invention can be used as a floor panel but also as a wall panel, ceiling panel or furniture panel due to the improved feel.
- the resin layer arranged on the carrier plate is ground before the application of the primer layer.
- the sanding can be done using a sanding machine with e.g. an 80 grit take place.
- the grain of the grinding machine is dependent on the properties (thickness, composition) of the resin layer and adjusted accordingly.
- the cleaning of the ground resin layer can be carried out by conventional methods, e.g. done with a brush.
- Solvents are especially suitable alcohols such as methanol, ethanol, propanol and butanol.
- the application of the primer layer can be done with a roll coater or by any other known method.
- the primer layer is then dried or flashed off at room temperature. This process can be assisted by using an IR emitter.
- the topcoat layer containing at least one of the silane compounds of the general formula (II) is then applied to the primer layer in an amount of 5 to 30 g / m 2 , preferably 10 to 20 g / m 2 , particularly preferably 10 to 15 g / m 2 .
- solvents such as methanol, ethanol, propanol and butanol.
- the application of the topcoat can also be done with the aid of a roll coater or other known application methods.
- the topcoat nanoparticles may be blended into the topcoat layer to adjust the level of gloss.
- the nanoparticles can be mixed in an amount of 5 to 30% by weight, preferably 10 to 20% by weight, particularly preferably 15% by weight, based on the topcoat layer.
- the subsequent hardening or curing of the topcoat layer in the next process step takes place by UV irradiation, e.g. with a gallium radiator.
- the present material plate has a number of advantages over the conventional material plates.
- the primer used contains a small amount of solvent, which is acceptable due to the low application rate.
- the topcoat is a UV system which can be adjusted to different gloss levels by adding matting agents.
- Another key benefit of the present process is that products with slightly defective resin surfaces or non-salable surfaces can be inexpensively converted into new products.
- FIG. 1 shows the cross section through an embodiment of the present wood-based panel consisting of a support plate 1 with a provided on top of the support plate 1 resin layer 2.
- the resin layer 2 may be, for example, a melamine-formaldehyde resin layer, directly on the support plate or on one on the support plate glued decorative paper is applied. It is also possible for a sound-absorbing layer to be applied to the underside of the carrier plate 1 (not shown).
- a primer layer 3 containing at least one silane compound of the general formula (I) is applied followed by a topcoat layer 4 containing at least one silane compound of the general formula (II).
- a topcoat layer 4 containing at least one silane compound of the general formula (II) In the topcoat layer 4 structures 5 can be embossed.
- a primer (Inosil HP17 from Inomat GmbH) was applied in an amount of about 5 g / m 2 (liquid).
- This primer contains an acidolysis product of bis (3-trimethoxysilyl-propyl) amine and p-toluenesulfonic acid.
- This UV varnish consists essentially of a reaction or hydrolysis product of methacryloxypropyltrimethoxysilane (MPTS) and aminoethylaminopropyltrimethoxysilane.
- a matting agent (Siloid 244) in an amount of about 15% by weight, based on the paint, was added.
- the paint is cured by means of a UV lamp (gallium radiator, power: 80 watts / cm).
- a crosshatch test (DIN EN ISO 2409) was carried out on the surface painted and cured in this way. In this case, the level 0 was reached which represents the best result according to this test.
- a gloss measurement (DIN EN ISO 2813, measuring angle: 85 °) averaged a value of 3.5. By varying the amount of matting agent in the topcoat also other gloss levels are possible.
Landscapes
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Claims (15)
- Panneau en matériau à base de bois présentant une surface matte, qui ne présente pas d'effets de repolissage, comprenant au moins un panneau support (1) et au moins une couche de résine (2) disposée sur au moins une face du panneau support, caractérisé en ce qu'au moins une couche d'apprêt (3) est disposée sur ladite au moins une couche de résine (2), ladite au moins une couche d'apprêt (3) présentant au moins un composé de formule générale (I)
R1 aSiX(4-a) (I),
et/ou son produit d'hydrolyse, dans laquelle- X représente H, OH ou un radical hydrolysable, choisi dans le groupe comprenant halogène, alcoxy, carboxy, amino, monoalkylamino ou dialkylamino, aryloxy, acyloxy, alkylcarbonyle,- R1 représente un radical organique non hydrolysable, R1 étant choisi dans le groupe comprenant alkyle substitué, cycloalkyle substitué, qui peuvent être interrompus par -O- ou -NH-, et- R1 présentant au moins un groupe fonctionnel Q1, qui est choisi dans un groupe contenant les groupes silyle, aryle, hydroxy, éther, amino, monoalkylamino, dialkylamino, anilino substitué et non substitué, amide, carboxy, mercapto, alcoxy, aldéhyde et alkylcarbonyle, et- a = 1, 2, 3, en particulier 1 ou 2, etau moins une couche en laque de recouvrement (4) étant disposée sur ladite au moins une couche d'apprêt (3), ladite au moins une laque de recouvrement (4) présentant au moins un composé de formule générale (II)
R2 aSiX(4-a) (II),
et/ou son produit d'hydrolyse, dans laquelle- X représente H, OH ou un radical hydrolysable, choisi dans le groupe comprenant halogène, alcoxy, carboxy, amino, monoalkylamino ou dialkylamino, aryloxy, acyloxy, alkylcarbonyle,- R2 représente un radical organique non hydrolysable, R2 étant choisi dans le groupe comprenant alkyle substitué, aryle substitué, alcényle substitué et, alcynyle substitué, cycloalkyle substitué, cycloalcényle substitué, qui peuvent être interrompus par -O- ou -NH-, et- R2 présentant au moins un groupe fonctionnel Q2 qui est choisi dans un groupe contenant les groupes époxyde, alcényle, alcynyle, acryle, acryloxy, méthacryle, méthacryloxy, cyano et isocyano et- a = 1, 2, 3, en particulier 1 ou 2. - Panneau en matériau à base de bois selon la revendication 1, caractérisé en ce que X est choisi dans le groupe contenant fluor, chlore, brome, iode, C1-6-alcoxy, en particulier méthoxy, éthoxy, n-propoxy et butoxy, C6-10-aryloxy, en particulier phénoxy, C2-7-acyloxy, en particulier acétoxy ou propionoxy, C2-7-alkylcarbonyle, en particulier acétyle, monoalkylamino ou dialkylamino en C1 à C12, en particulier en C1 à C6.
- Panneau en matériau à base de bois selon la revendication 1 ou 2, caractérisé en ce que R1 est choisi dans un groupe comprenant C1-C30-alkyle substitué, en particulier C5-C25-alkyle, et C3-C8-cycloalkyle substitué.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que R1 est choisi dans le groupe contenant méthyle, éthyle, n-propyle, isopropyle, n-butyle, s-butyle, t-butyle, pentyle, hexyle et cyclohexyle, de préférence méthyle, éthyle ou propyle.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que le groupe fonctionnel Q1 est un groupe amino, un groupe monoalkylamino, de préférence un groupe propylamino, un groupe butylamino, un groupe aminoéthylamino ou un groupe silylpropylamino, un groupe aryle, en particulier un groupe phényle, et un groupe hydroxy.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que R2 est choisi dans un groupe comprenant C1-C30-alkyle substitué, en particulier C5-C25-alkyle, C2-C6-alcényle substitué, C3-C8-cycloalkyle substitué et C3-C8-cycloalcényle substitué.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que R2 est choisi dans le groupe contenant méthyle, éthyle, n-propyle, isopropyle, n-butyle, s-butyle, t-butyle, pentyle, hexyle, cyclohexyle, vinyle, 1-propényle, 2-propényle, butényle, acétylényle, propargyle, butadiényle substitué ou cyclohexadiényle substitué, de préférence méthyle, éthyle, propyle ou vinyle.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que le groupe fonctionnel Q2 est un groupe acryle, un groupe acryloxy, un groupe méthacryle ou un groupe méthacryloxy, un groupe époxyde, de préférence un groupe 1,2-époxyéthyle, un groupe glycidyle ou un groupe glycidyloxy et/ou un groupe isocyano.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que ladite au moins une couche de laque de recouvrement (4) peut contenir des nanoparticules présentant une grosseur entre 2 et 400 nm, de préférence entre 2 à 100 nm, en particulier de préférence entre 2 à 50 nm.
- Panneau en matériau à base de bois selon la revendication 9, caractérisé en ce que les nanoparticules sont des nanoparticules oxydes, hydroxydes ou oxyhydroxydes, en particulier à base de SiO2, Al2O3, ZrO2, TiO2, SnO.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que le produit d'hydrolyse dudit au moins un composé de formule générale (I) dans la couche d'apprêt (3) et/ou dudit au moins un composé de formule générale (II) dans la couche de laque de recouvrement (4) peut être obtenu en présence d'au moins un composé à effet hydrolytique, en particulier d'un composé à réaction acide.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce que la couche de résine (2) est constituée par une résine de formaldéhyde, en particulier par une résine de mélamine-formaldéhyde, par une résine de mélamine-urée-formaldéhyde ou par une résine de urée-formaldéhyde.
- Panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, caractérisé en ce qu'au moins une couche décorative est prévue entre le panneau support (1) et la couche de résine (2).
- Procédé pour la préparation d'un panneau en matériau à base de bois selon l'une quelconque des revendications précédentes, comprenant les étapes de :- application de ladite au moins une couche d'apprêt (3) sur la couche de résine (2) durcie disposée sur au moins une face du panneau support ;- application de ladite au moins une couche de laque de recouvrement (4) sur la couche d'apprêt (4) ;- addition de nanoparticules à la couche de laque de recouvrement pour le réglage d'un degré de brillance, et- durcissement de la couche de laque de recouvrement par irradiation aux UV.
- Procédé selon la revendication 14, caractérisé en ce que la couche de résine (2) est poncée avant l'application de la couche d'apprêt (3).
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL13192704T PL2873523T3 (pl) | 2013-11-13 | 2013-11-13 | Płyta z tworzywa drzewnego o zmodyfikowanej powierzchni i sposób jej produkcji |
| ES13192704.8T ES2625704T3 (es) | 2013-11-13 | 2013-11-13 | Placa de material derivado de la madera con superficie modificada y procedimiento para su fabricación |
| PT131927048T PT2873523T (pt) | 2013-11-13 | 2013-11-13 | Placa de material à base de madeira com superfície modificada e processo para a sua preparação |
| EP13192704.8A EP2873523B1 (fr) | 2013-11-13 | 2013-11-13 | Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13192704.8A EP2873523B1 (fr) | 2013-11-13 | 2013-11-13 | Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2873523A1 EP2873523A1 (fr) | 2015-05-20 |
| EP2873523B1 true EP2873523B1 (fr) | 2017-04-12 |
Family
ID=49641493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13192704.8A Active EP2873523B1 (fr) | 2013-11-13 | 2013-11-13 | Plaque en matière dérivée du bois dotée d'une surface modifiée et son procédé de fabrication |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2873523B1 (fr) |
| ES (1) | ES2625704T3 (fr) |
| PL (1) | PL2873523T3 (fr) |
| PT (1) | PT2873523T (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11292926B2 (en) | 2019-04-02 | 2022-04-05 | Flooring Technologies Ltd. | Impregnate with antistatic properties |
| US11597188B2 (en) * | 2019-04-02 | 2023-03-07 | Flooring Technologies Ltd. | Wooden composite board with antistatic properties |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL3231596T3 (pl) * | 2016-04-12 | 2019-04-30 | SWISS KRONO Tec AG | Materiał nośny ze zmodyfikowaną warstwą żywicy i jego produkcja |
| EP3231597B1 (fr) * | 2016-04-12 | 2018-08-22 | Flooring Technologies Ltd. | Panneau en bois, particulièrement du type planchéiage, et un procédé pour sa production. |
| PT3878648T (pt) | 2020-03-11 | 2022-06-07 | Flooring Technologies Ltd | Material laminado com uma película termoplástica para utilização num painel de pavimento e um processo para a sua produção |
| EP3964553B1 (fr) * | 2020-09-03 | 2023-06-07 | SWISS KRONO Tec AG | Procédé de fabrication d'un support pourvu d'un revêtement antiviral |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3721071C1 (de) * | 1987-06-26 | 1989-01-19 | Benecke Gmbh J | Verfahren und Vorrichtung zur Herstellung matter Lackoberflaechen |
| EP2147956A2 (fr) * | 2008-07-23 | 2010-01-27 | Flooring Technologies Ltd. | Procédé de fabrication de surfaces de laque au moins enclines aux salissures sur des objets, comme des plaques de matière dérivée du bois |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006002417A1 (de) * | 2006-01-18 | 2007-07-19 | Kaindl Flooring Gmbh | Verfahren zur Herstellung eines Verkleidungselements |
| PL2251501T3 (pl) | 2009-05-14 | 2014-02-28 | Flooring Technologies Ltd | Sposób nanoszenia struktury na powierzchnię wykładziny |
-
2013
- 2013-11-13 PT PT131927048T patent/PT2873523T/pt unknown
- 2013-11-13 PL PL13192704T patent/PL2873523T3/pl unknown
- 2013-11-13 EP EP13192704.8A patent/EP2873523B1/fr active Active
- 2013-11-13 ES ES13192704.8T patent/ES2625704T3/es active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3721071C1 (de) * | 1987-06-26 | 1989-01-19 | Benecke Gmbh J | Verfahren und Vorrichtung zur Herstellung matter Lackoberflaechen |
| EP2147956A2 (fr) * | 2008-07-23 | 2010-01-27 | Flooring Technologies Ltd. | Procédé de fabrication de surfaces de laque au moins enclines aux salissures sur des objets, comme des plaques de matière dérivée du bois |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11292926B2 (en) | 2019-04-02 | 2022-04-05 | Flooring Technologies Ltd. | Impregnate with antistatic properties |
| US11597188B2 (en) * | 2019-04-02 | 2023-03-07 | Flooring Technologies Ltd. | Wooden composite board with antistatic properties |
| US11623995B2 (en) | 2019-04-02 | 2023-04-11 | Flooring Technologies Ltd. | Impregnate with antistatic properties |
Also Published As
| Publication number | Publication date |
|---|---|
| PL2873523T3 (pl) | 2017-09-29 |
| EP2873523A1 (fr) | 2015-05-20 |
| PT2873523T (pt) | 2017-07-06 |
| ES2625704T3 (es) | 2017-07-20 |
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