EP2931811A2 - Résines aminiques (méth)acrylées - Google Patents

Résines aminiques (méth)acrylées

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Publication number
EP2931811A2
EP2931811A2 EP13799550.2A EP13799550A EP2931811A2 EP 2931811 A2 EP2931811 A2 EP 2931811A2 EP 13799550 A EP13799550 A EP 13799550A EP 2931811 A2 EP2931811 A2 EP 2931811A2
Authority
EP
European Patent Office
Prior art keywords
acid
meth
independently
melamine
resins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13799550.2A
Other languages
German (de)
English (en)
Inventor
Christina HAAF-KLEINHUBBERT
Erich Beck
Markus Hickl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP13799550.2A priority Critical patent/EP2931811A2/fr
Publication of EP2931811A2 publication Critical patent/EP2931811A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/32—Modified amine-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/70—Other substituted melamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C08G12/42—Chemically modified polycondensates by etherifying
    • C08G12/424—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds
    • C08G12/425—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds based on triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C08G12/42—Chemically modified polycondensates by etherifying
    • C08G12/424—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds
    • C08G12/425—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds based on triazines
    • C08G12/427—Melamine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C08G12/44—Chemically modified polycondensates by esterifying
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate

Definitions

  • the present invention relates to amino resins bearing (meth)acrylic groups, to processes for preparing them, to their use, and to coating compositions comprising them.
  • Pigmented paints and transparent varnishes comprising or based on melamine-formaldehyde resins have been known for a number of decades.
  • Unplasticized melamine-formaldehyde resins serve, either on their own or in combination with further, chemically different crosslinkers, examples being blocked polyisocyanates, trisalkylcar- bamoyltriazines (TACT) or epoxides, as a crosslinking component in binder mixtures. Curing of the film-forming constituents produces a coating which is resistant to chemical, mechanical, and weathering-induced influences. Plasticized melamine-formaldehyde resins may feature modifications with carbamate structures, blends with polyesters or alkyd resins, and/or precondensa- tions with the latter. When used on flexible coating substrates lacking dimensional stability, unplasticized melamine-formaldehyde resins require external elastification in order for the coating not to tear; as a sole formulating constituent, the crosslinker forms only brittle networks.
  • Melamine-formaldehyde resins can be characterized according to application (molding compounds, glues, impregnating resins, coating materials), alkylating compounds (etherification with butanol, methanol, mixed etherification) or, as set out here, by the ratio of triazine to formaldehyde to etherifying alcohol:
  • the first major group of the fully etherified melamine-formaldehyde resins in which the molar melamine:formaldehyde:alcohol incorporation ratio is theoretically 1 :6:6, in practice generally 1 :>5.5:>5.0, and usually 1 :>5.5:>4.0, is distinguished by extremely good high-solids behavior (relatively low viscosity at high solids content).
  • the free formalde- hyde is readily reducible.
  • the commercial products usually comprise methanol as the alcohol, although grades with mixed etherification, and fully butylated grades, are also known.
  • the fully etherified melamine-formaldehyde resins are employed in practice preferably in can coating and coil coating and for all coats of the automobile finish.
  • the second major group of the partly etherified melamine-formaldehyde resins which in practice generally feature a molar melamine:formaldehyde:alcohol incorporation ratio of 1 :3 to 5.4:2 to 4.3, is distinguished by a thermal reactivity which is significantly increased in comparison to the first group, without acid catalysis.
  • the production of these crosslinkers is accompanied by self-condensation, leading to a higher viscosity (lower high-solids behavior) and making the removal of the free formaldehyde during distillation more difficult as a result.
  • the high-imino grades differ from the methylol grades, however, in a high degree of alkylation, i.e., in the proportion of the etherified methylol groups as a fraction of the incorporated formaldehyde equivalents, which is usually up to 80%, whereas for the methylol grades it is generally ⁇ 70%.
  • Reaction products of etherified melamines with hydroxyl acrylates are known for application in radiation-curable coating compositions; see, for example, T. J. Giacobbe et al., Macromole- cules, 4, 1971 , 630 ff. or JP63286426.
  • the presence of acid-labile formals or ⁇ , ⁇ -acetals makes such structures unstable in the acidic pH range, and this is manifested, for example, in lability under moisture exposure (see below).
  • WO 201 1/015539 discloses radiation-curable compounds obtainable by reacting at least one melamine-formaldehyde resin with at least one carbamato (meth)acrylate.
  • Such a carbamato (meth)acrylate is to be prepared from an carbamato alcohol by esterification or transesterification with (meth)acrylic acid or with a (meth)acrylic ester.
  • the invention relates to a process for the preparation of (meth)acrylated melamine- formaldehyde resins, wherein at least one at least one partially methylolated melamine- formaldehyde resin of formula (I)
  • R 1 , R 2 , R 3 , R 4 , R 5 und R 6 are each independently of another a Ci- to Ci2-alkyl radical and k, m, n, o, p und q are each independently of another a positive integer of 1 to 10 is reacted with (meth)acrylic acid in the presence of at least one acid (B) yielding a
  • R 7 , R 8 , R 9 , R 10 , R 11 und R 12 are each independently of another a Ci- to Ci2-alkyl residue or a (meth)acryloyl group and
  • r, s, t, u, v, and w are each independently of another 0 (zero) or a positive integer of 1 to 10, wherein at least one of r, s, t, u, v, and w is > 0 (zero),
  • radicals R 7 to R 12 are (meth)acryloyl groups.
  • R 1 to R 6 and R 7 to R 12 are independently of each other Ci- to C2o-alkyl, preferably Ci to C 4 alkyl, more preferably methyl, ethyl, isobutyl or n-butyl, very preferably methyl or n-butyl, and especially methyl.
  • Ci- to C2o-alkyl in the context of the present specification refers to straight-chain or branched alkyl groups having one to 20 carbon atoms, preferably Ci-Cs alkyl groups, i.e., for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, 2-butyl, tert-butyl, 1 -pentyl, 2-pentyl, isoamyl, n-hexyl, n-octyl or 2-ethylhexyl.
  • Ci-C 4 alkyl refers in this specification to methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, 2-butyl, or tert-butyl.
  • k, m, n, o, p und q are each independently of another a positive integer of 1 to 10.
  • r, s, t, u, v, and w are each independently of another 0 (zero) or a positive integer of 1 to 10, wherein at least one of r, s, t, u, v, and w is > 0 (zero), with the proviso that r ⁇ k, s ⁇ m, t ⁇ n, u ⁇ o, v ⁇ p, and w ⁇ q.
  • the amino resins (A) may preferably be melamine-formaldehyde resins of formula (I) and benzoguanamine/formaldehyde resins of formula (III) (see below), each of which may optionally be at least partly etherified, and which preferably are at least partly etherified.
  • the resins more preferably are at least partly etherified melamine-formaldehyde resins or benzoguanamine/formaldehyde resins, and very preferably are at least partly etherified melamine-formaldehyde resins.
  • the structure of melamine-formaldehyde resins which can be employed as amino resins (A) in accordance with the invention is, for example, as follows:
  • melamine-formaldehyde resins are frequently characterized by way of the molar melamine : formaldehyde : alcohol incorporation ratio.
  • the alcohol here equates to alcanols of the formula R 1 OH, R 2 OH, R 3 OH, R 4 OH, R 5 OH, and R 6 OH, and is preferably selected from the group consisting of methanol, ethanol, isobutanol and n-butanol or mixtures thereof, and more preferably selected from the group consisting of methanol and n-butanol.
  • Melamine-formaldehyde resins which can be used in accordance with the invention may have a molar incorporation ratio of 1 :2 to 6:1 to 6, though in individual cases, as a result of the formation of oligoformal chains, the formaldehyde incorporation ratio may even be up to 8.
  • Preferred molar incorporation ratios are 1 :3 to 6:1 .5 to 6.
  • molar incorporation ratios of 1 :3.6 to 5.7:2.1 to 4.7 are particularly preferred; very much preferred are molar incorporation ratios of 1 :5 to 6:3.5 to 6, more particularly 1 :5 to 6:4.0 to 5.0.
  • melamine-formaldehyde resins For n-butyl-etherified melamine-formaldehyde resins, molar incorporation ratios of 1 :3.2 to 5.7:1 .3 to 4 are particularly preferred; very much preferred are molar incorporation ratios of 1 :5 to 6:3.5 to 6, more particularly 1 :5 to 6:3.5 to 4.5.
  • the melamine-formaldehyde resins that can be used may have not only one melamine group per polycondensate but, indeed, two or more melamine groups, preferably up to six, more preferably up to four, very preferably up to three, and more particularly up to two.
  • benzoguanamine/formaldehyde resins which can be used as amino resins in accordance with the invention is, for example, as follows (formula (III)):
  • R 1 , R 2 , R 3 and R 4 are each independently of another a Ci- to Ci2-alkyl radical and
  • k, m, n, and o are each independently of another a positive integer of 1 to 10.
  • reaction product in this case is of formula (IV)
  • R 7 , R 8 , R 9 and R 10 are each independently of another a Ci- to Ci2-alkyl residue or a
  • r, s, t, and u are each independently of another 0 (zero) or a positive integer of 1 to 10, wherein at least one of r, s, t, and u is > 0 (zero),
  • radicals R 7 to R 12 are (meth)acryloyl group.
  • Benzoguanamine-formaldehyde resins as well are frequently characterized by way of the molar benzoguanamine:formaldehyde:alcohol incorporation ratio.
  • the alcohol in this case is preferably selected from the group consisting of methanol, ethanol, isobutanol and n-butanol or mixtures thereof, more preferably selected from the group consisting of methanol and n-butanol.
  • Benzoguanamine-formaldehyde resins which can be used in accordance with the invention may have a molar incorporation ratio of 1 :1.5 to 4:1 to 4, though in certain cases, as a result of formation of oligoformal chains, the formaldehyde incorporation ratio may even be up to 6. Preference is given to molar incorporation ratios of 1 :2 to 4:1 .5 to 4.
  • molar incorporation ratios of 1 :2.2 to 3.7:2.1 to 3.0 are particularly preferred; very particular preference is given to molar incorporation ratios of 1 :3 to 4:1.5 to 4, more particularly 1 :3 to 4:2.0 to 3.0.
  • molar incorporation ratios 1 :2.2 to 3.7:1.3 to 2 are particularly preferred; very particular preference is given to molar
  • the benzoguanamine-formaldehyde resins which can be used may have not only one benzoguanamine group per polycondensate but also, indeed, two or more benzoguanamine groups, preferably up to five, more preferably up to four, very preferably up to three, and more particularly up to two.
  • the amino resin used may comprise at least one solvent, such as water or alcohols.
  • Alcohols are for example methanol, ethanol, n-propanol, isopropanol, n-butanol, sec-butanol, isobutanol, pentanol isomer mixtures, hexanol isomer mixtures, 2-ethylhexanol or octanol.
  • Preferred solvents are water or C1-C4 alkyl alcohols, as for example, methanol, ethanol, isopropanol, n-propanol, n-butanol, isobutanol, sec-butanol or tert-butanol, or aromatic hydrocarbons, such as toluene or xylene isomer mixtures, for example.
  • the free formaldehyde content of the amino resin used is generally not more than 1 .5% by weight; for example, it may be not more than 1.0%, preferably not more than 0.5%, more preferably not more than 0.3%, and very preferably not more than 0.1 % by weight.
  • the amino resin is reacted with (meth)acrylic acid, preferably with acrylic acid.
  • the reaction to form the (meth)acrylated amino resins of the invention may take place between 40 and 120°C, more preferably between 60 and 1 10°C, and very preferably between 70 and 100°C for 1 to 12 hours, preferably 2 to 10 hours.
  • the reaction is conducted under reduced pressure, preferably from 10 to 700, very preferably from 15 to 500 and especially preferably from 20 to 300 hPa, so that alcohol R 1 OH to R 6 OH which is released during the reaction is distilled off.
  • the reaction can be carried out in bulk, but is preferably carried out in an inert, anhydrous solvent.
  • the reaction of the amino resin used with (meth)acrylic acid may take place in the presence of an acid (B) and with or without addition of an azeotrope former, such as toluene.
  • an acid (B) is used as a catalyst. Examples of acids are given below.
  • (meth)acrylic acid is used in a ratio of 1 :1 to 20:1 (molar) with respect to amino resin, preferably in a ratio of 6:6 to 15:6, particularly preferably in a ratio of approximately 10:6.
  • the excess (meth)acrylic acid is removed from the reaction mixture after the end of the reaction, under reduced pressure and at not more than 50°C.
  • One preferred embodiment of the present invention involves selecting the ratio of (meth)acrylic acid to amino resin (A) such that the resultant resin has an average degree of substitution with (meth)acryloyl groups per melamine nucleus of at least three, preferably three to five, very preferably three to 4.5 and especially preferably three to four.
  • the alcohol, preferably methanol liberated is collected continuously in a water separator and the reaction is terminated when the theoretical amount of methanol has been separated off. If water is present in the reaction mixture, it is advantageous to use a short Vigreux column for effective separation of the azeotrope, comprising (meth)acrylic acid and water, from the alcohol, preferably methanol formed. Preferably, however, the reaction is carried out in the absence of water.
  • Suitable acidic catalysts (B) exhibt a pKa-value of 3 or less, preferably 2.5 or less.
  • Preferred acids are sulfuric acid, nitric acid, phosphoric acid, hydrochloric acid, para-toluenesulfonic acid, benzenesulfonic acid, dodecylbenzenesulfonic acid, methanesulfonic acid,
  • nonylnaphthalenedisulfonic acid or mixtures thereof; acidic ion exchangers can also be contemplated. Particular preference is given to sulfonic acids, particular preference to para- toluenesulfonic acid.
  • the acidic catalyst (B) is added generally in amounts of 0.1 % to 1 % by weight, preferably 0.1 % to 0.5% by weight. It may be useful to introduce the catalyst in a number of portions.
  • the number-average molar weight M n of the (meth)acrylated amino resins obtained, especially melamine-formaldehyde resins, is generally less than 3500 g/mol, preferably less than
  • the acid number of the amino resins obtained, especially the melamine-formaldehyde resins is less than 80, more preferably less than 60 mg KOH/g and very preferably less than 50 mg KOH/g, as determined in accordance with ISO 3682.
  • the acid number may be further reduced by separating off unreacted (meth)acrylic acid from the reaction mixture.
  • the free formaldehyde content of the (meth)acrylated amino resins of the invention is generally not more than 0.2% by weight, preferably not more than 0.15% by weight, and more preferably not more than 0.1 % by weight.
  • the free formaldehyde content is determined in accordance with EN ISO 9020.
  • Another aspect of the present invention is a coating composition, comprising
  • Such a coating composition comprises
  • binder 10 to 50, preferably 20 to 40 % by weight of at least one binder (C), comprising groups that are reactive towards amino resins,
  • coating compositions of this kind comprise at least one binder comprising groups that are reactive toward amino resins. These are, generally, selected from the group consisting of epoxy-containing binders, hydroxyl-containing binders, carboxyl-containing binders, and amino-containing binders.
  • the hydroxyl-containing binder preferably comprises polyetherols, polyesterols, polyacrylate polyols, polycarbonate polyols, alkyd resins or epoxy resins. Polyesterols and polyacrylate polyols are particularly preferred, very particular preference being given to polyacrylate polyols.
  • the binders have on average per molecule at least two, preferably two to ten, more preferably three to ten, and very preferably three to eight hydroxyl groups.
  • the OH number measured to DIN 53240-2, is generally from 10 to 200 mg KOH/g, preferably from 30 to 140.
  • the binders may additionally have an acid number to DIN EN ISO 3682 of 0 to 200 mg KOH/g, preferably 0 - 100, and more preferably 0 to 10 mg KOH/g.
  • the polyacrylate polyols are, for example, those which are copolymers of (meth)acrylic esters with at least one compound having at least one, preferably precisely one, hydroxyl group and at least one, preferably precisely one, (meth)acrylate group.
  • the latter may be, for example, monoesters of ⁇ , ⁇ -unsaturated carboxylic acids, such as acrylic acid, methacrylic acid (referred to in this text for short as "(meth)acrylic acid”), with diols or polyols which have preferably 2 to 20 carbon atoms and at least two hydroxyl groups, such as ethylene glycol, diethylene glycol, triethylene glycol, 1 ,2-propylene glycol, 1 ,3-propylene glycol,
  • monoesters of ⁇ , ⁇ -unsaturated carboxylic acids such as acrylic acid, methacrylic acid (referred to in this text for short as "(meth)acrylic acid")
  • diols or polyols which have preferably 2 to 20 carbon atoms and at least two hydroxyl groups, such as ethylene glycol, diethylene glycol, triethylene glycol, 1 ,2-propylene glycol, 1 ,3-propylene glycol,
  • the hydroxyl-bearing monomers are employed in the copolymerization in mixture with other polymerizable, preferably free-radically polymerizable, monomers, preferably those composed of more than 50% by weight of C1-C20 alkyl (meth)acrylate, vinylaromatics having up to 20 carbon atoms, vinyl esters of carboxylic acids comprising up to 20 carbon atoms, vinyl halides, nonaromatic hydrocarbons having 4 to 8 carbon atoms and 1 or 2 double bonds, unsaturated nitriles, and mixtures thereof.
  • Particular preference is given to the polymers composed of more than 60% by weight of C1-C10 alkyl (meth)acrylates, styrene or mixtures thereof.
  • the polymers may further comprise hydroxyl-functional monomers in keeping with the above hydroxyl group content, and, if desired, further monomers, examples being ethylenically unsaturated acids, especially carboxylic acids, acid anhydrides or acid amides.
  • polyesterols such as are obtainable by condensing polycarboxylic acids, especially dicarboxylic acids, with polyols, especially diols.
  • Polyester polyols are known for example from UHmanns Encyklopadie der ischen Chemie, 4th edition, volume 19, pp. 62 to 65. It is preferred to use polyester polyols obtained by reacting dihydric alcohols with dibasic carboxylic acids.
  • the free polycarboxylic acids it is also possible to use the corresponding polycarboxylic anhydrides or polycarboxylic esters of lower alcohols, or mixtures thereof, to prepare the polyester polyols.
  • the polycarboxylic acids may be aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic and may be optionally substituted, by halogen atoms for example, and/or unsaturated.
  • Examples thereof that may be mentioned include the following: Oxalic acid, maleic acid, fumaric acid, succinic acid, glutaric acid, adipic acid, sebacic acid, dodecanedioic acid, o-phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, azelaic acid, 1 ,4-cyclohexanedicarboxylic acid or tetrahydrophthalic acid, suberic acid, azelaic acid, phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride,
  • tetrachlorophthalic anhydride endomethylenetetrahydrophthalic anhydride, glutaric anhydride, maleic anhydride, dimeric fatty acids, isomers thereof, hydrogenation products thereof, and esterifiable derivatives thereof, such as anhydrides or dialkyl esters, such as C1-C4 alkyl esters, preferably methyl, ethyl or n-butyl esters, of the stated acids.
  • dicarboxylic acids of the general formula HOOC-(CH2) y -COOH in which y is a number from 1 to 20, preferably an even number from 2 to 20; particular preference is given to succinic acid, adipic acid, sebacic acid, and dodecanedicarboxylic acid.
  • Suitable polyhydric alcohols for preparing the polyesterols include 1 ,2-propanediol, ethylene glycol, 2, 2-dimethyl-1 ,2-ethanediol, 1 ,3-propanediol, 1 ,2-butanediol, 1 ,3-butanediol, 1 ,4- butanediol, 3-methylpentane-1 ,5-diol, 2-ethylhexane-1 ,3-diol, 2,4-diethyloctane-1 ,3-diol, 1 ,6- hexanediol, polyTHF having a molar mass between 162 and 2000, poly-1 ,3-propanediol having a molar mass between 134 and 1 178, poly-1 ,2-propanediol having a molar mass between 134 and 898, polyethylene glycol having a molar mass between
  • lactone-based polyester diols which are homopolymers or copolymers of lactones, preferably hydroxy-terminal products of lactones with suitable difunctional starter molecules.
  • Suitable lactones are preferably those derived from compounds of the general formula HO-(CH2) z -COOH, in which z is a number from 1 to 20 and one hydrogen atom of a methylene unit may also be substituted by a Ci to C 4 alkyl radical.
  • Examples are ⁇ - caprolactone, ⁇ -propiolactone, gamma-butyrolactone and/or methyl- ⁇ -caprolactone, 4- hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid or pivalolactone, and mixtures thereof.
  • Suitable starter components are, for example, the low molecular mass dihydric alcohols specified above as a synthesis component for the polyester polyols.
  • the corresponding polymers of ⁇ -caprolactone are particularly preferred.
  • Lower polyester diols or polyether diols as well can be used as starters for preparing the lactone polymers.
  • the polymers of lactones it is also possible to use the corresponding, chemically equivalent polycondensates of the hydroxycarboxylic acids corresponding to the lactones.
  • Further suitable polymers are polyetherols, which are prepared by addition reaction of ethylene oxide, propylene oxide or butylene oxide with H-active components. Polycondensates of butanediol are suitable as well.
  • the polymers can of course also be compounds having primary or secondary amino groups.
  • polycarbonate polyols such as may be obtained, for example, by reacting phosgene with an excess of the low molecular mass alcohols specified as synthesis components for the polyester polyols.
  • Alkyd resins are polycondensation resins made from polyols, polybasic carboxylic acids, and fatty oils, or free natural and/or synthetic fatty acids; at least one polyol must have a functionality of three or more.
  • polyols and polybasic carboxylic acids it is possible for example to employ the components specified above in connection with the polyesterols.
  • Preferred polyhydric alcohols are glycerol, pentaerythritol, trimethylolethane, trimethylolpropane, various diols such as ethane-/propanediol, diethylene glycol, neopentyl glycol.
  • Preferred polybasic carboxylic acids are phthalic acid (anhydride) (PAA), isophthalic acid, terephthalic acid, trimellitic anhydride, adipic acid, azelaic acid, sebacic acid.
  • suitable oil components and/or fatty acids include drying oils, such as linseed oil, oiticica oil or tung oil, semidrying oils, such as soybean oil, sunflower oil, safflower oil, castor oil or tall oil, nondrying oils, such as castor oil, coconut oil or peanut oil, or free fatty acids of above oils, or synthetic monocarboxylic acids.
  • drying oils such as linseed oil, oiticica oil or tung oil
  • semidrying oils such as soybean oil, sunflower oil, safflower oil, castor oil or tall oil
  • nondrying oils such as castor oil, coconut oil or peanut oil, or free fatty acids of above oils, or synthetic monocarboxylic acids.
  • the molar mass of typical alkyd resins is between 1500 and 20 000, preferably between 3500 and 6000.
  • the acid number is preferably 2 to 30 mg KOH/g, or 35-65-mg KOH/g in the case of water-thinnable resins.
  • the OH number is generally up to 300, preferably up to 100 mg KOH/g.
  • Polyacrylate polyols, polyesterols and/or polyetherols of this kind have a molecular weight M n of preferably at least 1000, more preferably at least 2000, and very preferably at least 5000 g/mol.
  • the molecular weight M n can be for example up to 200 000, preferably up to 100 000, more preferably up to 80 000, and very preferably up to 50 000 g/mol.
  • co-crosslinkers examples being trisalkylcarbamoyltriazines (TACT), preferably trismethylcarbamoyltriazines, tris-n- butylcarbamoyltriazines and mixed methylated/n-butylated trisalkylcarbamoyltriazines.
  • TACT trisalkylcarbamoyltriazines
  • amino resins of the invention especially the melamine-formaldehyde resins, may also be used together with noncrosslinkable binders, i.e., those without groups that are reactive toward melamine-formaldehyde resins.
  • crosslinking is accelerated by addition of acids and other catalysts.
  • Weak acids for the purposes of this text are monobasic or polybasic, organic or inorganic, preferably organic, acids having a pK a of between 1 .6 and 5.2, preferably between 1.6 and 3.8.
  • Examples thereof are carbonic acid, phosphoric acid, formic acid, acetic acid, and maleic acid, glyoxylic acid, bromoacetic acid, chloroacetic acid, thioglycolic acid, glycine, cyanoacetic acid, acrylic acid, malonic acid, hydroxypropanedioic acid, propionic acid, lactic acid, 3- hydroxypropionic acid, glyceric acid, alanine, sarcosine, fumaric acid, acetoacetic acid, succinic acid, isobutyric acid, pentanoic acid, ascorbic acid, citric acid, nitrilotriacetic acid,
  • cyclopentanecarboxylic acid 3-methylglutaric acid, adipic acid, hexanoic acid, benzoic acid, cyclohexanecarboxylic acid, heptanedioic acid, heptanoic acid, phthalic acid, isophthalic acid, terephthalic acid, tolylic acid, phenylacetic acid, phenoxyacetic acid, mandelic acid or sebacic acid.
  • organic acids preferably monobasic or polybasic carboxylic acids.
  • Strong acids for the purposes of this text are monobasic or polybasic, organic or inorganic, preferably organic acids having a pK a of less than 1 .6 and more preferably less than 1 .
  • Examples thereof are sulfuric acid, pyrophosphoric acid, sulfurous acid, and tetrafluoroboric acid, trichloroacetic acid, dichloroacetic acid, oxalic acid, and nitroacetic acid.
  • organic acids preferably organic sulfonic acids. Particular preference is given to methanesulfonic acid, para-toluenesulfonic acid, benzenesulfonic acid,
  • dodecylbenzenesulfonic acid cyclododecanesulfonic acid, and camphorsulfonic acid.
  • the acids are used in amounts in general of up to 10% by weight, preferably 0.1 % to 8%, more preferably 0.3% to 6%, very preferably 0.5% to 5%, and in particular from 1 % to 3% by weight, based on the amino resin employed.
  • the acids may also be used as free acids or in blocked form.
  • the (meth)acrylated melamine-formaldehyde resins of the invention may be used as sole binder or, preferably, in combination with at least one further radically polymerizable compound (D).
  • Radically polymerizable groups are, for example, preferably (meth)acrylate groups and more preferably acrylate groups.
  • the radically polymerizable compounds (D) are preferably polyfunctional (compound having more than one radically polymerizable double bond) polymerizable compounds.
  • (Meth)acrylic acid stands in this specification for methacrylic acid and acrylic acid, preferably for acrylic acid.
  • Multifunctional polymerizable compounds are preferably multifunctional (meth)acrylates which carry at least 2, preferably 2 - 10, more preferably 3 - 6, and very preferably 3 - 4
  • (meth)acrylate groups preferably acrylate groups.
  • multifunctional polymerizable compounds are ethylene glycol diacrylate, 1 ,2- propanediol diacrylate, 1 ,3-propanediol diacrylate, 1 ,4-butanediol diacrylate, 1 ,3-butanediol diacrylate, 1 ,5-pentanediol diacrylate, 1 ,6-hexanediol diacrylate, 1 ,8-octanediol diacrylate, neopentyl glycol diacrylate, 1 ,1 -, 1 ,2-, 1 ,3-, and 1 ,4-cyclohexanedimethanol diacrylate, 1 ,2-, 1 ,3- or 1 ,4-cyclohexanediol diacrylate, dipropylene glycol diacrylate trimethylolpropane triacrylate, ditrimethylolpropane tipropylene glycol diacrylate penta- or hex
  • (meth)acrylates urethane (meth)acrylates or polycarbonate (meth)acrylates, which optionally may also have been modified with one or more amines.
  • C1-C18 alkyl therein, optionally substituted by aryl, alkyl, aryloxy, alkyloxy, heteroatoms and/or heterocycles is for example methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, pentyl, hexyl, heptyl, octyl, 2-ethylhexyl, 2,4,4-trimethylpentyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, 1 ,1 -dimethylpropyl, 1 ,1 -dimethylbutyl, 1 ,1 ,3,3-tetramethylbutyl, preferably methyl, ethyl or n-propyl, more preferably methyl or ethyl.
  • (meth)acrylates of singly to vigintuply and more preferably triply to decuply ethoxylated, propoxylated or mixedly ethoxylated and propoxylated, and in particular exclusively ethoxylated, neopentyl glycol, trimethylolpropane, trimethylolethane or pentaerythritol.
  • Preferred multifunctional polymerizable compounds are 1 ,2-propanediol diacrylate, 1 ,3- propanediol diacrylate, dipropylene glycol diacrylate, tripropylene glycol diacrylate,
  • trimethylolpropane triacrylate ditrimethylol tetracrylate, and dipentaerythritol hexaacrylate
  • polyester polyol acrylates polyetherol acrylates
  • alkoxylated more preferably singly to vigintuply ethoxylated trimethylolpropane, singly to vigintuply propoxylated glycerol or singly to vigintuply ethoxylated and/or propoxylated pentaerythritol.
  • epoxy (meth)acrylates are used as multifunctional polymerizable compounds.
  • Especially preferred multifunctional polymerizable compounds are trimethylolpropane triacrylate and triacrylate of singly to vigintuply ethoxylated trimethylolpropane, triacrylate of singly to vigintuply propoxylated glycerol or tetraacrylate of singly to vigintuply ethoxylated and/or propoxylated pentaerythritol.
  • Further constituents may also be polyalcohols with full or partial esterification with (meth)acrylic acid.
  • polyalcohols are at least divalent polyols, polyetherols or polyesterols, or polyacrylate polyols, having an average OH functionality of at least 2, preferably at least 3, more preferably at least 4, and very preferably 4 to 20.
  • Polyetherols in addition to the alkoxylated polyols, may also be polyethylene glycol having a molar mass of between 106 and 2000, polypropylene glycol having a molar weight of between 134 and 2000, polyTHF having a molar weight of between 162 and 2000, or poly-1 ,3- propanediol having a molar weight of between 134 and 400.
  • Polyester polyols are known for example from Ullmanns Encyklopadie der ischen Chemie, 4th edition, volume 19, pp. 62 to 65. Preference is given to using polyester polyols obtained by reacting dihydric alcohols with dibasic carboxylic acids. In lieu of the free polycarboxylic acids it is also possible to use the corresponding polycarboxylic anhydrides or corresponding polycarboxylic esters of lower alcohols or mixtures thereof to prepare the polyester polyols.
  • the polycarboxylic acids may be aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic and may optionally be substituted, by halogen atoms for example, and/or unsaturated.
  • Examples thereof that may be mentioned include the following: oxalic acid, maleic acid, fumaric acid, succinic acid, glutaric acid, adipic acid, sebacic acid, dodecanedioic acid, o-phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, azelaic acid, 1 ,4-cyclohexanedicarboxylic acid or tetrahydrophthalic acid, suberic acid, azelaic acid, phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride,
  • tetrachlorophthalic anhydride endomethylenetetrahydrophthalic anhydride, glutaric anhydride, maleic anhydride, dimeric fatty acids, their isomers and hydrogenation products, and also esterifiable derivatives, such as anhydrides or dialkyl esters, Ci-C4-alkyl esters for example, preferably methyl, ethyl or n-butyl esters, of said acids are used.
  • dicarboxylic acids of the general formula HOOC-(CH2) y -COOH Preference is given to dicarboxylic acids of the general formula HOOC-(CH2) y -COOH, y being a number from 1 to 20, preferably an even number from 2 to 20; more preferably succinic acid, adipic acid, sebacic acid, and dodecanedicarboxylic acid.
  • Suitable polyhydric alcohols for preparing the polyesterols include
  • ditrimethylolpropane dipentaerythritol, sorbitol, mannitol, diglycerol, threitol, erythritol, adonitol (ribitol), arabitol (lyxitol), xylitol, dulcitol (galactitol), maltitol or isomalt, which optionally may have been alkoxylated as described above.
  • Preferred alcohols are those of the general formula HO-(CH2)x-OH, x being a number from 1 to 20, preferably an even number from 2 to 20.
  • Suitable lactones include, preferably, those deriving from compounds of the general formula HO-(CH2) z -COOH, z being a number from 1 to 20 and it being possible for an H atom of a methylene unit also to have been substituted by a Ci to C 4 alkyl radical.
  • Examples are ⁇ - caprolactone, ⁇ -propiolactone, gamma-butyrolactone and/or methyl-e-caprolactone, 4- hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid or pivalolactone, and mixtures thereof.
  • starter components are the low molecular mass dihydric alcohols specified above as a synthesis component for the polyester polyols.
  • the corresponding polymers of ⁇ - caprolactone are particularly preferred.
  • Lower polyesterdiols or polyetherdiols as well can be used as starters for preparing the lactone polymers.
  • the polymers of lactones it is also possible to use the corresponding, chemically equivalent polycondensates of the
  • polycarbonatediols such as may be obtained, for example, by reacting phosgene with an excess of the low molecular weight alcohols specified as synthesis components for the polyester polyols.
  • the multifunctional polymerizable compound may also comprise urethane (meth)acrylates, epoxy (meth)acrylates or carbonate (meth)acrylates.
  • Urethane (meth)acrylates are obtainable for example by reacting polyisocyanates with hydroxyalkyl (meth)acrylates and optionally chain extenders such as diols, polyols, diamines, polyamines, dithiols or polythiols.
  • Urethane (meth)acrylates which can be dispersed in water without addition of emulsifiers additionally comprise ionic and/or nonionic hydrophilic groups, which are introduced into the urethane by means of synthesis components such as
  • Urethane (meth)acrylates of this kind comprise as synthesis components substantially:
  • Possible useful components (1 ), (2), and (3) may be the same as those described above as synthesis components (a), (b), and (e) for the polyurethanes of the invention.
  • the urethane (meth)acrylates preferably have a number-average molar weight M n of 500 to 20 000, in particular of 500 to 10 000 and more preferably 600 to 3000 g/mol (determined by gel permeation chromatography using tetrahydrofuran and polystyrene as standard).
  • the urethane (meth)acrylates preferably have a (meth)acrylic group content of 1 to 5, more preferably of 2 to 4, mol per 1000 g of urethane (meth)acrylate.
  • Epoxy (meth)acrylates are obtainable by reacting epoxides with (meth)acrylic acid.
  • suitable epoxides include epoxidized olefins, aromatic glycidyl ethers or aliphatic glycidyl ethers, preferably those of aromatic or aliphatic glycidyl ethers.
  • Examples of possible epoxidized olefins include ethylene oxide, propylene oxide, iso-butylene oxide, 1 -butene oxide, 2-butene oxide, vinyloxirane, styrene oxide or epichlorohydrin, preference being given to ethylene oxide, propylene oxide, isobutylene oxide, vinyloxirane, styrene oxide or epichlorohydrin, particular preference to ethylene oxide, propylene oxide or epichlorohydrin, and very particular preference to ethylene oxide and epichlorohydrin.
  • Aromatic glycidyl ethers are, for example, bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, bisphenol B diglycidyl ether, bisphenol S diglycidyl ether, hydroquinone diglycidyl ether, alkylation products of phenol/dicyclopentadiene, e.g., 2,5-bis[(2,3- epoxypropoxy)phenyl]octahydro-4,7-methano-5H-indene (CAS No. [13446-85-0]), tris[4-(2,3- epoxypropoxy)phenyl]methane isomers (CAS No. [66072-39-7]), phenol-based epoxy novolaks (CAS No. [9003-35-4]), and cresol-based epoxy novolaks
  • aliphatic glycidyl ethers examples include 1 ,4-butanediol diglycidyl ether, 1 ,6-hexanediol diglycidyl ether, trimethylolpropane triglycidyl ether, pentaerythritol tetraglycidyl ether, 1 ,1 ,2,2- tetrakis[4-(2,3-epoxypropoxy)phenyl]ethane (CAS No.
  • the epoxy (meth)acrylates preferably have a number-average molar weight M n of 200 to 20 000, more preferably of 200 to 10 000 g/mol, and very preferably of 250 to 3000 g/mol; the amount of (meth)acrylic groups is preferably 1 to 5, more preferably 2 to 4, per 1000 g of epoxy (meth)acrylate (determined by gel permeation chromatography using polystyrene as standard and tetrahydrofuran as eluent).
  • Carbonate (meth)acrylates comprise on average preferably 1 to 5, especially 2 to 4, more preferably 2 to 3 (meth)acrylic groups, and very preferably 2 (meth)acrylic groups.
  • the number-average molecular weight M n of the carbonate (meth)acrylates is preferably less than 3000 g/mol, more preferably less than 1500 g/mol, very preferably less than 800 g/mol (determined by gel permeation chromatography using polystyrene as standard, tetrahydrofuran as solvent).
  • the carbonate (meth)acrylates are obtainable in a simple manner by transesterifying carbonic esters with polyhydric, preferably dihydric, alcohols (diols, hexanediol for example) and subsequently esterifying the free OH groups with (meth)acrylic acid, or else by
  • transesterification with (meth)acrylic esters as described for example in EP-A 92 269. They are also obtainable by reacting phosgene, urea derivatives with polyhydric, e.g., dihydric, alcohols.
  • (meth)acrylates of polycarbonate polyols such as the reaction product of one of the aforementioned diols or polyols and a carbonic ester and also a hydroxyl-containing (meth)acrylate.
  • suitable carbonic esters include ethylene carbonate, 1 ,2- or 1 ,3-propylene carbonate, dimethyl carbonate, diethyl carbonate or dibutyl carbonate.
  • Suitable hydroxyl-containing (meth)acrylates are 2-hydroxyethyl (meth)acrylate, 2- or 3-hydroxypropyl (meth)acrylate, 1 ,4-butanediol mono(meth)acrylate, neopentyl glycol mono(meth)acrylate, glyceryl mono- and di(meth)acrylate, trimethylolpropane mono- and di(meth)acrylate, and pentaerythritol mono-, di-, and tri(meth)acrylate.
  • Particularly preferred carbonate (meth)acrylates are those of the formula: in which R is H or CH3, X is a C2-C18 alkylene group, and n is an integer from 1 to 5, preferably 1 to 3.
  • R is preferably H and X is preferably C2 to C10 alkylene, examples being 1 ,2-ethylene, 1 ,2- propylene, 1 ,3-propylene, 1 ,4-butylene, and 1 ,6-hexylene, more preferably C 4 to C& alkylene. With very particular preference X is C6 alkylene.
  • the carbonate (meth)acrylates are preferably aliphatic carbonate (meth)acrylates.
  • compounds of formula (Va) to (Vd) are particularly preferred. It may be useful to add photoinitiator to the coating composition of the invention.
  • Photoinitiators (E) may be, for example, photoinitiators known to the skilled person, examples being those specified in "Advances in Polymer Science", Volume 14, Springer Berlin 1974 or in K. K. Dietliker, Chemistry and Technology of UV and EB Formulation for Coatings, Inks and Paints, Volume 3; Photoinitiators for Free Radical and Cationic Polymerization, P. K. T. Oldring (Eds), SITA Technology Ltd, London.
  • Suitability is possessed, for example, by mono- or bisacylphosphine oxides, as described for example in EP-A 7 508, EP-A 57 474, DE-A 196 18 720, EP-A 495 751 or EP-A 615 980, examples being 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin ® TPO from BASF SE), ethyl 2,4,6-trimethylbenzoylphenylphosphinate (Lucirin ® TPO L from BASF SE), bis(2,4,6- trimethylbenzoyl)phenylphosphine oxide (Irgacure ® 819 from BASF SE), benzophenones, hydroxyacetophenones, phenylglyoxylic acid and its derivatives, or mixtures of these photoinitiators.
  • mono- or bisacylphosphine oxides as described for example in EP-A 7 508, EP-A 57 474, DE-A 196
  • Examples that may be mentioned include benzophenone, acetophenone, acetonaphthoquinone, methyl ethyl ketone, valerophenone, hexanophenone, ophenylbutyro- phenone, p-morpholinopropiophenone, dibenzosuberone, 4-morpholinobenzophenone, 4-morpholinodeoxybenzoin, p-diacetylbenzene, 4-aminobenzophenone, 4'-methoxyaceto- phenone, ⁇ -methylanthraquinone, tert-butylanthraquinone, anthraquinonecarboxylic esters, benzaldehyde, otetralone, 9-acetylphenanthrene, 2-acetylphenanthrene, 10-thioxanthone, 3-acetylphenanthrene, 3-acetylindole, 9-fluorenone, 1 -
  • photoinitiators are polymeric photoinitiators such as, for example, the diester of carboxymethoxybenzophenone with polytetramethylene glycols of different molar weights, preferably 200 to 250 g/mol (CAS 515136-48-8), and also CAS 1246194-73-9, CAS 813452-37-8, CAS 71512-90-8, CAS 886463-10-1 , or further polymeric benzophenone derivatives, of the kind available commercially, for example, under the trade name Omnipol® BP from IGM Resins B.V., Waalwijk, The Netherlands, or Genopol® BP1 from Rahn AG, Switzerland.
  • polymeric photoinitiators such as, for example, the diester of carboxymethoxybenzophenone with polytetramethylene glycols of different molar weights, preferably 200 to 250 g/mol (CAS 515136-48-8), and also CAS 1246194-73-9, CAS 813452-37-8,
  • polymeric thioxanthones examples being the diesters of carboxymethoxythioxanthones with polytetramethylene glycols of various molar weights, of the kind available commercially, for example, under the trade name Omnipol® TX from IGM Resins B.V., Waalwijk, The Netherlands.
  • polymeric oamino ketones examples being the diester of carboxyethoxythioxanthones with polyethylene glycols of various molar weights, of the kind available commercially, for example, under the trade name Omnipol® 910 or Omnipol® 9210 from IGM Resins B.V., Waalwijk, The
  • One preferred embodiment uses, as photoinitiators, silsesquioxane compounds having at least one initiating group, of the kind described in WO 2010/063612 A1 , particularly from page 2, line 21 to page 43, line 9 therein, hereby incorporated by reference as part of the present disclosure content, preferably from page 2, line 21 to page 30, line 5, and also the compounds described in the examples of WO 2010/063612 A1.
  • nonyellowing or low-yellowing photoinitiators of the phenylglyoxalic ester type as described in DE-A 198 26 712, DE-A 199 13 353 or WO 98/33761 , and silsesquioxane compounds.
  • photoinitiators Preference among these photoinitiators is given to 2,4,6-trimethylbenzoyldiphenylphosphine oxide, ethyl 2,4,6-trimethylbenzoylphenylphosphinate, bis(2,4,6-trimethylbenzoyl)phenylphos- phine oxide, 2-benzyl-2-dimethylamino-4'-morpholinobutyrophenone, 2-(dimethylamino)-1 -(4- morpholinophenyl)-2-(p-tolylmethyl)butan-1 -one, 2-hydroxy-1 -[4-[[4-(2-hydroxy-2-methylpro- panoyl)phenyl]methyl]phenyl]-2-methylpropan-1 -one, and also the above-described polymeric thioxanthone and benzophenone derivatives, and also those described in WO 2010/063612 A1.
  • Pigments (F) may likewise be comprised.
  • Pigments according to CD Rompp Chemie Lexikon - Version 1 .0, Stuttgart/New York: Georg Thieme Verlag 1995, with reference to DIN 55943, are particulate, organic or inorganic, chromatic or achromatic colorants which are virtually insoluble in the application medium.
  • Virtually insoluble here means a solubility at 25°C of below 1 g / 1000 g of application medium, preferably below 0.5 g, more preferably below 0.25 g, very preferably below 0.1 g, and in particular below 0.05 g / 1000 g of application medium.
  • pigments comprise any desired systems of absorption pigments and/or effect pigments, preferably absorption pigments. There are no restrictions whatsoever governing the number and selection of the pigment components. They can be adapted as desired to the particular requirements, such as the desired color impression, for example.
  • effect pigments are meant all pigments which exhibit a platelet-shaped construction and impart specific decorative color effects to a surface coating.
  • the effect pigments comprise, for example, all of the effect-imparting pigments which can be employed commonly in vehicle finishing and industrial coating.
  • effect pigments of this kind are pure metal pigments, such as aluminum, iron or copper pigments; interference pigments, such as titanium- dioxide-coated mica, iron-oxide-coated mica, mixed-oxide-coated mica (e.g., with titanium dioxide and Fe203 or titanium dioxide and ⁇ 2 ⁇ 3), metal-oxide-coated aluminum, and liquid- crystal pigments.
  • the color-imparting absorption pigments are, for example, customary organic or inorganic absorption pigments which can be used in the coatings industry.
  • organic absorption pigments are azo pigments, phthalocyanine pigments, quinacridone pigments, and pyrrol opyrrole pigments.
  • inorganic absorption pigments are iron oxide pigments, titanium dioxide, and carbon black.
  • Disazo pigments C.I. Pigment Orange 16, 34 and 44; C.I. Pigment Red 144, 166,
  • Anthanthrone pigments C.I. Pigment Red 168 (C.I. Vat Orange 3);
  • Anthraquinone pigments C.I. Pigment Yellow 147 and 177; C.I. Pigment Violet 31 ;
  • Anthraquinone pigments C.I. Pigment Yellow 147 and 177; C.I. Pigment Violet 31 ;
  • Anthrapyrimidine pigments C.I. Pigment Yellow 108 (C.I. Vat Yellow 20);
  • Quinacridone pigments C.I. Pigment Red 122, 202 and 206; C.I. Pigment Violet 19; - Quinophthalone pigments: C.I. Pigment Yellow 138;
  • C.I. Pigment Yellow 24 (C.I. Vat Yellow 1 );
  • C.I. Pigment Blue 60 C.I. Vat Blue 4
  • 64 C.I. Vat Blue 6
  • Phthalocyanine pigments C.I. Pigment Blue 15, 15:1 , 15:2, 15:3, 15:4, 15:6 and 16; C.I.
  • C.I. Pigment Orange 51 C.I. Pigment Red 216 (C.I. Vat Orange
  • Triarylcarbonium pigments C.I. Pigment Blue 1 , 61 and 62; C.I. Pigment Green 1 ; C.I. Pigment Red 81 , 81 :1 and 169; C.I. Pigment Violet 1 , 2, 3 and 27; C.I. Pigment Black 1 (aniline black);
  • Inorganic pigments - White pigments: titanium dioxide (C.I. Pigment White 6), zinc white, pigmented zinc oxide, barium sulfate, zinc sulfide, lithopones; lead white; calcium carbonate;
  • Color pigments chromium oxide, chromium oxide hydrate green; chromium green (C.I.
  • Pigment Green 48 cobalt green (C.I. Pigment Green 50); ultramarine green; cobalt blue (C.I. Pigment Blue 28 and 36); ultramarine blue; iron blue (C.I. Pigment Blue 27); manganese blue; ultramarine violet; cobalt and manganese violet; iron oxide red (C.I. Pigment Red 101 ); cadmium sulfoselenide (C.I. Pigment Red 108); molybdate red (C.I. Pigment Red 104); ultramarine red; Iron oxide brown, mixed brown, spinel and corundum phases (C.I. Pigment Brown 24, 29 and 31 ), chromium orange;
  • Iron oxide yellow (C.I. Pigment Yellow 42); nickel titanium yellow (C.I. Pigment Yellow 53; C.I. Pigment Yellow 157 and 164); chromium titanium yellow; cadmium sulfide and cadmium zinc sulfide (C.I. Pigment Yellow 37 and 35); chromium yellow (C.I. Pigment Yellow 34), zinc yellow, alkaline earth metal chromates; Naples yellow; bismuth vanadate (C.I. Pigment Yellow 184);
  • Interference pigments metallic effect pigments based on coated metal platelets
  • pearlescent pigments based on metal oxide coated mica platelets; liquid crystal pigments.
  • Preferred pigments (F) in this context are monoazo pigments (especially laked BONS pigments, Naphthol AS pigments), disazo pigments (especially diaryl yellow pigments, bisacetoacetanilide pigments, disazopyrazolone pigments), quinacridone pigments, quinophthalone pigments, peri- none pigments, phthalocyanine pigments, triarylcarbonium pigments (alkali blue pigments, laked rhodamines, dye salts with complex anions), isoindoline pigments, white pigments, and carbon blacks.
  • Particular preferred pigments (B) are specifically: carbon black, titanium dioxide, C.I. Pigment Yellow 138, C.I. Pigment Red 122 and 146, C.I.
  • typical coatings additives (G) used can be antioxidants, stabilizers, activators (accelerants), fillers, pigments, dyes, antistatic agents, flame retardants, thickeners, thixotropic agents, surface-active agents, viscosity modifiers, plasticizers or chelating agents.
  • Suitable thickeners in addition to free-radically (co)polymerized (co)polymers, include customary organic and inorganic thickeners such as hydroxymethylcellulose or bentonite.
  • Chelating agents which can be used include, for example, ethylenediamineacetic acid and its salts, and also ⁇ -diketones.
  • Suitable fillers comprise silicates, examples being silicates obtainable by silicon tetrachloride hydrolysis, such as Aerosil ® from Evonik, siliceous earth, talc, aluminum silicates, magnesium silicates, calcium carbonates, etc.
  • Suitable stabilizers comprise typical UV absorbers such as oxanilides, triazines, and
  • benzotriazole the latter available as Tinuvin ® grades from BASF
  • benzophenones can be used alone or together with suitable free-radical scavengers, examples being sterically hindered amines such as 2,2,6,6-tetramethylpiperidine, 2,6-di-tert-butylpiperidine or derivatives thereof, e.g., bis(2,2,6,6-tetramethyl-4-piperidyl) sebacinate.
  • Stabilizers are used usually in amounts of 0.1 % to 5.0% by weight, based on the solid components comprised in the preparation.
  • the coating materials may be applied one or more times by any of a very wide variety of spraying methods, such as compressed-air, airless or electrostatic spraying methods, using one- or two-component spraying units, or else by injecting, troweling, knifecoating, brushing, rolling, roller coating, pouring, laminating, injection backmolding or coextruding.
  • spraying methods such as compressed-air, airless or electrostatic spraying methods, using one- or two-component spraying units, or else by injecting, troweling, knifecoating, brushing, rolling, roller coating, pouring, laminating, injection backmolding or coextruding.
  • the coating thickness is generally in a range from about 3 to 1000 g/m 2 and preferably 10 to 200 g/m 2 .
  • Curing is generally accomplished by drying the coatings with the coating compositions or formulations comprising the amino resins of the invention, optionally admixed with further, typical coatings additives and thermally curable resins, preferably at a temperature below 80°C, preferably room temperature to 60°C, and more preferably room temperature to 40°C, for a time of 1 minute and not more than 72 hours, preferably of not more than 48 hours, more preferably of not more than 24 hours, very preferably of not more than 12 hours, and in particular of not more than 6 hours, and subjecting them to thermal treatment (curing) under an oxygen- containing atmosphere, preferably air, or under inert gas at temperatures between 80 and 270°C, preferably between 100 and 240°C, and more preferably between 120 and 180°C.
  • an oxygen- containing atmosphere preferably air, or under inert gas at temperatures between 80 and 270°C, preferably between 100 and 240°C, and more preferably between 120 and 180°C.
  • drying operation preferably at least 25%, more preferably at least 50%, and very preferably at least 60%, by weight, of the solvent present in the coating composition prior to application ought to be removed from the applied coating material.
  • Curing of the coating takes place, as a function of the amount of coating material applied, via high-energy radiation, heat transfer from heated surfaces, or via convection of gaseous media, over a period of from seconds, for example, in the case of coil coating in combination with NIR drying, up to 5 hours, for example, high-build systems on temperature-sensitive materials, usually not less than 10 minutes, preferably not less than 15 minutes, more preferably not less than 30 minutes, and very preferably not less than 45 minutes. Drying essentially comprises removal of existing solvent, and in addition there may also even at this stage be reaction with the binder, whereas curing essentially comprises reaction with the binder.
  • curing may also take place by means of IR and NIR radiation, with NIR radiation here denoting electromagnetic radiation in the wavelength range from 760 nm to 2.5 ⁇ , preferably from 900 to 1500 nm.
  • Curing takes place in a time of 1 second to 120 minutes, preferably of 1 minute to 60 minutes.
  • a method of coating substrates which involves applying the coating composition of the invention or paint formulations comprising it, optionally admixed with thermal- ly curable resins, to the substrate, drying it, and then curing it with electron beams or UV exposure under an oxygen-containing atmosphere or, preferably, under inert gas, optionally at temperatures up to the level of the drying temperature.
  • the method of coating substrates can also be practiced by irradiating the applied coating composition of the invention, or paint formulations, first with electron beams or UV exposure, under oxygen or, preferably, under inert gas, in order to obtain preliminary curing, then carrying out thermal treatment at temperatures up to 160°C, preferably between 60 and 160°C, and subsequently completely curing with electron beams or UV exposure under oxygen or, preferably, under inert gas.
  • drying and/or radiation curing may optionally take place after each coating operation.
  • suitable radiation sources for the radiation cure are low-pressure, medium- pressure, and high-pressure mercury lamps, and also fluorescent tubes, pulsed lamps, metal halide lamps, electronic flash devices, which allow radiation curing without a photoinitiator, or excimer lamps.
  • radiation sources used include high-pressure mercury vapor lamps, lasers, pulsed lamps (flash light), halogen lamps or excimer lamps.
  • the radiation dose typically sufficient for crosslinking in the case of UV curing is situated in the range from 80 to 3000 mJ/cm 2 . It will be appreciated that it is also possible to use two or more radiation sources for the cure, two to four for example.
  • NIR radiation refers to electromagnetic radiation in the wavelength range from 760 nm to 2.5 ⁇ , preferably from 900 to 1500 nm.
  • Irradiation can optionally also be carried out in the absence of oxygen, such as under an inert gas atmosphere.
  • Suitable inert gases are preferably nitrogen, noble gases, carbon dioxide, or combustion gases.
  • irradiation may take place with the coating composition being covered with transparent media.
  • transparent media are polymeric films, glass or liquids, water for example. Particular preference is given to irradiation in the manner described in DE-A1 199 57 900.
  • suitable substrates for the coating compositions of the invention include thermoplastic polymers, particularly polymethyl methacrylates, polybutyl methacrylates, polyethylene terephthalates, polybutylene terephthalates, polyvinylidene fluorides, polyvinyl chlorides, polyesters, polyolefins, acrylonitrile-ethylene-propylene-diene-styrene copolymers (A- EPDM), polyether imides, polyether ketones, polyphenylene sulfides, polyphenylene ethers or mixtures thereof.
  • thermoplastic polymers particularly polymethyl methacrylates, polybutyl methacrylates, polyethylene terephthalates, polybutylene terephthalates, polyvinylidene fluorides, polyvinyl chlorides, polyesters, polyolefins, acrylonitrile-ethylene-propylene-diene-styrene copolymers (A- EPDM), polyether imides, polyether ketones, polyphenylene
  • Mention may preferably be made of ABS, AES, AMMA, ASA, EP, EPS, EVA, EVAL, HDPE, LDPE, MABS, MBS, MF, PA, PA6, PA66, PAN, PB, PBT, PBTP, PC, PE, PEC, PEEK, PEI, PEK, PEP, PES, PET, PETP, PF, PI, PIB, PMMA, POM, PP, PPS, PS, PSU, PUR, PVAC, PVAL, PVC, PVDC, PVP, SAN, SB, SMS, UF, UP plastics (abbreviated names in accordance with DIN 7728), and aliphatic polyketones.
  • Particularly preferred substrates are glass and metals, which, if desired, may have been pretreated with a primer.
  • suitable metals may in principle be any desired metals.
  • they are metals or alloys of the kind customarily employed as metallic materials of construction, requiring protection against corrosion.
  • the surfaces in question are in particular those of iron, steel, Zn, Zn alloys, Al or Al alloys.
  • the elements may have been only coated with these metals and may themselves be composed of materials of other kinds, such as other metals, alloys, polymers or composite materials. They may be the surfaces of castings made from galvanized iron or steel. In one preferred embodiment of the present invention the surfaces are steel surfaces.
  • Zn alloys or Al alloys are known to the skilled worker.
  • the skilled worker selects the nature and amount of alloying constituents in accordance with the desired end-use application.
  • Typical constituents of zinc alloys comprise, in particular, Al, Pb, Si, Mg, Sn, Cu or Cd.
  • Typical constituents of aluminum alloys comprise, in particular, Mg, Mn, Si, Zn, Cr, Zr, Cu or Ti.
  • the alloys may also be Al/Zn alloys in which Al and Zn are present in an approximately equal amount.
  • Steel coated with alloys of these kinds is available commercially. The steel may comprise the customary alloying components known to the skilled worker.
  • the coating compositions of the invention for treating tin-plated iron/steel (tinplate).
  • the coating compositions and formulations of the invention are additionally suitable for coating substrates such as wood, paper, textile, leather, nonwoven, plastics surfaces, glass, ceramic, mineral building materials, such as cement moldings and fiber-cement slabs, or coated or uncoated metals, preferably plastics or metals, particularly in the form of sheets, more preferably metals.
  • amino resins, coating compositions or coating formulations of the invention are suitable as or in exterior coatings, i.e., applications where they are exposed to daylight, preferably parts of buildings, interior coatings, and coatings on vehicles and aircraft.
  • amino resins and coating compositions of the invention are used as or in automotive clearcoat and topcoat material(s). Further preferred applications are in can coating and coil coating.
  • the coating compositions are especially suitable for applications where there is a need for particularly high application reliability, external weathering resistance, optical qualities, solvent resistance and/or chemical resistance.
  • Luwipal® 066LF from BASF SE is a highly to fully methyl-etherified melamine-formaldehyde resin having a nonvolatiles content (as per ISO 3251 ) of 93-96% by weight, with a low free formaldehyde content of not more than 0.3% by weight.
  • the viscosity (ISO 3219 B) is 2.0-6.0 Pas at 23°C and a shear rate D of 41.3 s "1 .
  • a formulation of the product from example 1 was mixed with Irgacure® 500 (BASF SE) and applied to a substrate using a four-path frame-type wet film applicator with a gap depth of 100 ⁇ .
  • the film was exposed with 1900 mJ/cm 2 (high-pressure Hg lamp) at room temperature in a nitrogen atmosphere.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La présente invention porte sur des résines aminiques portant des groupes (méth)acryliques, sur des procédés permettant de les préparer, sur leur utilisation et sur des compositions de revêtement les comprenant.
EP13799550.2A 2012-12-14 2013-12-04 Résines aminiques (méth)acrylées Withdrawn EP2931811A2 (fr)

Priority Applications (1)

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EP13799550.2A EP2931811A2 (fr) 2012-12-14 2013-12-04 Résines aminiques (méth)acrylées

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12197236 2012-12-14
EP13799550.2A EP2931811A2 (fr) 2012-12-14 2013-12-04 Résines aminiques (méth)acrylées
PCT/EP2013/075472 WO2014090647A2 (fr) 2012-12-14 2013-12-04 Résines aminiques (méth)acrylées

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EP2931811A2 true EP2931811A2 (fr) 2015-10-21

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US12371573B2 (en) 2020-05-15 2025-07-29 Swimc Llc Thermoset undercoating compositions compatible with free-radically cured overcoating for metal substrates
CN113278369B (zh) * 2021-05-25 2022-06-28 佛山禾邦新材料科技有限公司 一种高附着紫外光固化三防胶及其制备方法

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DE2964089D1 (en) 1978-06-21 1982-12-30 Teijin Ltd Melamine group-containing acrylates and/or methacrylates, polymerizable and curable composition thereof, molded article made of the polymerized and cured composition and resin molded article coated with the composition
EP0007508B1 (fr) 1978-07-14 1983-06-01 BASF Aktiengesellschaft Acylphosphinoxydes, leur préparation et leur utilisation
DE2909994A1 (de) 1979-03-14 1980-10-02 Basf Ag Acylphosphinoxidverbindungen, ihre herstellung und verwendung
IT1151545B (it) 1982-04-15 1986-12-24 Anic Spa Composizione a base di policarbonati alifatici con terminazioni acriliche o metacriliche reticolabile in presenza di iniziatori radicalici
JPS63286426A (ja) 1987-05-20 1988-11-24 Nippon Shokubai Kagaku Kogyo Co Ltd メラミン環含有（メタ）アクリレ−トプレポリマ−及びこれを含んでなる硬化性樹脂組成物
EP0495751A1 (fr) 1991-01-14 1992-07-22 Ciba-Geigy Ag Bisacylphosphines
ZA941879B (en) 1993-03-18 1994-09-19 Ciba Geigy Curing compositions containing bisacylphosphine oxide photoinitiators
DE19618720A1 (de) 1995-05-12 1996-11-14 Ciba Geigy Ag Bisacyl-bisphosphine, -oxide und -sulfide
EP0956280B1 (fr) 1997-01-30 2002-10-30 Ciba SC Holding AG Esters phenylglyoxaliques non volatils
DE19826712A1 (de) 1998-06-16 1999-12-23 Basf Ag Strahlungshärtbare Massen, enthaltend Phenylglyoxylate
DE19913353A1 (de) 1999-03-24 2000-09-28 Basf Ag Verwendung von Phenylglyoxalsäureestern als Photoinitiatoren
DE19957900A1 (de) 1999-12-01 2001-06-07 Basf Ag Lichthärtung von strahlungshärtbaren Massen unter Schutzgas
KR101706395B1 (ko) 2008-12-01 2017-02-13 바스프 에스이 실세스퀴옥산 광개시제
EP2350154B1 (fr) * 2009-08-05 2012-09-19 Basf Se Résines mélamine-formaldéhyde (méth)acrylées
WO2012089516A1 (fr) * 2010-12-30 2012-07-05 Basf Se Préparations pigmentaires modifiées en surface

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WO2014090647A3 (fr) 2014-09-12

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