Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
  • D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
  • D06F43/02—Dry-cleaning apparatus or methods using volatile solvents having one rotary cleaning receptacle only
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
  • D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
  • D06F43/007—Dry cleaning methods
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
  • D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
  • D06F43/08—Associated apparatus for handling and recovering the solvents
  • D06F43/081—Reclaiming or recovering the solvent from a mixture of solvent and contaminants, e.g. by distilling
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
  • D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
  • D06F43/08—Associated apparatus for handling and recovering the solvents
  • D06F43/081—Reclaiming or recovering the solvent from a mixture of solvent and contaminants, e.g. by distilling
  • D06F43/083—Condensing arrangements
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
  • D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
  • D06F43/08—Associated apparatus for handling and recovering the solvents
  • D06F43/081—Reclaiming or recovering the solvent from a mixture of solvent and contaminants, e.g. by distilling
  • D06F43/085—Filtering arrangements; Filter cleaning; Filter-aid powder dispensers
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
  • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
  • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
  • D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
  • D06L1/10—Regeneration of used chemical baths

Definitions

• the object of the invention is a dry-cleaning plant for textile articles using a composite solvent comprising a plurality of components and recycling the spent composite solvent for reuse.
• the technical field of the invention may, in general, be defined as that of dry cleaning techniques for clothing, textiles, fabrics and the like, and more particularly techniques for recycling contaminated solvents for reuse.
• Dry cleaning processes for textile articles use an organic solvent in the washing phase.
• the latter may be a mono-component solvent such as perchlorethylene which is classified as a possible carcinogen (category 3) by the European Union and which is now banned in France, or a composite solvent comprising several components such as aqueous solutions.
• ethers of propylene glycols see, for example, US Patent 6,273,919 (Hayday, WA), US 7,144,850 (Galick et al.)); C10-C13 aliphatic hydrocarbon mixtures such as Ecosolv® solvent marketed by Chevron Phillips®; compositions comprising a volatile siloxane and an organic surfactant, and optionally water (see US 6521580 (Perry et al.)); or the compositions comprising a siloxane solvent and / or a hydrocarbon solvent and an enhancer compound of a KB value of the composition (US2012 / 0085634 (Douglas et al.).
• a method of dry cleaning textile articles comprises steps of: (a) contacting the textile articles to be cleaned with the liquid solvent in a washing and drying machine provided with a cleaning basket and rotating agitation about a horizontal axis; (b) subject the textile articles in the presence of the solvent to rotational (alternating-inverted) movements to ensure the removal of soiling contaminating the textile articles, (c) extracting the spent solvent from the basket by pumping, (d) subjecting the cleaned textile articles centrifugation to extract as much of the spent solvent as possible; and (e) removing the residual solvent by vaporization by injecting a stream of hot air through the textile articles.
• the recovered solvent is most often contaminated by different kinds of soiling, namely (i) insoluble soils such as dust, balls or strands isolated from textile fibers and dye pigments detached from cleaned items and (ii) soluble soils such as fats, fatty acids from perspiration, dyes, etc.
• the recovered solvent is also very often contaminated by the water which comes from the relative humidity of the air, the moisture (eg sweat) contained in the textile articles to be cleaned, and / or the water introduced into the cleaning apparatus after pretreatment operations of textile articles for example with water-based stain removers or aqueous pretransts.
• Document US2012 / 0085634 Discloses a process for dry cleaning textile articles using a composition consisting of a dry cleaning agent comprising a siloxane solvent, a hydrocarbon solvent or their mixture and an amplifier compound, which makes it possible to increase a KB value of said composition.
• This process also includes the recycling by distillation of the used cleaning composition for the purpose of reuse.
• this process requires the implementation of a first atmospheric distillation consuming energy (at more than 100 ° C) but especially time, during which water, azeotropic and other volatile compounds are eliminated, followed by a second distillation under reduced pressure (at about 150 ° C) during which the dry cleaning agent and the boosting compound are recovered and redirected to the storage tank for reuse.
• the present invention also aims to provide such a method and such a facility that are simple and safe and that can adapt to different composite solvents.
• the solution proposed by the invention is an installation for the dry cleaning of textile articles using a composite solvent comprising several components, said installation comprising:
• a dry cleaning chamber configured to mix, during a cleaning cycle, the textile articles to be cleaned with the composite solvent
• a treatment device for removing water and dirt and recycling at least a portion of the spent composite solvent for use in another dry cleaning cycle.
• This installation is remarkable in that it further comprises a rebalancing device for rebalancing the composition of the recycled composite solvent by incorporating at least the part of the component or components which has been lost in the treatment device, which rebalancing device comprises at least: a buffer tank equipped with at least one recycled composite solvent feed inlet, at least one feed inlet in at least the portion of the or components of the composite solvent to be introduced into said buffer tank in order to rebalance the composition of the recycled composite solvent, and of at least one output of the recycled and rebalanced composite solvent, this outlet being connected to the storage tank of the composite cleaning solvent dried up,
• a storage tank for one or more components of the composite solvent for dry cleaning
• a metering pump of the amount of the component or components of the composite solvent to be introduced into the buffer tank through said inlet for the rebalancing of the composition of the recycled composite solvent this pump is connected upstream to at least one storage tank containing a or more components of the composite dry cleaning solvent.
• the advantages of the present invention are that the installation is applicable to composite dry cleaning solvents currently available commercially, in particular to composite solvents whose components can form separate and / or with water azeotropic and thus making the regeneration by distillation of the spent composite solvent complicated and difficult to manage in the dry cleaning machine.
• the installation of the invention also has the advantage of allowing the reuse of the recycled composite solvent and under optimal conditions. Indeed, thanks to the rebalancing step, the recycled composite solvent finds at least the part of the component (s) or at least the component (s) that were lost during the treatment stage, and / or recycling, the treatment step can be carried out for example by filtration followed by a conventional distillation, preferably under vacuum, then a decantation; or fractional distillation, preferably under vacuum.
• the rebalancing device is provided with an analyzer enabling analyzing the composition of the recycled composite solvent, so as to determine the amount of component (s) of the composite solvent to be withdrawn from the storage tank (s) of one or more components of the composite dry cleaning solvent, and to be introduced into the buffer tank.
• the cleaning chamber is provided with a perforated drum intended to receive the textile articles to be cleaned, said perforated drum being rotatably mounted in said enclosure, the latter having:
• an opening for the placement of textile articles to be dry cleaned in the perforated drum which opening can be closed by a door or porthole
• the spent composite solvent treatment device comprises at least one insoluble soil filtration device contained in said spent composite solvent and a fractional distillation unit, said treatment device comprising:
• the fractional distillation unit is provided with a collection container configured to initially receive the head fraction F1 before it is discharged to the evacuation tank, and then, in a second step, the fraction intermediate F2 before sending it to the buffer tank, said collection container:
• the discharge tank intended to contain the head fraction F1 comprises a pipe connected to an injection device for injecting, after N dry cleaning cycles, said fraction F1 in the fractional distillation unit. in order to separate it into at least two fractions: a head fraction F'1 intended to be eliminated, and a fraction F'2 intended to be added, before the rebalancing of the recycled composite solvent, to the intermediate fraction F2 collected after the N cycle dry cleaning.
• the composite dry-cleaning solvent used in the installation according to the invention comprises at least:
• Figure 1 schematically shows an installation according to the invention.
• Figure 2 shows schematically a variant according to the invention.
• the present invention is based on the experimental finding that used composite solvents recovered after a first cycle of dry cleaning textile articles, recycled, especially by distillation, and reused in a new cleaning cycle, are less effective for the removal of hydrophilic soils and / or hydrophobic soils than the starting composite solvents.
• This decrease in performance can be explained by the fact that during the recycling operations, especially by distillation, the composite solvents lose one or more of their components or part of one or more of their components.
• Such a loss of component (s) or part of component (s) induces a change in the composition of recycled composite solvents, and therefore a significant change in dry cleaning properties.
• the Applicant has solved this problem of declining performance of recycled composite solvents by incorporating into the composition of the latter at least the part of the component (s) which has been lost during the recycling operations.
• Composite solvent means a solvent containing at least two components which plays an essential role in imparting dry cleaning properties of textile articles.
• “Dry cleaning” means the cleaning in which the composite solvents act as a solvent or a cleaning liquid to replace the water.
• textile articles means objects used in a personal or professional setting (eg various industries, hospitals, etc.), and made from natural fibers such as cotton, wool, flax, silk or otherwise, and / or from synthetic fibers such as nylon, polyamide, acrylic, polyester, acetate, viscose, or other.
• natural fibers such as cotton, wool, flax, silk or otherwise
• synthetic fibers such as nylon, polyamide, acrylic, polyester, acetate, viscose, or other.
• textile articles include shirts, pants, sweaters, jackets, coats, tablecloths, blankets, sheets, towels, duvets, leather clothing, suede, etc.
• Soiling means soil, hydrophilic or hydrophobic, soluble in the composite solvent, and soils which are insoluble therein, such as dust, insulated balls or strands of textile fibers and dye pigments detached from cleaned or other articles.
• Hydrophobic soiling means the soiling contaminating textile articles and generally consisting of organic materials or materials which are not water-soluble and insoluble therein.
• hydrophobic soiling include fat, oil, mayonnaise, mustard, body oils, tar stains or engine oil etc.
• Hydrophilic soiling means the soiling contaminating textile articles and consisting mainly of organic or inorganic matter which has certain affinities with water and which is wholly or partially soluble therein.
• body fluids such as perspiration, blood, urine, water-soluble food products such as sugar, salt, chocolate, fruit juice, tea, coffee, etc.
• Major part means according to the invention the initial composition of the composite solvent used for the dry cleaning of textile articles, reduced by at least a portion, by weight, of one or more components of the composite solvent lost during the treatment and recycling steps of the spent composite solvent.
• the percentages, contents and ratios used below are all given relative to the total weight of the composition "w / w composite w / w composite", unless otherwise indicated.
• the present invention is aimed primarily at a method of dry cleaning textile articles using a composite solvent comprising several components and recycling the spent composite solvent for reuse.
• this process comprises:
• a dry cleaning cycle comprising contacting the textile articles to be cleaned with the composite solvent
• step d) recycling at least a portion of the composite solvent treated in step c) for use in another dry cleaning cycle
• step d) rebalancing the composition of the composite solvent recycled in step d) by incorporating into this composition at least the part of the component (s) of the composite solvent which was lost in steps c) and / or d).
• composite solvent S comprising at least:
• DPM dipropylene glycol monomethyl ether
• an amphiphilic solvent A corresponding to the following formula: R - (O-C3H6) n -OH (I) in which n is an integer equal to 1 or 2, and R is a C 3 or C 4 alkyl group, and
• a dibasic ester B selected from the group consisting of dimethyl succinate, dimethyl glutarate, dimethyl adipate and mixtures thereof.
• This composite solvent S has recently been developed by the Applicant who has demonstrated that it has a high cleaning power vis-à- hydrophobic stains (particularly fat), but also with regard to hydrophilic soils (water-soluble organic or mineral materials) which may appear on textile articles.
• the Applicant has also demonstrated that such a composite solvent can be adapted to the type of soil (hydrophobic or hydrophilic) and to the type of textile articles to be dry cleaned by varying the proportions of the three essential ingredients namely monomethyl ether of dipropylene glycol, the amphiphilic solvent A and the dibasic ester B.
• this composite solvent also has the advantage of maintaining, in solution or in suspension, the liquid or solid dirt extracted during the cleaning operation. dry, thus avoiding their redeposition on the cleaned textile articles.
• This composite solvent S can advantageously replace perchlorethylene (PERC) which is classified as a possible carcinogen (category 3) by the European Union and which is now banned in France for use in dry cleaning machines.
• PERC perchlorethylene
• the Applicant has yet been able to demonstrate that the best dry cleaning results have been obtained with the composite solvents S comprising: (i) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono- / 7-butyl ether (PnB ) and dibasic ester DBE; (ii) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono- / 7-butyl ether (DPnB) and dibasic ester DBE; or (iii) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono- / e-7-butyl ether (DPtB) and dibasic ester DBE; or (iv) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono- / 7-butyl ether (DPnB), dipropylene glycol mono- / 7-propyl ether (DPnP), and dibasic ester DBE; or (
• the preferred dibasic ester (DBE) according to the invention is the dibasic ester Rhodiasolv® RPDE marketed by Rhodia.
• This composite solvent S may advantageously also comprise all sorts of additional components usually used in the field of dry cleaning.
• the additional components may be chosen from antioxidants, disinfecting agents, perfumes and their mixtures. These additional components may be present in the composition according to the present invention in an amount between 0.001% and 10% w / w C om P osition without substantially affecting its advantageous properties.
• antioxidant agents By way of example of anti-oxidizing agents (or stabilizers), mention may be made of 2,6-di-f-butyl-methylphenol (BHT) and 2-hexyl-butyl-4-hydroxyanisole. (2-BHA) and 3-B-butyl-4-hydroxyanisole (3-BHA) or mixtures thereof.
• BHT 2,6-di-f-butyl-methylphenol
• 2-hexyl-butyl-4-hydroxyanisole (2-BHA) and 3-B-butyl-4-hydroxyanisole (3-BHA) or mixtures thereof.
• Such antioxidant agents have the function of preventing or reducing or retarding possible formation of peroxides.
• disinfecting agents By way of examples of disinfecting agents, mention may be made of quaternary ammonium salts, aldehydes, phenol derivatives, halogenated compounds (eg iodinated compounds), alcohols or others. Such disinfecting agents will have the role of allowing a disinfecting action of textile articles to be cleaned, including household, medical or veterinary laundry. They also have a cleaning action of the enclosure dedicated to dry cleaning.
• a preferred composite solvent S for carrying out the method of dry cleaning articles according to the present invention comprises:
• Such a composite solvent S has the further advantage that it can be prepared by any method of mixing known to those skilled in the art, from non-toxic components, classified as readily biodegradable, inexpensive and commercially available. . It is advantageously in the form of a clear and colorless liquid and can be packaged, in an anhydrous state, in any container capable of receiving a liquid, such as, for example, a storage tank made of steel or plastics such as polyethylene. and polypropylene.
• Step a) of the process according to the present invention can be carried out by any dry cleaning method known to those skilled in the art.
• textile articles are: i) placed in a washing and drying machine (known to those skilled in the art) comprising for example a sealed enclosure which is provided with a rotating perforated drum and which is connected to a solvent circuit comprising a solvent circulation device, ii) contacted with the composite solvent, for example by immersion, iii) stirred in the solvent Composite in rotation (alternating-inverted) movements to allow the dissolution of contamination contaminating textile articles, iv) centrifugally wiped to extract as much as possible of the spent composite solvent, and dried v) to remove the residual solvent, by example by injecting a stream of hot air through the textile articles.
• the stirring phase iii) can be carried out at a temperature ranging from 15 ° C to 60 ° C depending on the composite solvent used and the textile articles to be cleaned.
• This brewing phase iii) can be repeated several times, for example twice.
• the hot air injected during the drying phase v) has a temperature above 40 ° C, preferably between 60 ° C and 80 ° C, depending on the composite solvent used and the textile articles to be cleaned.
• the spent composite solvent is recovered in step b), on the one hand, by pumping in the spinning step iv) and, on the other hand, by cooling the vapors generated during the step of drying v).
• the solvent thus recovered is generally contaminated with various kinds of soiling, namely (i) insoluble soils such as dusts, balls or strands isolated from textile fibers and dye pigments detached from the cleaned articles and (ii) soiling soluble, hydrophilic or hydrophobic, such as fats, fatty acids from perspiration, etc.
• soiling soluble, hydrophilic or hydrophobic such as fats, fatty acids from perspiration, etc.
• the spent composite solvent recovered is also contaminated with water which comes from the relative humidity of the air and / or moisture (eg sweat) contained in the textile articles to be cleaned, and / or or water introduced into the device cleaning after pretreatment operations of textile articles for example with aqueous stain removers or aqueous pre-brushing.
• the preferred composite solvent S developed by the Applicant is contaminated at this stage by at least 0.5% w / w composite water, in particular by at most 5%.
• Step c) of the process of the present invention aims to purify the spent composite solvent recovered in step b) by removing at least water, soiling.
• the elimination of insoluble soils is carried out by filtration on filtering means selected from the group consisting of button (or pin) filters, carbon filters and their combinations. This filtration is constant from the beginning to the end of the dry cleaning cycle.
• the spent composite solvent thus filtered is subjected to fractional distillation. This fractional distillation is preferably carried out under reduced pressure, so as to eliminate a head fraction F1, on the one hand, and to collect an intermediate fraction F2, on the other hand.
• F1 overhead fraction represents less than 15% w / w S oivant spent composite and contains at least water and one or more azeotrope formed between the water and one or more components of the composite solvent.
• the F1 head fraction may also contain one or more components or part of one or more components of the composite solvent distilling at the same time as the water without necessarily forming azeotropes with the water.
• w / w composite spent SO means that the percentage is calculated with respect to the total weight of the spent solvent to be treated by fractional distillation.
• the intermediate fraction F2 represents more than 75% w / w S and composite oivant used preferably contains the composite solvent dry cleaning decreased by at least a portion, by weight, of one or more of its components, which portion was removed, for example, with the F1 head fraction and / or was lost in the bottoms fraction as explained below.
• the bottom fraction of fractional distillation is usually not recovered. It is removed from the distillation unit and transferred to a tank for further processing. This bottoms fraction may contain insoluble soils and / or soluble soils.
• step c may also contain another part, by weight, of one or more components of the composite solvent, or even one or more components of the composite solvent whose boiling point is too high even under reduced pressure, such as antioxidants, disinfectants and surfactants that are optionally included in the composition of the dry cleaning composite solvent.
• the treatment step c preferably by filtration followed by fractional distillation, may be carried out during or in parallel with the dry cleaning cycle referred to in step a).
• the fraction fraction F1 removed by fractional distillation in stage c) distils at a temperature below 82 ° C. and at a pressure of 65 mbar (or at a pressure of temperature between 20 ° C and 121 ° C under 267 mbar) and comprises at least water, dipropylene glycol monomethyl ether, and optionally an amphiphilic solvent A 'corresponding to the following formula: R'-O-C3H6 -OH ( ⁇ ) wherein R 'represents a C 3 or C 4 alkyl group.
• This F1 head fraction may furthermore comprise a ⁇ 20% fraction of F1 head in dibasic ester depending on the conditions chosen for the fractional distillation. It represents less than 15% w / w composite solvent S usé and,
• the intermediate fraction F2 collected by fractional distillation in step b) distills at a temperature above 83 ° C, preferably between 83 ° C and 140 ° C, under a pressure of 65 mbar.
• This intermediate fraction F 2 represents more than 75% w / w composite solvent S used, preferably more than 95% w / w composite solvent S used as an example of an amphiphilic solvent A 'can be mentioned mono-n-butyl propylene glycol ether, propylene glycol mono-isobutyl ether, propylene glycol mono- tert-butyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-isopropyl ether and mixtures thereof.
• the intermediate fraction F2 collected in step c) therefore has a composition that is different from that of the composite solvent used for dry cleaning. To be able to use this fraction F2 in a new cycle of dry cleaning of textile articles, it is necessary to rebalance its composition.
• the intermediate fraction F 2 (or recycled composite solvent) is transferred from the treatment unit to a storage tank in which its composition will be completed by incorporating at least the part, by weight, of the component or components which has been lost in step c).
• the part to be incorporated in the composition of the recycled composite solvent (here intermediate fraction F 2) in step d) comprises at least dipropylene glycol monomethyl ether, and the optionally one or more amphiphiles A having the following formula R- (O-C3H6) n -OH (I) in which n is an integer equal to 1 or 2, R represents a C 3 or C 4 alkyl group .
• the portion, by weight, to be incorporated into the composition of the recycled composite solvent may further comprise one or more dibasic esters B and / or one or more additional components.
• the treatment and rebalancing cycle represented by steps c) to e) described above is completely automatic and can be carried out during or in parallel with the dry cleaning phase of textile articles.
• the present invention proposes to recover the F1 head fraction after N dry cleaning cycles and to subject it to fractional distillation.
• this second fractional distillation is carried out so as to eliminate a head fraction F'1, and to recover a fraction F'2, which fraction F'2 is intended to be added, before step e) of rebalancing, to the intermediate fraction F2 collected after the dry cleaning cycle N.
• the fraction of head F'1 removed during this second fractional distillation contains a preponderant amount of water.
• the number N of dry cleaning cycles after which the removed head fraction F1 is to be recovered can be determined by those skilled in the art depending on the composition of the composite solvent used and the selectivity of the fractional distillation.
• the recovered F1 head fraction is reprocessed by fractional distillation every N dry cleaning cycles, for example every 10 to 50 dry cleaning cycles, preferably every 20 to 30 dry cleaning cycles.
• the fraction F'1 containing a preponderant quantity (> 50% w / ntraction) of water distills at a temperature below 100 ° C. under 200 mbar and the fraction F'2 to be added to the fraction at F2 distills under pressures less than 70 mbar.
• FIGS 1 and 2 attached diagrammatically, according to two preferred embodiments, the organization of an installation according to the invention.
• This installation comprises at least one dry cleaning chamber (1) configured to mix, during a cleaning cycle, the textile articles to be cleaned with the composite solvent; a reservoir (5) for storing the clean composite solvent; a treatment device (8) for the composite solvent used to recycle the latter at least in part; and a rebalancing device (9) of the recycled composite solvent composition.
• the tank (5) can be of a capacity of 120 liters in the case of a cleaning installation provided for 12 to 14 KG of textile articles to be cleaned.
• a perforated drum (2) made of stainless steel for receiving the textile articles to be cleaned is rotatably mounted in the cleaning chamber (1).
• this drum (2) is made of stainless steel, has a capacity of 200L to 1500L and can receive from 9 Kg to 70 kg of textile articles to be dry cleaned.
• the rotational speed of the drum during a cleaning operation can vary, for example, from 1 rpm to several hundred rpm, preferably from 300 rpm to 600 rpm, preferably from 400 rpm to 500 rpm. 500 rpm.
• the cleaning chamber (1) which is otherwise sealed, has at least one opening (20) for the placement of the textile articles to be cleaned in the perforated drum (2), this opening (20) being closable (hermetically) by a door or porthole; an orifice (3) connected to an introduction line (4) of the clean composite solvent which is placed in the storage tank (5); and an orifice (6) connected to a recovery line (7) of the spent composite solvent after a cleaning cycle.
• the introduction pipe (4) is, in general, provided with at least the following means (not shown in FIG. 1):
• a feed pump for feeding the composite solvent stored in the tank (5) to the cleaning chamber (1)
• heating means such as a heat exchanger, for increasing the temperature of the composite solvent for cleaning the textile articles at a temperature above room temperature, for example at a temperature between 25 ° C and 50 ° C ,
• means such as a fan, for introducing a stream of hot air (heated to a temperature above 40 ° C, preferably between 65 ° C to 75 ° C) into the cleaning enclosure (1) for to dry the cleaned textile articles.
• a stream of hot air heated to a temperature above 40 ° C, preferably between 65 ° C to 75 ° C
• the spent composite solvent is discharged through the recovery line (7).
• the latter is generally provided with at least:
• a drain valve (not shown) controlled by a control device
• an evacuation pump (not shown) able, on the one hand, to suck the spent composite solvent, and if necessary residual solvent solvent evaporated and condensed from the enclosure (1), and, secondly, to transfer it to the treatment device (8) to be recycled at least in part.
• the treatment device (8) is equipped with a filtration device (12), such as a button filter (or pins), an activated carbon filter or their combination, to clarify the spent composite solvent, in particular for ridding it of insoluble soiling; and a fractional distillation unit (13) operable to allow, on one hand, the elimination of a F1 overhead fraction comprising less than 15% w / w S oivant composite used and containing at least the water, one or more azeotropes formed between the water and one or more components of the composite solvent; and, on the other hand, recycling of an intermediate fraction F2 representing more than 75% w / w S and composite oivant worn containing the composite solvent dry cleaning decreased by at least one part by weight of a or several of its components, which part was lost in the treatment step c).
• a filtration device (12) such as a button filter (or pins), an activated carbon filter or their combination
• the fractional distillation unit (13) comprises at least the following means (not shown in FIG. 1): a distillation column equipped at its base with a boiler and at its head a condenser associated with a vacuum pump . Said boiler is fed with spent composite solvent through line (12a) and has the function of vaporizing at least part of the spent composite solvent.
• the operating conditions of said boiler are conventional and are a function of the spent composite solvent to be treated by fractional distillation, the latter being able to be implemented by temperature gradient under a constant pressure, or by pressure gradient and temperature.
• the temperature in the boiler can be maintained at a value below 250 ° C, for example at a value ranging from 25 ° C to 180 ° C, preferably from 120 ° C to 160 ° C under a reduced pressure of 65 mbar.
• the fractional distillation unit (13) has at least a first outlet for the discharge according to the arrow F1 of the head fraction F1 to an evacuation tank (or fluid container) (30) for further processing in view a reuse, and a second output for the recovery according to the arrow F2 of the intermediate fraction F2 which is sent by the pipe (7a) to the buffer tank (10) in which it must be rebalanced for use in another cycle of dry cleaning.
• the capacity of the buffer tank (10) can be 60 liters in the case of a cleaning installation provided for 12 to 14 KG of textile articles.
• the discharge tank (30) containing the head fraction F1 comprises a pipe (300) connected to an injection device (301) for injecting, after N cleaning cycles. to dry, the fraction F1 in the fractional distillation unit (13) to separate it into at least two fractions: a head fraction F'1 to be eliminated, and a fraction F'2 to be added, before the rebalancing step e) of the recycled composite solvent, at the intermediate fraction F2 collected after the dry cleaning cycle N.
• the device (9) for balancing the composition of the recycled composite solvent consists of at least:
• the buffer tank (10) equipped with at least one recycled composite solvent feed inlet (10a) (intermediate fraction F2), at least one feed inlet (10b) in at least the portion, by weight, the component or components of the composite solvent to be introduced into the buffer tank (10) in order to rebalance the composition of the recycled composite solvent (or intermediate fraction F2), and at least one outlet (10c) of the recycled and rebalanced composite solvent, this outlet (10c) being connected to the storage tank (5) of the composite cleaning solvent at dry,
• the tank (1 1) can be of a capacity of 20 liters in the case of a cleaning installation provided for 12 to 14 KG of textile articles to be cleaned.
• the rebalancing device (9) can be provided with an analyzer (15) equipping the buffer tank (10) and making it possible to analyze the physical and / or chemical characteristics of the recycled composite solvent, so as to determine the quantity of the components of the composite solvent to be introduced into this buffer tank (10).
• the analyzer (15) consists, for example, of a weight detector; a liquid level detector; a UV, Visible or Infra-Red (IR) spectrometer; a refractometer; or else, said analyzer (15) being connected to a computer server of the type incorporating a processor and a memory in which are stored one or more computer programs. These include instructions that, when executed by the processor, implement the features defined below.
• the analyzer analyzes the physical and / or chemical characteristics of the recycled composite solvent and transfers this data to the server. The latter compares the characteristics determined for the recycled composite solvent contained in the buffer tank (10) with those of the clean dry cleaning composite solvent. It is then possible to determine the quantity of the component (s) to be taken from the (or the storage tank (s) (1 1) and to be introduced into the buffer tank (10).
• the analyzer (15) thus transmits a suitable control setpoint to the metering pump (14).
• the fractional distillation unit (13) is provided with a collection container (31) configured to initially receive the head fraction F1 before being discharged according to the invention.
• the collection vessel (31) has a lowering point (31 a) at its lower part, through which the head fraction F1 and the intermediate fraction F2 are discharged to their respective tanks.
• the collection container (31) is equipped with an analyzer (15a) making it possible to analyze the physical and / or chemical characteristics of the F1 head fraction of the F1 head fraction or the F 2 fraction before their evacuation of said collection container (31), so as to determine as described above the amount of the component or components of the composite solvent to be introduced into the buffer tank (10).
• the analyzer (15a) may be of the same type as the analyzer (15) described above.
• the buffer tank (10) can also be equipped with the analyzer (15a) (option not shown).
• only the buffer tank (10) is equipped with the analyzer (15a).
• the composite dry cleaning solvent comprises at least:
• the various pumps equipping the installation of the present invention are for example centrifugal, peristaltic or vortex type pumps. And, the various pipes of the installation are provided with valves whose arrangement makes it possible to circulate the fluids correctly. These different pumps and the different valves can be controlled independently of each other to ensure optimal operation of the installation according to the invention.
• the installation of the present invention is advantageously a semi-industrial installation (hospitals, hotels, etc.) or for a wash-room or an installation for domestic use. Note:
• the composite solvents exemplified in the present description can exist in the form of positional isomers, optical isomers or their combination.
• the treatment device in particular the distillation unit, can be arranged outside the cleaning installation, and if necessary be connected to one or more other cleaning facilities.
• the boiler of the distillation unit may be provided with a draw-off point at its lower part for the recovery of the heavy fractions which have not distilled, for subsequent treatment.
• the preferred composite solvents 1 to 6 of the invention are prepared from the ingredients indicated in the table below by any method known to those skilled in the art.
• DBE dibasic ester 22 20 10 30 12 22
• the DBE dibasic ester used in Examples 1 to 6 is Rhodiasolv® RPDE marketed by Rhodia®.
• Anhydrous (colorless), clear and colorless composite solvents 1 to 6 are obtained which are chemically stable. These composite solvents can be stored for more than 1 year or more than 2 years, at a temperature below 40 ° C, in closed containers and protected from air and light. They bring, in particular, the following properties:
• composite solvents 1 to 6 as dry cleaning solvents was studied on a panel of fabrics (10 cm x 10 cm) made of various fibers as well as on accessories frequently found on textile articles.
• a first study focused on the observation of tissue deformation and discoloration and the second on the effectiveness of stain cleaning.
• composite solvents 1 to 6 as a dry cleaning solvent has been studied on linings frequently encountered on textile articles such as buttons, plastic or metal zippers and glued flakes.
• the tissues studied contained soiling caused by the following contaminants: olive oil, chocolate (Nutella®), mayonnaise, lipstick, red wine, ink and were compared to perchlorethylene and hydrocarbons. These tests were carried out without the use of intensifier (surfactant).
• the composite solvents of Examples 1 to 6 made it possible to very easily clean greasy stains without the use of additives.
• the composite solvents of Examples 1, 2, 4 and 6 are particularly effective for dry cleaning stains due to butter or olive oil, which stains are no longer visible at the end of the cleaning process.
• the composite solvents of Examples 1 and 2 have in particular been very effective for dry cleaning, especially on stains due to chocolate, lipstick and wine, which spots have become less visible after the cleaning process. unlike perchlorethylene which leaves larger spots.

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• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
• Detergent Compositions (AREA)
• Processing Of Solid Wastes (AREA)
• Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
• Treatment Of Fiber Materials (AREA)

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• 2013
  • 2013-01-22 FR FR1350536A patent/FR3001235B1/fr active Active
• 2014
  • 2014-01-22 EP EP14706878.7A patent/EP2948585A2/de not_active Withdrawn
  • 2014-01-22 CN CN201480005689.5A patent/CN104955999B/zh not_active Expired - Fee Related
  • 2014-01-22 US US14/761,374 patent/US20160010269A1/en not_active Abandoned
  • 2014-01-22 WO PCT/FR2014/050120 patent/WO2014114879A2/fr not_active Ceased
  • 2014-01-22 WO PCT/FR2014/050121 patent/WO2014114880A2/fr not_active Ceased

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