Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
  • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
  • B01J20/3285—Coating or impregnation layers comprising different type of functional groups or interactions, e.g. different ligands in various parts of the sorbent, mixed mode, dual zone, bimodal, multimodal, ionic or hydrophobic, cationic or anionic, hydrophilic or hydrophobic
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D43/00—Separating particles from liquids, or liquids from solids, otherwise than by sedimentation or filtration
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
  • B01J20/3204—Inorganic carriers, supports or substrates
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
  • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
  • B01J20/3268—Macromolecular compounds
  • B01J20/327—Polymers obtained by reactions involving only carbon to carbon unsaturated bonds
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
  • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
  • B01J20/3268—Macromolecular compounds
  • B01J20/3272—Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F1/00—Treatment of water, waste water, or sewage
  • C02F1/28—Treatment of water, waste water, or sewage by sorption
  • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B82—NANOTECHNOLOGY
  • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
  • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
  • C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities

Definitions

• PCT application no. PCT/US12/39524 (Atty docket no. 712-002.359-1 ), entitled "Mineral separation using functionalized polymer membranes;
• PCT application no. PCT/US12/39540 (Atty docket no. 712-002.359-2), entitled "Mineral separation using sized, weighted and magnetized beads;
• PCT application no. PCT/US12/39576 (Atty docket no. 712-002.382), entitled “Synthetic bubbles/beads functionalized with molecules for attracting or attaching to mineral particles of interest;
• PCT application no. PCT/US/39596 (Atty docket no. 71 2-002.384), entitled "Synthetic bubbles and beads having hydrophobic surface;”
• This invention relates generally to a method and apparatus for separating valuable material from unwanted material in a mixture, such as a pulp slurry.
• flotation is used to separate valuable or desired material from unwanted material.
• the pulp slurry is a mixture of water, valuable material, unwanted material, and chemicals to render the value material to be hydrophobic.
• the valuable material and unwanted material from an ore are usually ground to a particle size between 45 to 250 microns or roughly 45 to 100 mesh.
• particles smaller than 400 mesh are usually required. Fine grinding consumes a great amount of electrical energy.
• known techniques for mineral separation include the following:
• U.S. Patent No. 4,657,666 discloses a magnetic separation technique for mineral upgrading or concentration that includes steps of:
• gangue associated mineral having a hydrophobic surface and in particulate form
• the magnetic material may include magnetite, haematite, ilmenite, a ferrite or magnetic metal or alloy.
• U.S. Patent No. 4,906,382 discloses a magnetic separation technique for separating particles of a nonmagnetic material from an aqueous mixture that includes steps of:
• each of the magnetic particles having a two layer surfactant coating including an inner layer and an outer layer, the inner layer covering the magnetic particle and being a monomolecular layer of a first water soluble, organic, heteropolar surfactant containing at least 3 carbon atoms and having a functional group on one end which forms a bond with the magnetic particle and a hydrophobic end, and the outer layer coating the inner layer and being monomolecular layer of a second water soluble, organic, heteropolar surfactant containing at least 3 carbon atoms and having a hydrophobic end which is bonded to the hydrophobic end of the first surfactant and a functional group on the other end capable of bonding with the nonmagnetic particles; and
• U.S. Patent No. 8,408,395 discloses another known technique for mineral separation that apparently tried to solve the aforementioned disadvantages associated with the aforementioned magnetic separation techniques disclosed in the '666 patent and the '382 patent.
• the '395 patent discloses a magnetic separation technique for separating a hydrophobic material from a mixture having a hydrophobic material and a hydrophilic material, that includes the steps of:
• step (B) contacting the slurry or dispersion from step (A) with a solid, hydrophobic surface to bind the hydrophobic material to be separated from the slurry or the dispersion, the solid hydrophobic surface being an interior wall of a tube, a surface of a plate, a surface of a conveyor belt or an interior wall of a reactor;
• step (C) removing the solid, hydrophobic surface to which the one hydrophobic material is bound in step (B) from the slurry or dispersion having a hydrophilic material;
• hydrophobic material present in the mixture is hydrophobicized by a substance before carrying out step (B), and also
• the substance is made up of a radical and an anchor group having 1 to 3 reactive groups which interact(s) with the hydrophobic material to be separated off.
• a hydrophobicizing substance increases efficiency of separation, citing an example provided in which a glass beaker is coated with hydrophobized magnetite so that a hydrophobic surface is present.
• hydrophobic coating or layer has no polar groups, and therefore has a water repellant character.
• the '395 patent appears to try to solve problems associated with the aforementioned high magnetic fields, e.g., by removing magnetite from the mixture and incorporating the magnetite into the coating or layer that forms the solid, hydrophobic surface.
• its mineral separation technique avoids coupling of magnetizable particles to the hydrophobic constituents in the mixture to be separated off, as well as the use of a stream of air.
• the mineral separation technique of the '395 patent is based on the use of magnetite and its associate magnetic forces in order to bind the hydrophobic material to be separated from the slurry or the dispersion to the coating or layer that forms the solid, hydrophobic surface.
• the present invention may provide mineral separation or filtration techniques based at least partly on using apparatus featuring a collection area comprising collection surfaces configured to contact with a mixture having water and valuable material, the valuable material having a plurality of mineral particles; and a synthetic material provided at least on the collection surfaces, the synthetic material having plurality of molecules comprising a siloxane functional group configured to attract the mineral particles to the collection surfaces.
• the collection surface may take the form of an impeller, a conveyor belt, a filter assembly, a flat plate, a membrane or membrane structure and a plurality of synthetic beads.
• a conveyor belt made of polyurethane and coated with a silicone gel able to collect value material of a wide range of sizes, including the particles far larger than about 500 microns.
• a surface used to collect the value material from a pulp slurry is herein referred to as a collection surface.
• the collection surface is functionalized to be hydrophobic so as to provide a bonding between the collection surface and a mineral particle that is hydrophobic.
• the collection surface comprises a surface made of a polymer and coated with a silicone gel to provide the siloxane functional group.
• bonding when used in relation to two hydrophobic articles, such as the surface of the polymer bubbles or beads and the mineral particle, is intended to refer to the situation of when two hydrophobic articles come together in an aqueous solution to reduce the exposed hydrophobic surface area. This new state is at a lower energy state than when the two articles are separated within the aqueous solution. The action of the
• hydrophobic effect originates from the disruption of highly dynamic hydrogen bonds between molecules of liquid water for example by the non-polar solute.
• hydrocarbon chain or a similar non-polar region or a big molecule is incapable of forming hydrogen bonds with water, and introduction of such a non-hydrogen bonding surface into water causes disruption of the hydrogen bonding network between water molecules.
• the hydrogen bonds are reoriented tangential to such a surface to minimize disruption of the hydrogen bonded 3D network of water molecules, thus leading to a structured water "cage" around the non-polar surface.
• the hydrophobic effect can be said to cause two hydrophobic articles to "attract " and / or "attach " to one another.
• polymer in this specification means a large molecule made of many units of the same or similar structure linked together.
• polymer bubbles or beads and “synthetic bubbles or beads” are used interchangeably.
• the polymer can be naturally hydrophobic or functionalized to be hydrophobic. Some polymers having a long hydrocarbon chain or silicon-oxygen backbone, for example, tend to be hydrophobic. Hydrophobic polymers include, but are not limited to,
• the collection surfaces can be rendered hydrophobic by having a coating of a product that contains chemicals with a siloxane functional group.
• the collection surface is coated with hydrophobic silicone polymer including polysiloxane so that the collection surface becomes hydrophobic.
• the collection surface is made of polyurethane rubber coated with a silicone gel, such as Dow-Corning ® 3-4222 Dielectric Firm Gel.
• Part A includes dimethyl siloxane, dimethylvinyl-terminated - 68083-19-2; polydimethylsiloxane (PDMS) - 63148-62-9; reaction of ethylene glycol and silica - 170424-65-4; hydrotreated light naphthenic petroleum distillate - 64742-53-6.
• Part B includes dimethyl siloxane, dimethylvinyl- terminated - 68083-19-2; polydimethylsiloxane - 63148-62-9; dimethyl siloxane, hydrogen-terminated - none; trimethylated silica - 68909-20-6: dimethyl,
• the mineral particle or the valuable material associated with one or more amphiphilic collector molecules is referred to as a wetted mineral particle.
• a wetted mineral particle When the pulp slurry contains a plurality of collectors or collector molecules, some of the mineral particles will become wetted mineral particles if the collectors are attached to mineral particles, thus making the surface of the mineral particles hydrophobic. Xanthates can be used in the pulp slurry as the collectors.
• the key mechanism for the materials is the combination of hydrophobicity, tackiness and compliance.
• the mechanism works as follows:
• the hydrophobicity of the surface provides the selectivity. When in the water based solution, the hydrophobic surface attracts the hydrophobic minerals of interest, and rejects the non-hydrophobic gangue materials.
• Compliance is also a key component. Material compliance is essential to allow surface area contact in hydrophobic conditions, and further to allows surface area contact under tacky conditions after withdrawal from the solution. This may also be due at least in part to Van der Waals forces.
• the present invention may take the form of apparatus such as a collection surface configured to contact with solid hydrophobic particles having mineral particles with hydrophobic elements attached thereon contained in an aqueous mixture.
• the collection surface comprises a plurality of molecules configured to render the surface hydrophobic, and the molecules comprising a siloxane functional group to attract the solid hydrophobic particles.
• the molecules may include a siloxane derivative, or polysiloxanes, or hydroxyl-terminated
• PDMS polydimethylsiloxanes
• the collection surface may include an impeller, a flat plate, a filter assembly, a conveyor belt, a membrane and/or a synthetic bead having a polymer surface coated with a siloxane derivative.
• the polymer surface may comprise urethane, polyurethane molecules, such as urethane rubber or polyurethane rubber.
• the polymer is selected from a group consisting of polystyrene, poly(dj-lactide),
• the synthetic bead may be configured to be magnetic, or para-, ferri- or ferro-magnetic.
• the synthetic bead may be configured to have a different density than the aqueous mixture so as to float or sink therein. According to some embodiments of the present invention, the synthetic bead may be configured to have substantially the same density as the aqueous mixture so as to neither float nor sink therein.
• the surface may include physical structures configured to trap the mineral particles, e.g., like grooves or dents, or configured as hair-like structures.
• an impeller is configured to rotate inside two chambers, tanks, cells or columns, one chamber, tank, cell or column having an environment conducive to attachment of a valuable material or mineral or particle of interest and the other chamber, tank, cell or column has an environment conducive for release of the valuable material or mineral or particle of interest.
• the impeller may comprise a collection surface having a siloxane functional group, configured to rotate inside the two chambers, tanks, cells or columns for attachment of and for releasing of the valuable material.
• a functionalized polymer conveyor belt may be configured to run between the two chambers, tanks, cells or columns, whereby it collects and releases the valuable material or mineral or particle of interest.
• a functionalized polymer collection filter may be placed into each chamber, tank, cell or column to collect and release the valuable material or mineral or particle of interest. This is a batch type process.
• the method may feature steps for receiving an aqueous mixture in a processor, the mixture comprising solid hydrophobic particles having mineral particles with hydrophobic elements attached thereon; causing a plurality of collection surfaces to contact with the aqueous mixture in the processor, where said collection surface comprises:
• a solid-phase body comprising a surface
• hydrophobic coating comprising a plurality of molecules configured to render the surface hydrophobic, the molecules comprising a siloxane functional group configured to attract to the surface the solid hydrophobic particles in the aqueous mixture.
• the solid-phase body may take the form of an impeller, a conveyor belt, a filter assembly with a plurality of collection surfaces, a synthetic bead, wherein the collection surface may comprise a polymer layer coated with a silicone gel to provide the siloxane functional group.
• the collection surface comprise polymer surface and the synthetic material comprise a siloxane derivative.
• the synthetic material may comprise polysiloxanes.
• the synthetic material may comprise one or more of dimethyl siloxane, dimethylvinyl-terminated; polydimethylsiloxane (PDMS); and dimethyl,
• the synthetic material may comprise hydroxyl-terminated
• the polymer surface comprises polyurethane.
• the collection surface may comprise a polymer selected from a group consisting of polyamides, polyesters, polyurethanes, phenol-formaldehyde, urea-formaldehyde, melamine- formaldehyde, polyacetal, polyethylene, polyisobutylene, polyacrylonitrile, polyvinyl chloride), polystyrene, poly(methyl methacrylates), polyvinyl acetate),
• poly(carbonate), phenolic resin, and polydimethylsiloxane are examples of poly(carbonate), phenolic resin, and polydimethylsiloxane.
• the collection surface may comprise a polymer from a group consisting of polystyrene, poly(d,l- lactide), poly(dimethylsiloxane), polypropylene, polyacrylic, polyethylene, hydrophobically-modified ethyl hydroxyethyl cellulose polysiloxanes, alkylsilane and fluoroalkylsilane.
• the collection area comprises one or more of an impeller, a filter assembly, a conveyor belt and a flat plate.
• the collection area comprises a plurality of synthetic beads.
• the method may include one or more of the features set forth herein.
• the method may feature steps for arranging a plurality of collection surfaces to contact with an aqueous mixture comprising solid hydrophobic particles having mineral particles with hydrophobic elements attached thereon, said collection surface comprising: a solid- phase body comprising a synthetic surface, and a coating of a silicone gel comprising a plurality of molecules configured to render the surface hydrophobic, the molecules also being configured to attract the solid hydrophobic particles to the collection surface; allowing the solid hydrophobic particles to attach to the collection surfaces for providing a plurality of enriched collection surfaces, the enriched collection surfaces comprising at least some of the solid hydrophobic particles attached thereto; and releasing said some of the solid hydrophobic particles from the surface of the enriched collection surfaces .
• the method may include a step of releasing that includes washing the enriched collection surfaces with water so as to remove at least some of the solid hydrophobic particles from the surface.
• a step of releasing that includes washing the enriched collection surfaces with water so as to remove at least some of the solid hydrophobic particles from the surface.
• ultrasonic waves can also be applied to the enriched collection surfaces for removing the solid
• the method may include removing the enriched collection surfaces from the aqueous mixture by one or more of the following mechanisms: mechanical brushing, magnetic agitation, change of pH, increased temperature, and chemical solvent.
• the method may include one or more of the features set forth herein.
• the apparatus may take the form of a hydrophobic synthetic structure having a solid-phase body comprising a surface; and a synthetic material provided on the surface, the synthetic material comprises a plurality of molecules configured to render the surface hydrophobic, and the combination of the molecules and the surface being configured to attract and retain solid hydrophobic particles having mineral particles with hydrophobic elements attached thereon contained in an aqueous mixture, the molecules comprising a siloxane functional group.
• the synthetic material may be selected from the following group: a siloxane derivative, polysiloxanes or hydroxyl-terminated polydimethylsiloxanes.
• the hydrophobic synthetic structure may take the form of some combination of a mesh-like structure, a membrane-like structure, a grooved structure, a grate- 1 ike structure, a tubular structure, a hairy structure, a course structure, a smooth structure, a rectangular structure, a honeycomb-like structure, a solid bead, or a two-part bead structure with an inner core and an outer covering, and the surface having a corresponding structural characteristic based at least partly on the configuration of the
• the present invention may also take the form of apparatus for use in, or forming part of, a separation process to be implemented in separation processor technology, the apparatus featuring collection surfaces configured with a polymer or polymer-based material functionalized with a siloxane functional group so as to attach to a wetted valuable material in a mixture to form an enriched collection surfaces having the valuable material attached thereto, and also configured to be separated from the mixture based at least partly on a difference in a physical property between the enriched collection surfaces having the valuable material attached thereto and the mixture.
• the separation process may be implemented in separation processor technology which combines the collection surfaces and the mixture, and which provides the enriched collection surfaces having the valuable material attached thereto that are separated from the mixture based at least partly on the difference in the physical property between the enriched collection surfaces having the valuable material attached thereto and the mixture.
• the collection surface carrying the mineral particles may be caused to contact with a liquid
• the step of interrupting may include applying a sonic agitation to the liquid for causing the mineral particles to separate from the collection surface, or the step of interrupting may include applying microwaves to the liquid for causing the mineral particles to separate from the collection surface.
• the step for interrupting may include providing an ultrasonic source to apply the sonic agitation to the liquid, and/or arranging the ultrasonic source to produce ultrasound signals for sonic agitation, for example ultrasound signals in the range of 20KHz to 300HKz for the sonic agitation.
• the step of interrupting may include providing an ultrasonic signal selected at the resonant frequency of the beads for causing the mineral particles to separate from the collection surface.
• the step of interrupting may include
• the brushing can be carried out in a solution containing a chemical solvent, such as alcohol, for example.
• the collection surface carrying the mineral particles may be received along with a mixture having a first pH value
• the step for interrupting may include causing the collection surface carrying the mineral particles to contact with a medium having a second pH value lower than the first pH value, including where the second pH value ranges from 0 to 7.
• the step of interrupting may include mechanically causing the collection surfaces, such as synthetic beads, to move against each other, including arranging a rotational means or device to stir the synthetic beads.
• the collection surface may be made of a polymer having a glass transition temperature, and the second temperature may be substantially equal to or higher than the glass transition temperature.
• part of the collection surfaces, such as synthetic beads, carrying the mineral particles may be made of a magnetic material, and the step of interrupting may include arranging a magnetic stirrer to stir the synthetic beads.
• the collection surface carrying the mineral particles may be received along with a mixture, wherein said interrupting comprises selecting two or more of the following interrupting techniques: 1 ) lowering pH value of the mixture, 2) applying an ultrasound to the mixture; 3) increasing temperature of the mixture, 4) mechanically brushing and 5) introduction of a chemical solvent.
• the selected interrupting techniques may be used on the mixture concurrently or sequentially.
• Figure 1 includes Figure 1 a is a side partial cutaway view in diagram form of a separation processor configured with two chambers, tanks or columns having a functionalized polymer coated impeller arranged therein according to some embodiments of the present invention, and includes Figure 1 b is a top partial cross- sectional view in diagram form of a functionalized polymer coated impeller moving in an attachment rich environment contained in an attachment chamber, tank or column and also moving in a release rich environment contained in a release chamber, tank or column according to some embodiments of the present invention.
• Figure 2 is diagram of a separation processor configured with two chambers, tanks or columns having a functionalized polymer coated conveyor belt arranged therein according to some embodiments of the present invention.
• Figure 3 is diagram of a separation processor configured with a functionalized polymer coated filter assembly for moving between two chambers, tanks or columns in a semi-continuous batch process according to some embodiments of the present invention.
• Figure 4 is an illustration of an impeller according to some embodiments of the present invention.
• Figure 5 is an illustration of a section of a conveyor belt according to some embodiments of the present invention.
• Figure 6 is an illustration of a filter according to some embodiments of the present invention.
• Figures 7a-7f illustrates various surface features of the impeller, conveyor belt and filter according to some embodiments of the present invention.
• Figures 8a illustrates a plurality of functional groups attached to a fiber for attracting mineral particles according to some embodiments of the present invention, according to some embodiments of the present invention.
• Figures 8b illustrates a plurality of hydrophobic molecules attached to a fiber for attracting mineral particles, according to some embodiments of the present invention.
• Figures 8c illustrates a plurality of hydrophobic molecules attached to a fiber for attracting non-mineral particles according to some embodiments of the present invention.
• Figure 9a illustrates a plurality of functional groups attached to surfaces for attracting mineral particles, according to some embodiments of the present invention.
• Figure 9b illustrates a plurality of hydrophobic molecules attached to surfaces for attracting mineral particles, according to some embodiments of the present invention.
• Figure 9c illustrates a plurality of hydrophobic molecules attached to surfaces for attracting non-mineral particles, according to some embodiments of the present invention.
• Figure 10a illustrates a plurality of filters placed in a horizontal pipeline to collect mineral particles, according to some embodiments of the present invention.
• Figure 10b illustrates a release apparatus configured to release mineral particles from a filter, according to some embodiments of the present invention.
• Figure 1 1 is a diagram showing a filter placed in a tailings pond to collect valuable material according to some embodiments of the present invention.
• Figure 12a illustrates an impeller using a plurality of synthetic beads or bubbles for collecting valuable material, according to some embodiments of the present invention.
• Figure 12b illustrates a filter using a plurality of synthetic beads or bubbles for collecting valuable material, according to some embodiments of the present invention.
• Figure 12c illustrates a sack of synthetic beads which can be used as a filter to collect valuable material in a tailings pond, for example, according to some embodiments of the present invention.
• Figure 13a illustrates a synthetic bead functionalized to attract hydrophobic particles, according to some embodiments of the present invention.
• Figure 13b is an enlarged surface portion of the synthetic bead functionalized to attract wetted mineral particles, according to some embodiments of the present invention.
• Figure 13c is an enlarged surface portion of the synthetic bead functionalized to attract non-mineral hydrophobic particles, according to some embodiments of the present invention.
• Figure 14a illustrates a synthetic bead having a functional group to attract mineral particles according to some embodiments of the present invention.
• Figure 14b is an enlarged surface portion of the synthetic bead functionalized to attract mineral particles, according to some embodiments of the present invention.
• FIGS 15a and 1 5b illustrate some embodiments of the present invention wherein the synthetic bead or bubble have one portion functionalized to have collector molecules and another portion functionalized to be hydrophobic, according to some embodiments of the present invention.
• Figure 16a shows a diagram of apparatus having a conveyor belt made of polyurethane and coated with a silicone gel for collecting value material of a wide range of sizes, including the particles far larger than about 500 microns, according to some embodiments of the present invention.
• Figure 16b shows an exploded or enlarged diagram of a part of the conveyor belt shown in Figure 16a, according to some embodiments of the present invention.
• Figures 16a and 1 6b shows a new embodiment of the present invention, while the remaining Figures 1 to 15b show the subject matter of the aforementioned PCT application no. PCT/US 12/39631 (712-2.385//CCS-0092).
• Figures 16a, 16b
• Figure 16a shows the present invention in the form of an apparatus generally indicated as 500 including a collection area or tank 502 having one or more collection surfaces 504 configured to contact with a mixture 506 having water and valuable material, the valuable material having a plurality of mineral particles 508 of interest; and a synthetic material 504a provided at least on the collection surfaces as shown in Figure 1 6b, the synthetic material 504a having plurality of molecules with a siloxane functional group configured to attract the mineral particles 508 of interest to the collection surfaces 504.
• the one or more collection surfaces 504 may form part of a conveyor belt also indicated as 504, as shown, that is driven through the collection area or tank 502, through a release area or tank 510, back through the collection area or tank 502, etc.
• the conveyor belt 504 is arranged on various pulleys 51 1 that may be driven by one or more motors (not shown) and configured with corresponding linkage (also not shown).
• Conveyor belts and conveyor belt systems are known in the art, and the scope of the invention is not intended to be limited to any particular type or kind thereof either now known or later developed in the future.
• the mixture 506 may include, or take the form of, a pulp slurry having ground ore with mineral particles of interest forming part thereof, including mineral particles of interest of about 500 microns or larger.
• the mixture 506 may include chemistry configured to enhance the attraction and/or attachment between the synthetic material having the siloxane functional group and the mineral particles 508 of interest in the mixture 506.
• the mixture 506 may include a hydrophobizing agent and/or polymeric collector, e.g., including polyethylenimine (PEI), although the scope of the invention is intended to include other types or kinds of hydrophobizing agents and/or polymeric collectors within the spirit of the present invention.
• PEI polyethylenimine
• the mixture 506 may include Xanthate or Xanthate salt, which is otherwise known in the art to be used as a flotation and/or hydrophobic agent in mineral processing.
• the chemistry set forth herein is intended to include chemistry or chemistries that are both now known or later developed in the future.
• the collection area or tank 502 may be configured with one or more stirrers, mixers or agitators 512 for stirring, mixing or agitating the mixture 506.
• the release area or tank 510 may be configured with one or more broom-like devices 514 for sweeping and/or releasing in whole or in part attached mineral particles 508 of interest from the synthetic material 504a of the collection surfaces 504.
• the broom-like device 514 is configured on either or both sides of the conveyor belt 504.
• the release area or tank 510 may have a corresponding mixture 516 configured to enhance the releasing in whole or in part of the attached mineral particles 508 of interest from the synthetic material 504a of the collection surfaces 504. As shown, the collection area or tank 502 and the release area or tank 510 are separated by a wall 518.
• the conveyor belt 504 may be made of polyurethane rubber indicated as 504b in Figure 16b and coated with a silicone gel indicated as 504a for collecting the valuable material of interest of a wide range of sizes, including particles far larger than about 500 microns.
• the silicone gel 504a will cure and harden to as to form part of, and stick to, the polyurethane rubber 504b.
• the polyurethane rubber 504b may be coated on either or both sides with the silicone gel 504a.
• the scope of the invention is intended to include, and embodiments are envisioned in which, the conveyor belt 504 may be made of some other elastic material either now known or later developed in the future.
• the silicone gel 504a may include, or take the form of, molecules having the siloxane functional group, e.g., including a siloxane that is, or may take the form of, a functional group in organosilicon chemistry with the Si-O-Si linkage.
• parent siloxanes may include, or take the form of, oligomeric and polymeric hydrides with the formulae H(OSiH 2 ) n OH and (OSiH 2 ) n -
• the scope of the invention is also intended to include other types or kinds of siloxanes either now known or later developed in the future, e.g., including branched compounds, where the defining feature includes each pair of silicon centers being separated by one oxygen atom.
• the silicone gei 504a took the form of a product from Dow-Corning® Corporation, Midland, Ml 48686-0994, USA, e.g., labeled as product no. 2986922-1 104 (Lot: 0007137499), that is sold in a combination that includes 3-4222 Dielectric Firm Gel Part A and 3-4222 Dielectric Firm Gei Part B.
• the gel comes with two parts: Part A includes dimethyl siloxane, dimethylvinyl-terminated - 68083-1 9-2;
• Part B includes dimethyl siloxane, dimethylvinyl-terminated - 68083-1 9-2;
• the one or more collection surfaces 504 may be configured or made substantially of a material that consists of a siloxane-based material in a non-gel form.
• PDMS is understood to be characterized by a chemical formula:
• PDMS includes oxygen, hydrogen, silicon and carbon. Because of the presence of oxygen, PDMS is normally considered or classified as being part of a polar group.
• polarity is generally understood to refer to a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment, and a polar molecule is generally understood to have a polarity that is characterized as being asymmetric.
• the scope of the invention is not intended to be limited to the collection surface 504 including, or taking the form of, a conveyor belt.
• the collection surface 504 includes, or takes the form of, one or more of an impeller, a filter assembly and/or a flat plate, as well as other types or kinds of collection surfaces either now known or later developed in the future, consistent with that set forth herein.
• Figure 1 shows the present invention is the form of a machine, device, system or apparatus 1 0, e.g., for separating valuable material from unwanted material in a mixture 1 1 , such as a pulp slurry, using a first processor 12 and a second processor 14.
• the first processor 1 2 and the second processor 14 are configured with a functionalized polymer coated member that is shown, e.g., as a functionalized polymer coated impeller 20 (Fig. 1 a), 20' (Fig. 1 b), according to some embodiments of the present invention.
• the impeller 20, 20' slowly rotates in relation to the first processor 12 and the second processor 14, the impeller blades slowly pass through the attachment rich environment 1 6 in the first processor 12 where the valuable material is attached to the blades and through the release rich environment 18 in the second processor 14. is released from the blades.
• the impeller 20 is shown rotating in a counterclockwise direction as indicated by arrow a, although the scope of the invention is not intended to be limited to the direction of the impeller rotation, or the manner in which the functionalized polymer coated impeller 20 (Fig. 1 a), 20' (Fig. 1 b) is arranged, mounted, or configured in relation to the first processor 12 and the second processor 14.
• the first processor 12 may take the form of a first chamber, tank, cell or column that contains an attachment rich environment generally indicated as 1 6.
• the first chamber, tank or column 12 may be configured to receive via piping 13 the mixture or pulp slurry 1 1 in the form of fluid (e.g., water), the valuable material and the unwanted material in the attachment rich environment 16, e.g., which has a high pH, conducive to attachment of the valuable material.
• the second processor 14 may take the form of a second chamber, tank, cell or column that contains a release rich environment generally indicated as 18.
• the second chamber, tank, cell or column 14 may be configured to receive via piping 15, e.g., water 22 in the release rich environment 18, e.g., which may have a low pH or receive ultrasonic waves conducive to release of the valuable material.
• the first processor 12 may be configured to receive the mixture or pulp slurry 1 1 of water, valuable material and unwanted material and the functionalized polymer coated member that is configured to attach to the valuable material in the attachment rich environment 16.
• the functionalized polymer coated member is shown as the functionalized polymer coated impeller 20 (Fig. 1 a), 20' (Fig. 1 b).
• the functionalized polymer coated impeller 20 has a shaft 21 and at least one impeller blade 20a, 20b, 20c, 20d, 2e, 20f, 20g and is configured to rotate slowly inside the first processor 1 2 and the second processor 14.
• the functionalized polymer coated impeller 20' has a shaft 21 ' and impeller blades 20a', 20b', 20c', 20d', 2e', 20f, 20g' and 20h'.
• Each impeller blade in Figures 1 is understood to be configured and functionalized with a polymer coating to attach to the valuable material in the attachment rich environment 16.
• the first processor 12 is configured to receive at least one impeller blade of the functionalized polymer coated impeller 20 (Fig. 1 a), 20' (Fig. 1 b).
• the at least one impeller blade is shown as impeller blade 20g' being received in an attachment zone 30 that forms part of the attachment rich
• the first processor 12 may also be configured with a first transition zone generally indicated as 40 to provide drainage from piping 41 of, e.g., tailings 42 as shown in Figure 1 a.
• the first processor 12 may also be configured to provide at least one enriched impeller blade having the valuable material attached thereto, after passing through the attachment rich environment 16.
• the at least one enriched impeller blade is shown as the at least one enriched impeller blade 20c' being provisioned from the attachment rich environment 1 6 in the first processor 12 to the release rich environment 18 in the second processor 14.
• the second processor 14 may be configured to receive via the piping 15 the fluid 22 (e.g. water) and the enriched functionalized polymer coated member to release the valuable material in the release rich environment 1 8.
• the second processor 14 is shown receiving the enriched impeller blade 20c' in a release zone 50, e.g., that forms part of the release rich environment 18 and is defined, e.g., by walls 30c and 30d.
• the second processor 14 may also be configured to provide the valuable material that is released from the enriched functionalized polymer coated member into the release rich environment 18.
• the second processor 14 is shown configured with a second transition zone 60 defined by walls 30a and 30d to provide via piping 61 drainage of the valuable material in the form of a concentrate 62 (Fig. 1 a).
• Figure 2 The Functionalized Polymer Coated Conveyor Belt
• Figure 2 shows the present invention is the form of a machine, device, system or apparatus 1 00, e.g., for separating valuable material from unwanted material in a mixture 101 , such as a pulp slurry, using a first processor 102 and a second processor 104.
• the first processor 102 and the second processor 104 are configured with a functionalized polymer coated member that is shown, e.g., as a functionalized polymer coated conveyor belt 120 that runs between the first processor 102 and the second processor 1 04, according to some
• the arrows A1 , A2, A3 indicate the movement of the functionalized polymer coated conveyor belt 1 20.
• Techniques, including motors, gearing, etc., for running a conveyor belt like element 120 between two processors like elements 102 and 1 04 are known in the art, and the scope of the invention is not intended to be limited to any particular type or kind thereof either now know or later developed in the future.
• the functionalized polymer coated conveyor belt 120 may be made of a mesh material.
• the first processor 102 may take the form of a first chamber, tank, cell or column that contains an attachment rich environment generally indicated as 1 06.
• the first chamber, tank or column 102 may be configured to receive the mixture or pulp slurry 101 in the form of fluid (e.g., water), the valuable material and the unwanted material in the attachment rich environment 106, e.g., which has a high pH, conducive to attachment of the valuable material.
• the second processor 104 may take the form of a second chamber, tank, cell or column that contains a release rich environment generally indicated as 108.
• the second chamber, tank, cell or column 104 may be configured to receive, e.g., water 122 in the release rich environment 108, e.g., which may have a low pH or receive ultrasonic waves conducive to release of the valuable material.
• water 122 in the release rich environment 108
• the second chamber, tank, cell or column 104 may be configured to receive, e.g., water 122 in the release rich environment 108, e.g., which may have a low pH or receive ultrasonic waves conducive to release of the valuable material.
• attachment rich environments like that forming part of element environment 1 06 conducive to the attachment of a valuable material of interest and release rich environments like that forming part of environment 108 conducive to the release of the valuable material of interest are known in the art, and the scope of the invention is not intended to be limited to any particular type or kind thereof either now known or later developed in the future.
• a person skilled in the art would be able to formulate an attachment rich environment like environment 106 and a
• any particular valuable mineral of interest e.g., copper, forming part of any particular mixture or slurry pulp.
• the first processor 102 may be configured to receive the mixture or pulp slurry 101 of water, valuable material and unwanted material and the functionalized polymer coated conveyor belt 120 that is configured to attach to the valuable material in the attachment rich environment 106.
• the belt 120 is understood to be configured and functionalized with a polymer coating to attach to the valuable material in the attachment rich environment 1 06.
• the first processor 102 may also be configured to provide drainage from piping 141 of, e.g., tailings 142 as shown in Figure 2.
• the first processor 102 may also be configured to provide an enriched functionalized polymer coated conveyor belt having the valuable material attached thereto, after passing through the attachment rich environment 106.
• the enriched functionalized polymer coated conveyor belt is shown, e.g., as that portion or part 1 20a of the belt 120 being provisioned from the attachment rich environment 106 in the first processor 102 to the release rich environment 1 08 in the second processor 104. It is understood that some other portions or parts of the belt 120 may be enriched, including the portion or part immediately leaving the attachment rich environment 106, as well as the portion or part immediately entering the release rich environment 108.
• the second processor 14 may be configured to receive the fluid 122 (e.g. water) and the portion 120a of the enriched functionalized polymer coated conveyor belt 120 to release the valuable material in the release rich environment 108.
• the fluid 122 e.g. water
• the second processor 104 may also be configured to provide the valuable material that is released from the enriched functionalized polymer coated member into the release rich environment 108.
• the second processor 104 is shown configured to provide via piping 161 drainage of the valuable material in the form of a concentrate 162.
• the first processor 102 is configured with the functionalized polymer coated conveyor belt 1 20 passing through with only two turns inside the attachment rich environment 106.
• the first processor 102 may be configured to process the functionalized polymer coated conveyor belt 1 20 using a serpentine technique for winding or turning the belt 120 one way and another way, back and forth, inside the first processor to maximize surface area of the belt inside the processor 102 and exposure of the belt 120 to the attachment rich environment 106.
• Figure 3 shows the present invention is the form of a machine, device, system or apparatus 200, e.g., for separating valuable material from unwanted material in a mixture 201 , such as a pulp slurry, using a first processor 202, 202' and a second processor 204, 204'.
• the first processor 202 and the second processor 204 are configured to process a functionalized polymer coated member that is shown, e.g., as a functionalized polymer coated collection filter 220 configured to be moved between the first processor 202 and the second processor 204' as shown in Figure 3 as part of a batch type process, according to some embodiments of the present invention.
• the batch type process is shown as having two first processor 202, 202' and second processor 204, 204, although the scope of the invention is not intended to be limited to the number of first or second processors. Moreover, embodiments are envisioned using a different number of first and second processor, different types or kinds of processors, as well as different types or kinds of processors both now known or later developed in the future.
• the functionalized polymer coated collection filter 220 may take the form of a membrane or a thin soft pliable sheet or layer.
• the arrow B1 indicates the movement of the functionalized polymer coated filter 220 from the first processor 202
• the arrow B2 indicates the movement of the functionalized polymer coated collection filter 220 into the second processor 202.
• Techniques, including motors, gearing, etc., for moving a filter like element 220 from one processor to another processor like elements 202 and 204 are known in the art, and the scope of the invention is not intended to be limited to any particular type or kind thereof either now know or later developed in the future.
• the first processor 202 may take the form of a first chamber, tank, cell or column that contains an attachment rich environment generally indicated as 206.
• the first chamber, tank or column 102 may be configured to receive the mixture or pulp slurry 201 in the form of fluid (e.g., water), the valuable material and the unwanted material in the attachment rich environment 206, e.g., which has a high pH, conducive to attachment of the valuable material.
• the second processor 204 may take the form of a second chamber, tank, cell or column that contains a release rich environment generally indicated as 208.
• the second chamber, tank, cell or column 204 may be configured to receive, e.g., water 222 in the release rich environment 208, e.g., which may have a low pH or receive ultrasonic waves conducive to release of the valuable material.
• the release rich environment 208 e.g., which may have a low pH or receive ultrasonic waves conducive to release of the valuable material.
• the first processor 202 may be configured to receive the mixture or pulp slurry 101 of water, valuable material and unwanted material and the functionalized polymer coated collection filter 220 that is configured to attach to the valuable material in the attachment rich environment 206.
• the functionalized polymer coated collection filter 220 that is configured to attach to the valuable material in the attachment rich environment 206.
• the functionalized polymer coated collection filter 220 is understood to be configured and functionalized with a polymer coating to attach to the valuable material in the attachment rich environment 106.
• the first processor 202 may also be configured to provide drainage from piping 241 of, e.g., tailings 242 as shown in Figure 3.
• the first processor 202 may also be configured to provide an enriched functionalized polymer coated collection filter having the valuable material attached thereto, after soaking in the attachment rich environment 1 06.
• the enriched functionalized polymer coated collection filter 220 is shown, e.g., being provisioned from the attachment rich environment 206 in the first processor 202 to the release rich environment 208 in the second processor 204.
• the second processor 204 may be configured to receive the fluid 222 (e.g. water) and the enriched functionalized polymer coated collection filter 220 to release the valuable material in the release rich environment 208.
• the fluid 222 e.g. water
• the enriched functionalized polymer coated collection filter 220 may be configured to release the valuable material in the release rich environment 208.
• the second processor 204 may also be configured to provide the valuable material that is released from the enriched functionalized polymer coated collection filter 220 into the release rich environment 208.
• the second processor 204 is shown configured to provide via piping 261 drainage of the valuable material in the form of a concentrate 262.
• the first processor 202' may also be configured with piping 280 and pumping 280 to recirculate the tailings 242 back into the first processor 202'.
• the scope of the invention is also intended to include the second processor 204' being configured with corresponding piping and pumping to recirculate the concentrate 262 back into the second processor 204'. Similar recirculation techniques may be implemented for the embodiments disclosed in relation to Figures 1 -2 above.
• the scope of the invention is not intended to be limited to the type or kind of batch process being implemented.
• the batch process may include the first and second processors 202, 204 being configured to process the enriched functionalized polymer coated collection filter 220 in relation to one type or kind of valuable material, and the first and second processors 202', 204' being configured to process the enriched functionalized polymer coated collection filter 220 in relation to either the same type or kind of valuable material, or a different type or kind of valuable material.
• the scope of the invention is intended to include batch processes both now known and later developed in the future.
• the polymer at least can be functionalized to attract particles in two different ways.
• the polymer surface has a plurality of molecules 73 ( Figures 8a, 9a) having a functional group 78 ( Figures 8a, 8b) to attract mineral particles 72 ( Figures 8a, 9a).
• the polymer surface has a plurality of molecules 79 ( Figures 8b, 9b, 9c,
• Molecules 79 represent siloxane functional groups.
• the siloxane functional groups may be provided by one or more of dimethyl siloxane, dimethylvinyl-terminated; polydimethylsiloxane; and dimethyl, methylhydrogen siloxane.
• the siloxane functional groups may be provided by dimethyl siloxane, hydrogen-terminated.
• polymer in this disclosure means a large molecule made of many units of the same or similar structure linked together.
• the polymer surface on a filter has a plurality of molecules 73 ( Figures 8a, 9a) having a functional group 78 ( Figures 8a, 8b) to attract mineral particles 72 ( Figures 8a, 9a).
• the unit can be a monomer or an oligomer which forms the basis of, for example, polyamides (nylon), polyesters, polyurethanes, phenol-formaldehyde, urea-formaldehyde, melamine-formaldehyde, polyacetal, polyethylene, polyisobutylene, polyacrylonitrile, polyvinyl chloride), polystyrene, poly(methyl methacrylates), polyvinyl acetate), poly(vinylidene chloride), polyisoprene, polybutadiene, polyacrylates, poly(carbonate), phenolic resin, polydimethylsiloxane and other organic or inorganic polymers.
• polyamides nylon
• polyesters polyurethanes
• phenol-formaldehyde urea-formaldehyde
• melamine-formaldehyde polyacetal
• polyethylene polyisobutylene
• polyacrylonitrile polyvinyl chloride
• the synthetic material can be hard or rigid like plastic or soft and flexible like an elastomer. While the physical properties of the filter can vary, the surface of the filter is chemically functionalized to provide a plurality of functional groups to attract mineral particles.
• the terms "valuable material” and “mineral particle” are used herein interchangeably.
• the molecule 76 can be a hydrocarbon chain, for example, and the functional group 78 can be ionic for attracting a mineral, such as copper to the surface 74.
• a xanthate for example, has both the functional group 78 and the molecular segment 76 to be incorporated into the polymer that is used to make or coat the surface.
• a functional group 78 is also known as a collector that is either ionic or non-ionic.
• the ion can be anionic or cationic.
• An anion includes, but not limited to, oxyhydryl, such as carboxylic, sulfates and sulfonates, and sulfhydral, such as xanthates and dithiophosphates.
• Other molecules or compounds that can be used to provide the function group 78 include thionocarboamates, thioureas, xanthogens,
• a chelating agent can be incorporated into the polymer as a collector site for attaching to a mineral, such as copper.
• a surface having a functionalized polymer is also referred herein as synthetic surface.
• At least the surface of a filter surface is functionalized so that the surface is hydrophobic. It is possible to functionalize a polymer surface to have a plurality of molecules 79 ( Figures 8b, 8c, 9b, 9c) to render the surface hydrophobic.
• the molecules 79 may comprise a siloxane functional group.
• hydrophobicity is the physical property of a molecule (known as a hydrophobe) that is repelled from a mass of water. Hydrophobic molecules tend to be non-polar and, thus, prefer other neutral molecules and non-polar solvents.
• Hydrophobic molecules in water often cluster together. According to
• thermodynamics matter seeks to be in a low-energy state, and bonding reduces chemical energy.
• Water is electrically polarized, and is able to form hydrogen bonds internally, which gives it many of its unique physical properties. But, since hydrophobes are not electrically polarized, and because they are unable to form hydrogen bonds, water repels hydrophobes, in favor of bonding with itself. It is this effect that causes the hydrophobic interaction.
• the hydrophobic effect is the observed tendency of nonpolar substances to aggregate in aqueous solution and exclude water molecules. It can be observed as the segregation and apparent repulsion between water and non-polar substances.
• the hydrophobic interaction is mostly an entropic effect originating from the disruption of hydrogen bonds between molecules of liquid water by the non-polar solute.
• a hydrocarbon chain or a similar non-polar region or a big molecule is incapable of forming hydrogen bonds with water.
• the introduction of such a non- hydrogen bonding surface into water causes disruption of the hydrogen bonding network between water molecules. By aggregating together, nonpolar molecules reduce the surface area exposed to water and minimize their disruptive effect.
• Froth flotation is a process for selectively separating hydrophobic materials from hydrophilic.
• the process has been adapted and applied to a wide variety of materials to be separated, and additional collector agents, including surfactants and synthetic compounds have been adopted for various applications.
• froth flotation is a process for separating minerals from gangue by taking advantage of differences in their hydrophobicity. Hydrophobicity differences between valuable minerals and waste gangue are increased through the use of surfactants and wetting agents. The selective separation of the minerals makes processing complex (that is, mixed) ores economically feasible.
• the flotation process is used for the separation of a large range of sulfides, carbonates and oxides prior to further refinement. Phosphates and coal are also upgraded (purified) by flotation technology.
• Froth flotation commences by comminution (that is, crushing and grinding), which is used to increase the surface area of the ore for subsequent processing. The ore include the desired minerals and other unwanted materials, know a gangue.
• the process of grinding the ore into a fine power is known as liberation.
• the fine powder ore is then mixed with water to form a slurry.
• the desired mineral is rendered hydrophobic by the addition of a surfactant or collector chemical. The particular chemical depends on which mineral is being refined.
• This slurry (more properly called the pulp) of hydrophobic mineral particles and hydrophilic gangue particles is then placed in a flotation column or horizontal pipeline wherein the concentrated mineral is separated from the tailings containing the gangue.
• the collectors are chosen based upon their selective wetting of the types of particles to be separated. A good collector will adsorb, physically or chemically, with one of the types of particles.
• a flotation circuit for mineral concentration various flotation reagents are added to a mixture of ore and water (called pulp) in a conditioning tank.
• the flow rate and tank size are designed to give the minerals enough time to be activated.
• the conditioner pulp is fed to a bank of rougher cells which remove most of the desired minerals as a concentrate.
• the rougher pulp passes to a bank of scavenger cells where additional reagents may be added.
• the scavenger cell froth is usually returned to the rougher cells for additional treatment, but in some cases may be sent to special cleaner cells.
• the scavenger pulp is usually barren enough to be discarded as tails.
• More complex flotation circuits have several sets of cleaner and re-cleaner cells, and intermediate re-grinding of pulp or concentrate. Because of a number of other factors, as much as 15% of the liberated minerals are not recovered and are discarded as gangue. Collectors
• Collectors either chemically bond (chemisorption) on a hydrophobic mineral surface, or adsorb onto the surface in the case of, for example, coal flotation through physisorption. Collectors increase the natural hydrophobicity of the surface, increasing the separability of the hydrophobic and hydrophilic particles.
• the hydrophobic particles of interest are depicted as particles 71 ', 72' in Figures 8b, 8c, 9b and 9c.
• the impeller 20 has a collection area 23 to support the functionalized polymer ( Figure 4).
• the conveyor belt 120 has a collection area 123 to support the functionalized polymer ( Figure 5).
• the filter 220 has a collection area 223 to support the functional polymer ( Figure 6).
• the collection area 23, 123 and 223 can take many forms and have various surface features (Figures 7a-7f) to attract the mineral particles of interest, when the impeller 20, conveyor belt 120 and the filter 220 are made contact with a mixture or pulp slurry 1 1 ( Figure 1 ), 101 ( Figure 2), 201 ( Figure 3) that includes water and valuable material.
• Figures 7a-7f Surface Features
• each of the collection areas 23, 123 and 223 may have a plurality of openings to allow the pulp slurry 1 1 (Figure 1 ), 101 ( Figure 2), 201 ( Figure 3) to pass through while collecting at least part of the valuable material in the pulp slurry.
• the surface inside an opening and the surfaces or edges around the opening will be provided with the functional groups to attract the mineral particles. Those surfaces are referred to as collection surfaces.
• the openings on the collection areas 23, 123 and 223 can take the form of holes or cylindrical passage ways 701 as shown in Figure 7a.
• the openings on the collection areas 23, 1 23 and 223 can take the form of hexagonal passage ways 702 arranged like honeycomb, as shown in Figure 7b.
• the collection areas 23, 1 23 and 223 can have a rectangular grid 703, as shown in Figure 7c.
• the collection areas 23, 123 and 223 may comprise a stack of wavy sheets 704 a shown in Figure 7d.
• the collection areas 23, 123 and 223 may comprise an irregular arrangement of fiber-like structures 705 as shown in Figure 7e.
• the collection areas 23, 1 23 and 223 may comprise a plain surface 706 as shown in Figure 7f.
• the plain surface 06 may be a smooth surface, a paper-like surface or matted surface, without larger structures.
• the collection area 23, 123 and 223 can be made of a synthetic material, such as a polymer functionalized for attracting the mineral particles. Alternatively, only the collection surfaces are coated with such a polymer.
• the collection area 223 comprises a panel, such as a glass panel, a ceramic panel and a metal sheet, wherein one or both sides of the panel has a plain surface 706.
• the impeller 20 and the filter 220 comprise a collection of synthetic bubbles or beads as shown in Figures 12a-1 2b.
• the fiber-like structures 705 ( Figure 7e) can be any fiber-like structures 705 ( Figure 7e).
• the fiber-like structures 705 as shown in Figure 7e can be made of individual fibers 401 , 401 ' as shown in Figure 8a-8c.
• the fiber 401 ( Figure 8a) can be made of a polymer that has a plurality of molecules 73 to provide the functional group 78 and the attaching molecular segment 76.
• a xanthate for example, has both the functional group 78 and the molecular segment 76 to be incorporated into the polymer that is used to make the fiber 401 .
• a functional group 78 is also known as a collector that is ionic or non-ionic to attract mineral particles 72.
• the ion can be anionic or cationic.
• An anion includes, but not limited to, oxyhydryl, such as carboxylic, sulfates and sulfonates, and sulfhydral, such as xanthates and dithiophosphates.
• Other molecules or compounds that can be used to provide the function group 78 include thionocarboamates, thioureas, xanthogens, monothiophosphates, hydroquinones and polyamines.
• the fiber 401 is coated with polymer that has the molecules 73 to provide the functional group 78 and the attaching molecular segment 76. With such a coating, the fiber 401 can be made of glass, ceramic, metal, nylon, cotton or a different polymer.
• a diagram of the fiber 401 and the attached molecules 73 is shown in Figure 8a.
• the fiber 401 ' ( Figure 8b) can be made of a polymer that has a plurality of molecules 79 to render the fiber 401 ' (and thus the collection areas 23, 123 and 223 of Figures 4, 5, 6) hydrophobic.
• the polymer can be a hydrophobic material such as polystyrene, poly(d,l-lactide), poly(dimethylsiloxane), polypropylene, polyacrylic, polyethylene, etc.
• the polymer can also be a hydrophobically-modified polymer, such as hydrophobically-modified ethyl hydroxyethyl cellulose.
• the fiber 401 ' can be made of glass, ceramic, metal, nylon, cotton or other fabric materials and coated with hydrophobic molecules, such as a siloxane functional group in a silicone gel.
• the molecules 79 cause the fiber 401 ' to become hydrophobic.
• a hydrophobically-modified mineral particle 72' can be attracted to the hydrophobic fiber 401 '.
• hydrophobically-modified, or wetted, mineral particle 72' comprises a mineral particle 71 and one or more molecules 73 attached thereon.
• the molecule 73, or collector has a functional group 78 attached to the mineral particle 71 and a hydrophobic chain or molecular segment 76.
• a diagram showing the attraction between the hydrophobic chain or molecular segments 76 and the hydrophobic fiber 401 ' is shown in Figure 8b.
• the particles 72' may be non- mineral and can be some harmful particles in a body of water.
• the hydrophobic fiber 401 ' can also be used to attract non-mineral particles.
• a non-mineral particle 71 ' has one or more hydrophobic chains or molecular segments 76
• the non-mineral particle 71 ' is also attracted to the hydrophobic fiber 401 '.
• a diagram showing the attraction between non-mineral particles 71 ' and the hydrophobic fiber 401 ' is shown in Figure 8c.
• the hydrophobic fiber 401 ' can be used in a filter, impeller or conveyor belt (similar to those shown in Figures 4-6) for water-pollution control, water purification, etc.
• the surfaces and edges around the openings or surface structures 701 , 702, 703, 704 can be functionalized to provide the molecules 73 ( Figures 9a, 9b).
• the exposed surfaces and edges around the openings or surface structures 701 , 702, 703, 704 are represented by surface portions 403, 403' as shown in Figures 9a-9c.
• the length L of the surface portions 403, 403' can be equal to the thickness of the impeller 20, conveyor belt 120 and filter 220 ( Figures 4-6).
• the surface portion 403 can be made of a polymer that has a plurality of molecules 73 to provide the functional group 78 and the attaching molecular segment 76.
• the surface portion 403 is coated with polymer that has the molecules 73 to provide the functional group 78 and the attaching molecular segment 76.
• the surface portion 403 can be made of glass, ceramic, metal, nylon, cotton or a different polymer.
• the surface portion 403' can be made of a polymer having a plurality of molecules 79 that render the surface portion 403' (and thus the collection areas 23, 123 and 223 of Figures 4, 5, 6) hydrophobic.
• the molecules 79 may comprise siloxane functional groups.
• the polymer can be a hydrophobic material such as polystyrene, poly(d,l-lactide), poly(dimethylsiloxane), polypropylene, polyacrylic, polyethylene, etc.
• the polymer can also be a hydrophobic material such as polystyrene, poly(d,l-lactide), poly(dimethylsiloxane), polypropylene, polyacrylic, polyethylene, etc.
• the polymer can also be a
• hydrophobically-modified polymer such as hydrophobically-modified ethyl hydroxyethyl cellulose.
• the surface portion 403' can be made of glass, ceramic, metal, nylon, cotton or other fabric materials and coated with hydrophobic molecules, such as polysiloxanes, alkylsilane and fluoroalkylsilane. The molecules
• hydrophobically-modified mineral particle 72' is attracted to the hydrophobic surface portion 403'.
• a diagram showing the attraction between the molecular segments 76 and the hydrophobic surface portion 403' is shown in Figure 9b.
• the particles 72' may be non-mineral and can be some harmful particles in a body of water.
• the hydrophobic surface portion 403' can also be used to attract non-mineral particles.
• a non-mineral particle 71 ' has one or more hydrophobic chains or molecular segments 76
• the non-mineral particle 71 ' is also attracted to the hydrophobic surface portion 403'.
• a diagram showing the attraction between the non-mineral particles 71 ' and the hydrophobic surface portion 403' is shown in Figure 9c.
• a filter, impeller or conveyor belt similar to those shown in Figures 4-6 that has hydrophobic surface portions
• the treatment of plain surface 706 can be made similar to the surface portions 403, 403' as shown in Figures 9a-9c. That is, the plain surface 706 can be functionalized to provide a functional group 78 as shown in Figure 9a.
• the plain surface 706 can also be functionalized to be hydrophobic, as shown in Figures 9b and 9c.
• the impeller 20 ( Figure 1 a), the conveyor belt 120 ( Figure 2) and the filter 220 ( Figure 3) are used in a horizontal pipeline for mineral separation.
• a group of filters 220 can be used in a first processor 202 as shown in Figure 3.
• a plurality of filters 220 are placed into a horizontal pipeline 300 to collect the valuable material in the slurry 322, as shown in Figure 10a. As the slurry passes through the filters 220, some of the mineral particles in the slurry will become attached to collection area 223 and the openings (see Figures 7a-7e).
• one or more of the filters 220 can be taken out of the horizontal pipeline 300 for mineral releasing (see Figure 10b) while other filters 220 continue to collect the mineral particles.
• the tailings 342 can be discharged or transported to a tailings pond or the like (see Figure 1 1 ).
• the attached mineral particles on the filter 220 can be released in a release rich environment with a low pH solution and/or ultrasonic agitation.
• the pH value of the low pH solution can be 0 to 7, for example.
• the filter 220 with collected mineral particles can be placed in a releasing apparatus 410 to be washed with a mixture of acid and water provided by water container 424 and acid container 422.
• the filter 200 comprises a panel, such as a glass panel, a ceramic panel, a metal sheet, a plastic sheet, wherein the panel is coated with a synthetic material comprising a plurality of molecules configured to attract the mineral particles.
• the surface of the panel can be a plain surface as shown in Figure 7f.
• the reclaimed water 427 can be channeled back for reuse.
• the concentrated mineral 440 can be taken out of the releasing apparatus 410.
• the pH value is lower than the pH value for mineral attachment. It should be noted that, however, when the valuable material is copper, for example, it is possible to provide a lower pH environment for the attachment of mineral particles and to provide a higher pH environment for the releasing of the mineral particles from the synthetic beads or bubbles.
• the pH value is chosen to facilitate the strongest attachment, and a different pH value is chosen to facilitate release.
• one pH value is chosen for mineral attachment, and a different pH value is chosen for mineral releasing. The different pH could be higher or lower, depending on the specific mineral and collector.
• Tailings scavenger cells are used to scavenge the unrecovered minerals from a tailings stream.
• Tailings cleaning cell is used to clean unwanted material from the tailings stream before it is sent to the disposal pond.
• Tailings reclamation machine that is placed in the tailings pond to recover valuable mineral that has been sent to the tailings pond.
• the filter 220 ( Figures 3, 6) can also be used for mineral recovery in a tailings point.
• one or more filters 220 may be placed in a tailings pond 350 to collect the mineral particles in the tailings 342.
• collector molecules such as xanthates should be added into the tailings 342 so that the mineral particles in the tailings can be wetted.
• synthetic beads and filters according to the present invention are also configured for use in oilsands separation - to separate bitumen from sand and water in the recovery of bitumen in an oilsands mining operation.
• the collection surfaces on the surface structures are coated with a synthetic material having particular molecules to attract mineral particles.
• the synthetic material can be used to provide those particular molecules on beads or bubbles, or to make the beads or bubbles (see Figures 13a-14b).
• the bubbles or beads that have the particular molecules to attract mineral particles are herein referred to as synthetic bubbles or beads.
• the synthetic beads or bubbles 1 70 are used in an impeller or a filter to collect mineral particles 72, 72' (see Figures 8a-9b, 13a- 14b).
• the impeller uses a cage or the like to contain a plurality of synthetic beads to provide the collection surfaces in the collection area 23.
• the filter uses a cage or the like to contain a plurality of synthetic beads 170 to provide the collection surfaces in the collection area 223.
• the synthetic beads or bubbles 170 are used to collect valuable material in a tailings pond 350 ( Figure 1 1 ), they can be put in a sack 320 as shown in Figure 12c.
• the synthetic material to be used on the synthetic beads or bubbles 170 may have the functional groups 78 to attract the mineral particles 72, or may have the hydrophobic molecules 79 comprising a siloxane functional group.
• Figure 13a illustrates a synthetic bead functionalized to attract hydrophobic particles.
• the synthetic bubble or bead 170 has a solid- phase bead body to provide a bead surface 174. At least the outside part of the bead body is made of a synthetic material, such as a hydrophobic polymer, or a coating of a hydrophobic chemical.
• the surface 174 of the synthetic bubble or bead comprises a plurality of molecules 79 which renders the surface 174 hydrophobic.
• Molecules 79 may comprise a siloxane functional group.
• the surface 1 74 may be a glass surface coated with polysiloxanes which can bind to the hydroxyl group of the glass surface.
• Polysiloxanes such as hydroxyl-terminated polydimethysiloxanes, have a silicon- oxygen chain to provide the hydrophobic molecules 79.
• the hydrophobic particle 72' can be a mineral particle 71 having one or more collectors 73 attached thereto. One end (78) of the collector 73 has an ionizing bond attached to the mineral particle 71 . The other end of the collector 73 has a hydrophobic chain 76 which tends to move into the hydrophobic molecules 79.
• the hydrophobic particle 72' can be a wetted mineral particle.
• a collector such as xanthate, has both the functional group 78 and the molecule 76.
• the hydrophobic particle 72 as shown in Figure 13c, can be a particle 71 ' that has a hydrophobic chain 76.
• Such particle can be non-mineral related, but it can be arranged to contact with the hydrophobic synthetic bubbles or beads 170 of the present inventions.
• the particle 71 may be non-mineral and can be harmful to the environment.
• the hydrophobic bubbles or beads 170 can be used in non-mining applications, such as water-pollution control and water purification.
• the size of the synthetic bead can be smaller than the minimum size of the mineral particles which is about 1 50 ⁇ , and can be larger than the maximum size of the mineral particles. In certain applications, the size of the synthetic bead can be 1 cm or larger.
• Figure 14a illustrates a synthetic bead having a functional group to attract mineral particles.
• the synthetic bead 1 70 has a bead body to provide a bead surface 174 to attract mineral particles 72.
• Figure 14b is an enlarged surface of the synthetic bead functionalized to attract mineral particles.
• At least the outside part of the bead body is made of a synthetic material, such as polymer, so as to provide a plurality of molecules or molecular segments 76 on the surface 1 74.
• the molecule 76 is used to attach a chemical functional group 78 to the surface 1 74.
• the molecule 76 can be a hydrocarbon chain, for example, and the functional group 78 can have an anionic bond for attracting a mineral, such as copper to the surface 174.
• a xanthate for example, has both the functional group 78 and the molecular segment 76 to be incorporated into the polymer that is used to make the synthetic bead 70.
• the functional group 78 is also known as a collector that can have a nonionizing or ionizing bond to attract the mineral particles 72.
• a chelating agent can be incorporated into the polymer as a collector site for attracting a mineral, such as copper.
• the releasing of the mineral particles from the synthetic beads can be similar to the releasing of the mineral particles from the impeller, conveyor belt or the filter.
• the synthetic beads 170 in the collection area 23 or 223 or in the sack 320 Figures 12a-12c
• the synthetic beads 170 can be made contact with a low pH solution and/or subjected to ultrasonic agitation (e.g., Figure 10b) in order to release the mineral particles.
• a high pH solution can also be used for releasing certain mineral particles while a low pH environment is used for mineral attachment.
• only a portion of the surface of the synthetic bead is functionalized to be hydrophobic. This has the benefits as follows:
• the weight of the mineral is likely to force the bead to rotate, allowing the bead to be located under the bead as it rises through the flotation cell;
• only a portion of the surface of the synthetic bead is functionalized with collectors. This also has the benefits of
• one part of the synthetic bead is functionalized with collectors while another part of same synthetic bead is functionalized to be hydrophobic as shown in Figures 15a and 15b.
• a synthetic bead 74 has a surface portion where polymer is functionalized to have collector molecules 73 with functional group 78 and molecular segment 76 attached to the surface of the bead 74.
• the synthetic bead 74 also has a different surface portion where polymer is functionalized to have hydrophobic molecules 79.
• the entire surface of the synthetic bead 74 can be functionalized to have collector molecules 73, but a portion of the surface is functionalized to have hydrophobic molecules 79 render it hydrophobic.
• Molecules 79 may comprise a siloxane functional group.
• This "hybrid" synthetic bead can collect mineral particles that are wetted and not wetted.
• the surface of a synthetic bead can be functionalized to have a collector molecule.
• the collector has a functional group with an ion capable of forming a chemical bond with a mineral particle.
• a mineral particle associated with one or more collector molecules is referred to as a wetted mineral particle.
• the synthetic bead can be functionalized to be hydrophobic in order to collect one or more wetted mineral particles.

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• Chemical & Material Sciences (AREA)
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• Life Sciences & Earth Sciences (AREA)
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• Water Supply & Treatment (AREA)
• Solid-Sorbent Or Filter-Aiding Compositions (AREA)
• Compositions Of Macromolecular Compounds (AREA)
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• 2014
  • 2014-05-13 AU AU2014265626A patent/AU2014265626A1/en not_active Abandoned
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• 2015
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• 2018
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