Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
  • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
  • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
  • C08G69/28—Preparatory processes
  • C08G69/30—Solid state polycondensation
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
  • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
  • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
  • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
  • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
  • C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
  • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
  • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
  • C08G69/28—Preparatory processes

Definitions

• the present invention relates to a polyamide resin and a method of preparing the same. More particularly, the present invention relates to a technology for improving transparency of a polyamide resin.
• polyamides are broadly applied to materials for clothes, fibers for industrial materials, engineering plastics, and the like.
• polyamides used in the field of transparent components for industrial devices, mechanical, electrical, electronic and automobile parts, and optical materials such as glasses or lenses are required to have further improved properties and functions.
• Patent Document 1 JP2009-203422A discloses a continuous preparation method of a polyamide resin, in which a dicarboxylic acid having a certain structure and a diamine are continuously supplied to a polymerization reactor to produce a low-order condensate (polyamide prepolymer), which in turn is continuously supplied to a twin-screw extruder to produce a resin having a high polymerization degree.
• the polyamine resin prepared by the method disclosed in Patent Document 1 fails to exhibit sufficient levels of properties in terms of transparency, color and mechanical strength, and is thus required to be further improved.
• the inventors of the present invention have conducted research to solve the problems as mentioned above. From the research, the inventors completed the present invention based on the finding that a polyamide resin prepared to have a high degree of polymerization through solid polymerization of a low-order condensate, prepared by polycondensation of a dicarboxylic acid having a certain structure and a diamine in the presence of a phosphorus compound, exhibited significant improvement in terms of various properties, particularly, transparency.
• the preparation method includes preparing a low-order condensate in a solid phase through polycondensation of a dicarboxylic acid and a diamine in the presence of about 0.01 wt% to about 0.5 wt% of a phosphorus compound based on the total amount of the dicarboxylic acid and the diamine; and solid polymerizing the low-order condensate, wherein the dicarboxylic acid includes about 70 mol% or more of a C 9 to C 12 aliphatic dicarboxylic acid based on the total amount of the dicarboxylic acid, the diamine includes about 50 mol% or more of a diamine represented by Formula 1 based on the total amount of the diamine, the polycondensation is performed at a maximum temperature of about 200°C to about 230°C, and the solid polymerization is performed at a maximum reaction temperature of about 170°C to about 230°C: wherein
• the polycondensation may be performed at a maximum reaction temperature of about 200°C to about 220°C.
• the solid polymerizing may be performed at a maximum reaction temperature of about 170°C to about 210°C.
• the phosphorus compound may include at least one selected from the group consisting of phosphorous acid, hypophosphorous acid, and salts thereof.
• the polyamide resin is prepared through polycondensation of a dicarboxylic acid and a diamine, and includes about 0.01 wt% to about 0.5 wt% of a phosphorus compound, wherein the dicarboxylic acid includes about 70 mol% or more of a C 9 to C 12 aliphatic dicarboxylic acid based on the total amount of the dicarboxylic acid, the diamine includes about 50 mol% or more of a diamine represented by Formula 1 based on the total amount of the diamine, and a 4 mm thick molded article produced using the polyamide resin has a total light transmission of about 85% or more and a yellowness index (YI) of about 5 or less: wherein R 1 is a C 1 to C 3 alkylene group.
• YI yellowness index
• the diamine may include about 70 mol% or more of the diamine represented by Formula 1 based on the total amount of the diamine.
• the dicarboxylic acid may include at least one of an alicyclic dicarboxylic acid and an aromatic dicarboxylic acid, and may include about 70 mol% to less than about 100 mol% of the C 9 to C 12 aliphatic dicarboxylic acid and higher than 0 mol% to about 30 mol% of the at least one of the alicyclic dicarboxylic acid and the aromatic dicarboxylic acid.
• the polyamide resin may have an inherent viscosity (IV) of about 0.6 dL/g to about 1.5 dL/g as measured at 25°C and at a concentration of 0.5 g/dL in concentrated sulfuric acid.
• IV inherent viscosity
• the aliphatic dicarboxylic acid may include at least one of sebacic acid and dodecanedioic acid.
• the at least one of the alicyclic dicarboxylic acid and the aromatic dicarboxylic acid may include at least one selected from the group consisting of 1,4-cyclohexanedicarboxylic acid, terephthalic acid, and isophthalic acid.
• the phosphorus compound may include at least one selected from the group consisting of phosphorous acid, hypophosphorous acid, and salts thereof.
• the present invention provides a polyamide resin that exhibits excellent properties, particularly, high transparency.
• a method of preparing a polyamide resin according to one embodiment of the invention includes two polymerization processes, that is, (1) a process of preparing a low-order condensate in a solid phase through polycondensation of a dicarboxylic acid and a diamine in the presence of about 0.01 wt% to about 0.5 wt% of a phosphorus compound based on the total amount of the dicarboxylic acid and the diamine (hereinafter, referred to as "Process (1)”), and (2) a process of solid polymerizing the low-order condensate (hereinafter, referred to as "Process (2)").
• the polycondensation may be performed at a maximum reaction temperature of about 200°C to about 230°C and the solid polymerization may be performed at a maximum reaction temperature of about 170°C to about 230°C.
• the polycondensation and the solid polymerization may be performed at a maximum reaction temperature of about 200°C to about 230°C.
• a polyamide resin prepared by this method exhibits better properties (transparency, color and mechanical strength), particularly, better transparency than typical polyamide resins in the related art.
• Properties of the polyamide resin are closely related to a crystal structure of a polycondensate (polyamide).
• the polyamide resin can have a completely amorphous structure or a crystalline structure depending upon structures of monomers thereof or a preparation method thereof, and a crystalline polyamide resin can exhibit various crystalline properties depending upon degree of crystallinity, rate of crystallization, and crystal size.
• the dicarboxylic acid having a specific structure and the diamine described in detail below are used as monomers, so that the low-order condensate can exhibit crystallinity and a molded product produced by melting a polyamide having a high degree of polymerization can have a fine crystal structure or an amorphous structure.
• the polyamide having a high degree of polymerization is obtained in a solid phase through solid polymerization of the crystallized low-order condensate, and a product having high transparency can be obtained through melt molding of the polyamide.
• improvement in transparency it is assumed that the amorphous structure or the fine crystal structure has a smaller size than wavelengths of light and thus makes light absorption or light scattering difficult.
• a predetermined amount of a phosphorus compound is added in order to further improve transparency of the polyamide resin finally obtained.
• the dicarboxylic acid essentially contains a C 9 to C 12 aliphatic dicarboxylic acid.
• the C 9 to C 12 aliphatic dicarboxylic acid may include any one of an acyclic aliphatic dicarboxylic acid and a cyclic aliphatic dicarboxylic acid (alicyclic dicarboxylic acid), and when the C 9 to C 12 aliphatic dicarboxylic acid is an acyclic aliphatic dicarboxylic acid, the C 9 to C 12 aliphatic dicarboxylic acid may include any one of a linear aliphatic dicarboxylic acid and a branched aliphatic dicarboxylic acid.
• linear aliphatic dicarboxylic acid examples include nonanedioic acid (azelaic acid), decanedioic acid (sebacic acid), undecanedioic acid, dodecanedioic acid, and the like. Preferably, at least one of sebacic acid and dodecanedioic acid is used.
• Examples of the branched aliphatic dicarboxylic acid may include trimethyl adipic acid, 1,6-decanedicarboxylic acid, and the like.
• Examples of the cyclic aliphatic dicarboxylic acid may include 2-methyl-1,4-cyclohexanedicarboxylic acid, 2,3-dimethyl-1,4-cyclohexanedicarboxylic acid, 2,5-dimethyl-1,4-cyclohexanedicarboxylic acid, 2,6-dimethyl-1,4-cyclohexanedicarboxylic acid, and the like.
• the acyclic aliphatic dicarboxylic acid more preferably, the linear aliphatic dicarboxylic acid is used.
• the C 9 to C 12 aliphatic dicarboxylic acid can improve crystallinity of the polyamide low-order condensate, and the properties of the polyamide resin (transparency, color and mechanical strength), particularly, transparency thereof.
• these C 9 to C 12 aliphatic dicarboxylic acids may be used alone or in combination thereof.
• the C 9 to C 12 aliphatic dicarboxylic acid may be present in an amount of about 70 mol% or more, about 80 mol% or more, about 90 mol% or more, about 95 mol% or more, about 98 mol% or more, or about 100 mol%, based on the total amount of the dicarboxylic acid.
• the polyamide low-order condensate can have improved crystallinity and the polyamide resin can exhibit improved properties (transparency, color and mechanical strength), particularly, improved transparency.
• the dicarboxylic acid may include other dicarboxylic acids excluding the C 9 to C 12 aliphatic dicarboxylic acid.
• the other dicarboxylic acids may include a cyclic (alicyclic) or acyclic aliphatic carboxylic acid and an aromatic carboxylic acid, without being limited thereto.
• dicarboxylic acid excluding the C 9 to C 12 aliphatic dicarboxylic acid may include terephthalic acid, malonic acid, dimethyl malonic acid, succinic acid, glutaric acid, adipic acid, 2-methyl adipic acid, pimelic acid, 2,2-dimethyl glutaric acid, 3,3-diethyl succinic acid, suberic acid, 1,3-cyclopentanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,4-phenylenedioxydiacetaic acid, 1,3-phenylenedioxydiacetaic acid, diphenic acid, 4,4'-oxydibenzoic acid, diphenylmethane-4,4'-dicarboxylic acid, diphenyl
• the dicarboxylic acid may include at least one of an alicyclic dicarboxylic acid and an aromatic carboxylic acid.
• terephthalic acid, 1,4-cyclohexanedicarboxylic acid and isophthalic acid may be used alone or in combination thereof.
• the dicarboxylic acid includes at least one of the alicyclic dicarboxylic acid and the aromatic carboxylic acid
• the at least one of the alicyclic dicarboxylic acid and the aromatic carboxylic acid may be present in an amount of greater than about 0 mol% to about 30 mol% or less, for example, about 5 mol% to about 20 mol%.
• the C 9 to C 12 aliphatic dicarboxylic acid may be present in an amount of about 70 mol% to less than about 100 mol%, for example, about 80 mol% to about 95 mol%.
• the diamine essentially contains a diamine represented by Formula 1: wherein R 1 is a C 1 to C 3 alkylene group.
• Examples of the C 1 to C 3 alkylene group may include a methylene group (-CH 3 -), an ethylene group (-CH 2 CH 2 -), a trimethylene group (-CH 2 CH 2 CH 2 -), a propylene group (-CH(CH 3 )CH 2 -), an isopropylidene group (-C(CH 3 ) 2 -), and a propylidene group (-CH(CH 2 CH 3 )-).
• the C 1 to C 3 alkylene group is preferably a linear alkylene group.
• the C 1 to C 3 alkylene group may be a methylene group, an ethylene group, or a trimethylene group.
• the polyamide low-order condensate has improved crystallinity and the polyamide resin can exhibit improved properties (transparency, color and mechanical strength), particularly, improved transparency. Further, the diamine represented by Formula 1 may be used alone or in combination thereof.
• the diamine represented by Formula 1 may be present in an amount of about 50 mol% or more, about 70 mol% or more, about 90 mol% or more, about 95 mol% or more, about 98 mol% or more, or about 100 mol% or more, based on the total amount of the diamine.
• the polyamide low-order condensate has improved crystallinity and the polyamide resin can exhibit improved properties (transparency, color and mechanical strength), particularly, improved transparency.
• the diamine may include other diamine components excluding the diamine represented by Formula 1.
• the other diamine components may include a cyclic or acyclic aliphatic diamine oran aromatic diamine, without being limited thereto.
• Examples of the other diamine components may include ethylenediamine, propanediamine, 1,4-butanediamine, 1,6-hexanediamine (hexamethylenediamine), 1,7-heptanediamine, 1,8-octanediamine, 1,9-nonanediamine, 1,10-decanediamine, 1,11-undecanediamine, 1,12-dodecanediamine, 2-methyl-1,5-pentanediamine, 3-methyl-1,5-pentanediamine, 2,2,4-trimethyl-1,6-hexanediamine, 2,4,4-trimethyl-1,6-hexanediamine, 2-methyl-1,8-octanediamine, 5-methyl-1,9-nonanediamine, cyclohexanediamine, methylcyclohexy
• the low-order condensate may be prepared by placing an aqueous solution of the monomers or salts thereof in, for example, a typical pressurized polymerization bath, and subjecting the same to polycondensation in an aqueous solvent while stirring.
• the aqueous solvent refers to a solvent that contains water as a main component.
• Usable solvents besides water are not particularly limited so long as the solvents do not influence polycondensation reactivity or solubility, and may include, for example, alcohols such as methanol, ethanol, propanol, butanol, ethylene glycol, and the like.
• the moisture content in a reaction system upon initiation of polycondensation may be set to be in the range of about 10 wt% to about 35 wt% upon completion of polycondensation, preferably 20 wt% to about 60 wt%. With the moisture content of about 20 wt% or more, a substantially homogeneous solution can be obtained upon initiation of polycondensation. In addition, with the moisture content of about 60 wt% or less, it is possible to reduce time and energy in distillation and removal of moisture upon polycondensation while suppressing thermal degradation of the low-order condensate through reduction in reaction time.
• a phosphorus compound is used. Any phosphorus compound can be used without limitation. Examples of the phosphorus compound may include phosphoric acid, phosphorous acid, hypophosphorous acid, phosphate, phosphite, hypophosphite, phosphate ester, polymetaphosphates, polyphosphates, phosphine oxides, phosphonium halogen compounds, and the like.
• the phosphorus compound in order to reduce solid polymerization temperature and reaction time while improving the color and transparency of the polyamide resin, may include at least one selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid, and salts thereof, for example, from the group consisting of phosphorous acid, hypophosphorous acid, and salts thereof.
• phosphate examples include sodium phosphate, potassium phosphate, potassium dihydrogen phosphate, calcium phosphate, vanadium phosphate, magnesium phosphate, manganese phosphate, lead phosphate, nickel phosphate, cobalt phosphate, ammonium phosphate, diammonium hydrogen phosphate, and the like.
• Examples of the phosphite may include potassium phosphite, sodium phosphite, calcium phosphite, magnesium phosphite, manganese phosphite, nickel phosphite, cobalt phosphite, and the like.
• hypophosphite examples include sodium hypophosphite, potassium hypophosphite, calcium hypophosphite, magnesium hypophosphite, aluminum hypophosphite, vanadium hypophosphite, manganese hypophosphite, zinc hypophosphite, lead hypophosphite, nickel hypophosphite, cobalt hypophosphite, ammonium hypophosphite, and the like.
• the phosphate ester may include, for example, monomethyl phosphate ester, dimethyl phosphate ester, trimethyl phosphate, monoethyl phosphate ester, diethyl phosphate ester, triethyl phosphate, propyl phosphate ester, dipropyl phosphate ester, tripropyl phosphate, isopropyl phosphate ester, diisopropyl phosphate ester, triisopropyl phosphate, butyl phosphate ester, dibutyl phosphate ester, tributyl phosphate, isobutyl phosphate ester, diisobutyl phosphate ester, triisobutyl phosphate, hexyl phosphate ester, dihexyl phosphate ester, trihexyl phosphate, octyl phosphate ester, dioctyl phosphate ester, trioctyl phosphate, 2-ethyl
• polymetaphosphates may include sodium trimetaphosphate, sodium pentametaphosphate, sodium hexametaphosphate, polymetaphosphate, and the like.
• the polyphosphoric acid may include, for example, sodium tetrapolyphosphate.
• the phosphine oxide may include, for example, hexamethyl phosphoramide. These phosphorus compounds may be provided in the form of hydrates.
• the phosphorus compound may be sodium hypophosphite or a hydrate thereof, or sodium phosphite or a hydrate thereof.
• These phosphorus compounds may be used alone or in combination thereof.
• the phosphorus compound may be present in an amount of about 0.01 wt% to about 0.5 wt%, based on the total amount of the dicarboxylic acid and the diamine. If the amount of the phosphorus compound is less than about 0.01 wt%, there is a problem of reduction in solid polymerization temperature and it is difficult to achieve reduction in reaction time and improvement in color and transparency of the polyamide resin. If the amount of the phosphorus compound exceeds about 0.5 wt%, the phosphorus compound is precipitated in the polyamide resin, thereby causing degradation of transparency, or a decomposition gas is generated, thereby causing poor external appearance such as silver mark. The phosphorus compound may be present in an amount of about 0.01 wt% to about 0.2 wt%, or about 0.01 wt% to about 0.15 wt%.
• polycondensation may be performed in the presence of an end capping agent.
• the end capping agent allows easy control of the molecular weight of the low-order condensate while improving melt stability of the low-order condensate.
• the end capping agents are not particularly limited so long as the end capping agents are mono-functional compounds having reactivity with a terminal amino group or a terminal carboxyl group, and examples of the end capping agents may include monocarboxylic acids, monoamines, acid anhydrides such as anhydrous phthalic acid and the like, monoisocyanate, monoacid halides, monoesters, and monoalcohols, without being limited thereto.
• monocarboxylic acids or monoamines may be used in terms of reactivity and stability of end capping. More preferably, monocarboxylic acids may be used for easy handling.
• any monocarboxylic acids can be used without limitation so long as the monocarboxylic acids are reactive with an amino group, and examples of the monocarboxylic acids may include aliphatic monocarboxylic acids such as acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, caprylic acid, lauric acid, tridecylic acid, myristic acid, palmitic acid, stearic acid, pivalic acid, and isobutyric acid; alicyclic monocarboxylic acids such as cyclohexane carboxylic acid; aromatic monocarboxylic acids such as benzoic acid, toluic acid, ⁇ -naphthalene carboxylic acid, ⁇ -naphthalene carboxylic acid, methylnaphthalene carboxylic acid, phenylacetic acid, and the like; and mixtures thereof.
• aliphatic monocarboxylic acids such as acetic acid, propionic acid, butyric acid, valeric acid
• acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, caprylic acid, lauric acid, tridecylic acid, myristic acid, palmitic acid, stearic acid, and benzoic acid may be used given reactivity, stability of end capping, price, and the like.
• any monoamine can be used without limitation so long as the monoamines have reactivity with a carboxylic group.
• the monoamines may include aliphatic monoamines such as methylamine, ethylamine, propylamine, butylamine, hexylamine, octylamine, decylamine, stearylamine, dimethylamine, diethylamine, dipropylamine, and dibutylamine; alicyclic monoamines such as cyclohexylamine, and dicyclohexylamine; aromatic monoamines such as aniline, toluidine, diphenyl amine, and naphthylamine; and mixtures thereof.
• butylamine, hexylamine, octylamine, decylamine, stearylamine, cyclohexylamine and aniline may be used given reactivity, melting point, stability of end capping, price, and the like.
• the amount of the end capping agent used in preparation of the low-order condensate may depend on reactivity and melting point, reaction apparatus, reaction conditions of the end capping agents, and the like, the end capping agent may be typically present in an amount of about 0.1 mol% to about 15 mol% relative to the total mole number of the dicarboxylic acid or the diamine.
• Preparation of the low-order condensate may be performed at elevated temperature and pressure while stirring the reactants.
• the polymerization temperature may be controlled after introducing the raw materials.
• the polymerization pressure may be controlled depending on the progress of polymerization.
• the polycondensation may be performed at a maximum reaction temperature of about 200°C to about 230°C. If the maximum reaction temperature is less than about 200°C, the obtained low-order condensate can have a significantly low degree of polycondensation, thereby causing problems such as adhesion and coloring upon solid polymerization. If the maximum reaction temperature exceeds about 230°C, the polyamide can suffer from deterioration in color and transparency due to thermal history of the reaction process.
• the maximum reaction temperature of the polycondensation may range, for example, from about 200°C to about 220°C.
• the maximum reaction temperature is not necessarily reached at the point at which polycondensation is completed and may be reached at any time before completion of polycondensation.
• polycondensation may be performed under milder conditions than typical melt polymerization, thereby securing a high degree of polymerization in solid polymerization while maintaining the crystal structure of the low-order condensate.
• the obtained polyamide resin can have improved properties (transparency, color, mechanical strength), particularly, high transparency.
• the reaction pressure may range about 1.0 MPa to about 3.5 MPa, for example, from about 1.0 MPa to about 3.0 MPa.
• the temperature or moisture content in a reaction system can be easily controlled during polycondensation in which a large amount of water is removed by distillation.
• the low-order condensate can be easily discharged.
• the polyamide resin can be prepared without increasing production costs. Further, the moisture content in the reaction system can be lowered, thereby increasing the degree of polymerization of the low-order condensate.
• the reaction time may range from about 0.5 hours to about 4 hours, for example, from about 1 hour to about 3 hours.
• the reaction time refers to a period of time from a time point of reaching the reaction temperature to initiation of an operation of discharging the low-order condensate.
• reaction pressure is set to about 0.5 hours or more, reaction can reach sufficient reaction rate, whereby unreacted materials do not remain in the system and a homogeneous low-order condensate can be obtained.
• the reaction pressure is set to about 4 hours or less, it is possible to prevent the low-order condensate from suffering excessive thermal history, and the degree of polymerization is not further increased even by extending the reaction time above this range.
• the moisture content in the reaction system upon completion of reaction of the low-order condensate may range from about 15 wt% to about 35 wt%, for example, from about 20 wt% to about 35 wt%.
• the expression "upon completion of reaction” refers to a time point when the low-order condensate has a certain degree of polymerization to initiate an operation of discharging the low-order condensate, and the moisture content includes water of condensation prepared during reaction.
• the moisture content to be introduced into the reaction system may be adjusted given the amount of water of condensation to be prepared, or a predetermined amount of water may be distilled off or removed upon adjustment of the reaction pressure in a reactor equipped with a condenser and a pressure control valve.
• the moisture content in the reaction system upon completion of reaction is about 15 wt% or more, precipitation or solidification of the low-order condensate substantially does not occur in the reaction system, whereby discharge of the low-order condensate can be easily performed.
• the moisture content in the reaction system upon completion of reaction is about 35 wt% or less, a low-order condensate having a sufficient degree of polymerization can be obtained.
• the discharge rate can be enhanced due to low moisture content to be separated by evaporation and a need for a drying process before solid state polymerization can be eliminated, thereby improving preparation efficiency.
• polycondensation in order to obtain the low-order condensate, may be performed in a batch mode or in a continuous mode. Further, polycondensation for producing the low-order condensate is preferably performed under stirring in order to inhibit adhesion of the low-order condensate to a reaction chamber while securing uniform polymerization.
• the low-order condensate obtained by this process may have a heat of fusion of about 10 J/g or more, for example, about 15 J/g or more, for example, about 20 J/g or more, as measured by a differential scanning calorimeter (DSC).
• DSC differential scanning calorimeter
• a method of measuring the heat of fusion using the differential scanning calorimeter (DSC) will be described in detail in Examples set forth below.
• the low-order condensate can be effectively polymerized while preventing uneven heating caused by fusion under solid polymerization conditions, whereby the polyamide resin can have improved properties (transparency, color and mechanical strength), particularly, improved transparency.
• the heat of fusion of the low-order condensate can be adjusted by adjusting the kinds of monomers used in preparation of the polyamide resin or by crystallization of the low-order condensate.
• the heat of fusion of the low-order condensate can be increased by increasing the ratio of the C 9 to C 12 aliphatic dicarboxylic acid to the total amount of the dicarboxylic acid, or the ratio of the diamine represented by Formula 1 to the total amount of the diamine while adjusting the temperature, moisture content, and discharge rate of the low-order condensate upon discharge of a polymerized solution of the low-order condensate from the reactor such that the low-order condensate can be discharged in a crystallized solid phase.
• the heat of fusion of the low-order condensate can be adjusted by heating the discharged low-order condensate at a temperature higher than or equal to the glass transition temperature thereof and less than or equal to a solid polymerization temperature, as needed.
• the low-order condensate obtained by this process may have an inherent viscosity (IV) of about 0.1 dL/g to about 0.4 dL/g, for example, about 0.1 dL/g to about 0.3 dL/g, for example, about 0.15 dL/g to about 0.3 dL/g, as measured at 25°C and at a concentration of 0.5 g/dL in concentrated sulfuric acid.
• IV inherent viscosity
• the inherent viscosity (IV) is about 0.1 dL/g or more, materials having low melting points such as the monomers and salts of the monomers, particularly, the low-order condensate, do not remain, and thus fusion or adhesion of resin powder to the reactor upon solid polymerization can be prevented.
• the inherent viscosity (IV) is about 0.40 dL/g or less, it is possible to prevent precipitation or solidification of the low-order condensate in the reaction system, thereby allowing the low-order condensate to be easily discharged.
• the inherent viscosity (IV) can be controlled by adjusting the kinds or mixing ratio of monomers in preparation of the polyamide resin, or by adjusting conditions for polycondensation (solvent amount (moisture content), reaction temperature, reaction time). For example, even under the same conditions in terms of the kinds of monomers and the mixing ratios of the monomers, the inherent viscosity (IV) can be increased by decreasing the solvent amount (moisture content), by increasing the reaction temperature, or by extending the reaction time.
• the process may further include a salt adjustment process and/or an enrichment process prior to polymerization of the low-order condensate, as needed.
• the salt adjustment process refers to generation of salts from the dicarboxylic acid component and the diamine component.
• the salt adjustment process may be regulated to pH ⁇ 0.5 of a neutralization point of the salts, for example, topH ⁇ 0.3 of a neutralization point of the salts.
• the raw materials may be enriched to have a concentration of about +2 wt% to about +90 wt%, for example, about +5 wt% to about +80 wt%.
• the enrichment process may be performed at about 90°C to about 220°C, or at about 100°C to about 210°C, specifically at about 130°C to about 200°C.
• the enrichment process is preferably performed at about 0.1 MPa to about 2.0 MPa.
• the pressure of the enrichment process is controlled to be not more than the polymerization pressure.
• forced discharge by, for example, a nitrogen stream may be performed.
• the enrichment process is effective in reduction of polymerization time.
• the method of preparing a polyamide resin may further include discharging the low-order condensate, followed by cooling.
• Discharging the low-order condensate from the reaction chamber is performed under atmospheric pressure or less in an inert gas atmosphere.
• the process of discharging does not require a pressure vessel controlled to a specific pressure and separate supply of steam into the reaction chamber during removal of the low-order condensate from the reaction chamber.
• the inert gas atmosphere preferably has an oxygen concentration of about 1% by volume or less in order to inhibit oxidative degradation of the low-order condensate.
• the discharge rate of the low-order condensate from the reaction chamber may be suitably adjusted depending upon the size of the reaction chamber, the amount of material in the reaction chamber, temperature, the size of a discharge outlet, the length of a nozzle, and the like.
• discharge of the low-order condensate may be performed such that the discharge rate per cross-sectional area of the discharge outlet is about 2,000 kg/s/m 2 to about 20,000 kg/s/m 2 .
• the obtained low-order condensate has a bulk density of, for example, about 0.35 g/cm 3 to about 0.8 g/cm 3 , collapse, aggregation, and fusion to a reactor wall can thus be prevented or do not occur during solid polymerization described below, handling properties are good, and a large amount of low-order condensate can be supplied into a polymerization apparatus, thereby improving volume efficiency of the apparatus employed in solid polymerization.
• the low-order condensate discharged from the reaction chamber exhibits almost no thermal or oxidative degradation since the temperature of the low-order condensate is preferably rapidly decreased to about 100°C or less due to latent heat of vaporization when discharged.
• the low-order condensate discharged from the reaction chamber vaporizes most moisture by latent heat thereof, this process allows cooling and drying of the low-order condensate to be performed simultaneously.
• Discharge under inert gas atmosphere such as nitrogen and the like or under pressure below atmospheric pressure is preferred since efficiency of drying and cooling can be improved.
• a cyclone type solid-gas separation apparatus may be used as a discharge container in order to improve efficiency of drying and cooling by preventing powder scattering upon discharge while enabling discharge at a high linear gas velocity.
• the low-order condensate may be subjected to compacting or crude milling in order to obtain further increased bulk density or a uniform particle diameter, as needed.
• the solid phase low-order condensate obtained as above is provided in crystal form, has a sufficiently high inherent viscosity and a low residual amount of unreacted materials, and thus allows solid polymerization at high temperature without causing adhesion or aggregation between the low-order condensate particles. Further, the low-order condensate suffers from little deterioration due to side reaction.
• the low-order condensate obtained in Process (1) is subjected to solid polymerization to obtain a polyamide resin.
• Solid polymerization may be performed subsequent to discharge of the low-order condensate from the reaction chamber; after drying the low-order condensate discharged from the reaction chamber; after storing the low-order condensate discharged from the reaction chamber; or after subjecting the low-order condensate discharged from the reaction chamber to compacting or crude milling.
• solid polymerization that is, high degree polymerization, it is possible to obtain a polyamide resin that suffers from little thermal degradation.
• the low-order condensate may be subjected to solid polymerization by any suitable method under any suitable conditions without limitation so long as high degree polymerization can be performed while maintaining a solid state without causing any fusion, aggregation and deterioration of the low-order condensate.
• solid polymerization may be performed in in an atmosphere of an inert gas such as helium gas, argon gas, nitrogen gas, and carbon dioxide gas or under a reduced pressure.
• an inert gas such as helium gas, argon gas, nitrogen gas, and carbon dioxide gas
• Solid polymerization may be performed at a maximum reaction temperature of about 170°C to about 230°C. If the maximum reaction temperature is less than about 170°C, it is difficult to obtain a polyamide resin having a sufficiently high degree of polycondensation. If the maximum reaction temperature exceeds about 230°C, the polyamide can suffer from deterioration in color or transparency due to adhesion or coloring upon solid polymerization.
• the maximum reaction temperature of the solid polymerization may range, for example, from about 170°C to about 210°C
• the maximum reaction temperature is not necessarily reached at the point at which solid polymerization is completed and may be reached at any time before completion of solid polymerization.
• solid polymerization may be performed under milder conditions than typical solid polymerization, thereby securing a high degree of polymerization while maintaining the crystal structure of the low-order condensate.
• the obtained polyamide resin has improved properties (transparency, color and mechanical strength), particularly, improved transparency.
• any known apparatus may be used without limitation.
• the apparatus for solid polymerization may include uniaxial disks, kneaders, twin axial paddles, a vertical tower type apparatus, a vertical tower type device, a rotatory drum type or double cone type solid polymerization apparatus, a drying device, and the like.
• solid polymerization may be performed for about 1 hour to about 20 hours.
• the low-order condensate may be stirred mechanically or by gas stream.
• various fiber materials such as glass fibers and carbon fibers, additives such as inorganic powder fillers, organic powder fillers, coloring agents, UV absorbers, light stabilizers, antioxidants, antistatic agents, flame retardants, crystallization accelerators, plasticizers, lubricants, and other polymers may be added in the process of preparing a low-order condensate, in the process of solid polymerization, or in an optional stage after solid polymerization.
• additives such as inorganic powder fillers, organic powder fillers, coloring agents, UV absorbers, light stabilizers, antioxidants, antistatic agents, flame retardants, crystallization accelerators, plasticizers, lubricants, and other polymers may be added in the process of preparing a low-order condensate, in the process of solid polymerization, or in an optional stage after solid polymerization.
• the polyamide resin prepared by the method according to the present invention exhibits excellent properties (transparency, color and mechanical strength), particularly, high transparency. Accordingly, a novel polyamide resin exhibiting these properties also falls within the scope of the present invention.
• a polyamide resin according to another embodiment of the present invention may be prepared by polycondensation of a dicarboxylic acid and a diamine, and includes about 0.01 wt% to about 0.5 wt% of a phosphorus compound, wherein the dicarboxylic acid includes about 70 mol% or more of a C 9 to C 12 aliphatic dicarboxylic acid based on the total amount of the dicarboxylic acid, the diamine includes about 50 mol% or more of a diamine represented by Formula 1 based on the total amount of the diamine: wherein R1 is a C 1 to C 3 alkylene group.
• the polyamide resin according to another embodiment of the present invention may have a total light transmission of about 85% or more and a yellowness index (YI) of about 5 or less on a 4 mm thick molded article produced using the polyamide resin.
• YI yellowness index
• the polyamide resin may have a total light transmission of about 85% or more, or about 86% or more, or about 87% or more on 4 mm thick molded article produced using the polyamide resin. A method of measuring the total light transmission will be described in detail in Examples set forth below.
• the polyamide resin may have a yellowness index (YI) of about 5 or less, for example, about 4 or less, before molding.
• YI yellowness index
• the polyamide resin may have a yellowness index (YI) of about 5 or less, for example, about 4 or less, for example, about 3 or less on the 4 mm thick molded article produced using the polyamide resin.
• YI yellowness index
• the polyamide resin may include about 0.01 wt% to about 0.5 wt% of the phosphorus compound, for example, about 0.01 wt% to about 0.2 wt% of the phosphorus compound.
• concentration of the phosphorus compound can be measured using an inductively coupled plasma atomic emission spectroscopy (ICP-AES), more specifically, by a method described in Examples set forth below.
• the phosphorus compound may include at least one selected from the group consisting of phosphorous acid, hypophosphorous acid, and salts thereof.
• the diamine may include about 70 mol% or more of the diamine represented by Formula 1.
• the dicarboxylic acid may include at least one of an alicyclic dicarboxylic acid and an aromatic dicarboxylic acid, and may include about 70 mol% to less than about 100 mol% of the C 9 to C 12 aliphatic dicarboxylic acid and higher than 0 mol% to about 30 mol% of the at least one of the alicyclic dicarboxylic acid and the aromatic dicarboxylic acid.
• the aliphatic dicarboxylic acid may include at least one of sebacic acid and dodecanedioic acid.
• the at least one of the alicyclic dicarboxylic acid and the aromatic dicarboxylic acid may include at least one selected from the group consisting of 1,4-cyclohexanedicarboxylic acid, terephthalic acid, and isophthalic acid.
• the polyamide resin may have an inherent viscosity (IV) of about 0.6 dL/g to about 1.5 dL/g, for example, about 0.7 dL/g to about 1.3 dL/g, as measured at 25°C and at a concentration of 0.5 g/dL in concentrated sulfuric acid. Within this range, the polyamide resin exhibits sufficient mechanical strength and good flowability and thus can produce a molded article having good color and transparency without excessively increasing the temperature upon molding.
• IV inherent viscosity
• the polyamide resin may have a glass transition temperature of about 120°C or more, for example, about 125°C or more. A method of measuring the glass transition temperature will be described in detail in Examples set forth below.
• the polyamide resin may have impact strength after an injection molding (Izod impact test) of about 8 kJ/m 2 or more, for example, about 9 kJ/m 2 or more. A method of measuring the impact strength will be described in detail in Examples set forth below.
• the polyamide resin may have a terminal amino group concentration ([NH 2 ]) of about 20 ⁇ mol/g to about 100 ⁇ mol/g, for example, about 30 ⁇ mol/g to about 80 ⁇ mol/g. If the terminal amino group concentration of the polyamide resin is less than about 20 ⁇ mol/g, the polyamide resin can suffer from degradation of heat-resistant color stability in thermal history since polycondensation is performed at high temperature for the purpose of improving reactivity of the polycondensation. If the terminal amino group concentration of the polyamide resin exceeds about 100 ⁇ mol/g, the terminal amino group can be easily colored, thereby causing degradation of heat-resistant color stability (discoloration resistance under heating conditions). Accordingly, the polyamide resin having a terminal amino group concentration within the above range exhibits good heat-resistant color stability.
• the terminal amino group concentration can be measured by a suitable method, more specifically, by a method disclosed in the description of examples.
• the polyamide resin may have a terminal carboxylic group concentration ([COOH]) of about 20 ⁇ mol/g to about 250 ⁇ mol/g, for example, about 30 ⁇ mol/g to about 200 ⁇ mol/g. If the terminal carboxylic group concentration of the polyamide resin is less than about 20 ⁇ mol/g, the polyamide resin can suffer from degradation of heat-resistant color stability in thermal history since polycondensation is performed at high temperature for the purpose of improving reactivity of the polycondensation. If the terminal carboxylic group concentration of the polyamide resin exceeds about 250 ⁇ mol/g, it can be difficult to obtain a desired molding material due to an insufficiently high degree of polymerization of the polyamide resin. Accordingly, the polyamide resin having a terminal carboxylic group concentration within the above range exhibits good heat-resistant color stability.
• the terminal carboxylic group concentration can be measured by a suitable method, more specifically, by a method disclosed in the description of examples.
• the polyamide resin can be suitably used in the field of transparent components for industrial devices, mechanical, electrical, electronic and automobile parts, and optical materials such as glasses or lenses.
• a specimen solution was prepared by dissolving a specimen at a concentration of 0.5 g/dL in 96% concentrated sulfuric acid. Flow seconds of each of the 96% concentrated sulfuric acid (blank) and the specimen solutions were measured using an Ubbelohde viscometer at 25°C and the inherent viscosity was calculated according to Equation 1.
• ⁇ inh ln ⁇ rel / c
• 0.5 g of a specimen was dissolved in 8 ml of hexafluoroisopropanol while stirring at room temperature (25°C). After completion of dissolution, 30 ml of phenol/ethanol (80 vol%/20 vol%) was added to the resulting solution and stirred for 5 minutes. Thereafter, the resulting solution was subjected to neutralization titration with 0.1N HCl solution and the end point was determined through measurement of potential difference.
• 0.3 g to 0.5 g of a specimen was accurately weighed and was dissolved in 20 ml of ortho-cresol by heating at 170°C while stirring in a nitrogen atmosphere. After completion of dissolution, the resulting solution was cooled, followed by adding 15 ml of benzyl alcohol and stirring for 5 minutes. The resulting solution was subjected to neutralization titration with 0.1N HCl (methanolic) solution and the end point was determined through measurement of potential difference.
• a non-crystalized sample which was obtained by heating the polyamide resin to 300°C or to a temperature 10°C higher than the melting point thereof in a nitrogen atmosphere, followed by quenching, was heated from 30°C to 300°C at a temperature increase rate of 10°C/min and at a flow rate of 10 ml/min in a nitrogen atmosphere, maintained for 5 minutes, and cooled to 100°C at a temperature decrease rate of 10°C/min to measure the glass transition temperature of the sample.
• an endothermic peak temperature in the course of temperature elevation was measured as the melting point
• an exothermic peak temperature through crystallization in the course of temperature decrease was measured as the crystallization temperature.
• the heat of fusion was calculated from a peak area of the endothermic peak.
• Illumination/Light reception conditions 45° annular illumination, 0° light reception
• a rectangular specimen (80 mm ⁇ 10 mm ⁇ 4.0 mm) was prepared under the following conditions using an injection molding machine SE18DUZ (Sumitomo Heavy Industries, Ltd).
• Total light transmission was measured using HAZE-GARD II (Toyo Seikiseisakusho Co., Ltd.) in accordance with ASTM D1003.
• a color of an injection-molded sample was measured using a compact color/whiteness meter (NW-11, Nippon Denshoku Industries Co., Ltd).
• the prepared low-order condensate was discharged to a container through the bottom discharge valve at room temperature (25°C) under a nitrogen atmosphere and atmospheric pressure while maintaining the temperature of the reaction bath and the moisture content (21 wt%) in a reaction system, thereby providing white low-order condensate powder.
• the obtained low-order condensate had an inherent viscosity (IV) of 0.14 and exhibited a DSC endothermic peak at 240°C and crystallinity with a heat of fusion of 47 J/g.
• the obtained polyamide resin had an IV of 0.87, a glass transition temperature of 137°C as measured by DSC, a melting point of 249°C and a YI of 2.1, did not have a crystallization temperature, and included 0.105 wt% of the phosphorus compound.
• the obtained polyamide resin had a sufficiently high degree of polymerization and exhibited a good color.
• An injection-molded specimen was prepared using the obtained polyamide resin at a barrel temperature of 305°C and a mold temperature of 45°C.
• the injection-molded specimen had a total light transmission of 89.1%, a YI of 2.3, and an impact strength of 10.5 kJ/m 2 .
• the injection-molded specimen exhibited high transparency and strength, and good external appearance and color without suffering from pitting caused by filling failure, silver mark caused by generation of moisture and gas, sticking or inclusion of gels, and discoloration such as a yellowing phenomenon.
• the low-order condensate had an IV of 0.15 and exhibited a DSC endothermic peak at 258°C and crystallinity with a heat of fusion of 42 J/g.
• the polyamide resin had an IV of 0.91, a glass transition temperature of 143°C, a melting point of 283°C, a crystallization temperature of 200°C and a YI of 2.0, and included 0.102 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 89.0%, a YI of 2.1, and an impact strength of 10.5 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.14 and exhibited a DSC endothermic peak at 256°C and crystallinity with a heat of fusion of 18 J/g.
• the polyamide resin had an IV of 0.88, a glass transition temperature of 144°C, a melting point of 245°C, a crystallization temperature of 193°C and a YI of 2.3, and included 0.101 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 89.4%, a YI of 2.5, and an impact strength of 10.8 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.13 and exhibited a DSC endothermic peak at 252°C and crystallinity with a heat of fusion of 22 J/g.
• the polyamide resin had an IV of 0.84 and a glass transition temperature of 150°C, and did not have a melting point and a crystallization temperature.
• the polyamide resin had a YI of 3.3 and included 0.102 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 86.2%, a YI of 4.5, and an impact strength of 9.5 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.15 and exhibited a DSC endothermic peak at 248°C and crystallinity with a heat of fusion of 32 J/g.
• the polyamide resin had an IV of 0.90, a glass transition temperature of 141°C, a melting point of 246°C, a crystallization temperature of 212°C and a YI of 2.0, and included 0.104 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 89.4%, a YI of 2.5, and an impact strength of 10.7 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.15 and exhibited a DSC endothermic peak at 251°C and crystallinity with a heat of fusion of 28 J/g.
• the polyamide resin had an IV of 0.87, a glass transition temperature of 133°C and a melting point of 242°C, and did not have a crystallization temperature.
• the polyamide resin had a YI of 2.4 and included 0.105 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 88.8%, a YI of 2.6, and an impact strength of 10.5 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.14 and exhibited a DSC endothermic peak at 255°C and crystallinity with a heat of fusion of 7 J/g.
• the polyamide resin had an IV of 0.80 and a glass transition temperature of 135°C, and did not have a crystallization temperature.
• the polyamide resin had a YI of 6.5 and included 0.107 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 86.2%, a YI of 4.6, and an impact strength of 10.8 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.22 and exhibited a DSC endothermic peak at 256°C and crystallinity with a heat of fusion of 36 J/g.
• the polyamide resin had an IV of 1.15, a glass transition temperature of 135°C, a melting point of 250°C, a crystallization temperature of 190°C.
• the polyamide resin had a YI of 3.9 and included 0.103 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 86.7%, a YI of 4.8, and an impact strength of 10.8 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.15 and exhibited a DSC endothermic peak at 242°C and crystallinity with a heat of fusion of 42 J/g.
• the polyamide resin had an IV of 1.02, a glass transition temperature of 134°C, a melting point of 255°C, a crystallization temperature of 198°C.
• the polyamide resin had a YI of 4.2 and included 0.106 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 86.5%, a YI of 4.8, and an impact strength of 10.8 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.14 and exhibited a DSC endothermic peak at 241°C and crystallinity with a heat of fusion of 45 J/g.
• the polyamide resin had an IV of 0.88, a glass transition temperature of 136°C and a melting point of 250°C, and did not have a crystallization temperature.
• the polyamide resin had a YI of 2.1 and included 0.049 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 89.4%, a YI of 1.9, and an impact strength of 10.7 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.14 and exhibited a DSC endothermic peak at 240°C and crystallinity with a heat of fusion of 43 J/g.
• the polyamide resin had an IV of 0.90, a glass transition temperature of 135°C and a melting point of 249°C, and did not have a crystallization temperature.
• the polyamide resin had a YI of 2.3 and included 0.025 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 89.5%, a YI of 2.3, and an impact strength of 10.8 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the polyamide resin had an IV of 0.85, a glass transition temperature of 135°C and a melting point of 250°C, and did not have a crystallization temperature.
• the polyamide resin had a YI of 2.0 and included 0.102 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 89.2%, a YI of 2.0, and an impact strength of 10.0 kJ/m 2 .
• the injection-molded specimen had good external appearance with high transparency and good color, and high mechanical strength.
• the low-order condensate had an IV of 0.13 and exhibited a DSC endothermic peak at 240°C and crystallinity with a heat of fusion of 45 J/g.
• the polyamide resin had an IV of 1.86, a glass transition temperature of 135°C, a melting point of 248°C, a crystallization temperature of 201°C.
• the polyamide resin had a YI of 5.6 and included 0.004 wt% of the phosphorus compound.
• the obtained polyamide resin exhibited a good color and a sufficiently high degree of polymerization.
• the injection-molded specimen had a total light transmission of 84.8%, a YI of 7.2, and an impact strength of 10.1 kJ/m 2 . Although the injection-molded specimen exhibited good mechanical strength, the injection-molded specimen had low transparency and an unpleasant color as compared with the polyamide resin according to the present invention.
• the low-order condensate had an IV of 0.17 and exhibited unclear endothermic and exothermic behavior at a temperature of 300°C or more in DSC measurement.
• the polyamide resin had an IV of 0.82, a glass transition temperature of 165°C, a melting point of 352°C, a crystallization temperature of 310°C, and a YI of 2.6. Although the polyamide resin exhibited a good color and a sufficiently high degree of polymerization, the polyamide resin has an excessively high melting point and thus, an injection-molded specimen could not be obtained using the polyamide resin due to generation of decomposition gas and reduction in viscosity upon injection molding after melting.
• the low-order condensate had an IV of 0.12 and did not have a DSC endothermic peak.
• the polyamide resin had an IV of 0.72, a glass transition temperature of 155°C, and did not have a melting point and a crystallization temperature.
• the polyamide resin had a YI of 6.5. It was confirmed that the polyamide resin tended to be colored due to adhesion of the resin upon solid polymerization.
• the injection-molded specimen had a total light transmission of 81.9%, a YI of 7.6, and an impact strength of 6.7 kJ/m 2 .
• the injection-molded specimen had low transparency, an unpleasant color, and low impact strength.
• the low-order condensate had an IV of 0.17 and exhibited unclear endothermic and exothermic behavior at a temperature of 300°C or more in DSC measurement.
• the polyamide resin had an IV of 0.79, a glass transition temperature of 154°C, a melting point of 355°C, a crystallization temperature of 318°C, and a YI of 2.8. Although the polyamide resin exhibited a good color and a sufficiently high degree of polymerization, the polyamide resin has an excessively high melting point and thus, an injection-molded specimen could not be obtained using the polyamide resin due to generation of decomposition gas and reduction in viscosity upon injection molding after melting.
• the low-order condensate had an IV of 0.12 and did not have a DSC endothermic peak.
• the polyamide resin had an IV of 0.73, a glass transition temperature of 133°C, and did not have a melting point and a crystallization temperature.
• the polyamide resin had a YI of 8.8, and it was confirmed that the polyamide resin tended to be colored due to adhesion of the resin upon solid polymerization.
• the injection-molded specimen had a total light transmission of 82.4%, a YI of 8.1, and an impact strength of 5.5 kJ/m 2 .
• the injection-molded specimen had low transparency, an unpleasant color, and low impact strength.
• Example 1 after polycondensation of a low-order condensate at 210°C, the temperature of the mixture was increased to 300°C while reducing the reaction pressure to atmospheric pressure for 1 hour. After the temperature of the mixture was maintained at 300°C for 30 minutes, the mixture was moved from the reaction bath to a water bath, followed by cooling, pulverization and drying.
• the obtained polyamide resin had an IV of 1.06, a glass transition temperature of 134°C and a melting point of 257°C, and did not have the crystallization temperature.
• the polyamide resin had a YI of 5.2 and exhibited a sufficiently high degree of polymerization and a slight yellow color.
• the injection-molded specimen had a total light transmission of 84.5%, a YI of 5.8, and an impact strength of 9.9 kJ/m 2 .
• the injection-molded specimen had low transparency and an unpleasant color as compared with the polyamide resin according to the present invention.
• Example 12 Composition ratio (mol%) PACM 100 100 100 100 70 50 100 100 100 100 100 100 100 100 100 MACM 30 50 1.12- dodecanedioic acid 100 90 70 90 100 100 100 100 100 100 100 100 100 1,10-decanedioic acid 100 Terephthalic acid 10 30 1,4-CHDA 10
• Low-order condensate Polymerization Temp Low-order condensate Polymerization Temp.
• the present invention can provide a polyamide resin that exhibits good properties in terms of transparency, color and impact strength.

Landscapes

• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Polyamides (AREA)

Applications Claiming Priority (3)

Publications (2)

Family

ID=53435669

Family Applications (1)

Country Status (5)

Families Citing this family (6)

Family Cites Families (31)

• 2013
  • 2013-11-29 JP JP2013248226A patent/JP6364183B2/ja active Active
• 2014
  • 2014-11-13 KR KR1020140158298A patent/KR20150062943A/ko not_active Ceased
  • 2014-11-21 EP EP14865737.2A patent/EP3075759A4/fr not_active Withdrawn
  • 2014-11-21 US US15/037,521 patent/US10287395B2/en active Active
  • 2014-11-21 CN CN201480064712.8A patent/CN105764956B/zh active Active
• 2018
  • 2018-02-19 KR KR1020180019217A patent/KR101903321B1/ko active Active

Also Published As

Similar Documents

Legal Events