EP3083930A1 - Chiffon de nettoyage à usage unique - Google Patents

Chiffon de nettoyage à usage unique

Info

Publication number
EP3083930A1
EP3083930A1 EP14815692.0A EP14815692A EP3083930A1 EP 3083930 A1 EP3083930 A1 EP 3083930A1 EP 14815692 A EP14815692 A EP 14815692A EP 3083930 A1 EP3083930 A1 EP 3083930A1
Authority
EP
European Patent Office
Prior art keywords
pad
dishwashing
rinsing
rinse
dishes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14815692.0A
Other languages
German (de)
English (en)
Inventor
Sandra Behr
Gabriele HÜRTGEN
Tobias Segler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3083930A1 publication Critical patent/EP3083930A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L17/00—Apparatus or implements used in manual washing or cleaning of crockery, table-ware, cooking-ware or the like
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L17/00—Apparatus or implements used in manual washing or cleaning of crockery, table-ware, cooking-ware or the like
    • A47L17/04—Pan or pot cleaning utensils
    • A47L17/08—Pads; Balls of steel wool, wire, or plastic meshes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B1/00—Cleaning by methods involving the use of tools
    • B08B1/10—Cleaning by methods involving the use of tools characterised by the type of cleaning tool
    • B08B1/14—Wipes; Absorbent members, e.g. swabs or sponges
    • B08B1/143—Wipes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the present invention relates to a manual dishwashing rinse pad for single use, wherein the rinse pad is coated with a dishwashing detergent, and the
  • dishwashing agents are usually used in combination with a means for applying the dishwashing detergent, usually a brush, a sponge or a rinse pad. It corresponds to the consumer behavior of this
  • dishwashing agents to antibacterial additives or appropriate means for applying, i.
  • sponges or wipes as a disposable medium for single use or for a limited time or a limited number of applications.
  • the rinsing pad described herein is intended for single use in manual dishwashing and is characterized in that at least one surface of the rinsing pad, in particular one side, preferably both sides, at least partially with a
  • Dishwashing agent is coated.
  • the dishwashing agent coating may comprise a visually perceptible indicator, in particular a dye or a dye mixture indicating the consumption of the dishwashing detergent and / or the end of the use cycle.
  • a visually perceptible indicator in particular a dye or a dye mixture indicating the consumption of the dishwashing detergent and / or the end of the use cycle.
  • the visually perceptible indicator can be chosen so that it during the
  • Dishwashing is solved by the Spülpad, in particular together and to the same extent as the dishwashing detergent. This makes it easy for the consumer to know when the
  • one side of the rinse pad may be comparatively rougher than the other side.
  • the cloth for a variety of stains and dishes, such as pans, pots, plates and glasses, usable.
  • the rough side is used to remove even stubborn stains, such as baked or dried stains on pans, pots, bakeware and the like, while the softer side for the gentle cleaning of delicate dishes, such as glasses, is suitable.
  • the flushing pad can have any shape. Preferably, it is in the form of a rinse pad or sponge and is suitable for single-handed use in dishwashing detergent solution, for example in a dishwashing basin, or under running water.
  • Rinse Pad refers particularly to a rectangular, square, oval or round sponge which can be comfortably grasped and applied with one hand The fact that the irrigation pad is intended for single use means that the irrigation pad is discarded after a dishwashing process and is not used a second time.
  • Dishwashing refers to manually rinsing a given amount of soiled dishes until substantially all stains are removed.
  • the rinsing pad is particularly hygienic and there is no formation of bad smells or the settling of bacteria in the rinsing pad. Furthermore, the coating with dishwashing detergent and the two-sided design of the rinsing pad with different roughnesses allow an "all in one" application, i.e. separate washing aids, such as sponge or brush, as well as a separate dishwashing detergent.
  • the indicator also has the advantage that it is clear to the consumer when the dishwashing detergent is used up and thus the end of the use cycle of the rinse pad is reached.
  • Dishwasher and then brought the Spülpad with the wet dishes or the wet Spülpad with the dishes in contact.
  • the cleaning of the dishes can then by manually guiding the cloth over the surface of the dishes, in particular by means of wiping or
  • the rinse pad is brought into contact with water in a dishwashing basin, it may be at least partially dissolved by soaking it with water several times and squeezing the wipe, whereby the dishwashing detergent composition is at least partially dissolved A cleaning solution for the subsequent rinsing process will be produced.
  • the cleaning can be carried out under running water, wherein successive dishwashing detergent is removed from the surface of the cloth.
  • the dishes may be rinsed or soaked with water prior to the actual rinsing process to facilitate the removal of soils in the following step.
  • the dishes may be rinsed with water, preferably clean water, and then either left to dry or actively, for example with a drying cloth,
  • the flushing pad can also be used for cleaning the dishwashing basin or other surfaces, in particular surfaces and work surfaces in the adjacent kitchen area.
  • the rinse pad preferably has two sides, wherein the two sides may have different surface textures.
  • one side is rougher than the other side.
  • the rinse pad resembles commonly available household sponges which also have a much rougher side and a softer side.
  • the differentiation between rougher and softer side, for example, is easily possible by subjects, the differences in roughness are such that they are easily assigned by a majority of subjects correctly.
  • the flushing pad may consist of all materials known and suitable for this purpose. Preferably, it is a nonwoven fabric, with the term “nonwoven fabric generally being directed to predominantly nonwoven fabric materials.” Also, paper materials may be suitable, but may alternatively be woven or sponged material. "Generally, it is not intended in that the term "rinse pad” as used herein means that it is necessarily a particular type of material. in the
  • the material is preferably permeable to water, flexible and elastic, and, after elimination of a stress by pressure, for example after manual
  • the flushing pad may be a cloth, a cloth, a sponge, a sponge cloth or the like.
  • the material may be of synthetic or natural origin and in particular contain synthetic or natural fibers.
  • Natural fibers include those that are naturally available without being modified, regenerated, or engineered, for example, derived from plants.
  • Preferred examples of natural fiber materials include, but are not limited to, cellulose fibers including pulp, cotton, hemp, jute, flax, and combinations thereof. "Synthetically,” however, means that the material mainly made of artificially manufactured or processed / modified natural materials.
  • Non-limiting examples of synthetic materials that may be useful herein include those selected from acrylics such as Acrilan, Creslan and Orion, cellulose esters such as cellulose acetate, polyamides such as nylon, polyesters such as Fortrel, Kodel, Dacron, PBT and PET , Polyolefins, such as polyethylene and polypropylene, polyvinyl alcohol,
  • fibers of the aforementioned materials are used. Fibers of these and other materials as well as the nonwovens made therefrom are known in the art and are commercially available.
  • the rinse pad may contain other ingredients or materials that impart to it the desired mechanical properties, such as binders that bind the fibers.
  • binders are, in particular, polymeric binders, preferably latex systems, in particular water-based latex systems.
  • the material is preferably an airy, cotton or sponge-like material.
  • the flushing pad at least partially be made of materials that are biodegradable and therefore largely harmless for environmental reasons.
  • materials include all of the above natural materials and some of the synthetic materials, such as certain cellulose esters.
  • Preferred synthetic materials are polypropylene based nonwoven fabrics, preferred natural or biodegradable materials
  • the flushing pad can also be made of two different materials, in particular such that the side with a rough surface is made of a different material than the side with the smoother surface.
  • the corresponding materials can be bonded, woven or otherwise connected to form the rinsing pads.
  • the rough side of the rinse pad has a surface with a greater scouring effect than the less rough side and will also be referred to as scouring side, whereas the other side is simply referred to as a cleaning side.
  • the scouring side as already described above, is useful for removing stubborn stains.
  • this side consists of synthetic fibers, such as polyamide, polyethylene, polypropylene fibers and mixtures thereof. The arrangement of the fibers may be random, but it is preferred that they are superimposed to form a nonwoven fabric.
  • a towel or rag-shaped article of a given thickness when referring herein to the "sides" of the rinse pad, by a towel or rag-shaped article of a given thickness is meant the two opposing surfaces having the greatest extent in the x and y directions (lateral) Expansion in the z-direction). It is usually the case with such dishcloths or pads, the aspect ratio, ie the ratio of the height to the smallest lateral extent, is small, in particular smaller than 0, 1.
  • the dishwashing detergent composition is applied to at least a portion of the surface of the rinse pad.
  • This surface is preferably the surface of one of the above-described sides of the rinse pad, more preferably the surface of both sides.
  • the composition is applied to the surface thereof in various embodiments after the preparation of the rinse pad.
  • the method of application is not limited, for example, come all sorts of methods for applying liquid
  • compositions into consideration include, but are not limited to, printing, spray coating, spin coating, dipping, extrusion, etc.
  • the coating can be uniform or uneven. In the latter case, the coating can be coated with respect to the amount, i. Thickness of the coating, and in terms of the
  • the coating may take the form of a pattern or a symbol or a lettering.
  • parts of the surface, including parts of the surface of a page, have no coating.
  • the dishwashing agent is preferably used in the form of a high-viscosity paste or in the form of a melt.
  • the rinse pad may feel damp or dry. However, it is preferred that the rinse pad feel substantially dry.
  • the amount of dishwashing detergent used depends on the quantity of dishes to be washed. Preferably, amounts ranging from 0.5 to 5 g are used per flushing pad.
  • the coated area is preferably about 25 to 80 cm 2 , particularly preferably 35 to 55 cm 2 .
  • the dishwashing composition may comprise a number of ingredients known as such in the art.
  • ingredients which in particular comprise surfactants, but also builders, enzymes, acids, bases, salts, complexing agents, polymers, fillers, bleaches and mixtures thereof, the dishwashing agent preferably contains a thickener which acts as a viscosity regulator and adhesion promoter ,
  • the thickener may comprise any compound commonly used in laundry and laundry
  • Detergents is used as a viscosity regulator, such as organic natural thickeners (agar-agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar flour, locust bean gum, starch, dextrins, gelatin, casein), organic modified natural products (carboxymethylcellulose and other cellulose ethers, hydroxyethyl and -propylcellulose and the like, core flour ethers), organic fully synthetic thickeners (polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides, polyisobutene succinic esters, hydrogenated polystyrene derivatives, olefin homopolymers, olefin copolymers, vinylmethylether / maleic acid copolymers,
  • organic natural thickeners agar-agar, carrageenan, tragacanth, gum arabic, algina
  • Alkyldimethylamine oxides aryl ethoxylates, alkyl aryl ethoxylates
  • inorganic ones alkyldimethylamine oxides, aryl ethoxylates, alkyl aryl ethoxylates
  • Thickeners include polysilicic acids, phyllosilicates, clay minerals such as montmorillonites, zeolites, silicas.
  • Polysaccharide gums for example gum arabic, agar, alginates, carrageenans and their salts, guar, guar gum, tragacanth, gellan, Ramzan, dextran or xanthan and their derivatives, e.g. propoxylated guar, as well as their mixtures.
  • Other polysaccharide thickeners such as starches or cellulose derivatives, may be used alternatively, but preferably in addition to a polysaccharide gum, for example starches of various origins and starch derivatives, e.g.
  • acrylic acid polymers are high molecular weight homopolymers of acrylic acid crosslinked with a polyalkylene polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI Carbomer), which are also referred to as carboxyvinyl polymers.
  • polyacrylic acids are i.a. from the company BFGoodrich under the
  • Suitable polymers are also the following acrylic acid copolymers: (i) Copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple esters preferably formed with C 1-4 -alkanols (INCI acrylates copolymer), including, for example, the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and for example from Messrs. Rohm & Haas under the trade names Aculyn ® and AcusoP and from Degussa (Goldschmidt) are available under the trade name Tego® Polymer; (ii) crosslinked
  • acrylic acid copolymers such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of Cio-30-alkyl acrylates with one or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably formed with Ci-4-alkanols, esters ( INCI Acrylates / C 10-30 alkyl acrylate crosspolymer) and which are available, for example, from BFGoodrich under the trade name CarbopoP.
  • inorganic thickeners usable phyllosilicates for example the magnesium available under the trade name Laponite ® or sodium magnesium include phyllosilicates the company Solvay Alkali, in particular the Laponite ® RD or Laponite ® RDS, as well as the magnesium silicates from the company Süd-Chemie, especially the Optigel ® SH.
  • the dishwashing composition may contain any surfactant known for use in dishwashing detergents.
  • at least one surfactant is selected which is selected from the group consisting of: nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants, preferably the at least one surfactant is selected from the group of nonionic surfactants, anionic surfactants, amphoteric surfactants and Mixtures thereof.
  • Nonionic surfactants in the invention may be alkoxylates such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters. Also useful are ethylene oxide / propylene oxide block polymers, fatty acid alkanolamides, and fatty acid polyglycol ethers.
  • Another important class of nonionic surfactants which can be used according to the invention are the polyol surfactants, in particular the glycerides, such as alkyl polyglycosides and fatty acid glucamides. Particularly preferred are the alkyl polyglycosides, in particular the
  • Alkylpolyglucoside wherein particularly preferably the alcohol is a long-chain fatty alcohol or a mixture of long-chain fatty alcohols with branched or unbranched Cs to Cis-alkyl chains and the degree of oligomerization (DP) of the sugar between 1 and 10, preferably 1 to 6, in particular 1, 1 to 3 , most preferably 1, 1 to 1, 7, is, for example, Cs-io-alkyl-1,5-glucoside (DP of 1, 5).
  • DP degree of oligomerization
  • fatty alcohol alkoxylates are also preferred, especially with ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated Cs-22 alcohols having a
  • composition may preferably further contain at least one anionic surfactant.
  • Preferred anionic surfactants are fatty alcohol sulfates, fatty alcohol ether sulfates,
  • Dialkyl ether sulfates monoglyceride sulfates, alkyl benzene sulfonates, olefin sulfonates, alkane sulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates and lignosulfonates.
  • Also useful in the present invention are fatty acid cyanamides, sulfosuccinates
  • fatty acid taurides (Fatty acid taurides), fatty acid sarcosinates, ether carboxylic acids and alkyl (ether) phosphates and o sulfo fatty acid salts, acyl glutamates, monoglyceride disulfates and alkyl ethers of glycerol disulfate.
  • alkanesulfonates in particular secondary alkanesulfonates, fatty alcohol sulfates and / or fatty alcohol ether sulfates.
  • Secondary alkanesulfonates are products of sulfation reactions on secondary alcohols
  • fatty alcohol sulfates are products of sulfation reactions on corresponding alcohols while
  • Fatty alcohol ether sulfates are products of sulfation reactions on alkoxylated alcohols.
  • the person skilled in the art generally understands, under alkoxylated alcohols, the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, in the context of the present invention preferably with longer-chain alcohols.
  • alkylene oxide preferably ethylene oxide
  • alcohols in the context of the present invention preferably with longer-chain alcohols.
  • n moles of ethylene oxide and one mole of alcohol depending on the reaction conditions, a complex mixture of
  • Another embodiment of the alkoxylation is the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
  • Preferred fatty alcohol ether sulfates are the sulfates
  • low ethoxylated fatty alcohols having 1 to 4 ethylene oxide units (EO), in particular 1 to 2 EO, for example, 1, 3 EO.
  • EO ethylene oxide units
  • the anionic surfactants are preferably used as sodium salts, but may also be present as other alkali or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts, in the case of the sulfonates also in the form their corresponding acid, eg Dodecylbenzenesulfonic.
  • the dishwashing detergent can continue to do so
  • Suitable amphoteric surfactants are, for example, betaines of the formula (R iii) (R iv) (R v) N + CH2COO _ in which R i is an optionally interrupted by hetero atoms or hetero atom groups alkyl radical having 8 to 25, preferably 10 to 21 carbon atoms, and R IV and R v are identical or different alkyl radicals having 1 to 3 carbon atoms, in particular Cio-Cis-alkyl dimethylcarboxymethylbetain and Cn-Ci7-alkylamidopropyl-dimethylcarboxymethylbetain.
  • Suitable cationic surfactants are i.a. the quaternary ammonium compounds of the formula
  • R VI (R VI ) (R vii ) (R viii ) (R ix ) N + X "
  • R vi to R ix for four identical or different, in particular two long and two short-chain, alkyl radicals and X " for an anion , in particular a halide ion, for example, didecyl-dimethyl-ammonium chloride, alkyl-benzyl-didecyl-ammonium chloride and mixtures thereof.
  • Suitable cationic surfactants are the quaternary
  • the agent can be designed with an antimicrobial effect or its possibly existing antimicrobial effect due to other ingredients can be improved.
  • the cationic surfactants with the anionic surfactant (s) contained are preferably used as anionic surfactant-compatible and / or as little as cationic surfactant or, in a particular embodiment of the invention, entirely dispensed with cationic surfactants.
  • the dishwashing detergent contains at least one
  • Fatty alcohol ether sulfate, at least one secondary alkanesulfonate, and at least one betaine In various embodiments, the at least one fatty alcohol ether sulfate is a C10-C18, preferably a C12-C14 fatty alcohol ether sulfate with 2 EO.
  • secondary alkanesulfonates Cu-C17 secondary alkanesulfonates are preferred.
  • betaine for example, Cs-Os is suitable
  • the at least one fatty alcohol ether sulfate is contained in an amount of 10 to 35% by weight, preferably 15-25% by weight, based on the total weight of the dishwashing detergent.
  • the secondary alkanesulfonate is preferably contained in an amount between 1 and 5 wt .-%, preferably 2 to 3 wt .-% based on the total weight of the dishwashing detergent.
  • the betaine may be contained in an amount of 5 to 30% by weight, preferably 15 to 25% by weight, based on the total weight of the dishwashing detergent.
  • the remainder of the cleaning agent block is composed in particular of thickeners, such as PEG.
  • the dishwashing detergent may contain one or more further customary auxiliaries and additives.
  • auxiliaries and additives include, for example, organic propellants (especially sugars, sugar alcohols, glycerol, glycols and polymers thereof),
  • Hydrophobizticiansvermittler Such as paraffin), UV stabilizers, perfume oils, pearlescent agents (INCI opacifying agents;., For example glycol distearate, for example Cutina ® AGS from Cognis, or mixtures comprising, for example, the Euperlane ® from Cognis.) more opacifiers, dyes, corrosion inhibitors, bitter substances, preservatives (for example, the technical also known as Bronopol 2-bromo-2-nitropropane-1, 3-diol (CAS 52-51-7), for example, as Myacide ® BT or as Boots Bronopol BT is commercially available from Boots, or bronopol containing mixtures as Preventol® ® (ex Lanxess) or Parmetol® ® (ex Schülke & Mayr))
  • Disinfectants, pH adjusters, fragrances and skin feel-improving or skin-care additives eg dermatologically active substances such as vitamin A, vitamin B2, vitamin B12, vitamin C, vitamin E, D-panthenol, sericerin, collagen partial hydrolyzate, various vegetable protein Partial hydrolyzates, protein hydrolyzate-fatty acid condensates, liposomes, Cholesterol, vegetable and animal oils such as lecithin, soybean oil, etc., plant extracts such as aloe vera, azulene, witch hazel extracts, algae extracts, etc., allantoin, AHA complexes, glycerol, urea, quaternized hydroxyethyl cellulose), additives to improve efficacy. and drying behavior or for stabilization.
  • These auxiliaries and additives are contained in particular in amounts of usually not more than 5 wt .-%.
  • the dishwashing agent may contain one or more perfumes, preferably in an amount of 0.01 to 10 wt .-%, in particular 0.05 to 8 wt .-%, particularly preferably 0.1 to 5 wt .-%.
  • a perfume component d-limonene may be contained.
  • the detergent block according to the invention thereby contains a perfume of essential oils (also referred to as essential oils). Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil, for example, can be used as such in the context of this invention.
  • Also suitable are Muskateller sage oil, chamomile oil, lavender oil, clove oil, lemon balm oil, mint oil, cinnamon oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and
  • fragrances usually used in detergents and cleaners are also suitable for use in the detergent block of the invention, such as other essential oils, esters, alcohols, aldehydes, or terpenes.
  • the dishwashing agent contains one or more antimicrobial agents, preferably in an amount of 0.01 to 1 wt .-%, preferably 0.02 to 0.8 wt .-%, in particular 0.05 to 0.5 Wt .-%, particularly preferably 0, 1 to 0.3 wt .-%, most preferably 0.2 wt .-%.
  • antimicrobial agents from the groups of alcohols, aldehydes, antimicrobial acids or their salts, carboxylic esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazoles and their derivatives are suitable according to the invention
  • Derivatives such as isothiazolines and isothiazolinones, phthalimide derivatives, pyridine derivatives, antimicrobial surface active agents
  • Preferred antimicrobial agents are preferably selected from the group comprising ethanol, n-propanol, i-propanol, 1, 3-butanediol,
  • Phenoxyethanol 1, 2-propylene glycol, glycerol, undecylenic acid, citric acid, lactic acid, benzoic acid, salicylic acid, thymol, 2-benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 2 , 4,4'-trichloro-2'-hydroxydiphenyl ether, N- (4-chlorophenyl) -N- (3,4-dichlorophenyl) -urea, N, N '- (1, 10-decanediyldi-1-pyridinyl-4 -ylidene) bis (1-octanamine) dihydrochloride, N, N'-bis (4-chlorophenyl) -3,12-diimino-2,4,1,1,1,3-tetraazatetradecandiimidamide, antimicrobial quaternary surfactant compounds, guanidines and sodium dichloroisocyanurate
  • Preferred antimicrobial surfactant Quaternary compounds contain an ammonium, sulfonium, phosphonium, iodonium or arsonium group. Furthermore, antimicrobially effective essential oils can be used, which at the same time provide for a scenting of the cleaning product.
  • particularly preferred antimicrobial agents are selected from the group comprising salicylic acid, quaternary surfactants, in particular benzalkonium chloride, peroxo compounds, in particular hydrogen peroxide, alkali metal hypochlorite, sodium dichloroisocyanurate and mixtures thereof.
  • Preservatives may also be included. As such, essentially the substances mentioned in the antimicrobial agents can be used.
  • Suitable corrosion inhibitors are, for example, the following named according to INCI: Cyclohexylamine, Diammonium Phosphate, Dilithium Oxalate, Dimethylamino Methylpropanol, Dipotassium Oxalate, Dipotassium Phosphate, Disodium
  • Suitable regulators are preferably solid long-chain fatty acids, such as stearic acid, but also salts of such fatty acids, fatty acid ethanolamides, such as KokosfettTexremonoethanolamid, or solid polyethylene glycols, such as those with molecular weights between 10,000 and 50,000.
  • the pH of the compositions according to the invention can be adjusted by means of customary pH regulators, for example citric acid or NaOH.
  • customary pH regulators for example citric acid or NaOH.
  • the composition according to the invention may further comprise one or more buffer substances (INCI Buffering Agents), usually in amounts of 0.001 to 5 wt .-%, preferably 0.005 to 3 wt .-%, in particular 0.01 to 2 wt .-%, particularly preferably 0.05 to 1 wt .-%, most preferably 0.1 to 0.5 wt .-%, for example, 0.2 wt .-%. Preference is given to buffer substances which are at the same time complexing agents or even chelating agents (chelating agents, INCI chelating agents).
  • chelating agents chelating agents, INCI chelating agents
  • the dishwashing detergent may contain one or more dyes (INCI Colorants).
  • dyes both water-soluble and oil-soluble dyes can be used, on the one hand the compatibility with other ingredients, such as bleaches, is observed and on the other hand, the dye used should not be substantive to the metal and ceramic even with prolonged exposure.
  • water-soluble dyes are preferred herein.
  • the dyes are preferably present in an amount of 0.0001 to 2 wt .-%, in particular 0.0005 to 1 wt .-%, particularly preferably 0.001 to 0.5 wt .-%, contained. As already described above, such dyes can the
  • Dishwashing coatings are added in amounts sufficient to allow visual perception by the consumer.
  • the dyes are preferably formulated to peel off along with the dishwashing detergent over the period of the rinse, thus reducing the consumption of the dishwashing detergent and also the end of the usability of the rinse pad, i. indicate the end of the usage cycle. In doing so, they preferably dissolve to the same extent, i. at the same rate as the dishwashing detergent.
  • the dye may also be formulated such that it does not dissolve until the dishwashing detergent has been used up completely. In this case, the consumer would be able to perceive the color visually as long as dishwashing detergent is present and as soon as it would have been used up, the colorant would immediately detach and indicate that dishwashing detergent is no longer available.
  • the invention also relates to the use of the dishwashing dishcloths herein and to methods of cleaning hard surfaces, particularly for manual dishwashing, using the rinse pad described herein.
  • Such uses and methods include the usual steps, in particular:
  • Example 1 Dishwashing agents in the form of a melt having the compositions shown in Table 1 were applied to a polypropylene nonwoven rinse pad either flat in circular form (50.24 cm 2 , 3-3.5 g) or as lettering (40 cm 2 , 1, 5-2 g) applied.
  • the compositions are shown in the table below, the quantities are in wt .-% active ingredient.
  • compositions contained the following dyes:

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne un chiffon de nettoyage pour le lavage manuel de la vaisselle à usage unique, le chiffon de nettoyage étant revêtu de liquide vaisselle, ainsi que l'utilisation de ce chiffon de nettoyage et un procédé pour le nettoyage manuel de la vaisselle l'utilisant.
EP14815692.0A 2013-12-18 2014-12-17 Chiffon de nettoyage à usage unique Withdrawn EP3083930A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013226512.3A DE102013226512A1 (de) 2013-12-18 2013-12-18 Einweg-Spülpad
PCT/EP2014/078279 WO2015091680A1 (fr) 2013-12-18 2014-12-17 Chiffon de nettoyage à usage unique

Publications (1)

Publication Number Publication Date
EP3083930A1 true EP3083930A1 (fr) 2016-10-26

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EP14815692.0A Withdrawn EP3083930A1 (fr) 2013-12-18 2014-12-17 Chiffon de nettoyage à usage unique

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US (1) US20160298063A1 (fr)
EP (1) EP3083930A1 (fr)
KR (1) KR20160101054A (fr)
AU (1) AU2014368720A1 (fr)
DE (1) DE102013226512A1 (fr)
WO (1) WO2015091680A1 (fr)

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WO2020210784A1 (fr) 2019-04-12 2020-10-15 Ecolab Usa Inc. Nettoyant antimicrobien multi-usages et procédés de fabrication et d'utilisation de celui-ci
US12226543B2 (en) 2019-05-10 2025-02-18 Ecolab Usa Inc. pH sensitive color indicator for sanitizing applications
DE202022106872U1 (de) 2022-12-08 2024-03-21 Lars Ehnert Artikel zum Reinigen von Oberflächen
DE102022132692B3 (de) 2022-12-08 2024-05-23 Lars Ehnert Artikel zum Reinigen von Oberflächen

Citations (1)

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Publication number Priority date Publication date Assignee Title
WO2012019657A1 (fr) * 2010-08-12 2012-02-16 Carl Freudenberg Kg Éponge de nettoyage en viscose

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CA2116061C (fr) * 1993-03-02 1998-12-22 George H. Geisinger Methode et trousse d'analyse et d'identification de matieres suspectes
US6677287B1 (en) * 1998-05-18 2004-01-13 The Procter & Gamble Company Implement containing cleaning composition and disappearing dye
DE19950925A1 (de) * 1999-10-21 2001-04-26 Henkel Kgaa Geschirrspülmittel-Portion
AUPQ747900A0 (en) * 2000-05-12 2000-06-08 Novapharm Research (Australia) Pty Ltd Biocidal cloth
US20060293205A1 (en) * 2005-06-27 2006-12-28 Jessica Chung Cleaning substrate with a visual cue
US8343908B2 (en) * 2007-07-12 2013-01-01 Kimberly-Clark Worldwide, Inc. Foaming hand sponge with color change indicator
US8772184B2 (en) * 2009-03-31 2014-07-08 Illinois Tool Works Inc. Reversible color-changing sanitizer-indicating nonwoven wipe
GB2510612A (en) * 2013-02-08 2014-08-13 Helen Fisher Cleaning product

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
WO2012019657A1 (fr) * 2010-08-12 2012-02-16 Carl Freudenberg Kg Éponge de nettoyage en viscose

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US20160298063A1 (en) 2016-10-13
AU2014368720A1 (en) 2016-08-04
KR20160101054A (ko) 2016-08-24
DE102013226512A1 (de) 2015-06-18
WO2015091680A1 (fr) 2015-06-25

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