EP3545066A1 - Compositions de détergents contenant un copolymère - Google Patents

Compositions de détergents contenant un copolymère

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Publication number
EP3545066A1
EP3545066A1 EP17807797.0A EP17807797A EP3545066A1 EP 3545066 A1 EP3545066 A1 EP 3545066A1 EP 17807797 A EP17807797 A EP 17807797A EP 3545066 A1 EP3545066 A1 EP 3545066A1
Authority
EP
European Patent Office
Prior art keywords
structural units
component
mol
detergent composition
copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP17807797.0A
Other languages
German (de)
English (en)
Other versions
EP3545066B1 (fr
Inventor
Hannah Benson
Carsten Cohrs
Natascha SCHELERO
Mike SAHL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant International Ltd
Original Assignee
Clariant International Ltd
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Filing date
Publication date
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Publication of EP3545066A1 publication Critical patent/EP3545066A1/fr
Application granted granted Critical
Publication of EP3545066B1 publication Critical patent/EP3545066B1/fr
Active legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the present invention relates to detergent compositions comprising one or more copolymers (polymer additives) containing cationic and macromonomer structural units, and one or more surfactants and water.
  • the invention further relates to the use of the detergent compositions or the copolymers for the treatment of hard
  • Surfaces for example, to provide a cleaning effect on the surface to impart hydrophilic properties to the surface to create surface gloss, have permanent properties such as "anti-stain", “anti-stains” or “anti-streaks"
  • the invention further relates to a method for treating or cleaning a hard surface under
  • Typical cleaning formulations allow the efficient cleaning of hard surfaces of industry, the household or the general public. They generally consist of an aqueous solution of surfactants, in particular nonionic and anionic surfactants, alcohol (s) to facilitate drying, bases for adjusting the pH and optionally quaternary amines as disinfectants.
  • surfactants in particular nonionic and anionic surfactants, alcohol (s) to facilitate drying, bases for adjusting the pH and optionally quaternary amines as disinfectants.
  • WO 2013/170001 and WO 2013/170002 describe detergent formulations which contain alkoxylated polyethylenedimine polymers and lead to the improvement of the gloss on hard surfaces.
  • WO 2009/156067 describes detergent formulations which contain graft copolymers of saccharides and can be used to improve the gloss retention of hard surfaces and / or hydrophilizing
  • WO 2003/031546 describes aqueous antimicrobial cleaning compositions for the treatment of hard surfaces, with the result that to obtain a gloss retention or a gloss improvement of the hard surfaces.
  • WO 98/49263 describes aqueous, acidic surface cleaners containing a
  • the object of the present invention was to develop polymer additives which are water-soluble or water-dispersible and detergent compositions can be added, and thus provide detergent compositions, in particular with the result that after their application to hard surfaces advantageous gloss effects the hard surfaces are observed.
  • Z1 containing one or more copolymers a) 0.1 to 99.9 mol%, preferably 25.0 to 80.0 mol% and particularly preferably 25.0 to 77.6 mol%, of one or more cationic
  • Structural units (A) are represented by the following general formulas (I) and / or (II):
  • R 1 and R 1 a are the same or different and are independent
  • R 1 b , R 3 , R 4 and R 5 are the same or different and are each independently
  • Y is the same or different and is oxygen, NH and / or
  • NR 3 is represented,
  • V is the same or different and is denoted by - (CH 2) x-, is represented,
  • x is the same or different and is an integer from 1 to
  • X and Xi are the same or different and are independent
  • in molar average is a number from 0 to 7 and preferably from 0 to 6, and
  • a number from 1 to 150, preferably from 1 to 150 and particularly preferably from 12 to 150 and one or more surfactants and
  • the invention therefore provides detergent compositions containing
  • Structural units (A) are represented by the following general formulas (I) and / or (II):
  • R 1 and R 1 a are the same or different and are independent
  • each of each represents hydrogen and / or a methyl radical
  • R 1 b , R 3 , R 4 and R 5 are the same or different and are each independently
  • Y is the same or different and is represented by oxygen, NH and / or NR 3 ,
  • V is the same or different and is denoted by - (CH 2) x-,
  • x is the same or different and is an integer from 1 to
  • X and Xi are the same or different and are independent
  • in molar average is a number from 0 to 7 and preferably from 0 to 6, and
  • in the molar average is a number from 1 to 150, preferably from 1 to 150 and more preferably from 12 to 150 and Z2) one or more surfactants and Z3) water.
  • hard surface in the sense of the invention means a surface made of dimensionally stable materials, eg of plastic, ceramic, stone, such as, for example,
  • Natural stone, porcelain, glass, wood, linoleum and metal such as stainless steel, typically surfaces in the kitchen and sanitary area, for example, in kitchens, bathrooms and toilets, in the household but also in the industrial sector, for example, in butchers, slaughterhouses, dairies, storage tanks for
  • WO 2012/076365 A1 discloses cationic copolymers comprising cationic structural units and macromonomer structural units and their
  • WO 2008/049549 A2 describes hydrophobically modified cationic copolymers which have at least three different structural units and of which one structural unit is a terminal phenyl group or especially substituted
  • WO 2008/141844 A1 describes dispersions comprising inorganic particles, water and at least one water-soluble polymer.
  • At least one water-soluble polymer has repeating units derived from monomers having at least one quaternary ammonium group, Repeating units derived from monomers having at least one carboxy group, and repeating units derived from
  • Polyalkoxyalkylengue-containing ester monomers are derived with a number average molecular weight in the range of 3000 g / mol to 10,000 g / mol, on.
  • the dispersions can be used in particular for the production of concrete and can be processed over a very long period of time.
  • WO 2008/046652 A1 describes graft polymers obtainable by copolymerization of at least one specific macromonomer and at least one further monomer which has a polymerizable ethylenically unsaturated double bond and their use as dispersants, for example in US Pat
  • JP 2008-05671 1 A discloses copolymers having a number average
  • Monomers can be copolymerized.
  • the copolymers may, for. B. be used as antistatic agents for thermoplastic polymers.
  • An advantage of the invention is that the copolymers of component Z1)
  • Detergent compositions can be added, thereby causing a gloss effect on the hard surfaces on which they were applied.
  • Another advantage of the invention is that the copolymers of component Z1) can be added to detergent compositions and impart hydrophilic properties to the hard surfaces to which they have been applied. The contact angle between a treated surface and a water drop or a drop of an aqueous detergent composition can be reduced. The presence of traces or stains on the hard surfaces due to water or water
  • Detergent compositions which have come into contact with them are associated with the phenomenon of contraction of the water droplets or droplets of aqueous detergent compositions upon contact with hard surfaces, which in the later
  • Drying on the surfaces leave traces.
  • the speed of drying the surface can be improved.
  • compositions according to the invention can be used in any combination.
  • Detergent compositions can be advantageously removed fat residues and lime soap residues and also can be advantageously removed lime and Kalkneustromronneus be reduced.
  • the formation of a biofilm on the surfaces can be minimized or prevented and, moreover, rinsing of the surfaces can be facilitated.
  • the application of the detergent compositions according to the invention or the copolymers of component Z1) may be such that they remain on the hard surface after application (“leave on” application) or are removed from it and preferably rinsed with water ("rinse
  • the application of the detergent compositions or the copolymers of component Z1) according to the invention may advantageously take place, for example, on hard surfaces in bathrooms or kitchens, on floors or on toilets several cationic
  • DMAC Diallyldimethylammonium chloride
  • Detergent Compositions The polymerization product of at least one monomer species selected from the group consisting of [3- (acryloylamino) -propyl] -trimethylammonium chloride, [3- (methacryloylamino) -propyl] -trimethylammonium chloride and diallyldimethylammonium chloride, and particularly preferably represents the one or more cationic repeating units (A) of the one or more copolymers of component Z1 ) of the detergent compositions of the invention the
  • the one or more macromonomers selected from the group consisting of [3- (methacryloylamino) -propyl] -trimethylammonium chloride and diallyldimethylammonium chloride.
  • Structural units (B) of the formula (III) of the one or more copolymers of component Z1) of the detergent compositions according to the invention the polymerization of at least one
  • Monomer species selected from the group consisting of polyethylene glycol vinyloxy-butyl ether, polyethylene glycol-co-polypropylene glycol-vinyloxybutyl ether (in which I, on a molar average, denotes a number from 1 to 7, preferably from 2 to 6 and particularly preferably from 3 to 6), Polyethylene glycol (meth) acrylate and polyethylene glycol-co-polypropylene glycol (meth) acrylate (wherein I, in molar means, a number from 1 to 7, preferably from 2 to 6 and particularly preferably from 3 to 6) is.
  • (meth) acrylate includes both the corresponding acrylate compound and the corresponding methacrylate compound.
  • the one or more copolymers of component Z1) of the detergent compositions of the invention contain one or more in addition to the structural units (A) and (B)
  • Structural units (C) other than the structural units (A) and (B), and wherein the one or more copolymers
  • the one or more structural units (C) of the one or more copolymers of component Z1) represents the
  • Methacrylamides and N-vinyl-substituted lactams having 5 to 7 ring atoms having 5 to 7 ring atoms.
  • compositions according to the invention selected from the Group consisting of the polymerization product of at least one N-vinyl-substituted lactam having 5 to 7 ring atoms and the structural units of the following general formulas (IV) and / or (V):
  • R 1 is the same or different and is hydrogen and / or methyl
  • R 3 and R 4 are each the same or different and independently of one another by hydrogen, an aliphatic hydrocarbon radical having 1 to 20, preferably 1 to 4, C atoms, a
  • cycloaliphatic hydrocarbon radical having 5 to 20, preferably 5 to 8, C atoms, an aryl radical having 6 to 14 C atoms, an alkylaryl radical having 7 to 14 C atoms, a branched or unbranched C 1 -C 5 -monohydroxyalkyl group and / or polyethylene glycol ( PEG)
  • R 11 is the same or different and is represented by H and / or methyl;
  • R 13 is the same or different and is represented by OH, N (CH 3) 2,
  • Lactams with 5 to 7 ring atoms is the polymerization product of
  • N-vinylpyrrolidone is preferred.
  • the groups SO 3 H, PO 3 H 2 , O-PO 3 H 2 and para-substituted C 6 H 4 -SO 3 H in the structural units of the formula (V) may also be present in salt form, preferably as NH 4 + -, Alkali or alkaline earth salt and more preferably as NH 4 + - or Na + salt.
  • the one or more structural units (C) of the one or more copolymers of component Z1) of the detergent compositions according to the invention are selected from the structural units of the general formula (IV).
  • the one or more structural units (C) of the one or more copolymers of component Z1) of the detergent compositions of the present invention at least provide the polymerization product a monomer species selected from the group consisting of ⁇ , ⁇ -dimethylacrylamide and N-isopropylacrylamide.
  • the one or more copolymers of component Z1) of the inventive detergent compositions contains structural units (A), (B) and (C) as repeating structural units, but no further
  • the recurring structural units of the one or more copolymers of component Z1) of the detergent compositions according to the invention consist of:
  • cationic repeating units (A) containing the polymerization product of at least one monomer species selected from the group consisting of [3- (methacryloylamino) -propyl] -trimethylammonium chloride and
  • the one or more copolymers of component Z1) contains the
  • compositions according to the invention in addition to the structural units (A), (B) and (C) one or more structural units (D), which differ from the structural units (A), (B) and (C) and wherein the one or several copolymers
  • W is the same or different and is represented by -CO-O- (CH 2) x,
  • x is an integer from 1 to 6, preferably 2 or 3,
  • R 1 is the same or different and is hydrogen and / or methyl
  • R 3 and R 4 are each the same or different and independently of one another by hydrogen, an aliphatic hydrocarbon radical having 1 to 20, preferably 1 to 4, C atoms, a
  • Cycloaliphatic hydrocarbon radical having 5 to 20, preferably 5 to 8, carbon atoms, an aryl radical having 6 to 14 carbon atoms and / or polyethylene glycol (PEG) are represented.
  • the one or more copolymers of component Z1) of the detergent compositions according to the invention contain one or more structural units (D), these are in a particularly preferred embodiment of the invention selected from the structural units of
  • the structural units of the formula (VIII) preferred are those which comprise the polymerization product of at least one monomer species the group consisting of [2- (methacryloyloxy) -ethyl] -dimethylannin,
  • the one or more copolymers of component Z1) of the detergent compositions according to the invention contain one or more structural units (D), in a further particularly preferred embodiment of the invention they contain one or more structural units (D) selected from the structural units of the following general formulas (IX) and / or (X):
  • R 11 is the same or different and is represented by H and / or methyl;
  • Z is the same or different and is represented by O and / or NH;
  • R 11 is the same or different and is represented by H and / or methyl;
  • Q is the same or different and is represented by O and / or NH;
  • the one or more copolymers of component Z1) of the detergent compositions according to the invention contain one or more structural units (D), these are selected in a further particularly preferred embodiment of the invention from the
  • the structural units of formula (X) can also be present in salt form, preferably as NH 4 + -, alkali or alkaline earth salt, and most preferably as NH + - or Na + salt.
  • maleic anhydride selected from the group consisting of maleic anhydride, maleic acid and the salts of maleic acid.
  • the one or more copolymers of component Z1) of the detergent compositions according to the invention contain one or more structural units (D), in a further particularly preferred embodiment of the invention they contain one or more structural units (D) selected from the structural units of the following general formula (VII):
  • Ci-C4-alkyl group is preferably represented by H or methyl
  • the one or more copolymers of component Z1) of the detergent compositions according to the invention contain one or more structural units (D), these are selected in a further particularly preferred embodiment of the invention from the
  • the one or more copolymers of component Z1) of the detergent compositions according to the invention contain one or more structural units (D), in a further particularly preferred embodiment of the invention they contain one or more structural units (D) selected from the structural units of the following general formulas (Va), (Vb) and / or (Vc):
  • R11 is the same or different and is represented by H and / or methyl
  • W is the same or different and is represented by O
  • R 12 is the same or different and is represented by a branched or unbranched C 1 -C 8 monohydroxyalkyl group
  • R 11 is the same or different and is represented by H and / or methyl;
  • R 13 is the same or different and is represented by OH, SO 3 H, PO 3 H 2 , O-PO 3 H 2 and / or para-substituted C 6 H 4 -SO 3 H;
  • R 14 , R 15 and R 16 are the same or different and are each independently represented by H and / or an unbranched or branched C 1 -C 4 -alkyl group;
  • n is the same or different and is represented by 0, 1, 2,
  • R 17 is the same or different and is represented by (C 6 H 5 ),
  • the one or more copolymers of component Z1) of the detergent compositions according to the invention contain one or more structural units (D), these are selected in a further particularly preferred embodiment of the invention from the
  • the one or more copolymers of component Z1) contains the
  • Detergent Compositions According to the Invention Structural units (A), (B), (C) and (D) as repeating structural units, but in addition no further repeating structural units.
  • the recurring structural units of the one or more copolymers of component Z1) of the detergent compositions according to the invention consist of:
  • Monomeric species selected from the group consisting of
  • Structural units (D) containing the polymerization of at least one
  • Monomeric species selected from the group consisting of
  • maleic anhydride maleic acid and the salts of maleic acid.
  • the structural units (A), (B) and optionally (C) and (D) of the one or more copolymers of component Z1) are identical to each other.
  • compositions according to the invention in random, block-shaped, alternating or gradient-like distribution in the copolymer before.
  • the weight-average molecular weights M w of the one or more copolymers of component Z1) of the detergent compositions according to the invention are from 10,000 to 250,000 g / mol, more preferably from 15,000 to 200,000 g / mol and particularly preferably from
  • copolymers of component Z1) of the detergent compositions according to the invention contain recurring structural units
  • Structural units derived, for example, from radical initiators or from chain transferers optionally used in the copolymerization are not repetitive
  • Structural units understood, for example, no terminal groups.
  • the quantities in mol% given for the structural units (A), (B), (C) and (D) are based on the total amount of repeating structural units contained in the respective copolymers of component Z1).
  • copolymers of component Z1) of the detergent compositions according to the invention can be prepared by methods which are familiar to the person skilled in the art. Particularly preferably, the copolymers of the
  • Component Z1) can be prepared by free radical solvent polymerization.
  • Common solvents can preferably polar solvents such as alcohols or
  • radical sources e.g. inorganic persulfates, organic azo compounds, peroxides, inorganic redox systems, or UV light started.
  • chain transfer agents can be used which form less reactive radicals to control the molecular weight of the copolymers.
  • chain transfer controllers are e.g. Phenols, thiols, for example
  • the copolymerization is then carried out at the desired temperature for the desired period of time.
  • the reaction mixture is then optionally cooled and the copolymer formed either further processed in solution or worked up, for. B., the copolymer-containing solution by partial evaporation of the
  • Solvent be concentrated or the solvent by
  • Evaporation or the copolymer are otherwise isolated, for example by freeze-drying or precipitation.
  • the detergent compositions of the invention contain the one or more copolymers of component Z1) in an amount of 0.005 to 10 wt .-%, particularly preferably in one
  • the detergent compositions of the invention contain as component Z2) one or more surfactants.
  • the one or more surfactants of component Z2) of the detergent compositions of the invention are selected from the group consisting of anionic, nonionic, amphoteric and cationic surfactants.
  • the detergent compositions of the invention may optionally contain anionic surfactants, e.g. As alkylbenzenesulfonates, alkyl sulfates, alkyl ether sulfates, alkanesulfonates, alkyl ether carboxylic acids, sulfosuccinates, isethionates, taurates, glycinates and / or acylglutamates.
  • the alkyl chains of said surfactants may be of synthetic or natural origin and consist of 8 to 30, preferably 8 to 18 and particularly preferably 12 to 14 C atoms in a linear or branched arrangement.
  • Anionic surfactants which are used according to the invention are preferably aliphatic sulfates, such as fatty alcohol sulfates, fatty alcohol ether sulfates,
  • Dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as
  • Estersulfonates and lignosulfonates are also usable in the context of the present invention.
  • alkylbenzenesulfonates are also usable in the context of the present invention.
  • fatty acid cyanamides are also usable in the context of the present invention.
  • Sulfosuccinates (sulfosuccinic acid esters), sulfosuccinamates, sulfosuccinamides, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides),
  • [alpha] sulfo fatty acid salts [alpha] sulfo fatty acid salts, acyl glutamates, monoglyceride disulfates and alkyl ethers of glycerol disulfate.
  • fatty alcohol sulfates and / or fatty alcohol ether sulfates, in particular the fatty alcohol sulfates.
  • Fatty alcohol sulfates are products of sulfation reactions on corresponding alcohols while Fettal kholethersulfate products of sulfation of alkoxylated
  • Alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, in the context of the present invention preferably with longer-chain alcohols.
  • alkylene oxide preferably ethylene oxide
  • alcohols in the context of the present invention preferably with longer-chain alcohols.
  • n moles of ethylene oxide and one mole of alcohol depending on the reaction conditions, a complex mixture of
  • Alkylene oxides preferably the mixture of ethylene oxide and propylene oxide.
  • Preferred fatty alcohol ethers are the lower ethoxylated sulfates
  • EO ethylene oxide units
  • alkylbenzenesulfonate alkanesulfonate, alkyl ether sulfate or alkyl sulfate.
  • the anionic surfactants are usually used as salts, but also as acid.
  • the salts are preferably alkali metal salts, alkaline earth metal salts, ammonium salts and mono-, di- or
  • Trialkanolammoniumsalze for example, mono-, di- or
  • Triethanolammoniumsalze in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or potassium salts, particularly preferably sodium salts.
  • Other surfactants may be nonionic, amphoteric and / or cationic surfactants, for example betaines, amidobetaines, amine oxides, amidoamine oxides,
  • Fettal koholpolyglykolether alkyl polyglycosides or quaternary
  • Nonionic surfactants may be, for example, alkoxylates
  • Polyglycol ethers fatty alcohol polyglycol ethers (fatty alcohol alkoxylates),
  • Alkylphenol polyglycol ethers end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
  • Ethylene oxide-propylene oxide block copolymers and fatty acid alkanolamides and fatty acid polyglycol ethers.
  • Another important class of nonionic surfactants that can be used according to the invention are the polyol surfactants, and in particular the glycated surfactants, such as alkyl polyglycosides, in particular
  • Suitable fatty alcohol polyglycol ethers are with ethylene oxide (EO) and / or
  • Cio-Ci8 fatty alcohols having a degree of ethoxylation of less than 30, more preferably 1 to 20, particularly preferably 1 to 12 and exceptionally preferably 1 to 8, for example Ci2-Ci4-fatty alcohol ethoxylates with 8 EO.
  • Alkyl polyglycosides are surfactants produced by the reaction of sugars and
  • Alcohols can be obtained by the relevant methods of preparative organic chemistry, and depending on the nature of the preparation to a mixture of monoalkylated, oligomeric or polymeric sugar comes.
  • Preferred alkylpolyglycosides are the alkylpolyglucosides, wherein the alcohol is particularly preferably a long-chain fatty alcohol or a mixture of long-chain fatty alcohols with branched or unbranched Cs to C18-alkyl chains and the
  • Degree of oligomerization (DP) of the sugars from 1 to 10, preferably from 1 to 6, more preferably from 1, 1 to 3 and particularly preferably from 1, 1 to 1, 7, for example C8-Cio-alkyl-1, 5 glucoside (DP of 1, 5).
  • amphoteric surfactants which can be used according to the invention include betaines, amine oxides, alkylamidoalkylamines, alkyl-substituted amino acids, acylated amino acids or biosurfactants.
  • Suitable betaines are the alkylbetaines, the alkylamidobetaines, the
  • Imidazoliniumbetaine the sulfobetaines (INCI Sultaines) and the amidosulfobetaines and the phosphobetaines.
  • suitable betaines and sulfobetaines are the following compounds named according to INCI: almondamidopropyl betaines, Apricotamidopropyl betaines, avocadamidopropyl betaines,
  • Cetylbetaines cocamidoethylbetaines, cocamidopropylbetaines,
  • Coco / oleamidopropylbetaines coco-sultaines, decylbetaines, dihydroxyethyl oleylglycinates, dihydroxyethyl soy glycinates, dihydroxyethylstearylglycinates, dihydroxyethyl tallow glycinates, dimethicones, propyl PG-betaines,
  • Isostearamidopropyl betaines lauramidopropyl betaines, lauryl betaines,
  • Oleamidopropylbetaines oleamidopropylhydroxysultaines, oleylbetaines,
  • Olivamidopropyl betaines palmamidopropyl betaines, palmitamidopropyl betaines, palmitoyl carnitines, palm kernel amidopropyl betaines, polytetrafluoroethylene acetoxypropyl betaines, ricinoleamidopropyl betaines, sesamidopropyl betaines, soy amidopropyl betaines, stearamidopropyl betaines, stearyl betaines,
  • amine oxides suitable according to the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and
  • Suitable amine oxides are the following named according to INCI
  • Decyltetradecylamines oxides diaminopyrimidines oxides, dihydroxyethyl Cs-Cio alkoxypropylamines oxides, dihydroxyethyl C9-C11 alkoxypropylamines oxides, dihydroxyethyl C12-C15 alkoxypropylamines oxides, dihydroxyethyl cocamines oxides, dihydroxyethyl lauramine oxides, dihydroxyethyl stearamines oxides, Dihydroxyethyl Tallowannine Oxide, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallowan Oxide, Hydroxyethyl Hydroxypropyl C12-C15
  • Trisphosphonomethylamine oxides sesamidopropylamine oxides
  • alkylamidoalkylamines are the following compounds designated as INCI: cocoamphodipropionic acid, cocobetainamido amphopropionate, DEA-cocoamphodipropionate, disodium caproamphodiacetate, disodium
  • Cocoamphodipropionate Disodium Isostearoamphodiacetate, Disodium
  • Isostearoamphodipropionate Disodium Laureth-5 Carboxyamphodiacetate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium Oleoamphodipropionate, Disodium PPG-2-lsodeceth-7 Carboxyamphodiacetate, Disodium Stearoamphodiacetate, Disodium Tallowamphodiacetate, Disodium Wheatgermamphodiacetate, Lauroamphodipropionic Acid, Quaternium-85, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Capryloamphoacetate, Sodium
  • Cocoamphopropionate Sodium Cornamphopropionate, Sodium Isostearoamphoacetate, Sodium Isostearoamphopropionate, Sodium Lauroamphoacetate, Sodium Lauroamphohydroxypropylsulfonate, Sodium Lauroampho PG-Acetate Phosphate, Sodium Lauroamphopropionate, Sodium Myristoamphoacetate, Sodium
  • Oleoamphoacetate Sodium Oleoamphohydroxypropylsulfonate, Sodium
  • alkyl-substituted amino acids are the following compounds designated according to INCI: Aminopropyl Laurylglutamine, Cocaminobutyric Acid, Cocaminopropionic Acid, DEA Lauraminopropionate, Disodium Cocaminopropyl Iminodiacetate, Disodium Dicarboxyethyl Cocopropylenediamine, Disodium Lauriminodipropionate, Disodium Steariminodipropionate, Disodium
  • the one or more surfactants is the
  • Component Z2) of the detergent compositions according to the invention selected from the group consisting of fatty alcohol polyglycol ethers,
  • Alkylpolyglycosides alkylbenzenesulfonates, alkanesulfonates, alkyl ether sulfates, alkyl sulfates and quaternary ammonium compounds.
  • the proportion of the one or more surfactants of component Z2) in the inventive detergent composition is preferably from 0.1 to 20 wt .-% and particularly preferably from 0.1 to 6.0 wt .-%, each based on the Total weight of the detergent composition according to the invention.
  • Component Z3 is preferably from 0.1 to 20 wt .-% and particularly preferably from 0.1 to 6.0 wt .-%, each based on the Total weight of the detergent composition according to the invention.
  • the proportion of water in the detergent compositions according to the invention is preferably from 10.00 to 99.89% by weight, more preferably from 40.00 to 98.00% by weight and especially preferably from 70 to 97.00% by weight. -%, in each case based on the total weight of
  • the detergent compositions according to the invention preferably comprise, in addition to the one or more copolymers of component Z1), the one or more surfactants of component Z2) and water of component Z3), one or more further substances selected from components Z4), Z5) , Z6) or / or Z7):
  • Preservatives, fragrances and dyes, as component Z7), and the pH of the detergent composition is preferably from 1 to 14 and more preferably from 3 to 1 1.
  • the acids may be inorganic acids, e.g. Hydrochloric acid,
  • Sulfuric acid, nitric acid, sulfamic acid and / or phosphoric acid act.
  • the acids containing are organic acids, more preferably non-complexing acids such as lactic acid, formic acid, acetic acid, glycolic acid and / or gluconic acid.
  • Adipic acid and / or succinic acid contain an acid.
  • the detergent compositions according to the invention comprise a mixture of two or more acids.
  • the amount of acid used if different from 0%, is
  • a salt of an acid may be added for buffering the pH, in particular the sodium, potassium or magnesium salt, but also other alkali or
  • Alkaline earth salts or ammonium salts in particular volatile amines such as monoethanolamine, ammonia, diethanolamine, but also triethanolamine.
  • volatile amines such as monoethanolamine, ammonia, diethanolamine, but also triethanolamine.
  • the salt or salts of the acid or acids already present are used.
  • Suitable complexing agents are known to the person skilled in the art and are described by way of example in DE-A-10 2009 001 559.
  • INCI chelating agents also called sequestrants, are ingredients that are capable of complexing and inactivating metal ions to their detrimental effects on the stability or appearance of the agents,
  • the complexing agents support the cleaning effect.
  • Tetraacetic Acid Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacydoheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl
  • Pentamethylene Phosphonate Sodium Dihydroxyethyl Glycinate, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphate, Sodium Hexametaphosphate, Sodium
  • the proportion of the component Z5) in the detergent composition according to the invention if it is different from 0%, preferably from 0.1 to 10 wt .-%, particularly preferably from 0.1 to 3.0 wt .-% and
  • Suitable water-soluble solvents are known to the person skilled in the art and are described by way of example in US 2005/0239674.
  • Alcohols, glycerol, glycols and glycol ethers are preferably used, preferably lower alcohols such as ethanol, isopropanol, butanol, isobutanol or Alkylenlykole, z.
  • propylene glycol, and glycol ethers e.g. As ethylene glycol n-butyl ether or propylene glycol n-butyl ether.
  • the proportion of the component Z6) in the detergent composition according to the invention is, if it is different from 0%, preferably from 0.1 to 10 wt .-%, particularly preferably from 0.1 to 3 wt .-% and particularly preferably from 0.5 to 1, 5 wt .-%.
  • Suitable additives are further customary ingredients of cleaning agents, for example disinfectants, pH adjusters, dyes, fragrances, buffers, viscosity regulators, corrosion inhibitors, organic and inorganic salts, optical brighteners, bleaching agents, antioxidants, opacifiers, hydrotropes, abrasives, preservatives, oxidizing agents and / or Insecticides.
  • cleaning agents for example disinfectants, pH adjusters, dyes, fragrances, buffers, viscosity regulators, corrosion inhibitors, organic and inorganic salts, optical brighteners, bleaching agents, antioxidants, opacifiers, hydrotropes, abrasives, preservatives, oxidizing agents and / or Insecticides.
  • cleaning agents for example disinfectants, pH adjusters, dyes, fragrances, buffers, viscosity regulators, corrosion inhibitors, organic and inorganic salts, optical brighteners, bleaching agents, antioxidants, opacifiers, hydrotropes, abra
  • bleaching agents can be added to the composition.
  • Suitable bleaching agents include peroxides, peracids and / or perborates, particularly preferred is H2O2.
  • the detergent compositions of the invention may also contain enzymes, preferably proteases, lipases, amylases, hydrolases and / or cellulases. They may be added to the detergent compositions of the invention in any form established in the art. These include liquid or gel
  • the enzymes may be encapsulated, for example by spray-drying or extrusion of the enzyme solution together with a, preferably natural polymer or in the form of capsules, for example those in which the enzymes are entrapped as in a solidified gel or in those of the core-shell type in which an enzyme-containing core with a water, air and water / or chemical impermeable protective layer is coated.
  • a, preferably natural polymer or in the form of capsules for example those in which the enzymes are entrapped as in a solidified gel or in those of the core-shell type in which an enzyme-containing core with a water, air and water / or chemical impermeable protective layer is coated.
  • further active ingredients for example stabilizers, emulsifiers, pigments, bleaches or dyes, may additionally be applied.
  • Such capsules are prepared by methods known per se, for example by shaking or
  • Roll granulation or applied in fluid-bed processes are advantageously, such granules, for example by applying polymeric film-forming agent, low in dust and storage stable due to the coating.
  • Enzyme stabilizers may also be present in enzyme-containing detergent compositions according to the invention in order to protect an enzyme contained in a detergent composition according to the invention from damage such as inactivation, denaturation or decomposition, for example by physical influences, oxidation or proteolytic cleavage.
  • Suitable enzyme stabilizers in each case depending on the enzyme used, are in particular: benzamidine hydrochloride, borax, boric acids, boronic acids or their salts or esters, especially derivatives with aromatic groups, for example substituted phenylboronic acids or their salts or esters; Peptide aldehydes (oligopeptides with reduced C-terminus),
  • Amino alcohols such as mono-, di-, triethanol- and -propanolamine and their
  • aliphatic carboxylic acids up to C12 such as succinic acid, other dicarboxylic acids or salts of said acids; end-capped fatty acid amide alkoxylates; lower aliphatic alcohols and especially polyols, for example glycerol, ethylene glycol, propylene glycol or sorbitol; such as
  • Reducing agents and antioxidants such as sodium sulfite and reducing sugars.
  • Other suitable stabilizers are known in the art.
  • stabilizers for example the combination of polyols, boric acid and / or borax, the combination of boric acid or borate, reducing salts and succinic acid or others Dicarboxylic acids or the combination of boric acid or borate with polyols or polyamino compounds and with reducing salts.
  • suitable as disinfectants and / or preservatives are, for example, antimicrobial active ingredients from the groups of alcohols,
  • Acid amides phenols, phenol derivatives, diphenyls, diphenylalkanes,
  • Phthalimide derivatives pyridine derivatives, antimicrobial surface active agents
  • antimicrobial agents are preferably selected from the group comprising ethanol, n-propanol, i-propanol, 1, 3-butanediol, phenoxyethanol, 1, 2-propylene glycol, glycerol, undecylenic acid, citric acid, lactic acid, benzoic acid, salicylic acid, thymol, 2- benzyl-4-chlorophenol,
  • polyacrylic and polymethacrylic compounds include the high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI name according to the International Dictionary of Cosmetic Ingredients of The Cosmetic, Toiletry, and Fragrance Association (US Pat. CTFA):
  • Carbomer also referred to as carboxyvinyl polymers.
  • Such polyacrylic acids are inter alia from the company 3V Sigma under the trade name Polygel ® , z. B. Polygel ® DA, and by the company BFGoodrich under the
  • Carbopol ® available, for. Carbopol ® 940 (molecular weight of about 4 000 000), Carbopol ® 941 (molecular weight approximately 1 250 000) or Carbopol ® 934 (molecular weight approx 3 000 000). It also includes the following
  • Ci-4-alkanols formed esters (INCI acrylates copolymer), which include about the copolymers of methacrylic acid, butyl acrylate and
  • Methyl methacrylate (CAS designation according to Chemical Abstracts Service: 25035-69-2) or of butyl acrylate and methyl methacrylate
  • Degussa (Goldschmidt) under the trade name Tego ® polymer are available, for.
  • Tego ® polymer As the anionic non-associative polymers Aculyn ® 22, Aculyn ® 28, Aculyn ® 33 (crosslinked), Acusol ® 810, Acusol ® 823 and Acusol ® 830 (CAS 25852-37-3);
  • crosslinked high molecular weight acrylic acid copolymers such as those crosslinked with an allyl ether of sucrose or pentaerythritol
  • carbbopol ® ETD 2623 and Carbopol ® 1382 As the hydrophobic Carbopol ® ETD 2623 and Carbopol ® 1382 (INCI
  • Further thickeners are the polysaccharides and heteropolysaccharides, in particular the polysaccharide gums, for example gum arabic, agar, alginates, carrageenans and their salts, guar, guar gum, tragacanth, gellan, Ramzan, dextran or xanthan and their derivatives, eg. B. propoxylated guar, and their mixtures.
  • Other polysaccharide thickeners such as starches or cellulose derivatives, may alternatively, but preferably in addition to a polysaccharide gum be used, for example, starches of various origins and
  • Starch derivatives e.g. As hydroxyethyl starch, starch phosphate esters or starch acetates, or carboxymethyl cellulose or its sodium salt, methyl, ethyl, hydroxyethyl, hydroxypropyl, hydroxypropylmethyl or hydroxyethylmethyl cellulose or cellulose acetate.
  • a particularly preferred polysaccharide thickener is the microbial anionic heteropolysaccharide xanthan gum produced by Xanthomonas campestris and some other species under aerobic conditions having a molecular weight of 2 - 15 x 10 6 and for example by Kelco under the trade names Keltrol ® and Kelzan ® or is also available from Rhodia under the trade name Rhodopol ®.
  • phyllosilicates include, for example those available under the trade name Laponite ®
  • Magnesium or sodium-magnesium sheet silicates from Solvay Alkali in particular Laponite ® RD or Laponite ® RDS, as well as the
  • the amount of the viscosity regulator when different from 0%, is preferably up to 0.5% by weight, more preferably from 0.001 to 0.3% by weight, most preferably from 0.01 to 0.2% by weight. %, and most preferably from 0.01 to 0.15% by weight, based in each case on the total weight of
  • the viscosity of the detergent composition according to the invention is preferably from 0.4 to 400 nrrPas.
  • detergent compositions according to the invention may contain one or more corrosion inhibitors.
  • Suitable corrosion inhibitors are, for example, the following named according to INCI substances: cyclohexylamine, diammonium phosphates, dilithium oxalates, dimethylamino methyl propanol, dipotassium
  • Hexametaphosphates Sodium Metasilicate, Sodium Molybdate, Sodium Nitrite, Sodium Oxalate, Sodium Silicate, Stearamidopropyl Dimethicone, Tetrapotassium Pyrophosphate, Tetrasodium Pyrophosphate, and Triisopropanolamine.
  • fragrance compounds for.
  • Fragrance compounds of the ester type are e.g. Benzyl acetate, phenoxyethyl isobutyrate,
  • the ethers include, for example, benzyl ethyl ether to the aldehydes z.
  • Citronellol, eugenol, geranion, linalol, phenylethyl alcohol and terpineol, to the Hydrocarbons mainly include the terpenes and balsams.
  • mixtures of different fragrances are used, which together produce an attractive fragrance.
  • fragrances and natural fragrance mixtures can be used, as they are available from plant or animal sources, eg. Pine, citrus, jasmine, lily, rose, or ylang-ylang oil.
  • essential oils of lower volatility, which are mostly used as aroma components are suitable as perfume oils, eg. B. sage oil, chamomile oil, clove oil, lemon balm oil, mint oil,
  • the amount of fragrances in the detergent compositions according to the invention is, if it is different from 0%, preferably from 0.001 to 2 wt .-% and particularly preferably from 0.01 to 2 wt .-%, based on the total weight of the inventive detergents - Compositions.
  • dyes and pigments both organic and inorganic dyes, from the corresponding positive list of
  • Pearlescent pigments eg. As fish silver (guanine / hypoxanthine mixed crystals from fish scales) and mother of pearl
  • Bismuth oxychloride (BiOCl)
  • layered substrate pigments e.g. Mica / metal oxide
  • silver-white pearlescent pigments of ⁇ 2 interference pigments ( ⁇ 2
  • Detergent compositions when different from 0%, are preferably from 0.01 to 1, 0 wt .-%, based on the total weight of the detergent compositions of the invention.
  • the proportion of component Z7) in the detergent compositions according to the invention is, if it is different from 0%, preferably from 0.01 to 10 wt .-%, particularly preferably from 0.1 to 1 wt .-% and
  • the detergent compositions according to the invention contain
  • the detergent compositions according to the invention or the one or more copolymers of component Z1) of the detergent compositions according to the invention are advantageously for the treatment of hard surfaces, preferably of ceramic, stone, porcelain, glass, stainless steel, metal, plastic, linoleum or Wood suitable.
  • Another object of the present invention is therefore the use of a detergent composition according to the invention or at least one copolymer of component Z1) of the inventive detergent compositions for the treatment of hard surfaces, preferably ceramic, stone, porcelain, glass, stainless steel, metal, plastic, linoleum or wood.
  • the use according to the invention for the treatment of hard surfaces is carried out in order to achieve a cleaning effect on the hard surface to which the detergent composition according to the invention or the at least one copolymer of component Z1) of the detergent compositions according to the invention has been applied.
  • the hard surface treatment of the invention is carried out to remove the hard surface on which the
  • Inventive detergent composition or the at least one copolymer of component Z1) of the detergent compositions according to the invention has been applied to impart hydrophilic properties.
  • the hard surface treatment of the invention is preferably used in order to produce gloss on the hard surface to which the detergent composition according to the invention or the at least one copolymer of component Z1) of the detergent compositions according to the invention has been applied.
  • the use according to the invention for the treatment of hard surfaces is carried out in order to improve the rate of drying of a hard surface to which the detergent composition according to the invention or the at least one copolymer of component Z1) of the detergent compositions according to the invention has been applied.
  • the use according to the invention for the treatment of hard surfaces is preferably carried out in order to obtain permanent properties, preferably "anti-stain”, “anti-stains” or “anti-streaks", on the hard surface on which the detergent composition according to the invention or the like at least one copolymer of component Z1) of the detergent compositions according to the invention has been applied to achieve.
  • the use according to the invention for the treatment of hard surfaces is preferably carried out in order to prevent the re-soiling of a hard surface on which the inventive detergent composition or the at least one copolymer of component Z1)
  • inventive detergent compositions has been applied to reduce.
  • the use according to the invention for the treatment of hard surfaces is carried out to the re-cleaning of the hard
  • inventive detergent compositions has been applied to facilitate. Furthermore, the use according to the invention for the treatment of hard surfaces is preferably carried out in order to achieve a repair effect of the hard surface on which the detergent composition according to the invention or the at least one copolymer of component Z1) of the invention
  • Detergent compositions has been applied to achieve.
  • the use according to the invention for the treatment of hard surfaces is preferably carried out in order to remove fat residues or lime soap residues on the hard surface on which the detergent composition according to the invention or the at least one copolymer of component Z1)
  • detergent compositions according to the invention has been applied to remove.
  • the hard surface treatment according to the invention is preferably carried out in order to remove lime on the hard surface to which the detergent composition according to the invention or the at least one copolymer of component Z1) of the detergent compositions according to the invention has been applied
  • the use according to the invention for the treatment of hard surfaces is preferably carried out in order to prevent the formation of a biofilm on the hard surface on which the inventive detergent composition or the at least one copolymer of component Z1)
  • Detergent compositions of the invention have been used to minimize or prevent.
  • the hard surface treatment of the invention is carried out to facilitate the rinsing of the hard surface to which the detergent composition of the invention or the at least one copolymer of component Z1) of the detergent compositions of the present invention has been applied.
  • the hard surface treatment of the invention is carried out to facilitate the rinsing of the hard surface to which the detergent composition of the invention or the at least one copolymer of component Z1) of the detergent compositions of the present invention has been applied.
  • inventive detergent composition or the at least one copolymer of component Z1) of
  • inventive detergent composition or the at least one copolymer of component Z1) of
  • Cleaning agent compositions according to the invention are removed after application from the hard surface and preferably rinsed with water (rinse-off application).
  • rinse-off application a further preferred embodiment of the invention.
  • Another object of the present invention is also a method for treating or cleaning a hard surface, characterized in that the hard surface in contact with a
  • Detergent composition or with at least one copolymer of component Z1) of the detergent compositions of the invention is brought.
  • Detergent compositions or of the one or more copolymers of component Z1) of the hard surface treatment detergent compositions of the invention and the process for treating or cleaning a hard surface using a detergent composition of the invention or at least one copolymer of component Z1 ) of the detergent compositions of the invention are explained in more detail below by examples without limiting it thereto. Unless explicitly stated otherwise in the examples, the percentages in the examples are to be understood as percent by weight (% by weight).
  • MAPTAC [3- (methacryloylamino) -propyl] -trimethylammonium chloride
  • Meth 1000 Polyethylene glycol-co-polypropylene glycol methacrylate, 1000 g / mol, 4-5 propylene glycol units (70% by weight active in aqueous solution)
  • V-PEG 1 100 polyethylene glycol-vinyloxy-butyl ether, 1 100 g / mol
  • V-PEG 5000 polyethylene glycol vinyloxy-butyl ether, 5000 g / mol
  • Monomers are these with base such.
  • alkali carbonate such as potassium carbonate
  • the aqueous solution is purged with nitrogen for 30 minutes and heated to 60 ° C if VA-44 is used as the initiator, or to 80 ° C if Na2S2Os is used as an initiator.
  • the amount of initiator (VA-44 or Na2S2O8) indicated in Table 1 is dissolved in 10 g of distilled water and taken over a period of
  • Black, shiny ceramic tiles (10 x 10 cm) are pre-cleaned and then about 10 drops of the detergent composition are applied centrally on the tiles.
  • the detergent composition is spread evenly on the tile using a folded cellulose kitchen towel. After the tiles have dried vertically for at least 30 minutes, a visual assessment (grades 1-10) of the tiles is made, with 1 being the best and 10 the worst.
  • Example formulations with and without copolymer of component Z1) of the detergent compositions according to the invention were prepared, and Gloss tests were carried out with these formulations.
  • the example formulations and gloss results are shown in Table 2.
  • the method is based on the natural frequency change of a piezoelectric quartz crystal as soon as it is loaded with a mass.
  • the surface of the quartz may be modified by spin-coating or vapor deposition.
  • the quartz crystal is located in a measuring cell.
  • the measuring cell is a flow cell, into which the solution to be investigated is pumped from sample vessels.
  • the pumping speed is kept constant during the measuring time. Typical pumping speeds are between 50-250 ⁇ / minute.
  • Typical pumping speeds are between 50-250 ⁇ / minute.
  • quartz crystal crystals with a 50 nm thick silica coating QSX303, Q-Sense, Vastra Frolinda, Sweden
  • quartz crystal crystals with a 50 nm thick stainless steel (SS2343) coating QSX304 Q-Sense, Vastra Frolinda, Sweden
  • Aqueous solutions of the copolymers of component Z1) of the detergent compositions according to the invention having an active content of 2000 ppm were investigated.
  • the water used was tap water at 20 ° dH.
  • the pH was adjusted to pH 10 with NaOH or citric acid
  • Component Z1) of the detergent compositions according to the invention are suitable for use on hard surfaces, since they adsorb on the investigated inorganic surfaces.
  • the contact angles were measured on various surfaces (ceramic, glass, stainless steel) by the surfaces were modified by the following method: The surfaces were dipped three times for 2 minutes in fresh demineralized water (DI water) and then for 20 minutes to modify Room temperature immersed with stirring in the respective aqueous copolymer solution. Thereafter, the surfaces were dried with a gentle stream of nitrogen. On the thus prepared surfaces, the contact angle was measured with DI water (apparatus: drop analyzer from Krüss, Hamburg, Model DSA 100).
  • DI water fresh demineralized water
  • the height of the contact angle of a drop of water on a surface is a measure of its hydrophilization.
  • a very hydrophilic surface is completely wetted by a drop of water. This phenomenon is also called spreading of the drop.
  • Detergent compositions as an aqueous solution with an active content of 2000 ppm examined.
  • the water used was tap water at 20 ° dH.
  • the pH was adjusted to pH 10 with NaOH or citric acid
  • Active content of 2000 ppm determines the topography (apparatus: contact-free optical 3D surface characterization of Sensofar, Barcelona, Model S neox).
  • Using the software MountainsMap Digital Surf SARL, Besancon, France) can be done by segmenting the topography of a surface in
  • Characteristics provide statements u.a. height information (calculation according to ISO 25178) and roughness (calculation according to ISO 4287). Table 9 Roughness of a black damaged tile before and after
  • Component Z1 of the detergent compositions according to the invention is Component Z1 of the detergent compositions according to the invention.

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Abstract

L'invention concerne des compositions de détergents contenant un ou plusieurs copolymères comprenant des motifs structuraux cationiques et des motifs structuraux macromonomères, ainsi qu'un ou plusieurs tensioactifs et de l'eau. Ces compositions de détergents sont notamment appropriées de manière avantageuse pour faire briller la surface traitée avec les compositions de détergents, et pour lui conférer des caractéristiques hydrophiles.
EP17807797.0A 2016-11-28 2017-11-21 Compositions de détergents contenant un copolymère Active EP3545066B1 (fr)

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ES2983683T3 (es) 2024-10-24
MX2019006053A (es) 2019-08-14
JP2020500970A (ja) 2020-01-16
AR110256A1 (es) 2019-03-13
EP3545066B1 (fr) 2024-05-01
CN109996858A (zh) 2019-07-09
US20200080029A1 (en) 2020-03-12
WO2018095915A1 (fr) 2018-05-31
BR112019009866B1 (pt) 2023-09-26
US11530373B2 (en) 2022-12-20
PL3545066T3 (pl) 2024-09-09
BR112019009866A2 (pt) 2019-08-06

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