EP4072821A1 - Verfahren und vorrichtung zur herstellung eines dekorierten wand- oder bodenpaneels - Google Patents
Verfahren und vorrichtung zur herstellung eines dekorierten wand- oder bodenpaneelsInfo
- Publication number
- EP4072821A1 EP4072821A1 EP20775341.9A EP20775341A EP4072821A1 EP 4072821 A1 EP4072821 A1 EP 4072821A1 EP 20775341 A EP20775341 A EP 20775341A EP 4072821 A1 EP4072821 A1 EP 4072821A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- carrier
- rollers
- calibration
- roller
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0023—Combinations of extrusion moulding with other shaping operations combined with printing or marking
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/44—Compression means for making articles of indefinite length
- B29C43/46—Rollers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0011—Combinations of extrusion moulding with other shaping operations combined with compression moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0021—Combinations of extrusion moulding with other shaping operations combined with joining, lining or laminating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/30—Extrusion nozzles or dies
- B29C48/35—Extrusion nozzles or dies with rollers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/355—Conveyors for extruded articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/90—Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article
- B29C48/906—Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article using roller calibration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/001—Producing wall or panel-like structures, e.g. for hulls, fuselages, or buildings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/44—Compression means for making articles of indefinite length
- B29C43/46—Rollers
- B29C2043/467—Rollers plurality of rollers arranged in a specific manner in relation to each other
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2795/00—Printing on articles made from plastics or substances in a plastic state
- B29C2795/007—Printing on articles made from plastics or substances in a plastic state after shaping
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92923—Calibration, after-treatment or cooling zone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
- B29C43/24—Calendering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
- B29C48/914—Cooling drums
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/002—Panels; Plates; Sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/42—Alternating layers, e.g. ABAB(C), AABBAABB(C)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/107—Ceramic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2272/00—Resin or rubber layer comprising scrap, waste or recycling material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
- B32B37/20—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of continuous webs only
Definitions
- the present invention relates to a method for producing a decorated wall or floor panel, comprising the method steps: a) providing a molten polymer mass; b) extruding the molten polymer mass through a die; c) Calibrating the molten polymer mass with the formation of a plate-shaped carrier by means of an arrangement of several rotatable rollers, the individual rollers being arranged one above the other and each individual roller with adjacent rollers forming at least one calibration gap through which the molten polymer mass is passed, the Calibration gap heights can be variably adjusted via a horizontal and / or vertical movement of individual rollers during the manufacturing process; d) applying a decoration simulating a decorative template to at least a partial area of the at least partially calibrated carrier, and e) applying a protective layer to at least a partial area of the decoration.
- the present invention also relates to a device for producing a decorated wall or floor panel and a wall or floor panel which is produced according to the method described above.
- Decorated panels are known per se and are used, for example, in interior construction as a floor or wall covering.
- the term wall panel is also to be understood as meaning panels which are suitable for covering the ceiling.
- the panels are usually made from a carrier or core made of a solid material, for example a wood material, which is provided on at least one side with a decorative layer and a cover layer and optionally with further layers, for example a wear layer arranged between the decorative and cover layer.
- the decorative layer is usually a printed paper that is impregnated with a resin.
- the top layer and the other layers are also mostly made of resin.
- Processes for the production of panels usually have several process steps. For example, a "cake" made of granulate pellets can be placed on the lower belt of a press using a spreader. In the course of production, this cake is usually fed into a hot belt press with steel and / or Teflon belts, in which the granulate pellets are heated and melted. At the same time as melting, the material can be pressed and shaped into a carrier. Then, through controlled cooling, solidification or crystallization of the carrier material is brought about, the waste heat largely remaining unused, since the usable temperature difference due to the controlled cooling is too low for any other use. In this belt press process, the heat is transferred from above and below through contact with the press.
- the method has the process steps: a) providing a pourable carrier material, in particular a granulate, b) arranging the carrier material between two belt-like conveyors, c) shaping the carrier material under the action of temperature to form a web-shaped carrier, d) compressing the carrier, e ) Treating the carrier under the action of pressure using a two-belt press, the carrier being cooled in or in front of the two-belt press, f) optionally further cooling of the carrier, g) optionally applying a decorative background to at least a partial area of the carrier; h) applying a decoration that simulates a decorative template on at least a partial area of the carrier, i) applying a protective layer to at least a partial area of the decor, j) optionally structuring the protective layer to insert pores and / or the edge area of the carrier to form connecting elements, and k) optionally treating the carrier for electrostatic discharge before one of the aforementioned process steps.
- the invention thus proposes a method for producing a decorated wall or floor panel, comprising the method steps: a) providing a molten polymer mass; b) extruding the molten polymer mass through a die; c) Calibrating the molten polymer mass with the formation of a plate-shaped carrier by means of an arrangement of several rotatable rollers, the individual rollers being arranged one above the other or one behind the other and each individual roller with adjacent rollers forming at least one calibration gap through which the molten polymer mass is passed, the Calibration gap heights can be variably adjusted via a horizontal and / or vertical movement of individual rollers during the manufacturing process; d) applying a decoration simulating a decorative template to at least a partial area of the at least partially calibrated carrier, and e) applying a protective layer to at least a partial area of the decoration.
- the method described above enables an improved production of a wall or floor panel.
- high-quality panels with improved decorative properties can be obtained within very short process times.
- the panels have particularly even support surfaces on which high-quality decorations can be applied particularly efficiently.
- decorations applied according to the invention exhibit particularly high-quality optical properties due to the particularly smooth and fault-free surface of the carrier material.
- the procedure specified above also enables a high throughput at high web speeds and reduces the proportion of non-compliant panels.
- the integration of the roller calibration step into the production of the proportion of air inclusions on the panel surface can be reduced, which can probably be attributed to an improved removal of existing in the carrier and an improved exclusion of air in the roller gaps.
- the flexible process using individually controllable rollers can also shorten the set-up and run-in times of the system, which results in higher process efficiency.
- a larger proportion of the process energy can also be recovered, which overall contributes to a smaller C0 2 footprint of the method used and thus also of the panel produced.
- the method according to the invention is a method for producing a decorated wall or floor panel.
- the term “decorated wall or floor panel” or “decorative panel” is to be understood as meaning in particular wall, ceiling or floor panels which have a decoration that is applied to a carrier plate and replicates a decorative template.
- Decorative panels are used in a variety of ways both in the area of interior design of rooms and for the decorative cladding of buildings, for example in trade fair construction.
- One of the most common areas of application for decorative panels is their use as flooring.
- the decor panels often have a decor that is intended to simulate a natural material.
- Examples of such modeled natural materials or decorative templates are types of wood such as maple, oak, birch, cherry, ash, walnut, chestnut, wenge or exotic woods such as panga-panga, mahogany, bamboo and bubinga.
- natural materials such as stones or ceramics can be modeled.
- a “decorative template” in the sense of the present invention can in particular be understood to mean that such a natural material or at least the surface of which is to be imitated or modeled by the decor.
- Process step a) comprises providing a molten polymer mass.
- the molten polymer mass shows, at least in part, the properties of a flowable viscous liquid and can be obtained, for example, by a thermal treatment step of polymers which are usually present as granules.
- the molten polymer mass can consist of only one homogeneous polymer mass or of several polymer masses which are mixed with one another or are layered one on top of the other in a defined form (feed block).
- a “granulate” or a “granular material” can be understood to mean a solid or a heap of a solid which comprises or consists of a large number of solid particles, such as grains or spheres.
- granular or powdery materials or suitable recycling materials present as regrind are mentioned here.
- the polymer mass or the granulate can have a carrier material based on a plastic, a compound based on inorganic fillers or a wood-plastic composite material (WPC).
- WPC wood-plastic composite material
- the molten polymer mass and thus also the carrier plate can essentially be formed from a thermoplastic, elastomeric or thermosetting plastic.
- recycling materials made of the materials mentioned can be used in the context of the method according to the invention.
- Thermoplastics such as polyvinyl chloride, polyolefins (for example polyethylene (PE), polypropylene (PP), polyamides (PA), polyurethanes (PU), polystyrene (PS), acrylonitrile-butadiene-styrene (ABS),
- plasticizers can be provided regardless of the base material of the carrier, in a range from> 0% by weight to ⁇ 20% by weight, in particular ⁇ 10% by weight, preferably ⁇ 7% by weight, for example in a range from> 5% by weight to ⁇ 10 Wt .-% can be present.
- Suitable plasticizers include, for example, the plasticizer sold by BASF under the trade name “Dinsch”.
- copolymers such as acrylates or methacrylates or blends with thermoplastic elastomers (TPEs) can be provided as a substitute for conventional plasticizers.
- dry plastic powders can be melted, for example, dry plastic powders with additives.
- fiber materials such as paper and nonwovens based on vegetable, animal, mineral or artificial fibers or cardboard can also be used as additives.
- animal fiber materials are keratin-based materials such as wool or horsehair.
- mineral fiber materials are made of mineral wool or glass wool.
- process step a can be provided in process step a), for example, by a screw extruder in which the polymeric material or the dry blends are melted, optionally homogenized, and passed on to process step b) by means of pressure, temperature and shear forces.
- the molten polymer mass is extruded through a nozzle.
- the melted and plasticized polymer mass is pressed through a nozzle by means of pressure, whereby part of the final product geometry is expediently already predetermined by the selection of the nozzle geometry.
- the choice of a slot or a wide slot nozzle has proven to be particularly suitable, which has a ratio of Slot width to height of more than approx. 4: 1 (width: height), preferably more than 10: 1, furthermore preferably more than 20: 1.
- this rather wide and narrow nozzle geometry allows a large part of the carrier structure to be preformed, which can keep the subsequent effort for the calibration of the extruded polymer mass small.
- the slot nozzle has means for adjusting the nozzle gap.
- These means can be used, for example, to extremely flatten the edge areas of the extruded flat strand, so that in these edge areas flatter connection points can be formed between different panels in a further process step compared to average panel thicknesses.
- the molten polymer mass is calibrated with the formation of a plate-shaped carrier by means of an arrangement of several rotatable rollers, the individual rollers being arranged one above the other and each individual roller with adjacent rollers forming at least one calibration gap through which the molten polymer mass is guided
- the heights of the calibration gap can be variably adjusted via a horizontal or vertical movement of individual rollers during the manufacturing process.
- the panels are not shaped and calibrated using a flat press, but rather using rollers.
- the molten polymer mass is guided through the gaps formed by the roll arrangement between the rolls and, due to the mechanical load in the roll gaps, the mass is squeezed and brought to the desired thickness.
- the polymer mass can also be cooled at the same time. This can be done via the rollers or by means of other coolants, for example by blowing air on them. That an efficient calibration can be obtained by means of the roller arrangement and by means of the roller gap is surprising, since the viscoelastic properties of the molten polymer mass suggest the use of presses with a large surface. Compared to the presses A rather small active calibration surface in the nips should rather lead to the fact that, due to the rheological properties of the polymer mass, such as thixotropic properties, only an inadequate calibration results on small calibration surfaces.
- rollers in this context mean more than four, for example five rollers, the several rollers forming at least 3 or 4 separate gaps.
- the gaps are preferably arranged one behind the other, separated by the rollers.
- the calibration of the carrier takes place only by guiding the molten carrier material through the roller gap.
- the method can entirely dispense with the use of plate-shaped pressing devices, such as belt presses, for example.
- the calibration of the carriers is carried out only by the rollers arranged one behind the other, in direct succession at one location of the device.
- a division of the roller arrangement for example first two roller gaps, followed by, for example, a cooling section and then again one or two roller gaps, would not be according to the invention in this case.
- the calibration takes place directly after the extrusion of the carrier material and further significant calibration or smoothing steps are omitted.
- the heights of the calibration gap can be set variably by moving individual rollers horizontally or vertically during the manufacturing process. This means that by changing the position of an individual roller, the gap dimensions of the one or those gaps which are formed in relation to adjacent rollers also change. In this way, the gap dimensions and thus the carrier height can be influenced by the distance between the rollers.
- the take-off or angle of incidence of the molten polymer material on the roller can also be changed via the relative height of the individual rollers to one another, which results in different mechanical forces, possibly different cooling properties and - Surfaces, as well as possible air inclusions between the roller and the polymer.
- a roller can be variably adjusted during the manufacturing process if the roller can change its X and / or Y position while the polymer material is passing through.
- the individual gaps can be controlled either isobarically or isochorically during production.
- the former mode of operation specifies a mechanical force on the polymeric carrier material in the roller gap, whereas the latter mode of operation is based on a constant thickness of the gap between two rollers.
- the roller positions are adjusted dynamically, whereas in the latter, the roller positions are more likely to be kept constant to one another.
- the diameter of the main rollers and the downstream rollers is selected so that the contact surfaces between the carrier and the rollers are largely the same on both sides of the carrier.
- IR emitters can be used for this purpose.
- Further measures for uniform cooling of the molded polymer mass can be vacuum boxes, which ensure air-free application of the polymer melt to the roller, or so-called edge pinning, with the edge area being fixed electrostatically on the roller.
- a decoration simulating a decoration template is applied to at least a partial area of the at least partially calibrated carrier.
- the application of the decorative template can therefore take place after passing through the roller arrangement on the fully calibrated carrier or else before passing through the last roller calibration gap.
- the carrier not only has a particularly smooth surface with a low degree of roughness, but also a surface with particularly few air inclusions. These two factors can contribute to a particularly reproducible and high-quality decorated carrier end product.
- the air in the carrier can escape significantly better compared to a flat press. This can lead to carriers and carrier surfaces that are particularly low in air inclusion.
- a second, white-colored polymer melt introduced on top of the melted and extruded polymer can be used to apply a smooth, void-free printing base which, contrary to the solutions from the prior art, does not have to be coated with non-polymer thermosetting plastics.
- This has the advantage that it consists of an almost identical thermoplastic polymer matrix of the carrier plate. The latter can be very beneficial for efficient recycling.
- a decoration which simulates a decoration template is applied to at least a partial area of the carrier.
- the decor can, for example, by a so-called Direct print can be applied.
- Direct printing is understood to mean the application of a decoration directly to the carrier of a panel or to a non-printed fiber material layer or a decorative substrate applied to the carrier.
- Different printing techniques such as flexographic printing, offset printing or screen printing can be used.
- inkjet or laser printing processes for example, can be used as digital printing techniques.
- the decoration can be applied identically to the template after passing through the roller arrangement.
- the three-dimensional decor data can be provided by three-dimensional scanning of the decor template by means of electromagnetic radiation, for example by a three-dimensional scanner (3D scanner).
- a plurality of decorative layers with at least partially different surface application can be applied successively on the basis of three-dimensional decorative data provided.
- the decorative layers can be formed from an in particular radiation-curable paint and / or ink.
- a UV curable paint or ink can be used.
- a particularly true-to-detail and matching replica of the decorative template can be achieved.
- a synchronous pore can be achieved with high precision in this way without the provision of further measures.
- a synchronous pore can in particular be a pore or some other type of structure which is spatially arranged exactly where it is optically represented by a haptic structuring that matches the optical decorative features. This is essentially the case automatically in this configuration, since the structural configuration is generated precisely by the color or ink.
- decorative templates such as wood-based materials, for example, often have a variation in the color impression not only along their width or length but also along their depth.
- this one Color impression or color gradient can be reproduced particularly true to detail in this embodiment in particular, which also makes the overall impression of the panel appear even more identical.
- the color or ink used is radiation-curable, particularly rapid solidification can be achieved, whereby the majority of layers can be applied quickly to one another, which can also make the overall process realizable in a shorter time and thus particularly cost-effective.
- the term radiation-curable paint is understood to mean a composition containing binders and / or fillers and containing color pigments, which can be at least partially polymerized, induced by electromagnetic radiation of a suitable wavelength, such as UV radiation or electron beams.
- the term radiation-curable ink is to be understood as meaning an essentially filler-free, color pigment-containing composition which, induced by electromagnetic radiation of suitable wavelength, such as UV radiation or electron beams, can be at least partially polymerized.
- the decorative layers can each be applied in thicknesses of> 5 pm to ⁇ 1 opm.
- a corresponding negative image of the decorative template is also applied.
- the use of digital data can be used to reverse the color impression, for example of a grain, so that a negative is created with regard to the color or, in particular, lighter and darker areas.
- the applied structure so that a negative can also be realized with regard to the structural design. Effects of this kind can also be integrated into a manufacturing process on the basis of digital three-dimensional data without problems and without lead time or modifications.
- a protective layer is applied to at least a partial area of the decoration.
- Such a layer to protect the applied decoration can in particular be applied as a wear or cover layer above the decorative layer in a subsequent process step, which in particular protects the decorative layer from wear and tear or damage from dirt, the influence of moisture or mechanical effects such as abrasion.
- the wear and / or cover layer is placed on the printed carrier as a pre-produced overlay layer, for example based on melamine, and is connected to it by the action of pressure and / or heat.
- a radiation-curable composition such as, for example, a radiation-curable lacquer, such as an acrylic lacquer, is also applied to form the wear and / or top layer.
- the wear layer has hard materials such as titanium nitride, titanium carbide, silicon nitride, silicon carbide, boron carbide, tungsten carbide, tantalum carbide, aluminum oxide (corundum), zirconium oxide or mixtures of these in order to increase the wear resistance of the layer.
- the application can be applied, for example, by means of rollers, such as rubber rollers, or by means of pouring devices.
- the top layer can first be partially cured and then a final coating with a urethane acrylate and final curing, for example with a gallium emitter, can be carried out.
- the cover and / or wear layer can have means for reducing the static (electrostatic) charging of the final laminate.
- the top and / or wear layer connections such as Has choline chloride.
- the antistatic agent can be used, for example, in a concentration between> 0.1% by weight and ⁇ 40.0% by weight, preferably between> 1.0% by weight and ⁇ 30.0% by weight in the cover and / or composition for forming the wear layer may be included.
- a transparent wear layer made of thermoplastic polymers can also be used, which is laminated onto the decorative layer as a film web. It may be necessary to use an adhesion promoter / primer for adequate adhesion, which is crosslinked with the decorative layer by radiation curing from above (“adhesive varnish”) or thermally sealed (“hotmelt”).
- a thermoplastic wear layer offers further advantages for the recycling process of the overall structure. A surface structuring can be introduced very easily via heated, structured metal sheets using a press or structured rollers using a calender (this also synchronized with the decor).
- a structuring in particular a surface structuring that matches the decor, is introduced into the protective or wear layer or cover layer by introducing pores.
- the carrier plate already has a structuring and an alignment of a printing tool for applying the decoration and the carrier plate to one another takes place by means of the structuring of the carrier plate detected by means of optical methods.
- the decorative panels are structured after the application of the top and / or wear layer.
- a hardenable composition is applied as the top and / or wear layer and a hardening process only takes place to the extent that only a partial hardening of the top layer and / or wear layer.
- a desired surface structure is embossed into the partially hardened layer by means of suitable tools, such as a hard metal structure roller or a stamp during or after the calibration step. The embossing is done in accordance with the applied decor. To ensure that the structure to be introduced matches the decoration sufficiently, provision can be made for the carrier plate and the embossing tool to be aligned with one another by means of corresponding relative movements.
- the carrier plate provided with a decoration can then be divided into individual panels by suitable mechanical processes. This can be done, for example, by cutting the extruded strand at regular intervals or at regular times. This process step can preferably be used to produce cut panels of the same length.
- the calibration in method step c) can be carried out using at least one main roller pair consisting of two rollers with a larger diameter and at least three consecutively arranged sizing rollers with a smaller diameter compared to the main roller pair.
- at least one main roller pair consisting of two rollers with a larger diameter and at least three consecutively arranged sizing rollers with a smaller diameter compared to the main roller pair.
- the main part of the desired and necessary deformation can take place via the larger pair of rollers, whereas the other, smaller calibration rollers only exert low forces to obtain a uniformly calibrated product and transport air out of the carrier in a controlled manner. As a result, only slight fluctuations in thickness of the produced Achieve high line speeds.
- the roller diameters differ in diameter if the corresponding diameters of the main and calibrating rollers differ by at least 10%.
- the above-mentioned arrangement results, for example, in the following gap arrangements for the molten polymer material.
- the molten polymer material necessarily passes through the gap between the skin rollers and at least the two gaps between the at least three sizing rollers.
- the arrangement can, for example, have a total of 8, preferably 6, furthermore preferably 4, calibration rollers. This number of individual columns has proven to be particularly suitable for obtaining decorated panels with improved surface and decorative properties.
- the height of the calibration nip of the main roller pair HH can differ by greater than or equal to 10% and less than or equal to 50% from the heights of the calibration nip of the calibration rollers HK.
- the above-mentioned gap height ratio between the main and calibrating rollers has proven to be particularly suitable for obtaining particularly smooth carrier surfaces and for obtaining carrier materials with particularly low mechanical stress.
- the force acting on the carrier can also be determined, so that a force distribution that is particularly suitable for the production of decorated panels is given for the roller arrangement. This results in particularly favorable properties both with regard to the presence of air inclusions and with regard to the occurrence of stress cracks in the carrier material.
- the distance between the action of mechanical force and the shaping of the carrier seems to play an important role in relation to the place where the decoration is applied.
- the height of the calibration gap or gaps it has been found to be particularly suitable for the height of the calibration gap or gaps to be greater than or equal to 10% and less than or equal to 50% less than the height of the main roller gap. This can contribute to high line speeds without losing the surface quality of the decorated panel.
- the height of the last and / or the penultimate calibration gap can be selected so that the height of the carrier is compressed by a factor of less than or equal to 10% and greater than or equal to 3%.
- the compression ratio given above has proven to be particularly advantageous for obtaining particularly smooth carrier surfaces with very little air inclusion. The ratio can be determined, for example, by measuring the thickness of the carrier before and after passing through the gap.
- the desired compression rate can be set via the height profile ratio of the calibrating roller gaps or via the force to be applied in the individual roller gaps.
- method step d) can additionally include the application of a decorative background to at least a partial area of the carrier before the decoration is applied.
- further optional layers such as, for example, a decorative background or a primer layer, can of course also be applied to the carrier. It can be advantageous, for example, to apply these further layers to the carrier before the last roller, since improved adhesion of these further layer (s) to the carrier can be achieved by the at least one mechanical treatment in the further calibration gap.
- the carrier can be pretreated by an electrostatic discharge between or after the roller arrangement. This can in particular serve to avoid the occurrence of blurring in the course of the application of the decoration.
- a possible device for dissipating electrostatic charges can have at least one of the rollers or a separate roller, brush or lip made of a conductive material with a conductivity> 1 * 10 3 Sm 1 , which makes electrically conductive contact with the carrier at least in the area of the printing unit and which with is connected to an electrical ground potential.
- the electrical ground potential can be provided, for example, by grounding.
- a device for dissipating electrostatic charges can be, for example, a device for generating a corona discharge.
- a decorative background can, for example, initially comprise a primer, in particular for printing processes, for example in a thickness of> 10 ⁇ m to ⁇ 60 ⁇ m.
- a liquid, radiation-curing mixture based on a urethane or a urethane acrylate, optionally with one or more of a photoinitiator, a reactive diluent, a UV stabilizer, a rheological agent such as a thickener, radical scavenger, flow control agent, defoamer or preservative, pigment and / or or a dye can be used.
- the urethane acrylate can be contained in the primer composition in the form of reactive oligomers or prepolymers.
- reactive oligomer or “prepolymer” in the context of the invention is to be understood as meaning a compound containing urethane acrylate units which can react induced by radiation, possibly with the addition of a reactive binder or a reactive diluent, to form the urethane or urethane acrylate polymer .
- Urethane acrylates in the context of the invention are compounds which are essentially built up from one or more aliphatic structural elements and urethane groups. Aliphatic structural elements include both alkylene groups, preferably with 4 to 10 carbon atoms, and cycloalkylene groups, preferably with 6 to 20 carbon atoms.
- Both the alkylene and the cycloalkylene groups can be substituted one or more times with Ci-C4-alkyl, in particular with methyl, and contain one or more non-adjacent oxygen atoms.
- the aliphatic structural elements are optionally superquaternary or tertiary carbon atoms, via urea groups, biureth, urethdione, allophanate, cyanurate, urethane, ester or amide groups or via ether oxygen or amine nitrogen linked together.
- urethane acrylates for the purposes of the invention can also have ethylenically unsaturated structural elements.
- ethylenically unsaturated structural units are acryloyl and methacryloyl groups such as acrylamido and methacrylamido and in particular acryloxy and methacryloxy.
- Radiation-curable in the context of the invention means that the primer composition can be at least partially polymerized induced by electromagnetic radiation of a suitable wavelength, such as, for example, UV or electron radiation.
- the use of radiation-curable primers based on urethane acrylates enables a decoration to be applied immediately after the application and the radiation-induced curing of the primer layer, for example by means of digital printing technology.
- the primer layer ensures good adhesion of the applied decoration to the carrier surface coated with the primer.
- Urethane acrylates have the advantage of good adhesion both to the carrier material and to the decorative layer, that is to say the decorative paint or ink. This is due, among other things, to the polymerization reactions that occur with this type of polymer, in which, on the one hand, radiation-induced radical polymerization of the OH groups occurs and, on the other hand, post-curing of the polymer via the NCO groups.
- the primer can preferably be applied by means of rubber rollers, a casting machine or by spraying onto the carrier plate running through the roller arrangement. It is also possible that the primer is applied after the roller arrangement but before the decoration is applied.
- the primer is preferably used in an amount between> 1 g / m 2 and ⁇ 100 g / m 2 , preferably between> 10 g / m 2 and ⁇ 50 g / m 2 , in particular between> 20 g / m 2 and ⁇ 40 g / m 2 applied.
- a primer in addition to the use of a primer, it is possible to apply the decor to a decor paper which can be printed with a corresponding decor and which can be provided as a connecting means, for example, by means of a resin layer previously applied to the carrier.
- a printing substrate is suitable both for flexographic printing, offset printing or screen printing processes and, in particular, for digital printing techniques such as, for example, inkjet processes or laser printing processes.
- a resin composition is applied which has at least one compound selected from the group consisting of melamine resin, formaldehyde resin, urea resin, phenolic resin, epoxy resin, unsaturated polyester resin, diallyl phthalate or mixtures thereof as resin component.
- the resin composition can be applied, for example, in an application amount between 5 5 g / m 2 and 40 g / m 2 , preferably 10 g / m 2 and 30 g / m 2 .
- a paper or fleece with a grammage between> 30 g / m 2 and ⁇ 80 g / m 2 , preferably between> 40 g / m 2 and ⁇ 70 g / m 2 , can be applied to the plate-shaped carrier.
- at least the application of the decorative background to a partial area of the carrier in method step d) can take place before the last roller of the roller arrangement of method step c).
- the calibrating rollers are used not only to adjust the carrier height, but also to apply and mechanically fix the decorative background.
- the measure enables a particularly efficient method to be implemented, with the drying of the decorative background also being able to be accelerated, since the carrier has higher temperatures at this point in the process. In this way, further mechanical components can be saved and the temperature control during cooling can be optimized.
- a total amount of heat to be dissipated by the material can be reduced, for example, by the heat capacity of the decorative background.
- the roller arrangement can have at least four further calibrating rollers in addition to the main roller pair, one of the roller gaps of the calibrating rollers being driven isobarically. Contrary to the operation with constant gap thicknesses between the calibrating rollers, it has been found to be particularly advantageous for the surface properties of the carrier that at least one of the gaps is operated isobarically, i.e. with constant force acting on the carrier. This enables very fast process times to be achieved while maintaining the smoothest possible carrier surface.
- Isobaric operation within the meaning of the invention means that, via the control of the roller spacing, the force acting on the carrier in the nip during the manufacture of the carrier fluctuates by less than 10%, preferably less than 5%, furthermore preferably less than 2.5% .
- the forces for producing a carrier can be measured, for example, by means of a force sensor on or in the roller or by means of one or more force sensors in the carrier material.
- the main and calibrating rollers can be equipped to be temperature-controlled and the temperature-controllable surface of the calibrating rollers can be larger than the main rollers by a factor of greater than or equal to 1.1 to less than or equal to 2.5.
- a thermal treatment of the carrier can also take place at the same time by means of the roller arrangement.
- the thermal treatment can in principle consist of partial heating or partial cooling of the carrier.
- the molten material is cooled by the rollers on the roller surface. This can be achieved, for example, in that the individual rollers inside the roller have a supply of heat transfer media, such as a cooling liquid, for example.
- the surface temperatures of the individual rollers of the roller arrangement can be regulated separately. This can contribute to a particularly reproducible and gentle molding and cooling process.
- the above-specified ratio of the cooling surfaces between the main and calibrating rollers has proven to be particularly suitable for obtaining decorated panels with particularly low mechanical stress and particularly few air inclusions.
- the higher quality decorations result from the amount of heat dissipated in a controlled manner in the individual steps, which is also proportional to the surface area of the roller pairs.
- very high web speeds and a particularly efficient expulsion of air inclusions from the carriers can also be achieved.
- the individual roller temperatures, and consequently also the cooling rates that can be achieved at them can be selected as a function of the mechanical force exerted on the carrier. Greater force effects, for example due to high compressions of the carrier material, can be accompanied by a higher temperature gradient between the roller and the carrier material, so that in total a carrier with less mechanical stress is obtained.
- a device for producing a decorated wall or floor panel is also according to the invention, the device having means for carrying out the method according to the invention.
- a preferred embodiment for the device can comprise a temperature-controllable screw extruder and a slot die with variable profile.
- the device can have rollers that can be temperature controlled and, in particular, be cooled.
- the individual rolls can be moved relative to one another in their positions in the production process and consequently the dimensions of the roll gaps formed between the rolls can also be changed.
- at least one larger pair of main rollers and several, preferably at least 3, more preferably 4, furthermore preferably 5 further, smaller calibration rollers can be used for shaping and calibrating the carrier.
- the rollers can each be equipped with adjustable temperatures.
- the device according to the invention can furthermore have means for applying further layers, such as, for example, a decorative background, a decoration and / or a wear protection layer.
- the means for applying these layers can be arranged after the calibrating rollers.
- the decoration is preferably applied after the roller arrangement using a direct printing process.
- a decorative protective layer can be applied, for example, by lamination under pressure or by brushing or knife-coating of a liquid or pasty protective layer compound.
- the device can also have further means for the final cooling of the carrier. It is also possible that the device also has further means to return the heat removed from the carrier to the product cycle. This can be done, for example, via heat exchangers. The waste heat obtained can be used, for example, to control the temperature of the extruder.
- the device can have further means for mechanical processing of the carrier, for example for special profiling of the carrier edges.
- the device can have further means for dividing the extruded plate into smaller panels of essentially the same length. This can be split or cut be done for example by his saw. Circular or band saws, for example, can be used for this purpose.
- the extruded and decorated plate can be divided into smaller panels by other physical means, such as, for example, a laser.
- a wall or floor panel produced by the method according to the invention is also in accordance with the invention.
- the method according to the invention can be used to obtain panels at very high line speeds which are characterized by particularly smooth surfaces and a low proportion of air in and in the form of pores on the surface of the panels.
- the number and size of surface defects caused by air can be significantly reduced.
- the temperature control and the mechanical treatment also result in very low-tension carriers.
- the method and the device are also suitable for processing a wide variety of materials.
- the carrier material can comprise or consist of wood-polymer materials (wood plastic composite, WPC).
- WPC wood plastic composite
- a wood and a polymer can be suitable, which can be present in a ratio of 40/60 to 70/30, for example 50/50.
- Polypropylene, polyethylene or a copolymer of the two aforementioned materials can be used as polymer components.
- Such materials offer the advantage that they can be formed into a carrier even at low temperatures, such as in a range from> 180 ° C to ⁇ 200 ° C in the above-described method, so that a particularly effective process control, for example with exemplary line speeds in a range of 6m / min.
- a WPC product with a 50/50 distribution of wood and Polymer proportions are possible with an exemplary product thickness of 4.1 mm, which can enable a particularly effective manufacturing process.
- the panel can have a WPC material or a PVC material greater than or equal to 50% by weight and less than or equal to 100% by weight.
- the carrier material comprises or consists of a PVC-based material.
- PVC-based carrier materials are also suitable for a particularly effective manufacturing process, since here, for example, line speeds of 8 m / min with an exemplary product thickness of 4.1 mm can be possible, which can enable a particularly effective manufacturing process.
- such carriers also have advantageous elasticity and water compatibility, which can lead to the aforementioned advantages.
- mineral fillers can be advantageous.
- Talc or calcium carbonate (chalk), aluminum oxide, silica gel, quartz flour, wood flour, gypsum are particularly suitable here.
- chalk can be provided in a range from> 30% by weight to ⁇ 70% by weight, with the fillers, in particular the chalk, in particular being able to improve the slip of the carrier. They can also be colored in a known manner. In particular, it can be provided that the plate material has a flame retardant.
- the carrier material of the panel can have a matrix material and a solid material, the matrix material in an amount, based on the carrier material, of> 25% by weight to ⁇ 55% by weight, in particular of > 35 wt .-% to ⁇ 45 wt .-%, and wherein the solid material in an amount, based on the carrier material, of> 45% by weight to ⁇ 75% by weight, in particular from> 55% by weight to ⁇ 65% by weight, and wherein the matrix material and the solid material together, based on the carrier material, in an amount of> 95% by weight, in particular> 99% by weight, the solid material being at least 50% by weight, in particular at least 80% by weight, in particular at least 95% by weight.
- -% based on the solid material, is formed from a solid composition consisting of at least a first layered silicate powder and a second layered silicate powder, and the matrix material is at least 50% by weight, in particular at least 80% by weight, in particular at least 95% by weight.
- -% based on the matrix material, is formed by a plastic composition consisting of a homopolymer and at least a first copolymer and a second copolymer.
- the carrier material has a solid material and a matrix material. It is provided that the matrix material is present in an amount, based on the carrier material, of> 25% by weight to ⁇ 55% by weight, in particular from> 35% by weight to ⁇ 45% by weight. Furthermore, it is provided that the solid material is present in an amount, based on the carrier material, of> 45% by weight to ⁇ 75% by weight, in particular from> 55% by weight to ⁇ 65% by weight.
- the proportions of matrix material or solid material can be selected. This enables good adaptability to the desired field of application. In principle, however, it can be preferred that the proportion of the solid material is greater than or equal to the proportion of the matrix material. It is further provided that the matrix material and the solid material are present together, based on the carrier material, in an amount of> 95% by weight, in particular> 99% by weight.
- the carrier material in addition to the solid material and the matrix material, further substances are only present in the carrier material in a proportion, based on the carrier material, of ⁇ 5% by weight, preferably ⁇ 1% by weight. It can thus be advantageous that the carrier material consists largely of the solid material and the matrix material. It can particularly preferably be provided that the matrix material and the solid material are present together, based on the carrier material, in an amount of 100% by weight, the carrier material thus consisting of the matrix material and the solid material.
- the carrier By restricting the materials of the carrier material and thus by using a small number of materials for producing the carrier, the carrier can be produced particularly inexpensively.
- the process control for the production of a carrier or a panel can be very simple, so that production is also possible in a simple and inexpensive manner.
- the solid material is formed to at least 50% by weight, in particular at least 80% by weight, in particular at least 95% by weight, based on the solid material, from a solid composition consisting of at least one first Layered silicate powder and a second layered silicate powder.
- Layered silicate powder is understood to mean, in a manner known per se, a powder made from a layered silicate.
- sheet silicates are minerals from the group of silicates, the silicate anions of which are usually arranged in layers.
- sheet silicates are understood to mean minerals from the mica group, the chlorite group, the kaolinite group and the serpentine group.
- the solid material is thus advantageously formed at least by a large part from the mineral substance sheet silicate, this substance being able to be used, for example, in powder form or in the carrier material in the form of particles.
- the solid material can consist of a powdery solid.
- Layered silicates offer the advantage that they can allow the production of a carrier with good mechanical properties and at the same time can be easily processed into corresponding powders due to their layered structure.
- the first layered silicate powder or the second layered silicate powder can comprise talc.
- talc is understood to mean a magnesium silicate hydrate which, for example, can have the chemical empirical formula Mg3 [Si 4 Oio (OH) 2 ].
- the first layered silicate powder and the second layered silicate powder can comprise talc.
- the first layered silicate powder and the second layered silicate powder can consist of at least 80% by weight, particularly preferably at least 95% by weight, of talc.
- Talc in particular, has the advantage that it enables the carrier to be produced in a particularly gentle manner, since it can be embedded in the matrix material without any problems and thus does not exert any abrasive effect on the press units used.
- a mixture of a homopolymer and a first copolymer and a second copolymer can enable particularly advantageous properties for the matrix material.
- Such materials also offer the advantage that they can be used even at low Temperatures, such as in a range from> 180 ° C to ⁇ 200 ° C in the above-described method, can be formed into a carrier, so that a particularly effective process control, for example with exemplary line speeds in a range of 6 m / min, can be made possible .
- the effective process control can in particular be achieved in that the carrier material has an advantageous mass flow rate.
- the carrier material has a mass flow rate of> 20 g / 10 min to ⁇ 30 g / 10 min, preferably> 24 g / 10 min to ⁇ 26 g / 10 min.
- the use of at least two copolymers can be of advantage, since this allows improved elastic properties of the carrier produced to be achieved.
- panels produced with the carrier material have an advantageous flexural modulus.
- a panel can be provided which has a flexural modulus of> 3000 MPa to ⁇ 4000 MPa, preferably from> 3400 MPa to ⁇ 3600 MPa. It can also be achieved that panels produced with the carrier material have an advantageous flexural strength. On the basis of the carrier material, for example, a panel can be provided which has a flexural strength of> 30 MPa to ⁇ 34 MPa, preferably of> 31 MPa to ⁇ 33 MPa. Furthermore, it can be achieved that panels produced with the carrier material have an advantageous flexural elongation. On the basis of the carrier material, for example, a panel can be provided which has a flexural elongation of> 2.0% to ⁇ 2.8%, preferably of> 2.3% to ⁇ 2.5%.
- the homopolymer, the first copolymer and the second copolymer comprise polypropylene.
- Polypropylene is particularly suitable as a matrix material because, on the one hand, it can be obtained inexpensively and, as a thermoplastic, also has good properties as a matrix material for embedding the solid material.
- the panel can have a multilaminar plastic carrier material with a plurality N of layer sequences ABA, where layer A has a first thermoplastic and layer B has a second thermoplastic, and the first thermoplastic is a virginal plastic and the second plastic is a recycled plastic, and where 250>N> 2, preferably 200>N> 3, preferably 125>N> 4, even more preferably 100>N> 5.
- plastic carrier material over the method according to the invention can be produced with high line speeds and with a high degree of dimensional accuracy.
- the different layers can be deposited as a co-extrudate via several nozzles at the same time or one behind the other and processed using the method according to the invention.
- Such wall, ceiling or floor panels have improved moisture resistance, in particular with reduced moisture or heat-related swelling, as well as good mechanical properties and improved machinability.
- the plastic carrier material according to the invention is ecologically advantageous, since it can be made from a significant proportion of recycled plastic and is therefore resource-saving.
- ABCBA composites are also suitable for this, for example as a variant of paint, filler, foam, in-house recycling, or even polymer composites.
- the recycled thermoplastic plastic of layer B can comprise, for example, an amorphous polyethylene terephthalate (PET).
- PET polyethylene terephthalate
- PET occurs in large quantities in the packaging industry, where it is used in particular for food packaging and beverage bottles. Since the highest standards have to be adhered to in the field of food packaging, recycling of PET is usually only possible to a limited extent.
- URRC United Resource Recovery Corporation
- large quantities of PET are not recycled locally, but are exported for the production of synthetic fibers.
- the method according to the invention offers another possible use for recycled PET.
- the proportion of recycled polyethylene terephthalate in layer B can preferably be in a range between> 10% by weight and ⁇ 100% by weight, based on the polymer proportion of layer B.
- the proportion of recycled polyethylene terephthalate in layer B can particularly preferably be in a range between> 15% by weight and ⁇ 90% by weight,> 20% by weight and ⁇ 80% by weight, in particular based on the polymer content of the layer B lie.
- a virginal polyethylene terephthalate can be provided in the B layer.
- the proportion of virgin PET can be in a range between> 0% by weight and ⁇ 90% by weight based on the polymer content of layer B.
- the proportion of virgin polyethylene terephthalate in layer B can particularly preferably be in a range between> 10% by weight and ⁇ 80% by weight,> 15% by weight and ⁇ 75% by weight, in particular based on the polymer content of the layer B lie.
- PET-based polymer compositions in particular can be subjected to a separate annealing / tempering process within the structure.
- the annealing / tempering process helps to reduce the tension present in the plate through the calibration and thus improves the dimensional stability.
- the subsequent heat treatment can take place, for example, in the form of further tempering rollers around which the web-shaped extrudate is wrapped.
- Further annealing options are temperature-controlled circulating air sections or heated water baths, whereby the annealing temperature should be selected so that it does not lead to recrystallization of the polymer mass.
- the layer B has a filler in addition to the thermoplastic material, the filler preferably being selected from the group consisting of chalk, non-asbestos silicate, preferably magnesium silicate, wood flour, expanded clay, volcanic ash, pumice, aerated concrete, in particular inorganic foams, cellulose or a blowing agent.
- the filler preferably being selected from the group consisting of chalk, non-asbestos silicate, preferably magnesium silicate, wood flour, expanded clay, volcanic ash, pumice, aerated concrete, in particular inorganic foams, cellulose or a blowing agent.
- the proportion of filler can preferably be in a range between> 1% by weight and ⁇ 60% by weight, in particular in a range between> 5% by weight and ⁇ 50% by weight, based on the total mass of layer B. forming material.
- the material properties of the multilaminar plastic carrier material such as, for example, its specific weight or also its calorific value.
- the latter is particularly relevant to the question of the wall, ceiling or floor covering formed on the basis of a corresponding multilaminar plastic carrier and the fire load introduced into a building by such a material.
- the proportions of thermoplastic material or filler material can be selected depending on the desired field of application and the desired properties of a panel formed on the basis of a multilaminar plastic carrier material according to the invention. This enables good adaptability to the desired field of application. It can particularly preferably be provided that a sheet silicate, such as talc, is provided as filler in layer B.
- talc is understood, in a manner known per se, to be a magnesium silicate hydrate which, for example, can have the chemical empirical formula Mg 3 [Si 4 0io (OH) 2 ].
- the solid fraction is advantageously formed at least by a large part of the mineral substance talc, wherein this substance can be used in powder form or can be present in the carrier material in the form of particles.
- the solid material can consist of a powdery solid.
- the panel can have wood and / or chalk particles with a particle size between> 0 ⁇ m and ⁇ 600 ⁇ m and a particle size distribution D50 of> 400 ⁇ m.
- the carrier material consists of a mixture of a PE / PP block copolymer with wood.
- the proportion of the PE / PP block copolymer and the proportion of wood can be between> 45% by weight and ⁇ 55% by weight.
- the carrier material can contain between> 0% by weight and ⁇ 10% by weight of further additives, such as flow aids, thermal stabilizers or UV stabilizers.
- the particle size of the wood is between> 0 pm and ⁇ 600 pm with a preferred particle size distribution D50 of> 400 pm.
- the carrier material can have wood with a particle size distribution D10 of> 400 ⁇ m. The particle size distribution is related to the volumetric diameter and relates to the volume of the particles.
- the carrier material is particularly preferably provided as a granulated or pelletized, pre-extruded mixture of a PE / PP block copolymer with wood particles of the specified particle size distribution.
- the granulate and / or the pellets can preferably have a grain size in a range from> 400 ⁇ m to ⁇ 10 mm, preferably> 600 ⁇ m to ⁇ 10 mm, in particular> 800 ⁇ m to ⁇ 10 mm.
- FIG. 1 shows schematically an apparatus configuration for carrying out the method according to the invention in cross section
- FIG. 2 schematically shows an apparatus configuration for carrying out the method according to the invention in a top view
- FIG. 3 shows schematically an embodiment of the apparatus for carrying out the method according to the invention in a top view
- Fig. 5 shows schematically the passage of molten polymer material through a
- Fig. 6 shows schematically the passage of molten polymer material through a
- FIG. 7 schematically shows a possibility for carrying out the method according to the invention in cross section.
- the device 1 according to FIG. 1 is suitable for a method for producing a decorated wall or floor panel.
- FIG. 1 shows, in cross section, the possible structure of the device for producing decorated panels 1, in this figure especially the assemblies extrusion device 2 with nozzle 5, main roller pair 3 and Calibrating roller arrangement 4 are shown.
- 6 calibration rollers 7 are shown, which can each be controlled independently of one another in their X and Y positions.
- a possible rotation direction sequence for the individual calibration rollers 7 is indicated by the arrows.
- the device 1 shows schematically the extrusion device 2, which is divided into an extruder (not shown separately) for the thermal treatment of polymer granulate and the actual nozzle 5.
- the molten polymer strand emerging from the nozzle can be guided through the nip of the main roller arrangement 3 with the individual main rollers 6.
- the height of the roller gap between the two main rollers 6 can be variably adjusted by moving the main rollers 6 relative to one another.
- the strand is transferred to the calibration roll arrangement 4.
- the calibrating roller arrangement 4 the molten polymer strand is further reduced or calibrated in height.
- the strand is guided through the gaps between the individual calibrating rollers 7 and changed in height as a function of the gap distance.
- the individual calibrating rollers 7 do not always have to be at the same distance from one another, so that different gap heights between the calibrating rollers 7 can be set during the process.
- the calibrating rollers 7 also do not have to have the same height, but can also be arranged offset to one another. This can change the mechanical stretch properties of the molten polymer strand.
- the calibrated and smoothed material can be provided with a decoration via a printing unit (not shown).
- the decorated surface of the panel can be provided with one or, if necessary, further layers, such as protective layers, for example.
- FIG. 2 shows a plan view of a device 1 according to the invention.
- the extrusion device 2 is shown, with an extruder and nozzle, which transfers a molten polymer strand to the main roller arrangement 3.
- the distance between the main roller assembly 3 and Extrusion device 2 is variable and can be varied, for example via controlled electric motors.
- the carrier which has been cooled in height by the main roller arrangement 3 and possibly already somewhat cooled, is guided into the calibrating roller arrangement 4.
- the calibrating roller arrangement 4 is composed of the individual calibrating rollers 7, which each form gaps among one another, through which the calibrated carrier is guided and further shaped.
- the individual calibrating rollers 7 can be moved as a whole or each separately in their relative position to one another. Furthermore, it is possible for the individual calibrating rollers 7 as a whole or each to be regulated separately in terms of their roller surface temperature.
- FIG. 3 essentially shows the embodiment of FIG. 2, the decorative arrangement 8 also being shown here.
- the decor arrangement 8 is arranged after the calibrating rollers 7 and applies a decor to the calibrated and optionally cooled carrier.
- the decoration arrangement 8 can for example consist of an inkjet printer and a further unit which at least partially applies a further protective layer to the printed decoration.
- the carrier can be further cooled, profiled or, for example, mechanically processed on the long sides at this point.
- FIG. 4 shows a possible way of guiding the molten polymeric carrier 9 through the calibrating roller gap.
- the molten polymeric carrier 9 can, for example, be cooled.
- the molten polymeric carrier 9 is changed in its thickness rather by the mechanical tension of the rollers.
- the individual calibrating rollers 7 are too far apart for the molten polymeric carrier 9 to experience a direct squeezing or upsetting through the gap between the calibrating rollers 7.
- FIG. 5 shows a similar calibrating roller arrangement 4 with two calibrating rollers 7 as in FIG.
- the calibrating rollers 7 standing closer together and forming a gap which is smaller than the thickness of the melted polymeric carrier 9 is partially thicker than the calibration gap, the height of the molten polymeric carrier 9 is evened out by the calibration gap between the calibration rollers 7.
- FIG. 6 shows once more the calibration roller section of FIG. 5 together with an enlarged section.
- the enlarged section it can be seen that excess material of the molten polymeric carrier 9 is pushed up at the beginning of the calibration gap.
- the height of the molten polymeric carrier 9 is adapted to the height of the calibration gap.
- the height of the calibration gap and thus the carrier height can be adjusted by the distance between the calibration rollers 7.
- it is advantageous that the calibration rollers 7 are so close together that as little ambient air as possible can get between the calibration rollers 7 and the molten polymeric carrier 9.
- the narrow gap ensures that as little additional air as possible is pressed into the carrier surface. The latter can contribute to an improved calibrated support surface.
- FIG. 7 shows a further embodiment according to the invention of a device 1 for producing decorated panels.
- the device 1 also has an extrusion device 2, for example with a slot die and an extruder.
- the molten polymer mass is extruded through the nozzle and passes through the gap between the main rollers 3 and the calibrating roller arrangement 4 with the individual calibrating rollers 7.
- This figure shows that the individual calibrating rollers 7 do not necessarily have to be at the same height as one another. By deflecting a calibration roller 7 in height, for example, the mechanical forces and also the cooling properties can be carried out over an air gap to be changed.
- the figure shows that within the calibrating roller arrangement 4 with the different calibrating rollers 7, an additional layer 10 can be applied, which is present, for example, as rolled goods and can be introduced at a wide variety of locations on the calibrating roller arrangement 4.
- the additional layer can be, for example, a primer or a decorative background.
- the decor arrangement 8 can, at least partially, apply a decor and a protective layer to the calibrated carrier.
- the carrier is either further tempered / cooled in a defined manner or mechanically reworked via further means 11.
- cooling or tempering surfaces or mechanical milling for further profiling, for example the carrier edges can be suitable as further means.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Civil Engineering (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Floor Finish (AREA)
- Finishing Walls (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP19215216.3A EP3835027A1 (de) | 2019-12-11 | 2019-12-11 | Verfahren und vorrichtung zur herstellung eines dekorierten wand- oder bodenpaneels |
| PCT/EP2020/076866 WO2021115653A1 (de) | 2019-12-11 | 2020-09-25 | Verfahren und vorrichtung zur herstellung eines dekorierten wand- oder bodenpaneels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP4072821A1 true EP4072821A1 (de) | 2022-10-19 |
| EP4072821B1 EP4072821B1 (de) | 2024-12-04 |
Family
ID=68886814
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19215216.3A Pending EP3835027A1 (de) | 2019-12-11 | 2019-12-11 | Verfahren und vorrichtung zur herstellung eines dekorierten wand- oder bodenpaneels |
| EP20775341.9A Active EP4072821B1 (de) | 2019-12-11 | 2020-09-25 | Verfahren und vorrichtung zur herstellung eines dekorierten wand- oder bodenpaneels |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19215216.3A Pending EP3835027A1 (de) | 2019-12-11 | 2019-12-11 | Verfahren und vorrichtung zur herstellung eines dekorierten wand- oder bodenpaneels |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US12325167B2 (de) |
| EP (2) | EP3835027A1 (de) |
| KR (2) | KR20250173580A (de) |
| CN (2) | CN114786911B (de) |
| CA (1) | CA3155741C (de) |
| ES (1) | ES3010475T3 (de) |
| MX (1) | MX2022006643A (de) |
| PL (1) | PL4072821T3 (de) |
| PT (1) | PT4072821T (de) |
| UA (1) | UA130698C2 (de) |
| WO (1) | WO2021115653A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4201697A1 (de) * | 2021-12-23 | 2023-06-28 | Akzenta Paneele + Profile GmbH | Verfahren zur herstellung eines dekorierten wand- oder bodenpaneels |
| WO2024023631A1 (en) * | 2022-07-29 | 2024-02-01 | Unilin, Bv | Device for manufacturing a sheet or panel shaped product and methods for manufacturing a polymeric board or sheet material and/or decorative panel |
| EP4658476A1 (de) | 2023-01-30 | 2025-12-10 | Ceraloc Innovation AB | Verfahren zur herstellung eines plattenelements mit hohlräumen |
| DE102023109411A1 (de) * | 2023-04-14 | 2024-10-17 | KraussMaffei Extrusion GmbH | Verfahren und Vorrichtung zum Herstellen eines mehrschichtigen Bodenbelags |
| DE102023131229B3 (de) | 2023-11-10 | 2025-01-23 | Koenig & Bauer Ag | Non Impact Druckmaschine mit Zentralzylinder und einer Aufladungseinrichtung |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10221522A1 (de) * | 2002-05-14 | 2003-12-04 | Marc Otto | Vorrichtung und Verfahren zur Bearbeitung von Polystyrol-Hartschaum |
| DE102011003604A1 (de) * | 2011-02-03 | 2012-08-09 | Battenfeld-Cincinnati Germany Gmbh | Kühlvorrichtung und Kühlverfahren |
| EP2942208A1 (de) | 2014-05-09 | 2015-11-11 | Akzenta Paneele + Profile GmbH | Verfahren zur Herstellung eines dekorierten Wand- oder Bodenpaneels |
| ES2847940T3 (es) | 2015-09-24 | 2021-08-04 | Akzenta Paneele Profile Gmbh | Procedimiento para la fabricación de un panel de pared o de suelo decorado |
| JP6207579B2 (ja) * | 2015-12-11 | 2017-10-04 | 株式会社日本製鋼所 | 多段ロール式のシート成形装置 |
| WO2017116851A1 (en) * | 2015-12-28 | 2017-07-06 | Graham Engineering Corporation | Multi-nip takeoff |
| ES2855111T3 (es) | 2016-10-27 | 2021-09-23 | Akzenta Paneele Profile Gmbh | Procedimiento para la fabricación de un panel de pared o de suelo decorado |
| BE1024723B1 (nl) * | 2016-11-10 | 2018-06-11 | Ivc Bvba | Vloerpaneel en werkwijze voor het vervaardigen van een vloerpaneel. |
| CN106985408A (zh) * | 2017-05-04 | 2017-07-28 | 青岛三益塑料机械有限公司 | 一种wpc木塑六层共挤一步法复合地板生产线 |
| CN207415828U (zh) * | 2017-07-17 | 2018-05-29 | 青岛三益塑料机械有限公司 | 压延机及发泡地板生产线 |
| KR102019446B1 (ko) | 2017-07-17 | 2019-09-06 | 칭다오 산이 플라스틱 머시너리 컴퍼니 리미티드 | 캘린더, 발포 바닥판 생산라인 및 일회성 성형 생산 공정 |
| CN107186937A (zh) | 2017-07-17 | 2017-09-22 | 青岛三益塑料机械有限公司 | 压延机、发泡地板生产线及一次成型生产工艺 |
-
2019
- 2019-12-11 EP EP19215216.3A patent/EP3835027A1/de active Pending
-
2020
- 2020-09-25 PT PT207753419T patent/PT4072821T/pt unknown
- 2020-09-25 UA UAA202202399A patent/UA130698C2/uk unknown
- 2020-09-25 ES ES20775341T patent/ES3010475T3/es active Active
- 2020-09-25 CA CA3155741A patent/CA3155741C/en active Active
- 2020-09-25 KR KR1020257039221A patent/KR20250173580A/ko active Pending
- 2020-09-25 EP EP20775341.9A patent/EP4072821B1/de active Active
- 2020-09-25 PL PL20775341.9T patent/PL4072821T3/pl unknown
- 2020-09-25 CN CN202080082383.5A patent/CN114786911B/zh active Active
- 2020-09-25 WO PCT/EP2020/076866 patent/WO2021115653A1/de not_active Ceased
- 2020-09-25 CN CN202610216529.XA patent/CN121946802A/zh active Pending
- 2020-09-25 MX MX2022006643A patent/MX2022006643A/es unknown
- 2020-09-25 US US17/782,816 patent/US12325167B2/en active Active
- 2020-09-25 KR KR1020227014869A patent/KR102997667B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA3155741A1 (en) | 2021-06-17 |
| CN114786911B (zh) | 2026-02-24 |
| ES3010475T3 (en) | 2025-04-03 |
| US20230018307A1 (en) | 2023-01-19 |
| CA3155741C (en) | 2024-02-06 |
| EP3835027A1 (de) | 2021-06-16 |
| PL4072821T3 (pl) | 2025-04-28 |
| KR102997667B1 (ko) | 2026-07-30 |
| UA130698C2 (uk) | 2026-04-22 |
| KR20250173580A (ko) | 2025-12-10 |
| KR20220074944A (ko) | 2022-06-03 |
| BR112022004979A2 (pt) | 2022-06-21 |
| EP4072821B1 (de) | 2024-12-04 |
| MX2022006643A (es) | 2022-07-04 |
| CN121946802A (zh) | 2026-05-01 |
| US12325167B2 (en) | 2025-06-10 |
| PT4072821T (pt) | 2025-02-18 |
| WO2021115653A1 (de) | 2021-06-17 |
| CN114786911A (zh) | 2022-07-22 |
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