ES2007986A6 - Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos. - Google Patents
Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos.Info
- Publication number
- ES2007986A6 ES2007986A6 ES8802493A ES8802493A ES2007986A6 ES 2007986 A6 ES2007986 A6 ES 2007986A6 ES 8802493 A ES8802493 A ES 8802493A ES 8802493 A ES8802493 A ES 8802493A ES 2007986 A6 ES2007986 A6 ES 2007986A6
- Authority
- ES
- Spain
- Prior art keywords
- olefins
- low pressure
- catalyzed hydroformylation
- rhodium catalyzed
- hydroformylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 3
- 229910052703 rhodium Inorganic materials 0.000 title abstract 3
- 239000010948 rhodium Substances 0.000 title abstract 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 150000003003 phosphines Chemical class 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- IFXORIIYQORRMJ-UHFFFAOYSA-N tribenzylphosphane Chemical compound C=1C=CC=CC=1CP(CC=1C=CC=CC=1)CC1=CC=CC=C1 IFXORIIYQORRMJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
SE DESCRIBE LA HIDROFORMILACION DE OLEFINAS CON CATALIZADORES DE COMPLEJOS DE RODIO. LOS CATALIZADORES EMPLEADOS COMPRENDEN UN COMPLEJO DE RODIO CON AL MENOS UNA FOSFINA QUE TIENE UNA ESTRUCTURA ESPECIFICA, POR EJEMPLO TRIS(BENCIL)FOSFINA. FOSFINAS PREFERIDAS TIENEN UN PKA EN EL INTERVALO DE APROXIMADAMENTE 3,5 A 5,3 Y UN ANGULO DEL CONO EN EL INTERVALO DE APROXIMADAMENTE 160 A 195G. MEDIANTE LA PRACTICA DEL PRESENTE INVENTO SE OBTIENEN REACCIONES DE HIDROFORMILACION A TEMPERATURAS Y PRESIONES RELATIVAMENTE BAJAS Y A PESAR DE ELLO CON ELEVADAS VELOCIDADES DE REACCION Y UNA ELEVADA SELECTIVIDAD AL PRODUCTO ALDEHIDO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8333087A | 1987-08-10 | 1987-08-10 | |
| US07/225,103 US4871878A (en) | 1987-08-10 | 1988-07-27 | Low pressure rhodium catalyzed hydroformylation of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2007986A6 true ES2007986A6 (es) | 1989-07-01 |
Family
ID=26769178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8802493A Expired ES2007986A6 (es) | 1987-08-10 | 1988-08-09 | Un metodo para la hidroformilacion de compuestos instaurados pra producir aldehidos. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4871878A (es) |
| EP (1) | EP0379515B1 (es) |
| JP (1) | JP2831011B2 (es) |
| KR (1) | KR960004183B1 (es) |
| CN (1) | CN1031835A (es) |
| CA (1) | CA1305491C (es) |
| DE (1) | DE3885103T2 (es) |
| ES (1) | ES2007986A6 (es) |
| WO (1) | WO1989001467A1 (es) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3920423A1 (de) * | 1989-06-22 | 1991-01-03 | Basf Ag | Verfahren zur herstellung von 2,3-dialkoxypropanalen |
| US5232989A (en) * | 1991-03-04 | 1993-08-03 | Monsanto Company | Functionalized polymers |
| CN1035543C (zh) * | 1993-01-09 | 1997-08-06 | 厦门大学 | 高碳数端烯氢甲酰化制高碳醛负载型水溶性催化剂 |
| GB2274457A (en) * | 1993-01-25 | 1994-07-27 | Shell Int Research | Hydroformylation of unsaturated carbonyl compounds |
| US5912364A (en) * | 1996-10-21 | 1999-06-15 | Eastman Chemical Company | Process for the preparation of 3-methyltetrahydrofuran |
| US5840647A (en) * | 1997-09-15 | 1998-11-24 | Eastman Chemical Company | Hydroformylation process using novel phosphite-metal catalyst system |
| US6130358A (en) | 1998-10-16 | 2000-10-10 | Eastman Chemical Company | Hydroformylation process using novel phosphite-metal catalyst system |
| US6225509B1 (en) * | 2000-01-06 | 2001-05-01 | Arco Chemical Technology, L.P. | Allyl alcohol hydroformylation |
| US6909019B1 (en) | 2004-05-25 | 2005-06-21 | Eastman Chemical Company | Process for preparing aldehydes |
| US8492593B2 (en) | 2011-08-16 | 2013-07-23 | Eastman Chemical Company | Amido-fluorophosphite compounds and catalysts |
| US9308527B2 (en) | 2014-03-17 | 2016-04-12 | Eastman Chemical Company | Phosphorous compounds useful as ligands and compositions and methods regarding them |
| CN113993977B (zh) | 2019-05-24 | 2024-09-13 | 伊士曼化工公司 | 进入气体裂化器中加工的液体流中混入少量热解油 |
| CN117700565A (zh) | 2019-05-24 | 2024-03-15 | 伊士曼化工公司 | 回收成分纤维素酯 |
| US11365357B2 (en) | 2019-05-24 | 2022-06-21 | Eastman Chemical Company | Cracking C8+ fraction of pyoil |
| WO2020247192A1 (en) | 2019-05-24 | 2020-12-10 | Eastman Chemical Company | Recycle content cracked effluent |
| WO2020242916A1 (en) | 2019-05-24 | 2020-12-03 | Eastman Chemical Company | Cracking a c4-c7 fraction of pyoil |
| EP4003948A4 (en) | 2019-07-29 | 2023-09-06 | Eastman Chemical Company | Recycle content (c4)alkanal |
| US20220281796A1 (en) | 2019-07-29 | 2022-09-08 | Eastman Chemical Company | Recycle content (c4)alkanoic acid |
| WO2021021902A1 (en) | 2019-07-29 | 2021-02-04 | Eastman Chemical Company | Process for the preparation of polyesters with recycled monomers from pyrolysis and methanolysis |
| KR20220043165A (ko) | 2019-07-29 | 2022-04-05 | 이스트만 케미칼 컴파니 | 재활용물 사이클로부탄 디올 폴리에스테르 |
| US12655356B2 (en) | 2019-10-31 | 2026-06-16 | ExxonMobil Product Solutions Company | Pyrolysis method and system for recycled waste |
| US12528995B2 (en) | 2019-10-31 | 2026-01-20 | ExxonMobil Product Solutions Company | Pyrolysis method and system for recycled waste |
| US11319262B2 (en) | 2019-10-31 | 2022-05-03 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| US12312540B2 (en) | 2019-10-31 | 2025-05-27 | Eastman Chemical Company | Pyrolysis method and system for recycled waste |
| US11945998B2 (en) | 2019-10-31 | 2024-04-02 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| EP4054996A4 (en) | 2019-11-07 | 2024-03-27 | Eastman Chemical Company | Recycle content oxo alcohols & oxo plasticizers |
| US12649805B2 (en) | 2019-11-07 | 2026-06-09 | Eastman Chemical Company | Recycle content poly(vinyl acetal) |
| WO2021092306A1 (en) | 2019-11-07 | 2021-05-14 | Eastman Chemical Company | Recycle content alpha olefins and fatty alcohols |
| WO2021092305A1 (en) | 2019-11-07 | 2021-05-14 | Eastman Chemical Company | Recycle content mixed esters and solvents |
| CN114728869B (zh) | 2019-11-07 | 2024-07-12 | 伊士曼化工公司 | 回收成分丙醇 |
| CN115052728A (zh) | 2020-02-10 | 2022-09-13 | 伊士曼化工公司 | 溶剂分解副产物流的化学回收 |
| US12686753B2 (en) | 2020-02-10 | 2026-07-21 | Eastman Chemical Company | Chemical recycling of solvolysis terephthalyl column bottoms coproduct streams |
| WO2021163104A1 (en) | 2020-02-10 | 2021-08-19 | Eastman Chemical Company | Chemical recycling of solvolysis glycol column bottoms coproduct streams |
| CN115052730A (zh) | 2020-02-10 | 2022-09-13 | 伊士曼化工公司 | 处理的混合塑料废物流的化学回收 |
| WO2021211517A1 (en) | 2020-04-13 | 2021-10-21 | Eastman Chemical Company | Liquefying and dehalogenating waste plastics |
| JP7707517B2 (ja) * | 2020-06-02 | 2025-07-15 | 三菱ケミカル株式会社 | アルデヒドの製造方法 |
| US12195674B2 (en) | 2021-09-21 | 2025-01-14 | Eastman Chemical Company | Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
| DE2045169A1 (en) * | 1970-09-12 | 1972-03-23 | Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen | Treatment of oxo reaction mixts - by addn of aqs alkali hydroxide |
| US4195042A (en) * | 1971-08-20 | 1980-03-25 | Phillips Petroleum Company | Rhodium hydroformylation catalyst |
| EP0002908B1 (en) * | 1977-12-16 | 1982-05-12 | Monsanto Company | Hydroformylation of formaldehyde with rhodium catalyst |
| US4593141A (en) * | 1979-02-12 | 1986-06-03 | Exxon Research And Engineering Co. | Hydroformylation catalysis by branched alkyl diaryl phosphine rhodium complexes |
| US4262142A (en) * | 1979-12-28 | 1981-04-14 | Union Carbide Corporation | Hydroformylation of ethylene with higher olefins |
| JPS56125329A (en) * | 1980-03-07 | 1981-10-01 | Sagami Chem Res Center | Preparation of aldehyde having perfluoro group |
| CA1166270A (en) * | 1981-04-30 | 1984-04-24 | Mitsuo Matsumoto | Method of producing 1,9-nonanedial and/or 9-hydroxy-7- nonen-1-al |
| DE3234701A1 (de) * | 1982-09-18 | 1984-04-05 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| US4528403A (en) * | 1982-10-21 | 1985-07-09 | Mitsubishi Chemical Industries Ltd. | Hydroformylation process for preparation of aldehydes and alcohols |
| DE3245883A1 (de) * | 1982-12-11 | 1984-06-14 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur hydroformylierung von olefinen |
| US4533756A (en) * | 1983-11-07 | 1985-08-06 | Texaco Inc. | Process for synthesis of acrylic acid precursors via hydroformylation of vinyl ether |
| DE3341035A1 (de) * | 1983-11-12 | 1985-05-23 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3413427A1 (de) * | 1984-04-10 | 1985-10-17 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| EP0173219B1 (de) * | 1984-08-30 | 1988-05-11 | Ruhrchemie Aktiengesellschaft | Verfahren zur Herstellung von Aldehyden |
| US4578523A (en) * | 1985-05-29 | 1986-03-25 | Ruhrchemie Aktiengesellschaft | Process for the preparation of aldehydes |
| DE3534314A1 (de) * | 1985-09-26 | 1987-04-02 | Ruhrchemie Ag | Verfahren zur herstellung von aldehyden |
| US4760194A (en) * | 1987-02-18 | 1988-07-26 | Eastman Kodak Company | Low pressure hydroformylation catalyst employing unique ligands and process using same |
| US4755624A (en) * | 1987-02-18 | 1988-07-05 | Eastman Kodak Company | Low pressure hydroformylation process |
| US4742178A (en) * | 1986-11-10 | 1988-05-03 | Eastman Kodak Company | Low pressure hydroformylation of dienes |
-
1988
- 1988-07-27 US US07/225,103 patent/US4871878A/en not_active Expired - Lifetime
- 1988-08-04 DE DE3885103T patent/DE3885103T2/de not_active Expired - Lifetime
- 1988-08-04 JP JP63507110A patent/JP2831011B2/ja not_active Expired - Lifetime
- 1988-08-04 WO PCT/US1988/002621 patent/WO1989001467A1/en not_active Ceased
- 1988-08-04 EP EP88908046A patent/EP0379515B1/en not_active Expired - Lifetime
- 1988-08-04 KR KR1019890700609A patent/KR960004183B1/ko not_active Expired - Lifetime
- 1988-08-08 CA CA000574087A patent/CA1305491C/en not_active Expired - Lifetime
- 1988-08-09 ES ES8802493A patent/ES2007986A6/es not_active Expired
- 1988-08-10 CN CN88106529A patent/CN1031835A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03500770A (ja) | 1991-02-21 |
| EP0379515B1 (en) | 1993-10-20 |
| US4871878A (en) | 1989-10-03 |
| CA1305491C (en) | 1992-07-21 |
| EP0379515A1 (en) | 1990-08-01 |
| CN1031835A (zh) | 1989-03-22 |
| JP2831011B2 (ja) | 1998-12-02 |
| KR960004183B1 (ko) | 1996-03-27 |
| KR890701524A (ko) | 1989-12-20 |
| WO1989001467A1 (en) | 1989-02-23 |
| DE3885103D1 (de) | 1993-11-25 |
| DE3885103T2 (de) | 1994-05-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PC1A | Transfer granted |