ES2011219T3 - Procedimiento para la preparacion de glicolatos de alquilo. - Google Patents

Procedimiento para la preparacion de glicolatos de alquilo.

Info

Publication number
ES2011219T3
ES2011219T3 ES89870015T ES89870015T ES2011219T3 ES 2011219 T3 ES2011219 T3 ES 2011219T3 ES 89870015 T ES89870015 T ES 89870015T ES 89870015 T ES89870015 T ES 89870015T ES 2011219 T3 ES2011219 T3 ES 2011219T3
Authority
ES
Spain
Prior art keywords
carbonilation
formaldehyde
procedure
preparation
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89870015T
Other languages
English (en)
Other versions
ES2011219A4 (es
Inventor
Robert Virgil Brill
David Ray Dyroff
Alistair Campbell Macfarlane
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22524936&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2011219(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of ES2011219A4 publication Critical patent/ES2011219A4/es
Application granted granted Critical
Publication of ES2011219T3 publication Critical patent/ES2011219T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN METODO DE CARBONILACION DE FORMALDEHIDO, QUE CONSISTE EN PONER EN CONTACTO UN CONCENTRADO ACUOSO DE FORMALDEHIDO QUE CONTIENE ENTRE 60 Y 85% EN PESO DE FORMALDEHIDO CON MONOXIDO DE C Y ACIDO SULFURICO, EN AUSENCIA DE UNA CANTIDAD EFECTIVA DE UN COCATALIZADOR DEL GRUPO IB EN UNA ZONA DE REACCION BAJO UNA PRESION PARCIAL DE MONOXIDO DE C NO MAYOR DE 1.72 X 10 EXP7 N/M2. ASI SE LLEVA A CABO UNA REACCION DE CARBONILACION EN LA QUE SE PRODUCE UN PRODUCTO DE CARBONILACION QUE CONTIENE AL MENOS UN 2% EN PESO DE ACIDO SULFURICO EN UNA MEZCLA DE COMPUESTOS DE FORMULA HO(CH2COO)NH EN LA QUE N ES UN ENTERO DE AL MENOS 1. TAMBIEN SE REFIERE LA INVENCION A UN METODO PARA PREPARAR UN GLICOLATO DE ALQUILO POR ESTERIFICACION DE LA MEZCLA DE LA REACCION DE CARBONILACION.
ES89870015T 1988-01-25 1989-01-24 Procedimiento para la preparacion de glicolatos de alquilo. Expired - Lifetime ES2011219T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/148,248 US4824997A (en) 1988-01-25 1988-01-25 Method for preparation of alkyl glycolates

Publications (2)

Publication Number Publication Date
ES2011219A4 ES2011219A4 (es) 1990-01-01
ES2011219T3 true ES2011219T3 (es) 1994-12-16

Family

ID=22524936

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89870015T Expired - Lifetime ES2011219T3 (es) 1988-01-25 1989-01-24 Procedimiento para la preparacion de glicolatos de alquilo.

Country Status (7)

Country Link
US (1) US4824997A (es)
EP (1) EP0326538B1 (es)
JP (1) JPH0667875B2 (es)
AT (1) ATE102180T1 (es)
CA (1) CA1321208C (es)
DE (1) DE68913314T2 (es)
ES (1) ES2011219T3 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4870208A (en) * 1988-06-03 1989-09-26 Monsanto Company Asymmetric hydrogenolysis of epoxides
US9227896B2 (en) 2010-08-18 2016-01-05 Eastman Chemical Company Process for the separation and purification of a mixed diol stream
US8829248B2 (en) 2010-08-18 2014-09-09 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8466328B2 (en) 2010-08-18 2013-06-18 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8709376B2 (en) 2010-09-23 2014-04-29 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8785686B2 (en) 2010-09-23 2014-07-22 Eastman Chemical Company Process for recovering and recycling an acid catalyst
JP2015509555A (ja) * 2012-03-08 2015-03-30 フロリダ大学 リサーチファウンデーション インコーポレイティッド Ｃ１原料から作られるポリグリコール酸およびその共重合体
US8829234B2 (en) 2012-03-27 2014-09-09 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst
US8927766B2 (en) 2012-03-27 2015-01-06 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst
US8703999B2 (en) 2012-03-27 2014-04-22 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration
CN105622419B (zh) * 2014-10-28 2018-01-23 中国科学院大连化学物理研究所 一种碳水化合物制备乙醇酸酯的方法
GB201615762D0 (en) * 2016-09-16 2016-11-02 Johnson Matthey Davy Technologies Ltd Process
WO2020087220A1 (en) * 2018-10-29 2020-05-07 Pujing Chemical Industry Co., Ltd Glycolide production with low solid residue
CN112209832B (zh) * 2019-07-12 2023-08-04 中国石油化工股份有限公司 一种草酸酯合成乙醇酸酯的方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE709983C (de) * 1936-12-31 1941-09-01 Du Pont Verfahren zur Herstellung von Glykolsaeure
US2152852A (en) * 1936-12-31 1939-04-04 Du Pont Process for manufacture of glycolic acid
DE829594C (de) * 1946-08-06 1952-01-28 Du Pont Verfahren zur kontinuierlichen Herstellung von Glykolsaeure
US3754028A (en) * 1972-08-21 1973-08-21 Chevron Res Glycolic acid production
US4016208A (en) * 1974-06-19 1977-04-05 Chevron Research Company Acid production
US3911003A (en) * 1974-06-19 1975-10-07 Chevron Res Process for the production of glycolic acid and oxydiacetic acid
IT1017804B (it) * 1974-08-01 1977-08-10 Montedison Spa Procedimento per la preparazione di acido glicolico e suoi polimeri
US3948986A (en) * 1975-01-20 1976-04-06 Chevron Research Company Alpha-hydroxy or alkoxy acid preparation
JPS5342292A (en) * 1976-09-30 1978-04-17 Mitsubishi Gas Chem Co Inc Preparation of copolymer from formaldehyde and carbon monoxide
JPS5371016A (en) * 1976-12-06 1978-06-24 Mitsubishi Gas Chem Co Inc Preparation of glycolic acid and/or diglycolic esters
US4136112A (en) * 1977-06-24 1979-01-23 Chevron Research Company Process for preparing glycolic acid from formaldehyde using acetic acid
US4140866A (en) * 1978-03-30 1979-02-20 Ppg Industries, Inc. Preparation of sulfate free glycolic acid ester
JPS5732235A (en) * 1980-08-06 1982-02-20 Mitsubishi Chem Ind Ltd Production of ester and ether of glycolic acid
DE3144794C2 (de) * 1980-12-19 1985-06-27 Director-General, Agency of Industrial Science and Technology, Tokio/Tokyo Verfahren zur Herstellung von Glycolsäure oder deren Alkylester
DE3133353C2 (de) * 1981-08-22 1985-07-18 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Glykolsäure oder ihrer Ester
US4431486A (en) * 1982-04-12 1984-02-14 E. I. Du Pont De Nemours And Company Azeotropic distillation of hydroxyacetic acid
GB9124247D0 (en) * 1991-11-14 1992-01-08 Dow Corning Novel organosilicon compounds and compositions containing them

Also Published As

Publication number Publication date
DE68913314T2 (de) 1994-08-11
EP0326538B1 (en) 1994-03-02
JPH01246243A (ja) 1989-10-02
US4824997A (en) 1989-04-25
JPH0667875B2 (ja) 1994-08-31
ES2011219A4 (es) 1990-01-01
ATE102180T1 (de) 1994-03-15
EP0326538A3 (en) 1990-09-19
CA1321208C (en) 1993-08-10
DE68913314D1 (de) 1994-04-07
EP0326538A2 (en) 1989-08-02

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