ES2029301T3 - Procedimiento para la obtencion de acido metacrilico. - Google Patents

Procedimiento para la obtencion de acido metacrilico.

Info

Publication number
ES2029301T3
ES2029301T3 ES198888110065T ES88110065T ES2029301T3 ES 2029301 T3 ES2029301 T3 ES 2029301T3 ES 198888110065 T ES198888110065 T ES 198888110065T ES 88110065 T ES88110065 T ES 88110065T ES 2029301 T3 ES2029301 T3 ES 2029301T3
Authority
ES
Spain
Prior art keywords
degrees
metacrolein
isobutirical
aldehide
aldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888110065T
Other languages
English (en)
Inventor
Richard Dr Krabetz
Gerd Dr. Duembgen
Franz Dr. Merger
Michael Jaeger
Fritz Dr. Thiessen
Herbert Dr. Vogel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2029301T3 publication Critical patent/ES2029301T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

EL ACIDO METACRILICO PUEDE OBTENERSE VENTAJOSAMENTE, POR OXIDACION EN FASE GASEOSA DE METACROLEINA O ALDEHIDO ISOBUTIRICO EN CATALIZADORES CONTENIENDO MO Y P A 250 A 400 GRADOS C BAJOENFRIAMIENTO DEL GAS DE REACCION CALIENTE POR DEBAJO DE 100 GRADOS C, ABSORCION DEL ACIDO METACRILICO EN UNA COLUMNA DE ABSORCION CON AGUA A TEMPERATURAS IFERIORES A 100 GRADOS C Y REINCORPORACION PARCIAL A UN REACTOR DE OXIDACION DESPUES DE MEZCLA DE METACROLEINA O ALDEHIDO ISOBUTIRICO Y OXIGENO, SI AL GAS DE ESCAPE DE REACCION SE AÑADE BAJO DOS TERCIOS DE LA COLUMNA DE ABSORCION UNA CANTIDAD DE METACROLEINA OLDEHIDO ISOBUTIRICO QUE ES IGUAL A LA CANTIDAD NECESITADA EN LA REACCION DE METACROLEINA O ALDEHIDO ISOBUTIRICO, JUNTO CON INHIBIDORES DE POLIMERIZACION EN FORMA LIQUIDA Y SE SEPARA DEL GAS DE ESCAPE POR DEBAJO DEL PUNTO DE ENTRADA DE LA METACROLEINA FRESCA O ALDEHIDO ISOBUTIRICO O DESPUES DE LA COLUMNA DE ABSORCION UNA CORRIENTE Y LA METACROLEINA NO TRANSFORMADA O ALDEHIDO ISOBUTIRICO SE PASAN POR UNACOLUMNA DE LAVADO CONAGUA A TEMPERATURA DE 10 GRADOS C Y SE OBTIENEN COMO SOLUCION ACUOSA EN LA CEBEZA DE LA COLUMNA DE ABSORCION.
ES198888110065T 1987-07-02 1988-06-24 Procedimiento para la obtencion de acido metacrilico. Expired - Lifetime ES2029301T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19873721865 DE3721865A1 (de) 1987-07-02 1987-07-02 Verfahren zur herstellung von methacrylsaeure

Publications (1)

Publication Number Publication Date
ES2029301T3 true ES2029301T3 (es) 1992-08-01

Family

ID=6330760

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888110065T Expired - Lifetime ES2029301T3 (es) 1987-07-02 1988-06-24 Procedimiento para la obtencion de acido metacrilico.

Country Status (6)

Country Link
US (1) US5087744A (es)
EP (1) EP0297445B1 (es)
JP (1) JP2574406B2 (es)
CA (1) CA1309418C (es)
DE (2) DE3721865A1 (es)
ES (1) ES2029301T3 (es)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3800991A1 (de) * 1988-01-15 1989-07-27 Basf Ag Verfahren zur herstellung von (alpha),(beta)-monoolefinisch ungesaettigten 3 bis 4 c-atome enthaltenden carbonsaeuren durch gasphasenoxidation
DE4335172A1 (de) 1993-10-15 1995-04-20 Basf Ag Verfahren zur Reinigung von Roh-(Meth)acrylsäure
US5482597A (en) 1994-11-23 1996-01-09 Basf Aktiengesellschaft Purification of crude (meth)acrylic acid
DE19501326A1 (de) * 1995-01-18 1996-07-25 Basf Ag Verfahren der rektifikativen Abtrennung von (Meth)acrylsäure aus einem (Meth)acrylsäure als Hauptbestandteil und niedere Aldehyde als Nebenbestandteile enthaltenden Gemisch in einer aus Abtriebsteil und Verstärkerteil bestehenden Rektifiaktionskolonne
DE19627679A1 (de) * 1996-07-10 1998-01-15 Basf Ag Verfahren zur Reinigung von Roh-Acrylsäure durch Kristallisation
US5877345A (en) * 1997-02-07 1999-03-02 Rohm And Haas Company Process for producing butyl acrylate
EP1163201B1 (de) 1999-03-06 2003-08-20 Basf Aktiengesellschaft Verfahren zur herstellung von acrylsäure
US6762148B2 (en) * 1999-09-17 2004-07-13 Nippon Kayaku Kabushiki Kaisha Catalyst process of making
JP4005750B2 (ja) * 1999-12-28 2007-11-14 株式会社日本触媒 （メタ）アクリル酸製造用装置および（メタ）アクリル酸の製造方法
JP4553440B2 (ja) * 2000-03-10 2010-09-29 三菱レイヨン株式会社 メタクリル酸の製造方法
BR0109929B1 (pt) 2000-04-11 2012-08-07 processo para a purificaÇço de uma massa fundida de Ácido acrÍlico bruto.
DE10220494A1 (de) 2002-05-07 2003-11-20 Basf Ag Verfahren zur Herstellung einer wässrigen Alkaliacrylat-Lösung
DE10237061A1 (de) 2002-08-09 2004-02-19 Basf Ag Verfahren zur Reinigung von Apparaten, in welchen(Meth)acrylsäure enthaltende organische Lösungsmittel behandelt und/oder erzeugt wurden
JP4056429B2 (ja) 2003-06-05 2008-03-05 株式会社日本触媒 （メタ）アクリル酸の製造方法
JP2005336142A (ja) * 2004-05-31 2005-12-08 Mitsubishi Chemicals Corp （メタ）アクリル酸の製造装置及び（メタ）アクリル酸の製造方法
US7705181B2 (en) 2005-03-01 2010-04-27 Basf Akiengesellschaft Process for removing methacrylic acid from liquid phase comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component
US7601866B2 (en) 2005-03-01 2009-10-13 Basf Aktiengesellschaft Process for removing methacrolein from liquid phase comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component
DE102005030416B4 (de) * 2005-06-30 2007-06-21 Stockhausen Gmbh Anordnung und Verfahren zur Erwärmung und Begasung eines polymerisationsfähigen Stoffes sowie Vorrichtung und Verfahren zur Herstellung hochreiner (Meth)Acrylsäure
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
DE102005042607A1 (de) 2005-09-07 2007-03-08 Basf Ag Polymerisationsverfahren
US8178718B2 (en) * 2007-02-05 2012-05-15 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
EP1995231B1 (en) * 2007-05-25 2013-11-20 Evonik Röhm GmbH Process for preparation of methyl methacrylate using recycled methanol
EP2085376B1 (en) 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
BRPI0913336A2 (pt) * 2008-06-02 2015-11-24 Nippon Kayaku Kk catalisador e método de produção de aldeído insaturado e ácido carboxílico insaturado
WO2013163806A1 (en) 2012-05-03 2013-11-07 Evonik Industries Ag Process for preparation of highly pure, non-yellowing methacrylic acid
JP2016516732A (ja) * 2013-03-18 2016-06-09 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ メタクリル酸及びメタクリル酸エステルの製造方法
DE102014203725A1 (de) 2014-02-28 2015-09-03 Basf Se Oxidationskatalysator mit sattelförmigem Trägerformkörper
JP6799581B2 (ja) * 2015-08-24 2020-12-16 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ モノマー生成で使用するための材料の不活性度を決定する方法
CN107848935B (zh) 2015-08-24 2022-01-04 罗门哈斯公司 单体生产中使用的材料的惰性的确定方法
BR112018071379B1 (pt) 2016-04-21 2022-05-17 Rohm And Haas Company Método para preparar monômeros de ácido carboxílico alfa,beta-insaturado e monômeros de aldeído insaturado
CN113413626A (zh) * 2021-08-24 2021-09-21 山东蓝湾新材料有限公司 一种塔顶气再循环制丙烯酸的急冷吸收塔

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE875194C (de) * 1939-08-24 1953-04-30 Basf Ag Herstellung ª‡-substituierter Acroleine
GB1513335A (en) * 1975-03-17 1978-06-07 Mitsubishi Rayon Co Process and a catalyst for the preparation of unsaturated carboxylic acid
JPS54141721A (en) * 1978-04-24 1979-11-05 Nippon Zeon Co Ltd Preparation of methacrylic acid
US4234519A (en) * 1979-01-26 1980-11-18 Halcon Research And Development Corp. Recovery of methacrolein
NL8001385A (nl) * 1979-03-15 1980-09-17 Halcon Res & Dev Werkwijze voor de bereiding van methacrylzuur.
JPS58126831A (ja) * 1982-01-22 1983-07-28 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸の捕集方法
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
DE3508702A1 (de) * 1985-03-12 1986-09-18 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von methacrylsaeure

Also Published As

Publication number Publication date
US5087744A (en) 1992-02-11
CA1309418C (en) 1992-10-27
EP0297445B1 (de) 1992-02-12
JP2574406B2 (ja) 1997-01-22
DE3868360D1 (de) 1992-03-26
JPS6429339A (en) 1989-01-31
EP0297445A2 (de) 1989-01-04
EP0297445A3 (en) 1989-10-18
DE3721865A1 (de) 1989-01-12

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