ES2030057T3 - Una silice amorfa precipitada y su metodo de preparacion. - Google Patents
Una silice amorfa precipitada y su metodo de preparacion.Info
- Publication number
- ES2030057T3 ES2030057T3 ES198787301689T ES87301689T ES2030057T3 ES 2030057 T3 ES2030057 T3 ES 2030057T3 ES 198787301689 T ES198787301689 T ES 198787301689T ES 87301689 T ES87301689 T ES 87301689T ES 2030057 T3 ES2030057 T3 ES 2030057T3
- Authority
- ES
- Spain
- Prior art keywords
- silice
- preparation
- precipitated amorphous
- silica
- precipitated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/02—Amorphous compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/19—Oil-absorption capacity, e.g. DBP values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Organic Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Silicon Compounds (AREA)
- Cosmetics (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Steroid Compounds (AREA)
Abstract
SILICE AMORFA, ESPECIALMENTE SILICE PRECIPITADA, APROPIADA PARA SU USO EN LAS PASTAS DE DIENTES, TIENE UNA ABRASIVIDAD ELEVADA REPRESENTADA POR UN VALOR DE ABRASION PERSPEX EN UN INTERVALO ENTRE 23 A 35 APROXIMADAMENTE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB868604985A GB8604985D0 (en) | 1986-02-28 | 1986-02-28 | Precipitated silicas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2030057T3 true ES2030057T3 (es) | 1992-10-16 |
Family
ID=10593833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES198787301689T Expired - Lifetime ES2030057T3 (es) | 1986-02-28 | 1987-02-26 | Una silice amorfa precipitada y su metodo de preparacion. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US4956167A (es) |
| EP (1) | EP0236070B1 (es) |
| JP (1) | JPS62223014A (es) |
| AT (1) | ATE73110T1 (es) |
| AU (1) | AU600256B2 (es) |
| CA (1) | CA1307646C (es) |
| DE (1) | DE3776922D1 (es) |
| ES (1) | ES2030057T3 (es) |
| GB (1) | GB8604985D0 (es) |
| ZA (1) | ZA871440B (es) |
Families Citing this family (85)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8610118D0 (en) * | 1986-04-25 | 1986-05-29 | Unilever Plc | Manufacture of silica gels |
| GB8707526D0 (en) * | 1987-03-30 | 1987-05-07 | Unilever Plc | Amorphous silicas |
| GB8721644D0 (en) * | 1987-09-15 | 1987-10-21 | Unilever Plc | Silicas |
| US5614177A (en) * | 1987-11-04 | 1997-03-25 | Rhone-Poulenc Chimie | Dentifrice-compatible silica particulates |
| FR2622565B1 (fr) * | 1987-11-04 | 1990-11-09 | Rhone Poulenc Chimie | Silice pour compositions dentifrices compatible notamment avec le zinc |
| FR2622439B1 (fr) * | 1987-11-04 | 1991-07-12 | Rhone Poulenc Chimie | Silice pour compositions dentifrices compatible notamment avec la chlorhexidine |
| US5286478A (en) * | 1987-11-04 | 1994-02-15 | Rhone-Poulenc Chimie | Dentifrice-compatible silica particulates |
| FR2625676B1 (fr) * | 1988-01-07 | 1994-03-04 | Pharmascience Laboratoires | Dentifrice a bon rapport pouvoir nettoyant/ pouvoir abrasif |
| FR2632185B1 (fr) * | 1988-06-01 | 1992-05-22 | Rhone Poulenc Chimie | Silice pour compositions dentifrices compatible notamment avec le zinc |
| FR2649089B1 (fr) * | 1989-07-03 | 1991-12-13 | Rhone Poulenc Chimie | Silice a porosite controlee et son procede d'obtention |
| US5234673A (en) * | 1990-02-20 | 1993-08-10 | J. M. Huber Corporation | Low temperature-very high structure silica and methods |
| US5094829A (en) * | 1990-06-21 | 1992-03-10 | Ppg Industries, Inc. | Reinforced precipitated silica |
| US5108734A (en) * | 1991-07-01 | 1992-04-28 | Colgate-Palmolive Company | Prophy mouthfeel dentifrice having low RDA value |
| KR960010781B1 (ko) * | 1991-10-02 | 1996-08-08 | 유니레버 엔브이 | 실리카 |
| KR0169542B1 (ko) * | 1992-10-28 | 1999-01-15 | 알. 브이. 타테 | 실리카 |
| WO1994011302A1 (en) * | 1992-11-12 | 1994-05-26 | Crosfield Limited | Silicas |
| FR2714369B1 (fr) * | 1993-12-29 | 1996-01-26 | Rhone Poulenc Chimie | Silices abrasives pour compositions dentifrices. |
| FR2722185B1 (fr) * | 1994-07-07 | 1996-09-27 | Rhone Poulenc Chimie | Suspension concentree de silice de precipitation, procedes pour sa preparation et utilisations de cette suspension |
| US5603920A (en) * | 1994-09-26 | 1997-02-18 | The Proctor & Gamble Company | Dentifrice compositions |
| US5589160A (en) * | 1995-05-02 | 1996-12-31 | The Procter & Gamble Company | Dentifrice compositions |
| US5651958A (en) * | 1995-05-02 | 1997-07-29 | The Procter & Gamble Company | Dentifrice compositions |
| US5658553A (en) * | 1995-05-02 | 1997-08-19 | The Procter & Gamble Company | Dentifrice compositions |
| PL184365B1 (pl) * | 1995-06-30 | 2002-10-31 | Crosfield Joseph & Sons | Bezpostaciowa krzemionka, sposób jej wytwarzania i przezroczysta kompozycja pasty do zębów zawierająca bezpostaciową krzemionkę |
| US6090359A (en) * | 1998-02-17 | 2000-07-18 | The Dow Chemical Company | Process for hydrogenating aromatic polymers |
| US6294155B1 (en) * | 1998-04-08 | 2001-09-25 | W. R. Grace & Co. -Conn. | Abrasive silica compositions and dentifrice compositions prepared therefrom |
| DE10062449A1 (de) | 2000-12-14 | 2002-06-20 | Degussa | Dotierte Fällungskieselsäure |
| GB0130907D0 (en) | 2001-12-22 | 2002-02-13 | Ineos Silicas Ltd | Amorphous silica |
| US6913634B2 (en) * | 2003-02-14 | 2005-07-05 | J. M. Huber Corporation | Abrasives for copper CMP and methods for making |
| WO2004073539A2 (en) * | 2003-02-14 | 2004-09-02 | J. M. Huber Corporation | Precipitated silica product, dentrifices containing same, and processes |
| US6946119B2 (en) * | 2003-02-14 | 2005-09-20 | J.M. Huber Corporation | Precipitated silica product with low surface area, dentifrices containing same, and processes |
| US20050158225A1 (en) * | 2004-01-20 | 2005-07-21 | Mcgill Patrick D. | Structure level of silica from silica slurry method |
| GB0525369D0 (en) * | 2005-12-14 | 2006-01-18 | Ineos Silicas Ltd | Silicas |
| US20080160053A1 (en) * | 2006-12-27 | 2008-07-03 | Mcgill Patrick | High electrolyte additions for precipitated silica material production |
| US20100047742A1 (en) * | 2008-08-25 | 2010-02-25 | Pitcock Jr William Henry | Tubule-blocking silica materials for dentifrices |
| US8609068B2 (en) * | 2010-02-24 | 2013-12-17 | J.M. Huber Corporation | Continuous silica production process and silica product prepared from same |
| RU2578465C2 (ru) | 2011-09-01 | 2016-03-27 | Дзе Проктер Энд Гэмбл Компани | Композиции для ухода за полостью рта с улучшенной реологией |
| US20140271900A1 (en) * | 2013-03-15 | 2014-09-18 | J.M. Huber Corporation | High Cleaning Silica with Low Abrasion and Method for Making Same |
| CN113226260B (zh) | 2018-12-24 | 2024-02-13 | 联合利华知识产权控股有限公司 | 口腔护理组合物 |
| CN109485054B (zh) * | 2019-01-02 | 2019-10-01 | 广州市飞雪材料科技有限公司 | 一种低吸油值高比表面积磨擦型二氧化硅及其制备方法 |
| CN113382711A (zh) | 2019-02-26 | 2021-09-10 | 联合利华知识产权控股有限公司 | 口腔护理组合物 |
| WO2020207633A1 (en) | 2019-04-08 | 2020-10-15 | Unilever Plc | Oral care composition comprising gingerdiol and process for producing the composition |
| CN113710223B (zh) | 2019-04-15 | 2023-08-01 | 联合利华知识产权控股有限公司 | 包含荜拔酰胺的个人护理组合物及制备该组合物的方法 |
| WO2020212098A1 (en) | 2019-04-15 | 2020-10-22 | Unilever Plc | A personal care composition comprising tetramethylcurcumin and process for producing the composition |
| BR112021022958A2 (pt) | 2019-05-28 | 2022-01-18 | Unilever Ip Holdings B V | Composição de cuidados orais e método de minimizar ou evitar manchas dos dentes |
| EP3976203A1 (en) | 2019-05-28 | 2022-04-06 | Unilever Global Ip Limited | Oral care composition |
| BR112021020505A2 (pt) | 2019-06-06 | 2021-12-21 | Unilever Ip Holdings Bv | Composição de dentifrício para higiene oral e uso de um sal de zinco |
| EP4065065A1 (en) | 2019-11-28 | 2022-10-05 | Unilever IP Holdings B.V. | Antimicrobial compositions comprising modified clay and copolymers |
| EP4120992B1 (en) | 2020-03-17 | 2023-11-22 | Unilever IP Holdings B.V. | Composition |
| KR20230123986A (ko) | 2020-12-11 | 2023-08-24 | 피큐 실리카스 유케이 리미티드 | 연마 실리카 입자 |
| CN116981440A (zh) | 2021-03-11 | 2023-10-31 | 联合利华知识产权控股有限公司 | 口腔护理组合物 |
| WO2023001777A1 (en) | 2021-07-20 | 2023-01-26 | Unilever Ip Holdings B.V. | An oral care composition |
| WO2023031026A1 (en) | 2021-09-01 | 2023-03-09 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2023031025A1 (en) | 2021-09-01 | 2023-03-09 | Unilever Ip Holdings B.V. | Oral care composition |
| EP4465955B1 (en) | 2022-01-19 | 2025-07-30 | Unilever IP Holdings B.V. | Oral care composition |
| EP4466075B1 (en) | 2022-01-19 | 2025-08-13 | Unilever IP Holdings B.V. | Oral care composition |
| WO2023152198A1 (en) | 2022-02-09 | 2023-08-17 | Unilever Ip Holdings B.V. | Use of oral care composition |
| WO2023152199A1 (en) | 2022-02-09 | 2023-08-17 | Unilever Ip Holdings B.V. | Use of oral care composition comprising zinc |
| CN118973551A (zh) | 2022-04-01 | 2024-11-15 | 联合利华知识产权控股有限公司 | 口腔护理组合物 |
| CN119053318A (zh) | 2022-04-01 | 2024-11-29 | 联合利华知识产权控股有限公司 | 口腔护理组合物 |
| WO2023186583A1 (en) | 2022-04-01 | 2023-10-05 | Unilever Ip Holdings B.V. | An oral care composition |
| WO2023227282A1 (en) | 2022-05-25 | 2023-11-30 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2023247290A1 (en) | 2022-06-23 | 2023-12-28 | Unilever Ip Holdings B.V. | Oral care composition for mitigation and/or reverstion of erosion of tooth enamel caused by wearing an aligner |
| WO2023247292A1 (en) | 2022-06-23 | 2023-12-28 | Unilever Ip Holdings B.V. | Oral care composition for mitigation and/or reversion of erosion of tooth enamel caused by wearing an aligner |
| EP4331563A1 (en) | 2022-08-31 | 2024-03-06 | Unilever IP Holdings B.V. | Use of oral care composition |
| CN120282769A (zh) | 2022-11-17 | 2025-07-08 | 联合利华知识产权控股有限公司 | 口腔护理组合物 |
| WO2024149491A1 (en) | 2023-01-13 | 2024-07-18 | Unilever Ip Holdings B.V. | Oral care composition |
| EP4417182A1 (en) | 2023-02-14 | 2024-08-21 | Unilever IP Holdings B.V. | Oral care composition |
| CN120813337A (zh) | 2023-02-22 | 2025-10-17 | 联合利华知识产权控股有限公司 | 牙膏组合物 |
| EP4420737A1 (en) | 2023-02-23 | 2024-08-28 | Unilever IP Holdings B.V. | Oral care composition |
| EP4420735A1 (en) | 2023-02-23 | 2024-08-28 | Unilever IP Holdings B.V. | Oral care composition |
| EP4494629A1 (en) | 2023-07-20 | 2025-01-22 | Unilever IP Holdings B.V. | Measurement of the olfactory effect of an oral care product |
| WO2025016962A1 (en) | 2023-07-20 | 2025-01-23 | Unilever Ip Holdings B.V. | Use of oral care composition comprising a zinc compound for absorbing odours in the mouth |
| WO2025031689A1 (en) | 2023-08-10 | 2025-02-13 | Unilever Ip Holdings B.V. | Oral care composition |
| EP4570236A1 (en) | 2023-12-12 | 2025-06-18 | Unilever IP Holdings B.V. | Use of a composition for providing antiviral protection |
| WO2025153301A1 (en) | 2024-01-19 | 2025-07-24 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2025153291A1 (en) | 2024-01-19 | 2025-07-24 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2025180682A1 (en) | 2024-02-29 | 2025-09-04 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2025195831A1 (en) | 2024-03-20 | 2025-09-25 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2025209772A1 (en) | 2024-04-03 | 2025-10-09 | Unilever Ip Holdings B.V. | Toothpaste tube and composition |
| WO2025209771A1 (en) | 2024-04-03 | 2025-10-09 | Unilever Ip Holdings B.V. | Toothpaste tube and composition |
| WO2026017454A1 (en) | 2024-07-17 | 2026-01-22 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2026021731A1 (en) | 2024-07-23 | 2026-01-29 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2026021848A1 (en) | 2024-07-23 | 2026-01-29 | Unilever Ip Holdings B.V. | Oral care composition comprising locust bean gum |
| WO2026027104A1 (en) | 2024-08-02 | 2026-02-05 | Unilever Ip Holdings B.V. | Oral care composition |
| WO2026032621A1 (en) | 2024-08-08 | 2026-02-12 | Unilever Ip Holdings B.V. | Oral care composition containing a zinc salt |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL289590A (es) * | 1962-03-02 | |||
| GB1416139A (en) * | 1971-11-26 | 1975-12-03 | Unilever Ltd | Fine silicas |
| US3928541A (en) * | 1972-09-05 | 1975-12-23 | Huber Corp J M | Amorphous precipitated siliceous pigments for cosmetic or dentrifrice use and methods for their production |
| FR2257658A1 (en) * | 1973-10-03 | 1975-08-08 | Sifrance | Polymsd synthetic silica pigments for toothpastes - prepd. by pptn. from a soln. contg. silicate, acid and electrolyte |
| US3977893A (en) * | 1973-10-03 | 1976-08-31 | J. M. Huber Corporation | Amorphous precipitated siliceous pigments and improved process for producing such pigments |
| US3960586A (en) * | 1973-10-03 | 1976-06-01 | J. M. Huber Corporation | Amorphous precipitated siliceous pigments and improved process for producing such pigments |
| AU497891B2 (en) * | 1974-05-22 | 1979-01-18 | J.M. Huber Corp. | Siliceous pigments & their production |
| US4100267A (en) * | 1975-10-01 | 1978-07-11 | Ortho Diagnostics Inc. | Method of detecting hepatitis B core antigen and antibody |
| JPS52102440A (en) * | 1976-02-05 | 1977-08-27 | Grace W R & Co | Mouth and tooth cleaning compound |
| FR2353486A1 (fr) * | 1976-06-04 | 1977-12-30 | Rhone Poulenc Ind | Nouvelle silice de synthese amorphe, procede pour son obtention et application de ladite silice dans les vulcanisats |
| US4100264A (en) * | 1976-12-23 | 1978-07-11 | Westinghouse Electric Corp. | Process for the preparation of calcium carbonate for use in fluorescent lamp phosphors |
| US4421527A (en) * | 1977-12-20 | 1983-12-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
| DE2853647C3 (de) * | 1978-12-13 | 1988-04-14 | Grace Gmbh, 2000 Norderstedt | Verfahren zur Herstellung von Kieselsäuregelen sowie deren Verwendung |
| DE3114493A1 (de) * | 1981-04-10 | 1982-10-28 | Degussa Ag, 6000 Frankfurt | "faellungskieselsaeuren und verfahren zu ihrer herstellung" |
| CA1189681A (en) * | 1981-04-10 | 1985-07-02 | Peter Nauroth | Precipitated silicas and process for producing same |
| JPS60105609A (ja) * | 1983-03-04 | 1985-06-11 | Taki Chem Co Ltd | 歯磨用シリカ基剤及びその製造方法 |
| JPS59163306A (ja) * | 1983-03-08 | 1984-09-14 | Taki Chem Co Ltd | 歯磨用シリカ基剤及びその製法 |
| FR2562534B1 (fr) * | 1984-04-06 | 1986-06-27 | Rhone Poulenc Chim Base | Nouvelle silice precipitee a caracteres morphologiques ameliores, procede pour son obtention et application, notamment comme charge |
-
1986
- 1986-02-28 GB GB868604985A patent/GB8604985D0/en active Pending
-
1987
- 1987-02-23 CA CA000530368A patent/CA1307646C/en not_active Expired - Lifetime
- 1987-02-24 AU AU69200/87A patent/AU600256B2/en not_active Ceased
- 1987-02-26 ES ES198787301689T patent/ES2030057T3/es not_active Expired - Lifetime
- 1987-02-26 AT AT87301689T patent/ATE73110T1/de not_active IP Right Cessation
- 1987-02-26 DE DE8787301689T patent/DE3776922D1/de not_active Expired - Lifetime
- 1987-02-26 EP EP19870301689 patent/EP0236070B1/en not_active Expired - Lifetime
- 1987-02-27 JP JP62045112A patent/JPS62223014A/ja active Granted
- 1987-02-27 ZA ZA871440A patent/ZA871440B/xx unknown
-
1989
- 1989-03-22 US US07/327,392 patent/US4956167A/en not_active Expired - Lifetime
-
1993
- 1993-11-29 US US08/158,818 patent/US5447704A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0522644B2 (es) | 1993-03-30 |
| EP0236070A3 (en) | 1988-05-04 |
| US4956167A (en) | 1990-09-11 |
| ATE73110T1 (de) | 1992-03-15 |
| US5447704A (en) | 1995-09-05 |
| CA1307646C (en) | 1992-09-22 |
| DE3776922D1 (de) | 1992-04-09 |
| AU6920087A (en) | 1987-09-03 |
| JPS62223014A (ja) | 1987-10-01 |
| GB8604985D0 (en) | 1986-04-09 |
| AU600256B2 (en) | 1990-08-09 |
| EP0236070B1 (en) | 1992-03-04 |
| ZA871440B (en) | 1988-10-26 |
| EP0236070A2 (en) | 1987-09-09 |
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