ES2030733T3 - Recuperacion de acidos a partir de materiales que comprenden acido y sal. - Google Patents
Recuperacion de acidos a partir de materiales que comprenden acido y sal.Info
- Publication number
- ES2030733T3 ES2030733T3 ES198787309053T ES87309053T ES2030733T3 ES 2030733 T3 ES2030733 T3 ES 2030733T3 ES 198787309053 T ES198787309053 T ES 198787309053T ES 87309053 T ES87309053 T ES 87309053T ES 2030733 T3 ES2030733 T3 ES 2030733T3
- Authority
- ES
- Spain
- Prior art keywords
- acid
- recovery
- product
- salt
- compartment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title abstract 11
- 238000011084 recovery Methods 0.000 title abstract 6
- 150000003839 salts Chemical class 0.000 title abstract 5
- 150000007513 acids Chemical class 0.000 title abstract 2
- 239000000463 material Substances 0.000 title 1
- 238000000034 method Methods 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 230000001172 regenerating effect Effects 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/36—Regeneration of waste pickling liquors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S204/00—Chemistry: electrical and wave energy
- Y10S204/13—Purification and treatment of electroplating baths and plating wastes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Supply & Treatment (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Urology & Nephrology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Electrochemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
HEMOS DESCUBIERTO UN METODO MEJORADO ENERGETICAMENTE EFICIENTE PARA RECUPERAR Y REGENERAR UN ACIDO DE UNA SOLUCION QUE COMPRENDE UN ACIDO Y UNA SAL. EL PROCESO COMPRENDE LOS PASOS DE EL APORTE DE UNA SOLUCION COMPRENDIENDO SAL Y UNA PRIMERA CONCENTRACION DE ACIDO A UN PRIMER COMPARTIMENTO DE UN APARATO DE ELECTRODIALISIS (2) QUE COMPRENDE UN PRIMER Y SEGUNDO COMPARTIMENTO (C), EL SUMINISTRO DE UN LIQUIDO QUE COMPRENDE AGUA AL SEGUNDO COMPARTIMENTO, LA APLICACION DE UNA CORRIENTE CONTINUA AL APARATO DE ELECTRODIALISIS PARA FORMAR, EN EL PRIMER COMPARTIMENTO, UN PRIMER PRODUCTO QUE COMPRENDE SAL Y UNA SEGUNDA CONCENTRACION DE ACIDO, LA SEGUNDA CONCENTRACION DE ACIDO SIENDO MENOR QUE LA PRIMERA CONCENTRACION DE ACIDO, Y COMO EN EL SEGUNDO COMPARTIMENTO, UN SEGUNDO PRODUCTO QUE COMPRENDE AGUA Y QUE ESTA ENRIQUECIDO EN ACIDO EN UNA CANTIDAD PROPORCIONAL, LA RECUPERACION DEL PRIMER PRODUCTO, LA RECUPERACION DEL SEGUNDO PRODUCTO, LA RECUPERACION DEL ACIDO DEL PRIMER PRODUCTO USANDO SEPARACION DEL AGUA MEDIANTE ELECTROLISIS PARA CONVERTIR AL MENOS UNA PARTE DE LA SAL EN UN TERCER PRODUCTO QUE COMPRENDE ACIDO, Y LA RECUPERACION DEL TERCER PRODUCTO. EL PROCESO TIENEN UNA UTILIDAD PARTICULAR PARA LA RECUPERACION Y REGENERACION DE ACIDOS MEZCLADOS PROCEDENTES DE LIQUIDOS DE ADOBO QUE CONTIENEN ACIDO NITRICO LIBRE Y SALES DE UN ANION DISTINTO DE ANINON DE NITRATO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/917,464 US4740281A (en) | 1986-10-14 | 1986-10-14 | Recovery of acids from materials comprising acid and salt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2030733T3 true ES2030733T3 (es) | 1992-11-16 |
Family
ID=25438829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES198787309053T Expired - Lifetime ES2030733T3 (es) | 1986-10-14 | 1987-10-14 | Recuperacion de acidos a partir de materiales que comprenden acido y sal. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4740281A (es) |
| EP (2) | EP0269234B1 (es) |
| JP (1) | JPH02500420A (es) |
| KR (1) | KR950006502B1 (es) |
| CN (1) | CN87106982A (es) |
| AT (1) | ATE66166T1 (es) |
| AU (1) | AU8159587A (es) |
| CA (1) | CA1324981C (es) |
| DE (1) | DE3772208D1 (es) |
| DK (1) | DK268488A (es) |
| ES (1) | ES2030733T3 (es) |
| WO (1) | WO1988002652A1 (es) |
| ZA (1) | ZA877724B (es) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3642164A1 (de) * | 1986-12-10 | 1988-06-23 | Basf Ag | Verfahren zum entfernen von saeure aus kathodischen elektrotauchlackier-baedern mittels elektrodialyse |
| JPS63291608A (ja) * | 1987-05-22 | 1988-11-29 | Tokuyama Soda Co Ltd | 酸廃液の再生方法 |
| JPH07112558B2 (ja) * | 1987-11-18 | 1995-12-06 | 神鋼パンテック株式会社 | 硝フッ酸廃液の再生回収処理方法 |
| US4969983A (en) * | 1988-07-11 | 1990-11-13 | Ionics, Incorporated | Apparatus and process for the removal of acidic and basic gases from fluid mixtures using bipolar membranes |
| US5162076A (en) * | 1988-11-30 | 1992-11-10 | Allied-Signal Inc. | Method for purification of acids from materials comprising acid and salt |
| US5135626A (en) * | 1988-12-01 | 1992-08-04 | Allied-Signal Inc. | Method for purification of bases from materials comprising base and salt |
| US4976838A (en) * | 1988-12-01 | 1990-12-11 | Allied-Signal Inc. | Method for purification of bases from materials comprising base and salt |
| US5006211A (en) * | 1989-04-19 | 1991-04-09 | Pulp And Paper Research Institute Of Canada | Electrodialylic water splitting process for the treatment of aqueous electrolytes |
| US4995956A (en) * | 1989-04-06 | 1991-02-26 | Allied-Signal Inc. | Method and apparatus to control a salt stream to be treated in an electrodialytic water splitter |
| US5049250A (en) * | 1989-08-14 | 1991-09-17 | Allied-Signal Inc. | Electrodialytic treatment of aqueous solutions containing amino acids |
| US5294316A (en) * | 1989-10-31 | 1994-03-15 | Lenzing Aktiengesellschaft | Process and apparatus for electrodialysis of an alkali sulfate containing aqueous solution |
| US5242552A (en) * | 1990-03-21 | 1993-09-07 | Eltech Systems Corporation | System for electrolytically generating strong solutions by halogen oxyacids |
| US5126026A (en) * | 1990-09-28 | 1992-06-30 | Allied-Signal Inc. | Guard membranes for use in electrodialysis cells |
| US5288378A (en) * | 1990-09-28 | 1994-02-22 | Alliedsignal Inc. | Guard membranes for use in electrodialysis cells |
| US5200046A (en) * | 1990-12-12 | 1993-04-06 | Allied-Signal Inc. | Apparatus and method for electrodialytic treatment of salts to produce acid and/or base of improved purity |
| US5198086A (en) * | 1990-12-21 | 1993-03-30 | Allied-Signal | Electrodialysis of salts of weak acids and/or weak bases |
| US5194130A (en) * | 1990-12-21 | 1993-03-16 | Allied-Signal Inc. | Method to produce sodium citrate using electrodialysis |
| CA2078223A1 (en) * | 1991-02-01 | 1992-08-02 | Krishnamurthy Nagasubramanian Mani | Separation/recovery of ammonium salts via electrodialytic water splitting |
| US5352345A (en) * | 1991-05-07 | 1994-10-04 | Alliedsignal Inc. | Ion exchange resin regenerant waste recovery and recycling via bipolar membranes |
| WO1993002227A1 (en) * | 1991-07-15 | 1993-02-04 | Eco-Tec Limited | Process and apparatus for treating fluoride containing acid solutions |
| DE4131794A1 (de) * | 1991-09-24 | 1993-03-25 | Metallgesellschaft Ag | Verfahren und vorrichtung zur aufarbeitung von abfallschwefelsaeure |
| JP3143222B2 (ja) * | 1992-08-21 | 2001-03-07 | 大王製紙株式会社 | 酸及びアルカリの製造方法 |
| US5431792A (en) * | 1993-12-20 | 1995-07-11 | Occidental Chemical Corporation | Method of making hypophosphorous acid |
| NL9302261A (nl) * | 1993-12-24 | 1995-07-17 | Elektrolyse Project B V | Werkwijze voor het reinigen van zuuroplossing. |
| EP0759805B1 (en) * | 1994-05-20 | 2003-12-10 | United States Filter Corporation | Polarity reversal and double reversal electrodeionization apparatus and method |
| FR2720061B1 (fr) * | 1994-05-20 | 1996-08-02 | Rhone Poulenc Chimie | Procédé de valorisation d'un effluent liquide acide contenant des métaux lourds. |
| JP2711241B2 (ja) * | 1996-06-17 | 1998-02-10 | 株式会社トクヤマ | 酸廃液の再生方法 |
| US5833832A (en) * | 1996-08-30 | 1998-11-10 | Sachem, Inc. | Preparation of onium hydroxides in an electrochemical cell |
| US6106795A (en) * | 1997-01-29 | 2000-08-22 | Waterworks International | Liquid hydrate regeneration of contaminated acids |
| AU6945498A (en) * | 1997-03-31 | 1998-10-22 | Waterworks International, Inc. | Sulfuric acid purification process |
| US5853555A (en) * | 1997-04-03 | 1998-12-29 | Sachem, Inc. | Synthesis of onium hydroxides from onium salts |
| DE19740164A1 (de) * | 1997-09-12 | 1999-03-18 | Steuler Industriewerke Gmbh | Verfahren zur Aufbereitung von metallhaltigen Säurelösungen aus Oberflächenbehandlungsanlagen |
| US6139714A (en) * | 1997-12-02 | 2000-10-31 | Gemma Industrial Ecology Ltd. | Method and apparatus for adjusting the pH of a liquid |
| EP1347823B3 (en) * | 2000-12-12 | 2009-07-29 | Jurag Separation A/S | A method and apparatus for isolation of ionic species from a liquid |
| AR067384A1 (es) * | 2007-06-29 | 2009-10-07 | Archer Daniels Midland Co | Proceso para desalar soluciones de glicerol y recuperacion de sustancias quimicas |
| JP5072477B2 (ja) * | 2007-08-10 | 2012-11-14 | 株式会社アストム | 硝フッ酸廃液からの酸の回収方法 |
| US8535502B2 (en) * | 2008-09-08 | 2013-09-17 | Palo Alto Research Center Incorporated | System and method for recovery of CO2 by aqueous carbonate flue gas capture and high efficiency bipolar membrane electrodialysis |
| DE102009001512A1 (de) * | 2009-03-12 | 2010-09-16 | Evonik Degussa Gmbh | Herstellung von hochreinen Suspensionen enthaltend gefällte Kieselsäuren durch Elektrodialyse |
| CN101898838B (zh) * | 2009-05-27 | 2012-09-19 | 王建刚 | 多级膜渗析分离钢铁酸洗废液的方法 |
| US8936770B2 (en) | 2010-01-22 | 2015-01-20 | Molycorp Minerals, Llc | Hydrometallurgical process and method for recovering metals |
| CN101844848A (zh) * | 2010-05-06 | 2010-09-29 | 湖州森蓝环境工程有限公司 | 不锈钢酸洗废液的回用处理方法 |
| DE102010017491A1 (de) * | 2010-06-21 | 2011-12-22 | WME Gesellschaft für windkraftbetriebene Meerwasserentsalzung mbH | Verfahren zur Erzeugung von Chlorwasserstoff oder einer wässrigen Lösung derselben unter Verwendung eines salzhaltigen Rohwassers, damit hergestelltes Produkt, Verwendung des Produkts und Elektrodialyse-System |
| CN103086528A (zh) * | 2011-10-31 | 2013-05-08 | 库特勒自动化系统(苏州)有限公司 | 光电池生产中废物体系的处理装置及处理方法 |
| KR101700684B1 (ko) | 2015-04-30 | 2017-01-31 | 재단법인 포항산업과학연구원 | 수산화리튬, 및 탄산리튬의 제조 방법 및 그 장치 |
| CN105566168A (zh) * | 2015-12-28 | 2016-05-11 | 江苏远洋药业股份有限公司 | 肌酸母液分离净化处理系统 |
| WO2017171113A1 (ko) * | 2016-03-29 | 2017-10-05 | (주) 테크윈 | 전해조 및 전해 방법 |
| KR101794843B1 (ko) * | 2016-03-29 | 2017-11-07 | (주)테크윈 | 전해 시스템 및 이를 이용한 전해 방법 |
| CN110270225B (zh) * | 2018-03-13 | 2023-04-07 | Bl 科技公司 | 用于高浓度酸或碱生产的多级双极电渗析系统 |
| EP4691612A1 (en) * | 2024-08-06 | 2026-02-11 | Bosaq BV | Bipolar membrane electrodialysis device for generating cleaning solutions |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3787304A (en) * | 1972-01-31 | 1974-01-22 | Allied Chem | Production of hf from fluorine by-products |
| HU169344B (en) * | 1973-11-27 | 1976-11-27 | Jozsef Kerti | Method for electrochemical cycle-processing pickle end-solutions containing sulfuric acid |
| JPS52101690A (en) * | 1976-02-24 | 1977-08-25 | Asahi Glass Co Ltd | Separation of acid and metal from solution containing acid and its met al salts and recovery of them |
| JPS5415273A (en) * | 1977-07-01 | 1979-02-05 | Hitachi Ltd | Device for supplying bar material |
| US4107015A (en) * | 1977-07-18 | 1978-08-15 | Allied Chemical Corporation | Method for removal of SO2 from gases |
| US4391680A (en) * | 1981-12-03 | 1983-07-05 | Allied Corporation | Preparing alkali metal hydroxide by water splitting and hydrolysis |
| US4504373A (en) * | 1982-06-01 | 1985-03-12 | Allied Corporation | Electrodialytic water splitting process and apparatus for conversion of alkali metal sulfate values derived from spent rayon spin baths |
| JPS58217682A (ja) * | 1982-06-01 | 1983-12-17 | アライド・コ−ポレ−シヨン | 使用済みレーヨン紡糸浴から誘導されるアルカリ金属硫酸塩有価物を変換するための電気透析水スプリット法 |
| EP0121611B1 (en) * | 1983-03-14 | 1990-04-25 | AlliedSignal Inc. | Brine acidification with simultaneous production of alkali metal hydroxide and hydrochloric acid by 3-compartment electrodialytic water splitting |
| US4636289A (en) * | 1983-05-02 | 1987-01-13 | Allied Corporation | Solution mining of sodium minerals with acids generated by electrodialytic water splitting |
| US4536269A (en) * | 1983-05-02 | 1985-08-20 | Allied Corporation | Multichamber two-compartment electrodialytic water splitter and method of using same for acidification of aqueous soluble salts |
| US4629545A (en) * | 1984-08-10 | 1986-12-16 | Allied Corporation | Electrodialytic water splitter and process for removal of SO2 from gases containing same and for recovery of SO2 and NaOH |
| US4584077A (en) * | 1984-08-13 | 1986-04-22 | Allied Corporation | Process for recovering sodium carbonate from trona and other mixtures of sodium carbonate and sodium bicarbonate |
| US4608141A (en) * | 1984-11-07 | 1986-08-26 | Allied Corporation | Multichamber two-compartment electrodialytic water splitter and method of using same for basification of aqueous soluble salts |
| US4645625A (en) * | 1984-11-26 | 1987-02-24 | Ionics, Incorporated | Decontamination of a radioactive waste liquid by electrodialysis |
| US4592817A (en) * | 1984-12-03 | 1986-06-03 | Allied Corporation | Electrodialytic water splitting process for gaseous products |
| WO1986006646A1 (en) * | 1985-05-03 | 1986-11-20 | Allied Corporation | Recovery of mixed acids from mixed salts |
-
1986
- 1986-10-14 US US06/917,464 patent/US4740281A/en not_active Expired - Fee Related
-
1987
- 1987-10-13 CA CA000549118A patent/CA1324981C/en not_active Expired - Fee Related
- 1987-10-14 DE DE8787907195T patent/DE3772208D1/de not_active Expired - Lifetime
- 1987-10-14 ES ES198787309053T patent/ES2030733T3/es not_active Expired - Lifetime
- 1987-10-14 JP JP62506603A patent/JPH02500420A/ja active Granted
- 1987-10-14 WO PCT/US1987/002631 patent/WO1988002652A1/en not_active Ceased
- 1987-10-14 ZA ZA877724A patent/ZA877724B/xx unknown
- 1987-10-14 EP EP87309053A patent/EP0269234B1/en not_active Expired - Lifetime
- 1987-10-14 CN CN198787106982A patent/CN87106982A/zh active Pending
- 1987-10-14 AT AT87907195T patent/ATE66166T1/de not_active IP Right Cessation
- 1987-10-14 AU AU81595/87A patent/AU8159587A/en not_active Abandoned
- 1987-10-14 EP EP87907195A patent/EP0327572B1/en not_active Expired - Lifetime
- 1987-10-14 KR KR1019880700655A patent/KR950006502B1/ko not_active Expired - Fee Related
-
1988
- 1988-05-17 DK DK268488A patent/DK268488A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA877724B (en) | 1988-03-03 |
| JPH0450052B2 (es) | 1992-08-13 |
| KR880701577A (ko) | 1988-11-03 |
| EP0327572A1 (en) | 1989-08-16 |
| JPH02500420A (ja) | 1990-02-15 |
| DK268488D0 (da) | 1988-05-17 |
| US4740281A (en) | 1988-04-26 |
| AU8159587A (en) | 1988-05-06 |
| ATE66166T1 (de) | 1991-08-15 |
| CN87106982A (zh) | 1988-04-27 |
| CA1324981C (en) | 1993-12-07 |
| EP0327572B1 (en) | 1991-08-14 |
| EP0269234B1 (en) | 1992-05-13 |
| KR950006502B1 (ko) | 1995-06-16 |
| EP0269234A1 (en) | 1988-06-01 |
| DE3772208D1 (de) | 1991-09-19 |
| WO1988002652A1 (en) | 1988-04-21 |
| DK268488A (da) | 1988-05-17 |
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