ES2031986T3 - Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno. - Google Patents

Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno.

Info

Publication number
ES2031986T3
ES2031986T3 ES198888119801T ES88119801T ES2031986T3 ES 2031986 T3 ES2031986 T3 ES 2031986T3 ES 198888119801 T ES198888119801 T ES 198888119801T ES 88119801 T ES88119801 T ES 88119801T ES 2031986 T3 ES2031986 T3 ES 2031986T3
Authority
ES
Spain
Prior art keywords
preparation
procedure
propylene copolymers
new crystal
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888119801T
Other languages
English (en)
Inventor
Luigi Maria Dr. Resconi
Enrico Dr. Albizzati
Romano Mazzocchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Syensqo Specialty Polymers Italy SpA
Himont Inc
Original Assignee
Montedison SpA
Ausimont SpA
Himont Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11250144&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2031986(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montedison SpA, Ausimont SpA, Himont Inc filed Critical Montedison SpA
Application granted granted Critical
Publication of ES2031986T3 publication Critical patent/ES2031986T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

NUEVOS COPOLIMEROS CRISTALINOS DE PROPILENO CON MENOS PROPORCION DE ETILENO Y/O ALFA - OLEFINAS CON MUY BUENAS PROPIEDADES MECANICAS, BAJO PUNTO DE FUSION Y UNA SOLUBILIDAD LIMITADA EN XILENO A 25 (GRADOS) C, Y EL PROCESO DE SU PREPARACION POR MEDIO DE POLIMERIZACION DE MEZCLAS DE PROPILENO CON ETILENO Y/O ALFA - OLEFINAS DE COMPOSICION ADECUADA, POR UTILIZACION DE CATALISIS OBTENIDA DE COMPUESTOS DE ZIRCONIO, Y COMPUESTOS METILALUMOXANICOS.
ES198888119801T 1987-11-27 1988-11-28 Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno. Expired - Lifetime ES2031986T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT41012/87A IT1221653B (it) 1987-11-27 1987-11-27 Copolimeri cristallini del propilene

Publications (1)

Publication Number Publication Date
ES2031986T3 true ES2031986T3 (es) 1993-01-01

Family

ID=11250144

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888119801T Expired - Lifetime ES2031986T3 (es) 1987-11-27 1988-11-28 Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno.

Country Status (15)

Country Link
US (2) US5516866A (es)
EP (1) EP0318049B2 (es)
JP (1) JP3112908B2 (es)
KR (1) KR950013682B1 (es)
CN (1) CN1040217C (es)
AU (1) AU604582B2 (es)
BR (1) BR8806244A (es)
CA (1) CA1338368C (es)
DE (1) DE3869921D1 (es)
DK (1) DK660088A (es)
ES (1) ES2031986T3 (es)
FI (1) FI96770C (es)
IT (1) IT1221653B (es)
NO (1) NO171791C (es)
ZA (1) ZA888859B (es)

Families Citing this family (41)

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DE3640924A1 (de) * 1986-11-29 1988-06-01 Hoechst Ag 1-olefin-stereoblockpolymer und verfahren zu seiner herstellung
IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene
DE3836059A1 (de) * 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
DE3916555A1 (de) * 1989-05-20 1990-11-22 Hoechst Ag Verfahren zur herstellung von ethylenpolymeren
DE3927257A1 (de) * 1989-08-18 1991-02-21 Hoechst Ag Verfahren zur herstellung eines polyolefins
US6414096B1 (en) 1990-08-17 2002-07-02 Basell Polyolefine Gmbh Process for the preparation of a polyolefin
DE4015254A1 (de) * 1990-05-12 1991-11-14 Hoechst Ag Verfahren zur herstellung eines polyolefins
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
JP2009120858A (ja) * 1993-10-06 2009-06-04 Mitsui Chemicals Inc プロピレン系共重合体からなるフィルム
DE69431444T2 (de) † 1993-12-06 2003-06-05 Sumitomo Chemical Co., Ltd. Alphaolefinpolymere, Katalysator zur Alphaolefinpolymerisation und Verfahren zur Herstellung von Alphaolefinpolymeren
ES2199966T3 (es) 1994-02-21 2004-03-01 Basell Polyolefine Gmbh Lamina de varias capas poliolefinica sellable, un procedimiento para su obtencion y su empleo.
SG63595A1 (en) * 1994-02-25 1999-03-30 Sumitomo Chemical Co Propylene random copolymer and film laminate thereof
EP0760744A1 (en) * 1994-05-24 1997-03-12 Exxon Chemical Patents Inc. Fibers and fabrics incorporating lower melting propylene polymers
US5571619A (en) * 1994-05-24 1996-11-05 Exxon Chemical Patents, Inc. Fibers and oriented films of polypropylene higher α-olefin copolymers
ES2144264T3 (es) 1995-08-29 2000-06-01 Exxon Chemical Patents Inc Polipropileno tolerante a la radiacion y sus articulos utiles.
JP3264148B2 (ja) * 1995-08-31 2002-03-11 住友化学工業株式会社 プロピレン−エチレンランダム共重合体、その製法及びフィルム
KR19990045740A (ko) * 1995-09-18 1999-06-25 만셀 케이쓰 로드니 차단성이 높은 폴리프로필렌 조성물 및 이들의 포장제품으로서의 용도
DE19545499A1 (de) * 1995-12-06 1997-06-12 Basf Ag Verbesserte statistische Propylencopolymerisate
US6649725B2 (en) * 1996-02-05 2003-11-18 Idemitsu Petrochemical Co., Ltd. Propylenic copolymer, and its film
IT1282691B1 (it) * 1996-02-27 1998-03-31 Montell North America Inc Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti
DE19746741A1 (de) 1996-10-30 1998-05-07 Idemitsu Petrochemical Co Propylen-Copolymer und Folie daraus
JP3569739B2 (ja) 1996-11-25 2004-09-29 出光石油化学株式会社 プロピレン系ランダム共重合体の製造方法
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
EP1522553B1 (en) 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US7067603B1 (en) 1999-12-22 2006-06-27 Exxonmobil Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
JP4966463B2 (ja) 1999-12-22 2012-07-04 エクソンモービル・ケミカル・パテンツ・インク プロピレン−ベース−接着剤組成物
EP1390417B1 (en) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Process for polymerizing propylene and ethylene in solution
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
EP1615961A1 (en) 2003-04-15 2006-01-18 ExxonMobil Chemical Patents Inc. Catalysts for propylene copolymers, polymerization process and copolymer of propylene
CN101516929B (zh) * 2006-07-28 2012-06-20 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物
DE102008005947A1 (de) 2008-01-24 2009-07-30 Evonik Degussa Gmbh Polyolefine mit Ataktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
BR112016024633B1 (pt) 2014-05-06 2022-05-03 Basell Poliolefine Italia S.R.L. Copolímeros de propileno-etileno aleatórios, processo para a preparação dos mesmos e artigos compreendendo os mesmos
US20180371219A1 (en) * 2015-11-24 2018-12-27 Basell Polyolefine Gmbh Blown polyolefin films

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US4048409A (en) * 1973-09-27 1977-09-13 Mitsui Toatsu Chemicals, Incorporated Article made of propylene-ethylene copolymer
JPS5179195A (ja) * 1974-12-28 1976-07-09 Chisso Corp Ketsushoseipuropiren arufua orefuinnechiren 3 genkyojugotaino seizoho
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EP0115940B2 (en) * 1983-01-25 1997-03-19 Mitsui Petrochemical Industries, Ltd. Film-forming propylene copolymer, film thereof and process for production of the film
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DK170561B1 (da) * 1984-11-02 1995-10-23 Mitsui Petrochemical Ind Krystallinsk propylencopolymerblanding og laminat indeholdende en sådan blanding
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
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JPH0753766B2 (ja) * 1985-11-22 1995-06-07 三井石油化学工業株式会社 α−オレフイン系ランダム共重合体の製造法
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KR920000173B1 (ko) * 1986-10-09 1992-01-09 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체
IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene

Also Published As

Publication number Publication date
JP3112908B2 (ja) 2000-11-27
DK660088D0 (da) 1988-11-25
IT8741012A0 (it) 1987-11-27
CA1338368C (en) 1996-06-04
EP0318049A1 (en) 1989-05-31
ZA888859B (en) 1989-08-30
FI96770B (fi) 1996-05-15
AU604582B2 (en) 1990-12-20
US6355758B1 (en) 2002-03-12
FI885462L (fi) 1989-05-28
EP0318049B2 (en) 2003-07-16
CN1034551A (zh) 1989-08-09
NO885281D0 (no) 1988-11-25
EP0318049B1 (en) 1992-04-08
KR950013682B1 (ko) 1995-11-13
BR8806244A (pt) 1989-08-15
KR890008188A (ko) 1989-07-10
JPH01266116A (ja) 1989-10-24
US5516866A (en) 1996-05-14
NO171791B (no) 1993-01-25
AU2595288A (en) 1989-06-01
CN1040217C (zh) 1998-10-14
DK660088A (da) 1989-05-28
IT1221653B (it) 1990-07-12
FI885462A0 (fi) 1988-11-24
DE3869921D1 (de) 1992-05-14
FI96770C (fi) 1996-08-26
NO885281L (no) 1989-05-29
NO171791C (no) 1993-05-05

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