ES2031986T3 - Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno. - Google Patents

Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno.

Info

Publication number
ES2031986T3
ES2031986T3 ES198888119801T ES88119801T ES2031986T3 ES 2031986 T3 ES2031986 T3 ES 2031986T3 ES 198888119801 T ES198888119801 T ES 198888119801T ES 88119801 T ES88119801 T ES 88119801T ES 2031986 T3 ES2031986 T3 ES 2031986T3
Authority
ES
Spain
Prior art keywords
preparation
procedure
propylene copolymers
new crystal
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888119801T
Other languages
English (en)
Inventor
Luigi Maria Dr. Resconi
Enrico Dr. Albizzati
Romano Mazzocchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Syensqo Specialty Polymers Italy SpA
Himont Inc
Original Assignee
Montedison SpA
Ausimont SpA
Himont Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11250144&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2031986(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montedison SpA, Ausimont SpA, Himont Inc filed Critical Montedison SpA
Application granted granted Critical
Publication of ES2031986T3 publication Critical patent/ES2031986T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

NUEVOS COPOLIMEROS CRISTALINOS DE PROPILENO CON MENOS PROPORCION DE ETILENO Y/O ALFA - OLEFINAS CON MUY BUENAS PROPIEDADES MECANICAS, BAJO PUNTO DE FUSION Y UNA SOLUBILIDAD LIMITADA EN XILENO A 25 (GRADOS) C, Y EL PROCESO DE SU PREPARACION POR MEDIO DE POLIMERIZACION DE MEZCLAS DE PROPILENO CON ETILENO Y/O ALFA - OLEFINAS DE COMPOSICION ADECUADA, POR UTILIZACION DE CATALISIS OBTENIDA DE COMPUESTOS DE ZIRCONIO, Y COMPUESTOS METILALUMOXANICOS.
ES198888119801T 1987-11-27 1988-11-28 Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno. Expired - Lifetime ES2031986T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT41012/87A IT1221653B (it) 1987-11-27 1987-11-27 Copolimeri cristallini del propilene

Publications (1)

Publication Number Publication Date
ES2031986T3 true ES2031986T3 (es) 1993-01-01

Family

ID=11250144

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888119801T Expired - Lifetime ES2031986T3 (es) 1987-11-27 1988-11-28 Procedimiento para la preparacion de nuevos copolimeros cristalinos de propileno.

Country Status (15)

Country Link
US (2) US5516866A (es)
EP (1) EP0318049B2 (es)
JP (1) JP3112908B2 (es)
KR (1) KR950013682B1 (es)
CN (1) CN1040217C (es)
AU (1) AU604582B2 (es)
BR (1) BR8806244A (es)
CA (1) CA1338368C (es)
DE (1) DE3869921D1 (es)
DK (1) DK660088A (es)
ES (1) ES2031986T3 (es)
FI (1) FI96770C (es)
IT (1) IT1221653B (es)
NO (1) NO171791C (es)
ZA (1) ZA888859B (es)

Families Citing this family (41)

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DE3640924A1 (de) * 1986-11-29 1988-06-01 Hoechst Ag 1-olefin-stereoblockpolymer und verfahren zu seiner herstellung
IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene
DE3836059A1 (de) * 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
DE3916555A1 (de) * 1989-05-20 1990-11-22 Hoechst Ag Verfahren zur herstellung von ethylenpolymeren
US6414096B1 (en) 1990-08-17 2002-07-02 Basell Polyolefine Gmbh Process for the preparation of a polyolefin
DE3927257A1 (de) * 1989-08-18 1991-02-21 Hoechst Ag Verfahren zur herstellung eines polyolefins
DE4015254A1 (de) * 1990-05-12 1991-11-14 Hoechst Ag Verfahren zur herstellung eines polyolefins
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
JP2009120858A (ja) * 1993-10-06 2009-06-04 Mitsui Chemicals Inc プロピレン系共重合体からなるフィルム
EP0657476B2 (en) † 1993-12-06 2007-12-19 Sumitomo Chemical Company, Limited Alpha-olefin polymers, alpha-olefin polymerizing catalyst and process for producing alpha-olefin polymers
ES2199966T3 (es) * 1994-02-21 2004-03-01 Basell Polyolefine Gmbh Lamina de varias capas poliolefinica sellable, un procedimiento para su obtencion y su empleo.
EP0669348B1 (en) 1994-02-25 1998-06-10 Sumitomo Chemical Company Limited Propylene random copolymer and film laminate thereof
CN1094419C (zh) * 1994-05-24 2002-11-20 埃克森美孚化学专利公司 包含低熔点丙烯聚合物的纤维和织物
US5571619A (en) * 1994-05-24 1996-11-05 Exxon Chemical Patents, Inc. Fibers and oriented films of polypropylene higher α-olefin copolymers
EP0847420B1 (en) 1995-08-29 2000-02-16 Exxon Chemical Patents Inc. Radiation tolerant polypropylene and its useful articles
JP3264148B2 (ja) * 1995-08-31 2002-03-11 住友化学工業株式会社 プロピレン−エチレンランダム共重合体、その製法及びフィルム
EP0862593B1 (en) * 1995-09-18 2004-02-18 ExxonMobil Chemical Patents Inc. High barrier polypropylene compositions and their use in packaging applications
DE19545499A1 (de) * 1995-12-06 1997-06-12 Basf Ag Verbesserte statistische Propylencopolymerisate
US6649725B2 (en) * 1996-02-05 2003-11-18 Idemitsu Petrochemical Co., Ltd. Propylenic copolymer, and its film
IT1282691B1 (it) 1996-02-27 1998-03-31 Montell North America Inc Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti
DE19746741A1 (de) 1996-10-30 1998-05-07 Idemitsu Petrochemical Co Propylen-Copolymer und Folie daraus
JP3569739B2 (ja) 1996-11-25 2004-09-29 出光石油化学株式会社 プロピレン系ランダム共重合体の製造方法
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
AU4962399A (en) * 1998-07-01 2000-01-24 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
EP1263909A2 (en) 1999-12-22 2002-12-11 ExxonMobil Chemical Patents Inc. Polypropylene-based adhesive compositions
US7067603B1 (en) 1999-12-22 2006-06-27 Exxonmobil Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
EP1390417B1 (en) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Process for polymerizing propylene and ethylene in solution
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
EP1615961A1 (en) 2003-04-15 2006-01-18 ExxonMobil Chemical Patents Inc. Catalysts for propylene copolymers, polymerization process and copolymer of propylene
CN101516929B (zh) * 2006-07-28 2012-06-20 巴塞尔聚烯烃意大利有限责任公司 丙烯聚合物
DE102008005947A1 (de) 2008-01-24 2009-07-30 Evonik Degussa Gmbh Polyolefine mit Ataktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US9593179B2 (en) 2014-02-07 2017-03-14 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
KR101764561B1 (ko) 2014-05-06 2017-08-02 바셀 폴리올레핀 이탈리아 에스.알.엘 랜덤 프로필렌-에틸렌 공중합체 및 이의 제조 방법
US20180371219A1 (en) * 2015-11-24 2018-12-27 Basell Polyolefine Gmbh Blown polyolefin films

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FR76947E (fr) * 1960-01-21 1961-12-15 Infrastructure de wagon ferroviaire
US4048409A (en) * 1973-09-27 1977-09-13 Mitsui Toatsu Chemicals, Incorporated Article made of propylene-ethylene copolymer
JPS5179195A (ja) * 1974-12-28 1976-07-09 Chisso Corp Ketsushoseipuropiren arufua orefuinnechiren 3 genkyojugotaino seizoho
JPS5287489A (en) * 1976-01-19 1977-07-21 Mitsui Petrochem Ind Ltd Polymerization of olefins
DE2637990A1 (de) * 1976-08-24 1978-03-02 Hoechst Ag Propylen-terpolymer
IT1193760B (it) * 1978-06-14 1988-08-24 Sumitomo Chemical Co Procedimento per produrre copolimeri di propilene e pellicola di polipropilene a piu' strati con esso ottenuta
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JPS58138721A (ja) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd プロピレンランダム共重合体
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ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
JPS60127133A (ja) * 1983-12-14 1985-07-06 Sumitomo Chem Co Ltd シユリンク包装用フイルム
CA1300788C (en) * 1984-11-02 1992-05-12 Mitsui Chemicals, Incorporated Crystalline random propylene copolymer composition and composite laminate comprising said composition
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
EP0217803A1 (en) * 1985-04-01 1987-04-15 Aristech Chemical Corporation Terpolymer production
JPH06104698B2 (ja) * 1985-11-20 1994-12-21 三井石油化学工業株式会社 プロピレン系ランダム共重合体およびそれからなる熱可塑性樹脂用ヒートシール性改善剤
JPH0753766B2 (ja) * 1985-11-22 1995-06-07 三井石油化学工業株式会社 α−オレフイン系ランダム共重合体の製造法
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KR920000173B1 (ko) * 1986-10-09 1992-01-09 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체
IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene

Also Published As

Publication number Publication date
BR8806244A (pt) 1989-08-15
JPH01266116A (ja) 1989-10-24
ZA888859B (en) 1989-08-30
CN1040217C (zh) 1998-10-14
DK660088D0 (da) 1988-11-25
AU604582B2 (en) 1990-12-20
NO171791B (no) 1993-01-25
EP0318049A1 (en) 1989-05-31
NO885281D0 (no) 1988-11-25
EP0318049B1 (en) 1992-04-08
EP0318049B2 (en) 2003-07-16
DK660088A (da) 1989-05-28
KR890008188A (ko) 1989-07-10
FI885462L (fi) 1989-05-28
JP3112908B2 (ja) 2000-11-27
US6355758B1 (en) 2002-03-12
FI96770B (fi) 1996-05-15
NO171791C (no) 1993-05-05
FI885462A0 (fi) 1988-11-24
IT1221653B (it) 1990-07-12
KR950013682B1 (ko) 1995-11-13
DE3869921D1 (de) 1992-05-14
CN1034551A (zh) 1989-08-09
CA1338368C (en) 1996-06-04
NO885281L (no) 1989-05-29
US5516866A (en) 1996-05-14
IT8741012A0 (it) 1987-11-27
AU2595288A (en) 1989-06-01
FI96770C (fi) 1996-08-26

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