ES2045428T3 - Procedimiento para la separacion por adsorcion de hidrocarburos para-dialquil-aromaticos a partir de alimentaciones que tambien contienen por lo menos un isomero de los mismos. - Google Patents
Procedimiento para la separacion por adsorcion de hidrocarburos para-dialquil-aromaticos a partir de alimentaciones que tambien contienen por lo menos un isomero de los mismos.Info
- Publication number
- ES2045428T3 ES2045428T3 ES89305091T ES89305091T ES2045428T3 ES 2045428 T3 ES2045428 T3 ES 2045428T3 ES 89305091 T ES89305091 T ES 89305091T ES 89305091 T ES89305091 T ES 89305091T ES 2045428 T3 ES2045428 T3 ES 2045428T3
- Authority
- ES
- Spain
- Prior art keywords
- isomer
- aromaticos
- dialquil
- para
- foods
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 2
- 235000013305 food Nutrition 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000000926 separation method Methods 0.000 title 1
- 238000001179 sorption measurement Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- 230000002745 absorbent Effects 0.000 abstract 2
- 239000002250 absorbent Substances 0.000 abstract 2
- 238000010521 absorption reaction Methods 0.000 abstract 2
- IHPYMWDTONKSCO-UHFFFAOYSA-N 2,2'-piperazine-1,4-diylbisethanesulfonic acid Chemical compound OS(=O)(=O)CCN1CCN(CCS(O)(=O)=O)CC1 IHPYMWDTONKSCO-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000007990 PIPES buffer Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003562 lightweight material Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Abstract
EL PARA-ISOMERO DE UN HIDROCARBONO DIALQUIL-AROMATICO SE SEPARA DE UNA MEZCLA CON AL MENOS OTRO ISOMERO DEL HIDROCARBONO, MEDIANTE EL CONTACTO DE LA MEZCLA CON UN ALUMINOSILICATO CRISTALINO ABSORBENTE CONTENIENDO IONES DE BARIO Y POTASIO EN PUNTOS CATIONICOS CAMBIABLES EN UNA RATIO DE MOL CORRESPONDIENTE A UN BAO A K2O RATIO DE 0.6:1 A 1.2:1 EN CONDICIONES DE ABSORCION SELECCIONADAS PARA EFECTUAR LA ABSORCION DE DICHO PARA-ISOMERO Y DESPUES PONER EN CONTACTO EL PARA-ISOMERO CONTENEDOR DEL ABSORBENTE CON UN MATERIAL DESORBENTE SELECCIONADO DE LOS MONOFLUOROAROMATICOS, DIFLUOROAROMATICOS O MEZCLAS DE ELLOS EN CONDICIONES DE DESORBCION SELECCIONADAS PARA LLEVAR A CABO LA RECUPERACION DE DICHOS ISOMEROS.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/061,948 US4886929A (en) | 1987-06-15 | 1987-06-15 | Separation of para-xylene |
| CA000600093A CA1322176C (en) | 1987-06-15 | 1989-05-18 | Use of a fluoro-aromatic desorbent in a process for adsorptive separation of para-alkylaromatic hydrocarbons |
| HU892522A HU205057B (en) | 1987-06-15 | 1989-05-22 | Process for the adsorption separation of paraalkyl aromatic hydrocarbons by using fluoroaromatic adsorbent |
| RO139905A RO103750B1 (ro) | 1987-06-15 | 1989-05-25 | Procedeu pentru separarea para-xilenului dintr-un flux hidrocarbonat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2045428T3 true ES2045428T3 (es) | 1994-01-16 |
Family
ID=27426667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES89305091T Expired - Lifetime ES2045428T3 (es) | 1987-06-15 | 1989-05-19 | Procedimiento para la separacion por adsorcion de hidrocarburos para-dialquil-aromaticos a partir de alimentaciones que tambien contienen por lo menos un isomero de los mismos. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4886929A (es) |
| EP (1) | EP0397944B1 (es) |
| AU (1) | AU611802B2 (es) |
| CA (1) | CA1322176C (es) |
| ES (1) | ES2045428T3 (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5107062A (en) * | 1988-05-23 | 1992-04-21 | Uop | Zeolitic para-xylene separation with tetralin derivatives as heavy desorbent |
| DE4239151A1 (de) * | 1992-11-20 | 1994-05-26 | Thomae Gmbh Dr K | N,N-Disubstituierte Arylcycloalkylamine, deren Salze, diese Verbindungen enthaltende Arzneimittel und deren Verwendung sowie Verfahren zu ihrer Herstellung |
| US5453560A (en) * | 1994-05-20 | 1995-09-26 | Uop | Process for adsorptive separation of ethylbenzene from aromatic hydrocarbons |
| US6036865A (en) * | 1998-06-15 | 2000-03-14 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
| US6045703A (en) * | 1998-06-15 | 2000-04-04 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
| CA2394378A1 (en) * | 2000-02-22 | 2001-08-30 | Exxonmobil Chemical Patents Inc. | Process for producing para-xylene |
| KR100674285B1 (ko) * | 2002-02-20 | 2007-01-24 | 에스케이 주식회사 | 디에틸벤젠 이성질체 혼합물로부터 1,4-디에틸벤젠 및1,3-디에틸벤젠을 분리하는 방법 |
| US7381858B2 (en) * | 2004-01-30 | 2008-06-03 | Bp Corporation North America Inc. | Xylene process using perm-selective separations |
| US7358414B2 (en) | 2004-01-30 | 2008-04-15 | Miller Jeffrey T | Para-xylene process using perm-selective separations |
| KR101048568B1 (ko) * | 2006-04-25 | 2011-07-12 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 파라-크실렌의 생산방법 |
| WO2008033200A1 (en) | 2006-09-14 | 2008-03-20 | Exxonmobil Chemical Patents Inc. | Process for producing para-xylene |
| US8273934B2 (en) * | 2008-12-15 | 2012-09-25 | Exxonmobil Chemical Patents Inc. | Process for producing para-xylene |
| US8283274B2 (en) * | 2009-07-20 | 2012-10-09 | Uop Llc | Binderless zeolitic adsorbents, methods for producing binderless zeolitic adsorbents, and processes for adsorptive separation of para-xylene from mixed xylenes using the binderless zeolitic adsorbents |
| US8557028B2 (en) * | 2011-03-31 | 2013-10-15 | Uop Llc | Binderless zeolitic adsorbents, methods for producing binderless zeolitic adsorbents, and adsorptive separation processes using the binderless zeolitic adsorbents |
| US12358857B2 (en) | 2020-07-31 | 2025-07-15 | Exxonmobil Chemicals Patents Inc. | Processes for producing high-octane-number fuel component |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2985589A (en) * | 1957-05-22 | 1961-05-23 | Universal Oil Prod Co | Continuous sorption process employing fixed bed of sorbent and moving inlets and outlets |
| GB899314A (en) * | 1960-02-15 | 1962-06-20 | Union Oil Co | Separation of aromatic isomers |
| US4014949A (en) * | 1962-06-06 | 1977-03-29 | Sun Ventures, Inc. | Separation of cyclic compounds with molecular sieve adsorbent |
| US3201491A (en) * | 1962-09-05 | 1965-08-17 | Universal Oil Prod Co | Continuous sorption process with emphasis on product purity |
| US3626020A (en) * | 1969-03-12 | 1971-12-07 | Universal Oil Prod Co | Separation of paraxylene from mixture of c aromatic utilizing crystalline aluminosilicate adsorbent |
| US3558732A (en) * | 1969-05-12 | 1971-01-26 | Universal Oil Prod Co | Aromatic hydrocarbon separation by adsorption |
| US3665046A (en) * | 1969-10-13 | 1972-05-23 | Universal Oil Prod Co | Separation of para-xylene from mixtures of c8 aromatics utilizing crystalline aluminositicate adsorbents |
| US3668266A (en) * | 1969-11-26 | 1972-06-06 | Mobil Oil Corp | Sodium mordenite separation of para-xylene |
| US3663638A (en) * | 1970-08-31 | 1972-05-16 | Universal Oil Prod Co | Aromatic hydrocarbon separation by adsorption |
| US3700744A (en) * | 1970-09-18 | 1972-10-24 | Universal Oil Prod Co | Simultaneous recovery and production of pure xylenes from a c aromatic mixture |
| US3686342A (en) * | 1970-09-18 | 1972-08-22 | Universal Oil Prod Co | Aromatic hydrocarbon separation by adsorption |
| US3686343A (en) * | 1970-10-01 | 1972-08-22 | Exxon Research Engineering Co | Paraxylene recovery with zeolite adsorbent |
| US3996306A (en) * | 1971-04-21 | 1976-12-07 | Uop Inc. | Aromatic hydrocarbon isomer separation process |
| US4051192A (en) * | 1971-04-21 | 1977-09-27 | Uop Inc. | Separation of bi-alkyl substituted monocyclic aromatic isomers |
| US3734974A (en) * | 1971-07-26 | 1973-05-22 | Universal Oil Prod Co | Hydrocarbon separation process |
| US3707550A (en) * | 1971-10-26 | 1972-12-26 | Universal Oil Prod Co | Process for the production and recovery of ortho-xylene,para-xylene and ethylbenzene |
| US3843518A (en) * | 1972-08-23 | 1974-10-22 | Exxon Research Engineering Co | Commercial chromatography for more than two components |
| US3878129A (en) * | 1973-05-02 | 1975-04-15 | Universal Oil Prod Co | Method of manufacturing a zeolitic adsorbent useful for aromatic separation |
| US3894109A (en) * | 1973-05-02 | 1975-07-08 | Universal Oil Prod Co | Aromatic hydrocarbon isomer separation by adsorption |
| US3878127A (en) * | 1973-05-02 | 1975-04-15 | Universal Oil Prod Co | Method of manufacturing a zeolitic absorbent |
| JPS515562A (en) * | 1974-07-05 | 1976-01-17 | Hitachi Metals Ltd | Indakutansuno choseihoho |
| GB1526065A (en) * | 1974-10-16 | 1978-09-27 | Asahi Chemical Ind | Process for separation of hydrocarbon mixture |
| US3997620A (en) * | 1975-10-28 | 1976-12-14 | Uop Inc. | Process for separating para-xylene |
| GB1529945A (en) * | 1976-02-18 | 1978-10-25 | British Petroleum Co | Separating c8 aromatic isomers |
| GB1589213A (en) * | 1977-09-23 | 1981-05-07 | Uop Inc | Method of manufacturing a zeolitic adsorbent |
| GB2031013B (en) * | 1978-09-07 | 1983-02-16 | Asahi Chemical Ind | Separation of c8 aromatic isomers |
| US4584424A (en) * | 1984-10-29 | 1986-04-22 | Exxon Research & Engineering Company | Process for separating ethylbenzene from xylenes by selective adsorption on a Beta zeolite |
-
1987
- 1987-06-15 US US07/061,948 patent/US4886929A/en not_active Expired - Fee Related
-
1989
- 1989-05-18 CA CA000600093A patent/CA1322176C/en not_active Expired - Fee Related
- 1989-05-19 ES ES89305091T patent/ES2045428T3/es not_active Expired - Lifetime
- 1989-05-19 EP EP89305091A patent/EP0397944B1/en not_active Expired - Lifetime
- 1989-05-24 AU AU35096/89A patent/AU611802B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP0397944A1 (en) | 1990-11-22 |
| EP0397944B1 (en) | 1993-07-21 |
| US4886929A (en) | 1989-12-12 |
| CA1322176C (en) | 1993-09-14 |
| AU3509689A (en) | 1990-12-06 |
| AU611802B2 (en) | 1991-06-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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