ES2046461T3 - Procedimiento para la polimerizacion de propileno. - Google Patents

Procedimiento para la polimerizacion de propileno.

Info

Publication number
ES2046461T3
ES2046461T3 ES198989301132T ES89301132T ES2046461T3 ES 2046461 T3 ES2046461 T3 ES 2046461T3 ES 198989301132 T ES198989301132 T ES 198989301132T ES 89301132 T ES89301132 T ES 89301132T ES 2046461 T3 ES2046461 T3 ES 2046461T3
Authority
ES
Spain
Prior art keywords
propylene
ethylene
halide
mol
absence
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198989301132T
Other languages
English (en)
Inventor
George C. Allen
Brian J. Pellon
Michael P. Hughes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rexene Products Co
Original Assignee
Rexene Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rexene Products Co filed Critical Rexene Products Co
Application granted granted Critical
Publication of ES2046461T3 publication Critical patent/ES2046461T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/906Comminution of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

UN PROCESO DE ELEVADA EFICACIA PARA LA PRODUCCION DE COPOLIMEROS SUSTANCIALMENTE AMORFOS DE ETILENO - PROPILENO QUE SON UTILES COMO ADHESIVOS DE APLICACION POR FUSION, COMO COMPONENTES DE MEZCLA EN MATERIALES PARA TEJADOS Y COMO AGENTES LUBRICANTES PARA CABLES. EL PROCESO IMPLICA HACER REACCIONAR DESDE 70 A 96.5% EN PESO DE PROPILENO Y DESDE 3.5 A 30% EN PESO DE ETILENO A UNA TEMPERATURA ENTRE 55 Y 80 (GRADOS) C Y A UNA PRESION EN EL REACTOR SUFICIENTE PARA MANTENER EL PROPILENO EN FASE LIQUIDA, EN PRESENCIA DE ENTRE 0.7 Y 3.0 MOLES % DE H SOBRE LA BASE DE LA ALIMENTACION DE MONOMERO Y EMPLEANDO UN CATALIZADOR CUYA COMPOSICION Y PROCESO DE PREPARACION SE DAN DETALLADAMENTE Y QUE CONTIENE HALURO DE MG, TRIHALURO DE AL Y TETRAHALURO DE TI. SE OBTIENE UN COPOLIMERO DE ETILENO - PROPILENO ESTADISTICO SUSTANCIALMENTE AMORFO CON UN INDICE DE TACTICIDAD M/R EN LA GAMA DE 2.5 A 4 CUANDO SE DETERMINA MEDIANTE ESPECTRO RMN CON C13.
ES198989301132T 1988-02-16 1989-02-06 Procedimiento para la polimerizacion de propileno. Expired - Lifetime ES2046461T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/156,047 US4847340A (en) 1986-06-30 1988-02-16 Novel propylene polymerization process

Publications (1)

Publication Number Publication Date
ES2046461T3 true ES2046461T3 (es) 1994-02-01

Family

ID=22557850

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198989301132T Expired - Lifetime ES2046461T3 (es) 1988-02-16 1989-02-06 Procedimiento para la polimerizacion de propileno.

Country Status (10)

Country Link
US (1) US4847340A (es)
EP (1) EP0329319B1 (es)
JP (1) JP2703571B2 (es)
KR (1) KR0134777B1 (es)
CN (1) CN1035301A (es)
AT (1) ATE94567T1 (es)
AU (1) AU620333B2 (es)
CA (1) CA1309799C (es)
DE (1) DE68909066T2 (es)
ES (1) ES2046461T3 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2647454B1 (fr) * 1989-05-29 1993-01-22 Solvay Suspensions de particules contenant des composes de metaux de transition dans des huiles et procedes de polymerisation d'alpha-olefines effectues en presence de ces suspensions
AU643315B2 (en) * 1990-09-07 1993-11-11 Huntsman Polymers Corporation Amorphous elastomeric propylene homopolymers
CA2049373A1 (en) * 1990-09-07 1992-03-08 Brian J. Pellon Process for the production of amorphous elastomeric propylene homopolymers
US5302380A (en) * 1992-06-08 1994-04-12 Revlon Consumer Products Corporation Cosmetic compositions containing atactic polypropylenes and related methods
US5714554A (en) * 1992-09-08 1998-02-03 Rexene Corporation High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers
US5302675A (en) * 1992-09-08 1994-04-12 Rexene Corporation High tensile strength amorphous 1-butene/propylene copolymers
US6586536B1 (en) * 1993-06-18 2003-07-01 Joseph M. Kelley High temperature process for the production of atactic, amorphous, tacky propylene homopolymers or copolymers
IT1275857B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Copolimeri atattici del propilene con l'etilene
US6586543B1 (en) * 1999-09-01 2003-07-01 Degussa Ag Process for the preparation of substantially amorphous poly-α-olefins
CA2508216A1 (en) * 2005-04-14 2006-10-14 Sercel, Inc. Solid flooding compound for marine seismic cable
US10350325B2 (en) * 2013-05-29 2019-07-16 H.B. Fuller Company Disposable absorbent article and a method for making the same
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
WO2016176821A1 (en) 2015-05-05 2016-11-10 Dow Global Technologies Llc Functionalized, halogenated olefin-based adhesive, articles containing and process for using thereof
US20170292047A1 (en) 2016-04-12 2017-10-12 Rextac Llc Hexene-1 Containing Amorphous Polyalphaolefins For Improved Hot Melt Adhesives
US10752815B2 (en) 2016-04-12 2020-08-25 Rextac Llc Low molecular weight butene-1-co-hexene-1 amorphous poly alpha olefins for hot-melt adhesives with enhanced properties
JP2019528329A (ja) 2016-08-03 2019-10-10 エイチ.ビー.フラー カンパニー 弾性材取り付けホットメルト接着剤組成物及びそれを用いて製造される使い捨て吸収性物品
KR102352173B1 (ko) * 2020-02-13 2022-01-19 대한유화(주) 내구성과 저온유연성이 동시에 우수한 비결정성 폴리프로필렌 공중합체 및 이의 제조방법
US12435163B2 (en) * 2020-04-01 2025-10-07 3M Innovative Properties Company Compositions comprising romp catalyst and dispersant, cartridges, and methods

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL163523C (nl) * 1970-07-31 1983-11-16 Montedison Spa Werkwijze om een polymerisatiekatalysator te bereiden.
NL7113778A (es) * 1970-10-13 1972-04-17
US4234710A (en) * 1976-07-08 1980-11-18 Phillips Petroleum Company Catalyst and a polymerization process employing the catalyst
US4175171A (en) * 1976-08-02 1979-11-20 Mitsui Toatsu Chemicals, Inc. Catalyst for polymerizing α-olefins
JPS6042805B2 (ja) * 1979-02-27 1985-09-25 日石三菱株式会社 共重合体の製法
JPS62157960A (ja) * 1985-12-28 1987-07-13 Casio Comput Co Ltd 小型電子式計算機
DE3769528D1 (de) * 1986-06-30 1991-05-29 Rexene Prod Co Propylenpolymere und ihre herstellung.
US4736002A (en) 1986-06-30 1988-04-05 El Paso Products Company Novel propylene polymerization process
CA1282546C (en) * 1986-06-30 1991-04-02 Brian Jay Pellon Propylene polymers

Also Published As

Publication number Publication date
CN1035301A (zh) 1989-09-06
DE68909066D1 (de) 1993-10-21
AU620333B2 (en) 1992-02-20
KR890013065A (ko) 1989-09-21
AU1866688A (en) 1989-09-21
CA1309799C (en) 1992-11-03
JPH01210407A (ja) 1989-08-24
KR0134777B1 (ko) 1998-04-20
ATE94567T1 (de) 1993-10-15
JP2703571B2 (ja) 1998-01-26
DE68909066T2 (de) 1994-05-05
EP0329319B1 (en) 1993-09-15
US4847340A (en) 1989-07-11
EP0329319A1 (en) 1989-08-23

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