ES2048936T3 - Procedimiento para la obtencion de metilformiato. - Google Patents
Procedimiento para la obtencion de metilformiato.Info
- Publication number
- ES2048936T3 ES2048936T3 ES90120549T ES90120549T ES2048936T3 ES 2048936 T3 ES2048936 T3 ES 2048936T3 ES 90120549 T ES90120549 T ES 90120549T ES 90120549 T ES90120549 T ES 90120549T ES 2048936 T3 ES2048936 T3 ES 2048936T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- methylformiate
- obtaining
- mgo
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007792 gaseous phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
- C07C67/40—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of primary alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA FABRICACION DE FORMIATO DE METILO MEDIANTE LA REACCION DE METANOL EN CATALIZADORES QUE CONTIENEN COBRE A UNA ALTA TEMPERATURA Y EN FASE GASEOSA, UTILIZANDO UN CATALIZADOR QUE CONTIENE, ADEMAS DE 30 A 80 PESOALCULADO COMO CUO, DE UN 20 A 70 PESO IO CALCULADO COMO MGO MAS SIO SUB 2, EN LOS CUALES, LA RELACION MOLECULAR MGO/SIO SUB 2 ES DE 0,3 A 1,5. EL CATALIZADOR PUEDE INCORPORAR, ADEMAS, LOS METALES CINC, CROMO Y/O BARIO EN CANTIDADES DE HASTA 1,5 PESO 3 Y BAO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3936854A DE3936854A1 (de) | 1989-11-06 | 1989-11-06 | Verfahren zur herstellung von methylformiat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2048936T3 true ES2048936T3 (es) | 1994-04-01 |
Family
ID=6392936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90120549T Expired - Lifetime ES2048936T3 (es) | 1989-11-06 | 1990-10-26 | Procedimiento para la obtencion de metilformiato. |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5194675A (es) |
| EP (1) | EP0427062B1 (es) |
| DE (2) | DE3936854A1 (es) |
| ES (1) | ES2048936T3 (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4309731A1 (de) * | 1993-03-25 | 1994-09-29 | Basf Ag | Verfahren zur Herstellung von Methylformiat |
| JP3358631B2 (ja) * | 1993-05-17 | 2002-12-24 | 三菱瓦斯化学株式会社 | メタノ−ルの脱水素方法 |
| RU2185370C1 (ru) * | 2000-12-04 | 2002-07-20 | Институт катализа им.Г.К.Борескова СО РАН | Способ получения метилформиата, катализатор для его осуществления и способ получения катализатора |
| RU2185369C1 (ru) * | 2001-04-02 | 2002-07-20 | Тверской государственный технический университет РАН | Способ получения 2-кето-l-гулоновой кислоты |
| US20050027195A1 (en) * | 2003-08-01 | 2005-02-03 | Assaf Govari | Calibration data compression |
| US20050059839A1 (en) * | 2003-09-15 | 2005-03-17 | The Regents Of The University Of California | Process and catalysts for the oxidation of methanol and/or ethanol |
| US6956134B2 (en) * | 2004-01-08 | 2005-10-18 | The Regents Of The University Of California | Oxidation of methanol and/or dimethyl ether using supported molybdenum-containing heteropolyacid catalysts |
| RU2377232C2 (ru) * | 2007-03-28 | 2009-12-27 | Олег Николаевич Новиков | Способ получения метилформиата |
| ES2436625T3 (es) | 2009-05-12 | 2014-01-03 | Basf Se | Proceso para producir óxido de propileno |
| KR101802535B1 (ko) | 2009-07-16 | 2017-11-28 | 바스프 에스이 | 물로부터 아세토니트릴을 분리하는 방법 |
| US8558025B2 (en) | 2009-10-20 | 2013-10-15 | Greenyug, Llc | Ethyl acetate production |
| US9447018B2 (en) | 2009-10-20 | 2016-09-20 | Greenyug, Llc | Ethyl acetate production |
| ES2712067T3 (es) | 2011-10-12 | 2019-05-09 | Greenyug Llc | Producción de acetato de etilo |
| US9079851B2 (en) | 2012-02-01 | 2015-07-14 | Greenyug, Llc | Ethyl acetate production |
| WO2014130465A1 (en) | 2013-02-19 | 2014-08-28 | Greenyug, Llc | Production of higher alcohols |
| KR102245980B1 (ko) | 2013-04-29 | 2021-04-29 | 바스프 에스이 | 부분-스트림 증류 |
| ES2685811T3 (es) | 2013-07-24 | 2018-10-11 | Basf Se | Un proceso para preparar óxido de propileno |
| CN105764609B (zh) | 2013-07-24 | 2018-02-23 | 巴斯夫欧洲公司 | 制备环氧丙烷的方法 |
| US9688648B2 (en) | 2013-07-24 | 2017-06-27 | Basf Se | Process for the preparation of propylene oxide |
| BR112016012629B1 (pt) | 2013-12-04 | 2020-12-01 | Rescurve, Llc | método e sistema de destilação reativa |
| MY182496A (en) | 2014-10-27 | 2021-01-25 | Dow Global Technologies Llc | Part-stream distillation |
| CA3225290A1 (en) | 2015-08-19 | 2017-02-23 | Viridis Chemical, Llc | Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols |
| WO2017140774A1 (en) | 2016-02-17 | 2017-08-24 | Basf Se | A process for the preparation of propylene oxide |
| US10544077B2 (en) | 2017-08-02 | 2020-01-28 | Eastman Chemical Company | Process for making formic acid utilizing higher-boiling formate esters |
| US10266467B2 (en) | 2017-08-02 | 2019-04-23 | Eastman Chemical Company | Synthesis of glycols via transfer hydrogenation of alpha-functional esters with alcohols |
| US10570081B2 (en) | 2017-08-02 | 2020-02-25 | Eastman Chemical Company | Process for making formic acid utilizing lower-boiling formate esters |
| US10266466B2 (en) | 2017-08-02 | 2019-04-23 | Eastman Chemical Company | Iron-catalyzed transfer hydrogenation of esters to alcohols |
| US10435349B2 (en) | 2017-08-02 | 2019-10-08 | Eastman Chemical Company | Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters |
| CN107774266B (zh) * | 2017-11-13 | 2020-03-17 | 山西洁泰达煤化工工程有限公司 | 一种中空氧化锌包覆铜催化剂的制备方法及其应用 |
| DE102018121607A1 (de) | 2018-09-05 | 2020-03-05 | Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen | Verfahren zur Herstellung von Dimethoxymethan |
| CN111774070B9 (zh) * | 2020-07-13 | 2023-09-29 | 陕西延长石油（集团）有限责任公司 | 一种催化甲醇脱氢制备甲酸甲酯的催化剂及其制备方法与应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1400195A (en) * | 1918-12-24 | 1921-12-13 | Us Ind Alcohol Co | Process of making methyl formate |
| BE361508A (es) * | 1928-06-14 | |||
| US1975853A (en) * | 1931-04-11 | 1934-10-09 | Du Pont | Catalytic dehydrogenation of primary alcohols |
| US2160064A (en) * | 1936-06-17 | 1939-05-30 | Carbide & Carbon Chem Corp | Manufacture of formic acid |
| JPS5165708A (en) * | 1974-12-05 | 1976-06-07 | Mitsui Petrochemical Ind | Gisanmechiruno seizohoho |
| DE2716842C2 (de) * | 1976-04-16 | 1984-08-30 | Mitsubishi Gas Chemical Co., Inc., Tokio/Tokyo | Verfahren zur Herstellung von Methylformiat |
| JPS5371008A (en) * | 1976-12-02 | 1978-06-24 | Mitsubishi Gas Chem Co Inc | Preparation of methyl formate |
| JPS53108916A (en) * | 1977-03-04 | 1978-09-22 | Mitsui Petrochem Ind Ltd | Preparation of methyl formate |
-
1989
- 1989-11-06 DE DE3936854A patent/DE3936854A1/de not_active Withdrawn
-
1990
- 1990-10-26 EP EP90120549A patent/EP0427062B1/de not_active Expired - Lifetime
- 1990-10-26 DE DE90120549T patent/DE59004601D1/de not_active Expired - Fee Related
- 1990-10-26 ES ES90120549T patent/ES2048936T3/es not_active Expired - Lifetime
-
1992
- 1992-01-09 US US07/819,590 patent/US5194675A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0427062A2 (de) | 1991-05-15 |
| US5194675A (en) | 1993-03-16 |
| DE59004601D1 (de) | 1994-03-24 |
| EP0427062B1 (de) | 1994-02-16 |
| DE3936854A1 (de) | 1991-05-08 |
| EP0427062A3 (en) | 1992-02-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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