ES2054695T3 - Procedimiento sin disolvente para producir copolimeros de acetato de vinilo y fumarato de dialquilo. - Google Patents

Procedimiento sin disolvente para producir copolimeros de acetato de vinilo y fumarato de dialquilo.

Info

Publication number
ES2054695T3
ES2054695T3 ES87311165T ES87311165T ES2054695T3 ES 2054695 T3 ES2054695 T3 ES 2054695T3 ES 87311165 T ES87311165 T ES 87311165T ES 87311165 T ES87311165 T ES 87311165T ES 2054695 T3 ES2054695 T3 ES 2054695T3
Authority
ES
Spain
Prior art keywords
vinyl acetate
solvent
dialkyl fumarate
producing vinyl
free procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES87311165T
Other languages
English (en)
Inventor
Chung Kun Shish
Craig Wallace Gleason
Edmund Harvey Ii Braun
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2054695T3 publication Critical patent/ES2054695T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • C10L10/16—Pour-point depressants
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/14—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
    • C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of a saturated carboxylic or carbonic acid
    • C10M145/08—Vinyl esters of a saturated carboxylic or carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/16—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Emergency Medicine (AREA)
  • Combustion & Propulsion (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

SE DESCRIBEN PROCEDIMIENTOS PARA LA POLIMERIZACION DE ACETATO DE VINILO CON UN DIESTER, QUE SE LLEVAN A CABO EN AUSENCIA DE DISOLVENTE E INCLUYEN LA REACCION DE ACETATO DE VINILO Y DIESTER DE ACIDO FUMARICO CON UN CATALIZADOR PEROXIDO, EN RELACIONES MOLARES ESPECIFICAS Y A TEMPERATURAS DE REACCION DE HASTA 124-160 (GRADOS) C, PARA OBTENER COPOLIMEROS DE ACETATO DE VINILO FUMARATO, QUE TIENEN PESOS MOLECULARES MEDIOS INFERIORES A 50000, PARA UTILIZAR COMO ACEITES LUBRICANTES Y ADITIVOS A FUELOIL.
ES87311165T 1986-12-18 1987-12-18 Procedimiento sin disolvente para producir copolimeros de acetato de vinilo y fumarato de dialquilo. Expired - Lifetime ES2054695T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/943,613 US4772674A (en) 1986-12-18 1986-12-18 Solventless process for producing dialkyl fumarate-vinyl acetate copolymers

Publications (1)

Publication Number Publication Date
ES2054695T3 true ES2054695T3 (es) 1994-08-16

Family

ID=25479944

Family Applications (1)

Application Number Title Priority Date Filing Date
ES87311165T Expired - Lifetime ES2054695T3 (es) 1986-12-18 1987-12-18 Procedimiento sin disolvente para producir copolimeros de acetato de vinilo y fumarato de dialquilo.

Country Status (8)

Country Link
US (1) US4772674A (es)
EP (1) EP0272133B1 (es)
JP (1) JP2858575B2 (es)
AU (1) AU596252B2 (es)
BR (1) BR8706893A (es)
CA (1) CA1275344C (es)
DE (1) DE3785731T2 (es)
ES (1) ES2054695T3 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304315A (en) * 1992-04-15 1994-04-19 Exxon Chemical Patents Inc. Prevention of gel formation in two-cycle oils
US5939365A (en) * 1996-12-20 1999-08-17 Exxon Chemical Patents Inc. Lubricant with a higher molecular weight copolymer lube oil flow improver
US6444784B1 (en) 1998-05-29 2002-09-03 Exxonmobil Research & Engineering Company Wax crystal modifiers (LAW657)
WO1999063029A1 (en) * 1998-05-29 1999-12-09 Exxon Research And Engineering Company Dialkyl fumarate copolymers and their use as flow improvers in oleaginous fluids
US6017370A (en) * 1998-09-25 2000-01-25 The Lubrizol Corporation Fumarate copolymers and acylated alkanolamines as low temperature flow improvers
US6583247B1 (en) 1999-03-16 2003-06-24 Infineum International Ltd. Process for producing free radical polymerized copolymers
US9518244B2 (en) * 2007-12-03 2016-12-13 Infineum International Limited Lubricant composition comprising a bi-modal side-chain distribution LOFI
JP5934273B2 (ja) * 2014-03-26 2016-06-15 デンカ株式会社 変性ポリ酢酸ビニルの製造方法
GB201810852D0 (en) * 2018-07-02 2018-08-15 Innospec Ltd Compositions, uses and methods

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE410558A (es) * 1934-07-26
US2448531A (en) * 1943-07-23 1948-09-07 Eastman Kodak Co Resinous copolymer of isopropenyl acetate
NL74949C (es) * 1949-08-30
US2825717A (en) * 1954-05-06 1958-03-04 Exxon Research Engineering Co Dialkyl fumarate-vinyl acetate copolymers
US2876213A (en) * 1954-07-28 1959-03-03 Exxon Research Engineering Co Multifunctional lubricant additives
NL95991C (es) * 1955-11-16
US3507908A (en) * 1963-07-29 1970-04-21 Sinclair Research Inc Copolymer of a vinyl ester of a fatty acid and a dialkyl fumarate
AT356380B (de) * 1977-11-17 1980-04-25 Vianova Kunstharz Ag Verfahren zur herstellung von polymerisaten durch radikalisch initiierte substanzpoly- merisation
JPS6060118A (ja) * 1983-09-14 1985-04-06 Nippon Oil & Fats Co Ltd 新規な共重合体
US4670130A (en) * 1984-03-14 1987-06-02 Exxon Research & Engineering Co. The use of dialkyl fumarate-vinyl acetate copolymers as dewaxing aids

Also Published As

Publication number Publication date
DE3785731T2 (de) 1993-08-19
DE3785731D1 (de) 1993-06-09
AU596252B2 (en) 1990-04-26
JPS63225607A (ja) 1988-09-20
JP2858575B2 (ja) 1999-02-17
AU8264787A (en) 1988-06-23
EP0272133A2 (en) 1988-06-22
US4772674A (en) 1988-09-20
CA1275344C (en) 1990-10-16
BR8706893A (pt) 1988-07-26
EP0272133A3 (en) 1990-03-07
EP0272133B1 (en) 1993-05-05

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