ES2055322T3 - Proceso para preparar acidos carboxilicos. - Google Patents
Proceso para preparar acidos carboxilicos.Info
- Publication number
- ES2055322T3 ES2055322T3 ES90303593T ES90303593T ES2055322T3 ES 2055322 T3 ES2055322 T3 ES 2055322T3 ES 90303593 T ES90303593 T ES 90303593T ES 90303593 T ES90303593 T ES 90303593T ES 2055322 T3 ES2055322 T3 ES 2055322T3
- Authority
- ES
- Spain
- Prior art keywords
- iodides
- methylimidazole
- prepare
- carbon atoms
- carboxilic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- NURQLCJSMXZBPC-UHFFFAOYSA-N 3,4-dimethylpyridine Chemical compound CC1=CC=NC=C1C NURQLCJSMXZBPC-UHFFFAOYSA-N 0.000 abstract 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N 4-methylimidazole Chemical compound CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- LLXWQABBXSMICP-UHFFFAOYSA-M 1-hydroxypyridin-1-ium;iodide Chemical class [I-].O[N+]1=CC=CC=C1 LLXWQABBXSMICP-UHFFFAOYSA-M 0.000 abstract 1
- JBOIAZWJIACNJF-UHFFFAOYSA-N 1h-imidazole;hydroiodide Chemical group [I-].[NH2+]1C=CN=C1 JBOIAZWJIACNJF-UHFFFAOYSA-N 0.000 abstract 1
- VJXRKZJMGVSXPX-UHFFFAOYSA-N 4-ethylpyridine Chemical compound CCC1=CC=NC=C1 VJXRKZJMGVSXPX-UHFFFAOYSA-N 0.000 abstract 1
- YSHMQTRICHYLGF-UHFFFAOYSA-N 4-tert-butylpyridine Chemical compound CC(C)(C)C1=CC=NC=C1 YSHMQTRICHYLGF-UHFFFAOYSA-N 0.000 abstract 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- BJDYCCHRZIFCGN-UHFFFAOYSA-N pyridin-1-ium;iodide Chemical class I.C1=CC=NC=C1 BJDYCCHRZIFCGN-UHFFFAOYSA-N 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pyridine Compounds (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
SE PROVEE UN PROCESO PARA PREPARAR UN ACIDO CARBOXILICO QUE TIENE (N+1) ATOMOS DE CARBONO (P.EJ. ACIDO ACETICO) A PARTIR DE UN ALCOHOL QUE TIENE N ATOMOS DE CARBONO (P.EJ.METANOL) EN FASE GASEOSA, CATALIZANDO LA CARBONILACION CON RODIO. EL PROCESO SE CARACTERIZA POR USAR UN CATALIZADOR ESTABILIZADOR SELECCIONADO DE CIERTAS CLASES DE YODO IMIDAZOLES, YODO ALQUILO PIRIDINO SUSTITUIDO, Y YODO HIDROXIPIRIDINO. SON PREFERIDOS AQUELLOS DERIVADOS DE LAS 2-ETILO-4-METILIMIDAZOL, 4-METILIMIDAZOL, 4-ETILOPIRIDINA, 4-T-BUTILOPIRIDINA O 3,4-LUTIDINO AMINAS POR CUATERNIZACION CON UN GRUPO METILO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898907763A GB8907763D0 (en) | 1989-04-06 | 1989-04-06 | Process for preparing carboxylic acids |
| GB898918588A GB8918588D0 (en) | 1989-08-15 | 1989-08-15 | Process for preparing carboxylic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2055322T3 true ES2055322T3 (es) | 1994-08-16 |
Family
ID=26295177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90303593T Expired - Lifetime ES2055322T3 (es) | 1989-04-06 | 1990-04-04 | Proceso para preparar acidos carboxilicos. |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0391680B1 (es) |
| JP (1) | JP2839367B2 (es) |
| KR (1) | KR0163040B1 (es) |
| AT (1) | ATE107271T1 (es) |
| BR (1) | BR9006285A (es) |
| CA (1) | CA2028821A1 (es) |
| DE (1) | DE69009829T2 (es) |
| ES (1) | ES2055322T3 (es) |
| NO (1) | NO173935C (es) |
| WO (1) | WO1990011991A1 (es) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9021454D0 (en) * | 1990-10-03 | 1990-11-14 | Bp Chem Int Ltd | Process |
| GB9120902D0 (en) * | 1991-10-02 | 1991-11-13 | Bp Chem Int Ltd | Purification process |
| GB9211671D0 (en) * | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
| FR2735399B1 (fr) * | 1995-06-16 | 1997-07-25 | Inst Francais Du Petrole | Nouvelle composition catalytique a base de complexes de metaux de transition et procede pour l'hydrogenation des composes insatures |
| US5731472A (en) * | 1995-12-06 | 1998-03-24 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US6090987A (en) * | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| GB9819079D0 (en) | 1998-09-03 | 1998-10-28 | Bp Chem Int Ltd | Carbonylation process |
| GB9819606D0 (en) | 1998-09-08 | 1998-11-04 | Bp Chem Int Ltd | Carbonylation process |
| JP4160555B2 (ja) | 2002-05-06 | 2008-10-01 | イーストマン ケミカル カンパニー | 連続的カルボニル化方法 |
| US7737298B2 (en) | 2006-06-09 | 2010-06-15 | Eastman Chemical Company | Production of acetic acid and mixtures of acetic acid and acetic anhydride |
| US7582792B2 (en) | 2006-06-15 | 2009-09-01 | Eastman Chemical Company | Carbonylation process |
| US7253304B1 (en) | 2006-06-20 | 2007-08-07 | Eastman Chemical Company | Carbonylation process |
| US7629491B2 (en) * | 2006-06-26 | 2009-12-08 | Eastman Chemical Company | Hydrocarboxylation process |
| TW200930698A (en) | 2008-01-07 | 2009-07-16 | China Petrochemical Dev Corp | Method for manufacturing carboxylic acid anhydride |
| EP2093209A1 (en) | 2008-02-19 | 2009-08-26 | BP Chemicals Limited | Process for the production of acetic acid |
| US7820855B2 (en) * | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| TW201022202A (en) | 2008-12-04 | 2010-06-16 | China Petrochemical Dev Corp | Method for producing carboxylic acid anhydride |
| TW201209034A (en) | 2010-08-31 | 2012-03-01 | China Petrochemical Dev Corp | Production method for carboxylic acid anhydride |
| US9012683B2 (en) | 2010-11-12 | 2015-04-21 | Eastman Chemical Company | Coproduction of acetic acid and acetic anhydride |
| US8637699B2 (en) | 2011-04-15 | 2014-01-28 | Lyondell Chemical Technology, L.P. | Process for the manufacture of acetic acid |
| US8742168B2 (en) | 2011-05-31 | 2014-06-03 | Lyondell Chemical Technology, L.P. | Process for the production of acetic acid |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1058636A (en) * | 1975-03-10 | 1979-07-17 | Nabil Rizkalla | Process for preparing carboxylic acid anhydrides |
| DE3144772A1 (de) * | 1981-11-11 | 1983-05-19 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von essigsaeureanhydrid und essigsaeure |
| DE3371779D1 (en) * | 1982-11-04 | 1987-07-02 | Bp Chem Int Ltd | Process for the preparation of acids |
| GB8404136D0 (en) * | 1984-02-16 | 1984-03-21 | Bp Chem Int Ltd | Carbonylation process |
| CA1228867A (en) * | 1984-05-03 | 1987-11-03 | Celanese Corporation | Methanol carbonylation process |
-
1990
- 1990-04-04 ES ES90303593T patent/ES2055322T3/es not_active Expired - Lifetime
- 1990-04-04 WO PCT/GB1990/000502 patent/WO1990011991A1/en not_active Ceased
- 1990-04-04 EP EP90303593A patent/EP0391680B1/en not_active Expired - Lifetime
- 1990-04-04 CA CA002028821A patent/CA2028821A1/en not_active Abandoned
- 1990-04-04 BR BR909006285A patent/BR9006285A/pt not_active Application Discontinuation
- 1990-04-04 JP JP2505190A patent/JP2839367B2/ja not_active Expired - Lifetime
- 1990-04-04 AT AT90303593T patent/ATE107271T1/de not_active IP Right Cessation
- 1990-04-04 KR KR1019900702566A patent/KR0163040B1/ko not_active Expired - Fee Related
- 1990-04-04 DE DE69009829T patent/DE69009829T2/de not_active Expired - Fee Related
- 1990-12-05 NO NO905267A patent/NO173935C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO905267D0 (no) | 1990-12-05 |
| KR920700187A (ko) | 1992-02-19 |
| AU623002B2 (en) | 1992-04-30 |
| DE69009829T2 (de) | 1994-10-13 |
| JP2839367B2 (ja) | 1998-12-16 |
| EP0391680A1 (en) | 1990-10-10 |
| EP0391680B1 (en) | 1994-06-15 |
| DE69009829D1 (de) | 1994-07-21 |
| KR0163040B1 (ko) | 1999-01-15 |
| BR9006285A (pt) | 1991-08-06 |
| AU5333790A (en) | 1990-11-05 |
| JPH03505331A (ja) | 1991-11-21 |
| CA2028821A1 (en) | 1990-10-07 |
| NO173935B (no) | 1993-11-15 |
| NO173935C (no) | 1994-02-23 |
| ATE107271T1 (de) | 1994-07-15 |
| WO1990011991A1 (en) | 1990-10-18 |
| NO905267L (no) | 1990-12-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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