ES2059176T3 - Catalizadores de oxidacion conteniendo molibdeno, fosforo y vanadio con canales formados de materiales de fibra combustibles. - Google Patents

Catalizadores de oxidacion conteniendo molibdeno, fosforo y vanadio con canales formados de materiales de fibra combustibles.

Info

Publication number
ES2059176T3
ES2059176T3 ES92106755T ES92106755T ES2059176T3 ES 2059176 T3 ES2059176 T3 ES 2059176T3 ES 92106755 T ES92106755 T ES 92106755T ES 92106755 T ES92106755 T ES 92106755T ES 2059176 T3 ES2059176 T3 ES 2059176T3
Authority
ES
Spain
Prior art keywords
oxidation
vanadium
phosphorus
catalysts
oxidation catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92106755T
Other languages
English (en)
Inventor
Ernst Dr Bielmeier
Thomas Dr Haeberle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm GmbH Darmstadt
Original Assignee
Roehm GmbH Darmstadt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm GmbH Darmstadt filed Critical Roehm GmbH Darmstadt
Application granted granted Critical
Publication of ES2059176T3 publication Critical patent/ES2059176T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION CONCIERNE A CATALIZADORES POR OXIDACION CON MOLIBDENO, FOSFORO Y VANADIO COMO ELEMENTOS ESENCIALES EN FORMA DE OXIDO COMO MATERIAL ACTIVO PARA LA OXIDACION DE FASES GASEOSAS DE COMPUESTOS ORGANICOS, EN QUE PARA DARLES FORMA SE ELABORAN MATERIALES FIBROSOS COMBUSTIBLES, COMO FIBRAS DE CARBONO O FIBRAS DE POLIMEROS ORGANICOS, NATURALES O SINTETICOS EN CANTIDADES DE 0,5 A 5% EN PESO REFERIDO AL MATERIAL ACTIVO CATALITICO, FINAMENTE DISTRIBUIDO, Y QUE DESPUES DE QUEMAN EN UN MARGEN DE TEMPERATURA DE 100 A 380 GRADOS C A PARTIR DE LAS FORMAS EN PRESENCIA DE OXIGENO. LOS CATALIZADORES CON SUPERFICIES INTERIORES DE APROX. 0,1 A 5 M2/G MUESTRAN EN LA OXIDACION DE PROPILENO O ISOBUTILENO EN ACROLEINA O METACROLEINA O EN SU OXIDACION POSTERIOR A ACIDO ACRILICO O ACIDO METACRILICO O EN LA OXIHIDROGENACION DE ACIDO ISOBUTILICO O SUS ESTERES EN ACIDO METACRILICO O SUS ESTERES, UN COMPORTAMIENTO DE ACTIVIDAD SELECTIVO Y MEJORADO.
ES92106755T 1991-04-25 1992-04-21 Catalizadores de oxidacion conteniendo molibdeno, fosforo y vanadio con canales formados de materiales de fibra combustibles. Expired - Lifetime ES2059176T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4113423A DE4113423A1 (de) 1991-04-25 1991-04-25 Mit makroporen durchsetzter oxidationskatalysator

Publications (1)

Publication Number Publication Date
ES2059176T3 true ES2059176T3 (es) 1994-11-01

Family

ID=6430285

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92106755T Expired - Lifetime ES2059176T3 (es) 1991-04-25 1992-04-21 Catalizadores de oxidacion conteniendo molibdeno, fosforo y vanadio con canales formados de materiales de fibra combustibles.

Country Status (6)

Country Link
US (1) US5215952A (es)
EP (1) EP0510566B1 (es)
JP (1) JPH05138028A (es)
AT (1) ATE109380T1 (es)
DE (2) DE4113423A1 (es)
ES (1) ES2059176T3 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5550095A (en) * 1992-05-08 1996-08-27 Mitsubishi Rayon Co., Ltd. Process for producing catalyst used for synthesis of methacrylic acid
DE4240085A1 (de) * 1992-11-28 1994-06-01 Roehm Gmbh Katalytische Oxidation von Isobutan zu Methacrylsäure und Methacrolein
FR2716634B1 (fr) * 1994-02-28 1996-04-05 Atochem Elf Sa Système catalytique contenant de l'oxygène, du molybdène, du phosphore et au moins un métal de transition, et son application à l'oxydéshydrogénation d'acides carboxyliques saturés ou de leurs esters.
US5510308A (en) * 1994-10-19 1996-04-23 E. I. Du Pont De Nemours And Company Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation
US6228340B1 (en) 1997-08-25 2001-05-08 The Regents Of The University Of California Method for the production of macroporous ceramics
US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
JP3702710B2 (ja) 1999-06-15 2005-10-05 住友化学株式会社 メタクリル酸製造用触媒およびメタクリル酸の製造方法
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
JP5301110B2 (ja) * 2007-05-15 2013-09-25 三菱レイヨン株式会社 メタクロレインの製造方法
CN103861640B (zh) * 2014-03-13 2015-07-29 万华化学集团股份有限公司 一种杂多酸催化剂及其制备方法
CN105772087B (zh) * 2014-12-26 2019-03-22 上海华谊新材料有限公司 杂多酸盐催化剂及其制备方法
CN109985649B (zh) * 2018-01-02 2021-05-04 上海华谊新材料有限公司 (甲基)丙烯醛氧化催化剂及其制备方法
JP6973618B2 (ja) * 2018-03-14 2021-12-01 三菱ケミカル株式会社 触媒成形体並びにこれを用いた不飽和アルデヒド及び不飽和カルボン酸の製造方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA943944A (en) * 1967-10-27 1974-03-19 Michael C. Chervenak Catalysts, methods of preparation of same and processes for using same
FR1582730A (es) * 1967-10-31 1969-10-03
JPS52138499A (en) * 1976-05-17 1977-11-18 Mitsubishi Chem Ind Ltd Production of heteropolyacid
US4092269A (en) * 1976-10-15 1978-05-30 Monsanto Company Phosphorus-vanadium-oxygen catalysts having a specific pore volume
EP0005769B1 (en) * 1978-05-31 1982-04-21 Nippon Kayaku Kabushiki Kaisha A process for producing methacrolein and methacrylic acid
JPS55124734A (en) * 1979-03-22 1980-09-26 Nippon Kayaku Co Ltd Preparation of methacrylic acid
US4329520A (en) * 1980-03-21 1982-05-11 Union Carbide Corporation Process and catalyst for olefin hydration
DE3145091A1 (de) * 1981-11-13 1983-05-19 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von methacrylsaeure
DE3248600A1 (de) * 1982-12-30 1984-07-12 Röhm GmbH, 6100 Darmstadt Verwendung von mo-v-cu-p-katalysatoren zur oxydehydrierung von isobuttersaeure oder deren estern
JPS60150834A (ja) * 1984-01-17 1985-08-08 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒の製造法
DE3508649A1 (de) * 1985-03-12 1986-09-18 Röhm GmbH, 6100 Darmstadt Heteropolysaeure h(pfeil abwaerts)8(pfeil abwaerts)pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)9(pfeil abwaerts), deren anhydrid pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)5(pfeil abwaerts)und ihre verwendung
JPS62201643A (ja) * 1986-02-28 1987-09-05 Nippon Oil Co Ltd 水素化触媒の製造法
DE3626256A1 (de) * 1986-08-02 1988-02-11 Roehm Gmbh Heteropolymolybdat-gemische und ihre verwendung als katalysatoren
JPH0753686B2 (ja) * 1986-10-27 1995-06-07 三菱レイヨン株式会社 メタクリル酸の製造法
DE3710784A1 (de) * 1987-03-31 1988-10-13 Roehm Gmbh Heteropolysaeure-oxidations-katalysatoren mit verbessertem langzeit-aktivitaets-verhalten
US4968877A (en) * 1988-09-14 1990-11-06 Sensor Frame Corporation VideoHarp
DE3844087A1 (de) * 1988-12-28 1990-07-05 Basf Ag Verfahren zur herstellung von methacrylsaeure durch oxidation von methacrolein
DD284947A5 (de) * 1989-09-28 1990-11-28 Veb Maschinen- Und Apparatebau,Dd Zentralelastisch gelagertes ventilatoraggregat mit spiralgehaeuse und keilriemenantrieb

Also Published As

Publication number Publication date
EP0510566A1 (de) 1992-10-28
EP0510566B1 (de) 1994-08-03
DE4113423A1 (de) 1992-10-29
ATE109380T1 (de) 1994-08-15
US5215952A (en) 1993-06-01
DE59200339D1 (de) 1994-09-08
JPH05138028A (ja) 1993-06-01

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