ES2062524T3 - Co-catalizadores de polimerizacion de compuestos tiolicos. - Google Patents

Co-catalizadores de polimerizacion de compuestos tiolicos.

Info

Publication number
ES2062524T3
ES2062524T3 ES90906994T ES90906994T ES2062524T3 ES 2062524 T3 ES2062524 T3 ES 2062524T3 ES 90906994 T ES90906994 T ES 90906994T ES 90906994 T ES90906994 T ES 90906994T ES 2062524 T3 ES2062524 T3 ES 2062524T3
Authority
ES
Spain
Prior art keywords
polymerization
accelerators
thyolic
compounds
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90906994T
Other languages
English (en)
Inventor
Gualtiero Giovando
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Peter Srl
Akzo NV
Original Assignee
Saint Peter Srl
Akzo NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT8967302A external-priority patent/IT1232851B/it
Priority claimed from IT8967301A external-priority patent/IT1232850B/it
Priority claimed from IT67954A external-priority patent/IT1239005B/it
Priority claimed from IT06810989A external-priority patent/IT1238066B/it
Application filed by Saint Peter Srl, Akzo NV filed Critical Saint Peter Srl
Application granted granted Critical
Publication of ES2062524T3 publication Critical patent/ES2062524T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/687—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
    • C08F299/0442—Catalysts
    • C08F299/0464—Metals or metal containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/66—Mercaptans
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerization Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

ESTA INVENCION SE REFIERE A UNAS COMPOSICIONES ACELERADORAS PARA LA POLIMERIZACION DE RADICALES LIBRES DE POLIESTERES NO SATURADOS Y PARA LA CURA DE POLIESTERES Y POLIURETANOS NO SATURADOS. MAS ESPECIFICAMENTE, SE HACE USO DE COMPLEJOS DE COMPUESTOS TIOLICOS CON SALES METALICAS PARA ACTUAR COMO ACELERADORES. EN OTRAS FORMAS DE ESTA INVENCION, LOS ACELERADORES TAMBIEN INCLUYEN COMPUESTOS CONTENIENDO OXIGENO O COMPUESTOS CONTENIENDO FOSFORO. TAMBIEN SE DESCRIBEN COMPOSICIONES DE RESINA CURABLE QUE INCLUYEN DICHOS ACELERADORES Y LOS PROCESOS DE POLIMERIZACION Y CURACION QUE EMPLEAN ESTOS ACELERADORES.
ES90906994T 1989-04-26 1990-04-26 Co-catalizadores de polimerizacion de compuestos tiolicos. Expired - Lifetime ES2062524T3 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
IT8967302A IT1232851B (it) 1989-04-26 1989-04-26 Composti tiolici attivi come co-catalizzatori per la polimerizzazione di resine poliesteri insature, maleiche, alliliche o epossidiche
IT8967301A IT1232850B (it) 1989-04-26 1989-04-26 Acceleranti per l'indurimento di resine poliesteri insature, maleiche, alliliche ed epossidiche e procedimenti di indurimento che li utlizzano
IT67954A IT1239005B (it) 1989-11-07 1989-11-07 Fosfiti e fosfine organiche come catalizzatori ed acceleranti per l'indurimento di resine epossidiche anche in presenza di mercaptani, sali di litio ed anidridi organiche.
IT06810989A IT1238066B (it) 1989-12-18 1989-12-18 Composti tiolici attivati od inibiti, con gruppi funzionali particolari nella loro molecola o con composti ad essi aggiunti, ad azione complessante e/o sinergica, impiegati come co-catalizzatori od induritori per la polimerizzazione di resine epossidiche e resine insature: poliesteri, maleiche, alliliche, viniliche

Publications (1)

Publication Number Publication Date
ES2062524T3 true ES2062524T3 (es) 1994-12-16

Family

ID=27452968

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90906994T Expired - Lifetime ES2062524T3 (es) 1989-04-26 1990-04-26 Co-catalizadores de polimerizacion de compuestos tiolicos.

Country Status (7)

Country Link
US (1) US5310826A (es)
EP (1) EP0470139B1 (es)
JP (1) JPH04504873A (es)
CA (1) CA2053856A1 (es)
DE (1) DE69005819T2 (es)
ES (1) ES2062524T3 (es)
WO (1) WO1990012826A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6265519B1 (en) 1998-12-08 2001-07-24 Molex Incorporated Thiolamide curing agents
DE102004022106A1 (de) 2004-05-05 2005-11-24 Bayer Ag Verwendung von Metall-Alkandithiole als Vernetzungsagenzien für ungesättigte Kautschuke
EP1705215A1 (en) * 2005-03-23 2006-09-27 DSM IP Assets B.V. Gel time drift-free resin compositions
EP1772502A1 (en) * 2005-10-07 2007-04-11 DSMIP Assets B.V. Oxidatively drying composition to be employed in thin layers comprising 1,2 dioxo compounds
US8349968B2 (en) * 2006-07-06 2013-01-08 Dsm Ip Assets B.V. Method for radically curing
EP2038316B1 (en) * 2006-07-06 2009-12-30 DSM IP Assets B.V. Unsaturated polyester resin or vinyl ester resin compositions
KR20160098237A (ko) * 2013-12-12 2016-08-18 아크조 노벨 케미칼즈 인터내셔널 비.브이. 라디칼 경화형 수지의 경화 방법
WO2015100412A1 (en) * 2013-12-26 2015-07-02 Itaconix Corporation Soluble aqueous compositions of selected polyitaconic acid polymers
US9790395B2 (en) 2013-12-26 2017-10-17 Itaconix Corporation Soluble aqueous compositions of zinc salts of selected polyitaconic acid polymers
EP3481893A1 (de) 2016-07-08 2019-05-15 United Initiators GmbH Beschleunigte härtung von ungesättigten polymerharzen
MX2019002823A (es) * 2016-09-12 2019-09-18 Poly6 Tech Inc Metodo de reciclaje de alto desempeño, de un solo recipiente para residuo de polímero usando síntesis de polímero renovable.
US10975227B2 (en) * 2016-10-26 2021-04-13 Showa Denko K.K. Curing accelerator and radical polymerizable resin composition
CN111741938A (zh) 2018-02-19 2020-10-02 阿科玛股份有限公司 具有延长的开放时间的加速的过氧化物固化的树脂组合物
JP7329350B2 (ja) * 2019-03-29 2023-08-18 株式会社ダイセル 硬化性エポキシ樹脂組成物
EP4775555A1 (de) * 2025-01-13 2026-07-15 Hilti Aktiengesellschaft Härterzusammensetzung mit einem thiol für radikalisch härtbare verbindungen und deren verwendung
CN119978493B (zh) * 2025-03-17 2025-09-05 山东光轩新材料有限公司 一种无色透明耐黄变玻纤增强环氧树脂预浸料及其制备方法

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE607559A (es) * 1960-08-26
US3291776A (en) * 1962-10-26 1966-12-13 Shell Oil Co Process for curing polyepoxides with polymercaptans
US3318974A (en) * 1965-03-23 1967-05-09 Bell Telephone Labor Inc Unsaturated polyester curing system consisting of cumene hydroperoxide, methylethyl ketone peroxide and thioglycolic acid
US3553283A (en) * 1967-06-29 1971-01-05 Phillips Petroleum Co Epoxy resin cured with polymercaptan ester as olefin polymer coating
GB1170983A (en) * 1967-08-04 1969-11-19 Bp Chem Int Ltd Process for the Production of Cured Products.
US3626031A (en) * 1968-06-04 1971-12-07 Atlantic Richfield Co Vinyl halide polymer stabilized with partial ester salt of maleic anhydride-vinyl compound polymer
DE2025410C3 (de) * 1970-05-25 1978-04-13 Bayer Ag, 5090 Leverkusen Verfahren zum Härten ungesättigter Polyesterform- und -Überzugsmassen
US3839494A (en) * 1970-11-16 1974-10-01 Dow Chemical Co Thiol-diene adducts as epoxy resin curing agents
US4120875A (en) * 1974-08-26 1978-10-17 M&T Chemicals Inc. Novel curing agents derived from organothiostannoic acids
US4092293A (en) * 1976-06-24 1978-05-30 Diamond Shamrock Corporation Polymercaptans for curing epoxy resins and method of preparation thereof
DE2901685A1 (de) * 1978-01-20 1979-07-26 Ciba Geigy Ag Epoxidhaltige massen und deren polymerisation
US4153586A (en) * 1978-03-13 1979-05-08 Ppg Industries, Inc. Process of making epoxy resins modified with mercaptocarboxylates
US4177173A (en) * 1978-12-20 1979-12-04 Diamond Shamrock Corporation Polyepoxide curing by polymercaptans catalyzed by dimethylamino alkyl ethers
JPS5740524A (en) * 1980-08-25 1982-03-06 Toshiba Corp Epoxy resin composition
US4329263A (en) * 1980-12-01 1982-05-11 Tenneco Chemicals, Inc. Accelerator systems for polyester resin compositions
US4380605A (en) * 1981-09-21 1983-04-19 Pennwalt Corporation Room temperature crosslinking unsaturated polyester resins
US4446264A (en) * 1982-04-15 1984-05-01 The Goodyear Tire & Rubber Company Synergistic antioxidant mixtures
JPS59126430A (ja) * 1983-01-07 1984-07-21 Denki Kagaku Kogyo Kk 半導体封止用エポキシ樹脂組成物
US4571420A (en) * 1984-02-17 1986-02-18 Rohm And Haas Company Quick-cure, flexible polymer composition
EP0160621B1 (de) * 1984-04-28 1989-08-09 Ciba-Geigy Ag Härtbare Zusammensetzungen
US4663072A (en) * 1984-12-24 1987-05-05 Ford Motor Company Acid anhydride mixtures in paste form useful for curing epoxy resins and a dual catalyst system therefor
JPS62212418A (ja) * 1986-03-13 1987-09-18 Mitsubishi Petrochem Co Ltd 一液性エポキシ樹脂組成物
JPS62257936A (ja) * 1986-05-02 1987-11-10 Showa Highpolymer Co Ltd 硬化可能な組成物
JPS63186727A (ja) * 1987-01-29 1988-08-02 Kashima Kogyo Kk ゴム状弾性を有するエポキシ樹脂組成物
JPH0784512B2 (ja) * 1987-06-24 1995-09-13 三菱電機株式会社 半導体封止用エポキシ樹脂組成物
JPH01174518A (ja) * 1987-12-28 1989-07-11 Mitsui Petrochem Ind Ltd トナー用エポキシ樹脂およびこれをバインダー樹脂とする静電荷像現像用トナー
US4879414A (en) * 1988-02-17 1989-11-07 Henkel Corporation Polythiols and use as epoxy resin curing agents
JPH01294726A (ja) * 1988-05-20 1989-11-28 Mitsubishi Petrochem Co Ltd 一液性エポキシ樹脂組成物

Also Published As

Publication number Publication date
JPH04504873A (ja) 1992-08-27
EP0470139B1 (en) 1994-01-05
WO1990012826A1 (en) 1990-11-01
US5310826A (en) 1994-05-10
DE69005819T2 (de) 1994-07-28
CA2053856A1 (en) 1990-10-27
DE69005819D1 (de) 1994-02-17
EP0470139A1 (en) 1992-02-12

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