ES2063078T3 - Procedimiento para la obtencion de materias sinteticas celulares segun el procedimiento de poliadicion de poliisocianato mediante una emulsion estable al almacenaje que contiene propulsantes y estas emulsiones. - Google Patents
Procedimiento para la obtencion de materias sinteticas celulares segun el procedimiento de poliadicion de poliisocianato mediante una emulsion estable al almacenaje que contiene propulsantes y estas emulsiones.Info
- Publication number
- ES2063078T3 ES2063078T3 ES89112035T ES89112035T ES2063078T3 ES 2063078 T3 ES2063078 T3 ES 2063078T3 ES 89112035 T ES89112035 T ES 89112035T ES 89112035 T ES89112035 T ES 89112035T ES 2063078 T3 ES2063078 T3 ES 2063078T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- emulsions
- ferments
- polyadition
- polyisocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000839 emulsion Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 229920001228 polyisocyanate Polymers 0.000 title abstract 2
- 239000005056 polyisocyanate Substances 0.000 title abstract 2
- 239000000463 material Substances 0.000 title 1
- 239000003380 propellant Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910018503 SF6 Inorganic materials 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- SFZCNBIFKDRMGX-UHFFFAOYSA-N sulfur hexafluoride Chemical compound FS(F)(F)(F)(F)F SFZCNBIFKDRMGX-UHFFFAOYSA-N 0.000 abstract 1
- 229960000909 sulfur hexafluoride Drugs 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
- C08J9/148—Halogen containing compounds containing carbon and halogen atoms only perfluorinated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
ESTE INVENTO CONSISTE EN UN PROCEDIMIENTO PARA LA PRODUCCION DE PLASTICOS QUE CONTIENEN CELULAS DE POLIISOCIANATO-POLIADICION, MEDIANTE LA TRANSFORMACION DE: A) POLIISOCIANATOS ORGANICOS U ORGANICOS MODIFICADOS, CON B) AL MENOS UNA CADENA DE ELEVADO PESO MOLECULAR, CON AL MENOS DOS ATOMOS DE HIDROGENOS REACTIVOS Y, SI HACE AL CASO, C) MEDIOS DE BAJA MOLECULARIDAD PARA EL ALARGAMIENTO O LA RETICULACION DE CADENAS, EN PRESENCIA DE D)FERMENTOS, E)CATALIZADORES, F)MEDIOS AUXILIARES O SUSTANCIAS ADICIONALES. EN EL APARTADO (D), LOS FERMENTOS SON DE BAJO PUNTO DE EBULLICION; EN (A-C), LAS SUSTANCIAS SON HIDROCARBUROS FLUORADOS O PERFLUORADOS CON 3-8 ATOMOS DE CARBONO DUROS O INSOLUBLES, HEXAFLUORURO DE AZUFRE, O MEZCLAS DE LOS COMPUESTOS ANTERIORES, DE MODO QUE SE OBTIENEN EMULSIONES DE COMPONENTES DE LOS APARTADOS (B) Y (C) O BIEN (A) Y (B). DE MODO QUE SE FORMAN EMULSIONES INALTERABLES AL ALMACENAMIENTO Y QUE CONTIENEN FERMENTOS, MEZCLANDO LOS FERMENTOS (D) CON LA MEZCLA O EMULSION FORMADA POR (A), POR (B) O POR (B) Y (C).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3824354A DE3824354A1 (de) | 1988-07-19 | 1988-07-19 | Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren mittels lagerstabiler, treibmittelhaltiger emulsionen und diese emulsionen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2063078T3 true ES2063078T3 (es) | 1995-01-01 |
Family
ID=6358954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES89112035T Expired - Lifetime ES2063078T3 (es) | 1988-07-19 | 1989-07-01 | Procedimiento para la obtencion de materias sinteticas celulares segun el procedimiento de poliadicion de poliisocianato mediante una emulsion estable al almacenaje que contiene propulsantes y estas emulsiones. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4972002A (es) |
| EP (1) | EP0351614B1 (es) |
| JP (1) | JP2921863B2 (es) |
| AT (1) | ATE113303T1 (es) |
| CA (1) | CA1328560C (es) |
| DE (2) | DE3824354A1 (es) |
| ES (1) | ES2063078T3 (es) |
Families Citing this family (111)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3903336A1 (de) * | 1989-02-04 | 1990-08-09 | Bayer Ag | Verwendung von c(pfeil abwaerts)3(pfeil abwaerts)- bis c(pfeil abwaerts)5(pfeil abwaerts)-polyfluoralkanen als treibgase |
| US4972003A (en) * | 1989-05-10 | 1990-11-20 | The Dow Chemical Company | Foaming system for rigid urethane and isocyanurate foams |
| DE3930824A1 (de) * | 1989-06-28 | 1991-02-28 | Bosch Siemens Hausgeraete | Hartschaumstoff sowie verfahren zur herstellung desselben |
| US5585112A (en) | 1989-12-22 | 1996-12-17 | Imarx Pharmaceutical Corp. | Method of preparing gas and gaseous precursor-filled microspheres |
| US20020150539A1 (en) | 1989-12-22 | 2002-10-17 | Unger Evan C. | Ultrasound imaging and treatment |
| US6088613A (en) | 1989-12-22 | 2000-07-11 | Imarx Pharmaceutical Corp. | Method of magnetic resonance focused surgical and therapeutic ultrasound |
| US5542935A (en) | 1989-12-22 | 1996-08-06 | Imarx Pharmaceutical Corp. | Therapeutic delivery systems related applications |
| US4997706A (en) * | 1990-02-09 | 1991-03-05 | The Dow Chemical Company | Foaming system for closed-cell rigid polymer foam |
| DE4006952A1 (de) * | 1990-03-06 | 1991-09-12 | Hoechst Ag | Verfahren zur herstellung von schaumstoffen mit hilfe von treibmitteln, die fluoralkane und fluorierte ether enthalten, sowie nach diesem verfahren erhaeltliche schaumstoffe |
| AU7312491A (en) * | 1990-03-23 | 1991-10-21 | E.I. Du Pont De Nemours And Company | Polymer foams containing blocking agents |
| US5516811A (en) * | 1990-03-23 | 1996-05-14 | E. I. Du Pont De Nemours And Company | Polymer foams containing blocking agents |
| JPH05505634A (ja) * | 1990-03-23 | 1993-08-19 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ガスバリアー樹脂を含むポリマーフォーム |
| IT1243425B (it) * | 1990-09-26 | 1994-06-10 | Montedipe Srl | Procedimento per la preparazione di corpi formati in schiume poliuretaniche e corpi formati cosi' ottenuti. |
| US5286759A (en) * | 1991-03-08 | 1994-02-15 | The Dow Chemical Company | Foaming system for rigid urethane and isocyanurate foams |
| US5238970A (en) * | 1991-04-03 | 1993-08-24 | Imperial Chemical Industries, Plc | Manufacture of rigid foams and compositions therefor |
| AU654333B2 (en) * | 1991-04-03 | 1994-11-03 | Huntsman Ici Chemicals Llc | Manufacture of cellular polymers and compositions therefor |
| US5240965A (en) * | 1991-04-03 | 1993-08-31 | Imperial Chemical Industries Plc | Manufacture of cellular polymers and compositions therefor |
| US5205290A (en) | 1991-04-05 | 1993-04-27 | Unger Evan C | Low density microspheres and their use as contrast agents for computed tomography |
| US5254400A (en) * | 1991-04-18 | 1993-10-19 | E. I. Du Pont De Nemours And Company | Microcellular and ultramicrocellular materials containing hydrofluorocarbon inflatants |
| US5489619A (en) * | 1991-08-27 | 1996-02-06 | Bp Chemicals Limited | Process for producing improved phenolic foams from phenolic resole resins |
| US5162384A (en) * | 1991-09-13 | 1992-11-10 | Minnesota Mining And Manufacturing Company | Making foamed plastic containing perfluorinated heterocyclic blowing agent |
| US5210106A (en) * | 1991-10-04 | 1993-05-11 | Minnesota Mining And Manufacturing Company | Fine-celled plastic foam containing fluorochemical blowing agent |
| US5211873A (en) * | 1991-10-04 | 1993-05-18 | Minnesota Mining And Manufacturing Company | Fine-celled plastic foam containing fluorochemical blowing agent |
| JPH05125138A (ja) * | 1991-11-05 | 1993-05-21 | Onkyo Corp | 発泡ウレタン及びこれを用いたスピーカエツジ |
| US5439948A (en) * | 1991-11-20 | 1995-08-08 | Imperial Chemical Industries Plc | Process for cellular polymeric products |
| DE4205934A1 (de) * | 1992-02-27 | 1993-09-02 | Basf Ag | Verfahren zur herstellung von fluorchlorkohlenwasserstoff freien, niedrigdichten polyurethan-weichschaumstoffen und weichelastischen polyurethan-formschaumstoffen sowie hierfuer verwendbare, mit urethangruppen modifizierte polyisocyanatmischungen auf diphenylmethan-diisocyanatbasis |
| DE4212362A1 (de) * | 1992-04-13 | 1993-10-14 | Linde Ag | Herstellung aufgeschäumter Kunststoffe |
| ES2088679T5 (es) * | 1992-08-04 | 2006-06-16 | Bayer Ag | Uso de compuestos que presentan atomos de hidrogeno activos. |
| DE4225765C1 (es) * | 1992-08-04 | 1993-09-16 | Bayer Ag, 51373 Leverkusen, De | |
| US5428104A (en) * | 1992-11-27 | 1995-06-27 | Imperial Chemical Industries Plc | Polyol compositions |
| DE69324784T2 (de) * | 1992-12-30 | 1999-10-21 | Imperial Chemical Industries Plc, London | Verfahren zur Herstellung von Hartschaumstoffen |
| CA2107274C (en) * | 1992-12-31 | 1998-11-03 | Valeri L. Valoppi | 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles |
| US5278196A (en) * | 1993-03-25 | 1994-01-11 | Great Lakes Chemical Corp. | Hydrofluorocarbon compositions as blowing agents for cellular plastics |
| GB9403334D0 (en) * | 1993-04-23 | 1994-04-13 | Ici Plc | Process for rigid polyurethane foams |
| US7083572B2 (en) | 1993-11-30 | 2006-08-01 | Bristol-Myers Squibb Medical Imaging, Inc. | Therapeutic delivery systems |
| GB9324510D0 (en) * | 1993-11-30 | 1994-01-19 | Ici Plc | Process for rigid polyurethane foams |
| US5539008A (en) * | 1993-12-29 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Foamable composition containing unsaturated perfluorochemical blowing agent |
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| KR0180613B1 (en) | 1994-09-07 | 1999-05-15 | Matsushita Electric Industrial Co Ltd | Thermal insulating foamed material and method for manufacturing the same |
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| KR20000053020A (ko) | 1996-11-04 | 2000-08-25 | 네바드 에드워드 죤 | 경질 폴리우레탄 발포체 |
| CA2218819A1 (en) * | 1996-11-18 | 1998-05-18 | The Celotex Corporation | Foams made with polyester polyols and hydrofluorocarbons as blowing agents |
| US6090800A (en) | 1997-05-06 | 2000-07-18 | Imarx Pharmaceutical Corp. | Lipid soluble steroid prodrugs |
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| US6416740B1 (en) | 1997-05-13 | 2002-07-09 | Bristol-Myers Squibb Medical Imaging, Inc. | Acoustically active drug delivery systems |
| US5817706A (en) * | 1997-08-27 | 1998-10-06 | Owens Corning Fiberglas Technology, Inc. | Manufacture of non-CFC cellular resol foams using perflurinated ethers |
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| TWI385189B (zh) * | 2003-11-26 | 2013-02-11 | Asahi Glass Co Ltd | 軟質聚胺基甲酸酯泡沫,其製造方法,及使用其之汽車用座墊 |
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| BRPI0403713B1 (pt) * | 2004-08-30 | 2021-01-12 | Universidade Estadual De Campinas - Unicamp | processo de fabricação de um pigmento branco baseado na síntese de partículas ocas de ortofosfato ou polifosfato de alumínio |
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| EP2072548B1 (de) | 2007-12-19 | 2017-02-22 | Basf Se | Verfahren zur Herstellung von Urethangruppen und Isocyanuratgruppen enthaltenden Hartschaumstoffen |
| US9023145B2 (en) | 2008-02-12 | 2015-05-05 | Bunge Amorphic Solutions Llc | Aluminum phosphate or polyphosphate compositions |
| WO2009138379A2 (de) | 2008-05-13 | 2009-11-19 | Basf Se | Verfahren zur herstellung von polyoldispersionen |
| DE102009045648A1 (de) | 2008-08-21 | 2010-04-29 | Basf Se | Mischungen von Formkörpern und ihre Verwendung |
| US20100056660A1 (en) * | 2008-08-29 | 2010-03-04 | Bayer Materialscience Llc | Decorative molded foams with good fire retardant properties |
| DE102009045647A1 (de) | 2008-10-22 | 2010-05-06 | Basf Se | Formkörper und ihre Verwendung in Staubsaugern |
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| US9951174B2 (en) | 2015-05-20 | 2018-04-24 | Covestro Llc | Polyol compositions, a process for the production of these polyol compositions, and their use in the production of open celled polyurethane foams having high airflow |
| US10767008B2 (en) | 2017-01-16 | 2020-09-08 | Covestro Llc | Polymer polyols comprising amine based polyether polyols and a process for preparing these polymer polyols |
| WO2018169833A1 (en) | 2017-03-15 | 2018-09-20 | Covestro Llc | Viscoelastic polyurethane foams with reduced temperature sensitivity |
| WO2019053143A1 (en) | 2017-09-13 | 2019-03-21 | Basf Se | POLYURETHANE AND MELAMINE THERAPEUTIC MOUSES BY TRIAXIAL COMPRESSION |
| US10766998B2 (en) | 2017-11-21 | 2020-09-08 | Covestro Llc | Flexible polyurethane foams |
| KR102787398B1 (ko) | 2017-12-05 | 2025-03-27 | 바스프 에스이 | 우레탄 기 및 이소시아누레이트 기를 포함하는 연속 기포 경질 폼의 제조 방법 |
| US10479862B2 (en) | 2017-12-07 | 2019-11-19 | Covestro Llc | Amine based polymer polyol stabilizers |
| US10526484B2 (en) | 2017-12-20 | 2020-01-07 | Covestro Llc | Dithiocarbonate containing polyols as polymer polyol stabilizers |
| US10793692B2 (en) | 2018-10-24 | 2020-10-06 | Covestro Llc | Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers |
| US20240025094A1 (en) | 2019-10-09 | 2024-01-25 | Covestro Llc | Methods, systems and computer program products for producing polyurethane foam products using optical and infrared imaging |
| CN111911716A (zh) * | 2020-08-13 | 2020-11-10 | 江苏嘉德管道工程有限公司 | 一种深冷工况预制保冷管 |
| US11572433B2 (en) | 2021-03-12 | 2023-02-07 | Covestro Llc | In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation |
| US11718705B2 (en) | 2021-07-28 | 2023-08-08 | Covestro Llc | In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams |
| US20230039276A1 (en) | 2021-07-28 | 2023-02-09 | Covestro Llc | Novel polyether polyol blends, a process for their preparation, foams prepared from these polyether polyol blends and a process for their preparation |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3391093A (en) * | 1959-04-01 | 1968-07-02 | Gen Tire & Rubber Co | Polyester-polyurethane foams and method of making same |
| CH572269A5 (es) * | 1972-07-20 | 1976-01-30 | Bbc Brown Boveri & Cie | |
| US3993833A (en) * | 1976-01-19 | 1976-11-23 | Minnesota Mining And Manufacturing Company | Polyurethane foam-backed pressure-sensitive adhesive tape |
| DE2738719A1 (de) * | 1977-08-27 | 1979-03-08 | Bayer Ag | Verfahren zur herstellung von geschaeumten kunststoffen |
| KR101841289B1 (ko) | 2009-10-20 | 2018-03-22 | 섀플러 테크놀로지스 아게 운트 코. 카게 | 블라인드 리베팅을 이용한 피스톤 플레이트 연결 |
-
1988
- 1988-07-19 DE DE3824354A patent/DE3824354A1/de not_active Withdrawn
-
1989
- 1989-07-01 ES ES89112035T patent/ES2063078T3/es not_active Expired - Lifetime
- 1989-07-01 AT AT89112035T patent/ATE113303T1/de not_active IP Right Cessation
- 1989-07-01 DE DE58908555T patent/DE58908555D1/de not_active Expired - Lifetime
- 1989-07-01 EP EP89112035A patent/EP0351614B1/de not_active Expired - Lifetime
- 1989-07-03 US US07/374,829 patent/US4972002A/en not_active Expired - Lifetime
- 1989-07-06 CA CA000604951A patent/CA1328560C/en not_active Expired - Fee Related
- 1989-07-14 JP JP1180636A patent/JP2921863B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4972002A (en) | 1990-11-20 |
| JPH0286635A (ja) | 1990-03-27 |
| DE58908555D1 (de) | 1994-12-01 |
| EP0351614B1 (de) | 1994-10-26 |
| EP0351614A3 (en) | 1990-05-16 |
| JP2921863B2 (ja) | 1999-07-19 |
| CA1328560C (en) | 1994-04-19 |
| EP0351614A2 (de) | 1990-01-24 |
| DE3824354A1 (de) | 1990-01-25 |
| ATE113303T1 (de) | 1994-11-15 |
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