ES2067124T3 - Copolimero de injerto de varias etapas y su empleo para la obtencion de masas de moldeo de pvc. - Google Patents

Copolimero de injerto de varias etapas y su empleo para la obtencion de masas de moldeo de pvc.

Info

Publication number
ES2067124T3
ES2067124T3 ES91119431T ES91119431T ES2067124T3 ES 2067124 T3 ES2067124 T3 ES 2067124T3 ES 91119431 T ES91119431 T ES 91119431T ES 91119431 T ES91119431 T ES 91119431T ES 2067124 T3 ES2067124 T3 ES 2067124T3
Authority
ES
Spain
Prior art keywords
sub
weight
monomer
minimum
emulsion polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91119431T
Other languages
English (en)
Inventor
Hans-Helmut Dr Goertz
Rainer Dr Nolte
Guenter Dr Hatzmann
Werner Dr Oschmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2067124T3 publication Critical patent/ES2067124T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/22Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L27/24Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

COPOLIMERIZADOS DE INJERTO, QUE SE PUEDEN OBTENER POR: A) POLIMERIZACION POR EMULSION EN UN 5 A 20% EN PESO DE UNA MEZCLA DE MONOMEROS DE A SUB 1) 60-79 % EN PESO DE UN MONOMERO VINILAROMATICO, COMO MINIMO A SUB 2) 21-40% EN PESO DE UN NITRILO ETILENICO INSATURADO, COMO MINIMO A SUB 3) 0-10% EN PESO DE UN MONOMERO ETILENICO INSATURADO DOS O MAS VECES, COMO MINIMO A SUB 4) 0-5% EN PESO DE OTRO MONOMERO MAS, COMO MINIMO B) LUEGO, POLIMERIZACION POR EMULSION, EN PRESENCIA DEL POLIMERIZADO POR EMULSION OBTENIDO SEGUN LA ETAPA A), DE 50-75% EN PESO DE UNA MEZCLA DE MONOMEROS DE B SUB 1) 75-100% EN PESO DE UN DIENO CONJUGADO, COMO MINIMO B SUB 2) 0-25% EN PESO DE UN MONOMERO VINILAROMATICO O NITRILO INSATURADO, COMO MINIMO B SUB 3) 0-10% EN PESO DE UN MONOMERO ETILENICO INSATURADO UNA O MAS VECES, COMO MINIMO B SUB 4) 0-5% EN PESO DE UN SEGUNDO MONOMERO, COMO MINIMO C) LUEGO, POLIMERIZACION POR EMULSION, EN PRESENCIA DEL POLIMERIZADO POR EMULSION OBTENIDO EN LA ETAPA B), DE 5-45% EN PESO DE UNA MEZCLA DE MONOMEROS DE C SUB 1) 40-80% EN PESO DE UN MONOMERO VINILAROMATICO, COMO MINIMO C SUB 2) 5-35% EN PESO DE UN NITRILO ETILENICO INSATURADO, COMO MINIMO C SUB 3) 0-35% EN PESO DE UN C SUB 1-C SUB 18-ALQUILMETACRILATO C SUB 4) 0-10% EN PESO DE UN MONOMERO ETILENICO INSATURADO UNA O MAS VECES, COMO MINIMO C SUB 5) 0-25% EN PESO DE UN C SUB 1-C SUB 18-ALQUILACRILATO, COMO MINIMO , Y D) LUEGO, POLIMERIZACION POR EMULSION, EN PRESENCIA DEL POLIMERIZADO POR EMULSION OBTENIDO EN LA ETAPA C), DE 0-5% EN PESO DE UNA MEZCLA DE MONOMEROS DE D SUB 1) 60-100% EN PESO DE UN C SUB 1-C SUB 4-ALQUILMETACRILATO, COMO MINIMO D SUB 2) 0-5% EN PESO DE UN MONOMERO ETILENICO INSATURADO UNA O MAS VECES, COMO MINIMO D SUB 3) 0-40% EN PESO DE UN SEGUNDO MONOMERO, COMO MINIMO DE TAL MODO QUE LOS PESOS PORCENTUALES DE LAS MEZCLAS AÑADIDAS EN LAS ETAPAS A) A D) SE REFIEREN AL POLIMERIZADO POR INJERTO, Y QUE JUNTOS SUMAN EL 100% EN PESO.
ES91119431T 1990-11-24 1991-11-14 Copolimero de injerto de varias etapas y su empleo para la obtencion de masas de moldeo de pvc. Expired - Lifetime ES2067124T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4037439A DE4037439A1 (de) 1990-11-24 1990-11-24 Mehrstufiges pfropfcopolymerisat und seine verwendung zur herstellung von pvc-formmassen

Publications (1)

Publication Number Publication Date
ES2067124T3 true ES2067124T3 (es) 1995-03-16

Family

ID=6418860

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91119431T Expired - Lifetime ES2067124T3 (es) 1990-11-24 1991-11-14 Copolimero de injerto de varias etapas y su empleo para la obtencion de masas de moldeo de pvc.

Country Status (3)

Country Link
EP (1) EP0489288B1 (es)
DE (2) DE4037439A1 (es)
ES (1) ES2067124T3 (es)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL128410C (es) * 1965-12-10
DE2244519C2 (de) * 1971-09-29 1987-04-23 Rohm And Haas Co., Philadelphia, Pa. Pfropfpolymermasse und ihre Verwendung
JPS5938246B2 (ja) * 1976-06-25 1984-09-14 三菱レイヨン株式会社 多層構造重合体組成物の製造法
DE3843371A1 (de) * 1988-12-23 1990-07-05 Basf Ag Pfropfpolymerisate
DE3901448A1 (de) * 1989-01-19 1990-07-26 Basf Ag Emulsionscopolymerisate

Also Published As

Publication number Publication date
EP0489288B1 (de) 1995-01-25
EP0489288A1 (de) 1992-06-10
DE4037439A1 (de) 1992-05-27
DE59104405D1 (de) 1995-03-09

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