ES2075493T3 - Copolimero de injerto multietapa y su empleo para la obtencion de masas de moldeo transparentes de pvc. - Google Patents

Copolimero de injerto multietapa y su empleo para la obtencion de masas de moldeo transparentes de pvc.

Info

Publication number
ES2075493T3
ES2075493T3 ES92102913T ES92102913T ES2075493T3 ES 2075493 T3 ES2075493 T3 ES 2075493T3 ES 92102913 T ES92102913 T ES 92102913T ES 92102913 T ES92102913 T ES 92102913T ES 2075493 T3 ES2075493 T3 ES 2075493T3
Authority
ES
Spain
Prior art keywords
weight
sub
monomer
ethylenically
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92102913T
Other languages
English (en)
Inventor
Hans Helmut Dr Goertz
Guenter Dr Hatzmann
Werner Dr Oschmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2075493T3 publication Critical patent/ES2075493T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902Core-shell

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

LA INVENCION SE REFIERE A UN COPOLIMERIZADO PROPF QUE SE OBTIENE POR A) POLIMERIZACION DE EMULSION DE 5 A 35% DEL PESO DE UNA MEZCLA DE MONOMEROS DE A SUB 1) 60-80% DEL PESO DE AL MENOS UN MONOMERO AROMATICO DE VINILO A SUB 2) 20-40% DEL PESO DE AL MENOS UN NITRILO ETILENICAMENTE NO SATURADO A SUB 3) 0-10% DEL PESO DE AL MENOS UN MONOMERO ETILENICAMENTE NO SATURADO DOS O MAS VECES Y B) UNA SIGUIENTE POLIMERIZACION DE EMULSION EN PRESENCIA DEL POLIMERIZADO EN EMULSION OBTENIDO TRAS LA FASE A) DE 20-45% DEL PESO DE UNA MEZCLA DE MONOMEROS DE B SUB 1) 50-75% DEL PESO DE AL MENOS UN MONOMERO AROMATICO DE VINILO, B SUB 2) 25-50% DEL PESO DE AL MENOS UN ALQUILACRILATO DE 1 A 18 CARBONOS B SUB 3) 0-10% DEL PESO DE AL MENOS UN MONOMERO ETILENICAMENTE NO SATURADO DOS O MAS VECES Y C) UNA SIGUIENTE POLIMERIZACION DE EMULSION EN PRESENCIA DEL POLIMERIZADO EN EMULSION OBTENIDO TRAS LA FASE B) DE 5-35% DEL PESO DE UNA MEZCLA DE MONOMEROS DE C SUB 1) 60-80% DEL PESO DE AL MENOS UN MONOMERO AROMATICO DE VINILO, C SUB 2) 20-40% DEL PESO DE AL MENOS UN NITRILO ETILENICAMENTE NO SATURADO , C SUB 3) 0-10% DEL PESO DE AL MENOS UN MONOMERO ETILENICAMENTE NO SATURADO DOS O MAS VECES Y D) UNA SIGUIENTE POLIMERIZACION DE EMULSION EN PRESENCIA DEL POLIMERIZADO EN EMULSION OBTENIDO TRAS LA FASE C) DE 15-45% DEL PESO DE UNA MEZCLA DE MONOMEROS DE D SUB 1) 80-99,9% DEL PESO DE AL MENOS UN ALQUILACRILATO DE 1 A 18 CARBONOS D SUB 2) 0,1-10% DEL PESO DE AL MENOS UN MONOMERO ETILENICAMENTE NO SATURADO DOS O MAS VECES.
ES92102913T 1991-03-05 1992-02-21 Copolimero de injerto multietapa y su empleo para la obtencion de masas de moldeo transparentes de pvc. Expired - Lifetime ES2075493T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4106909A DE4106909A1 (de) 1991-03-05 1991-03-05 Mehrstufiges pfropfcopolymerisat und seine verwendung zur herstellung transparenter pvc-formmassen

Publications (1)

Publication Number Publication Date
ES2075493T3 true ES2075493T3 (es) 1995-10-01

Family

ID=6426468

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92102913T Expired - Lifetime ES2075493T3 (es) 1991-03-05 1992-02-21 Copolimero de injerto multietapa y su empleo para la obtencion de masas de moldeo transparentes de pvc.

Country Status (4)

Country Link
US (1) US5247025A (es)
EP (1) EP0502375B1 (es)
DE (2) DE4106909A1 (es)
ES (1) ES2075493T3 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5306776A (en) * 1992-05-06 1994-04-26 Sumitomo Chemical Company, Limited Multilayered polymer

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3971835A (en) * 1970-07-17 1976-07-27 Rohm And Haas Company Vinyl halide polymer impact modifiers
JPS57212246A (en) * 1981-06-23 1982-12-27 Kureha Chem Ind Co Ltd Vinyl chloride resin composition
CA1188442A (en) * 1981-12-21 1985-06-04 Theodore D. Goldman Diene/acrylate base impact modifier for pvc
US4397992A (en) * 1982-04-21 1983-08-09 Wyrough And Loser, Inc. Predispersed liquid or low melting solid peroxide vulcanizing agent or coagent compositions
IE57758B1 (en) * 1983-08-31 1993-03-24 Mitsubishi Rayon Co Impact modifier and thermoplastic resin compositions using the same
JPH0699666B2 (ja) * 1986-04-18 1994-12-07 日本ペイント株式会社 複合三次元化樹脂粒子ならびにその製法
JPS63199255A (ja) * 1987-02-13 1988-08-17 Kureha Chem Ind Co Ltd 塩化ビニル系樹脂組成物
DE3843371A1 (de) * 1988-12-23 1990-07-05 Basf Ag Pfropfpolymerisate
DE3901448A1 (de) * 1989-01-19 1990-07-26 Basf Ag Emulsionscopolymerisate

Also Published As

Publication number Publication date
EP0502375B1 (de) 1995-08-23
DE59203331D1 (de) 1995-09-28
DE4106909A1 (de) 1992-09-10
US5247025A (en) 1993-09-21
EP0502375A1 (de) 1992-09-09

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