ES2068575T3 - TABLETS OF CLEANING AGENTS FREE OF PHOSPHATE, BIFUNCTIONAL, STABLE FOR MACHINE SCRUBBING OF THE TABLEWARE. - Google Patents
TABLETS OF CLEANING AGENTS FREE OF PHOSPHATE, BIFUNCTIONAL, STABLE FOR MACHINE SCRUBBING OF THE TABLEWARE.Info
- Publication number
- ES2068575T3 ES2068575T3 ES91906795T ES91906795T ES2068575T3 ES 2068575 T3 ES2068575 T3 ES 2068575T3 ES 91906795 T ES91906795 T ES 91906795T ES 91906795 T ES91906795 T ES 91906795T ES 2068575 T3 ES2068575 T3 ES 2068575T3
- Authority
- ES
- Spain
- Prior art keywords
- bifunctional
- phosphate
- stable
- tablets
- tableware
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000001588 bifunctional effect Effects 0.000 title abstract 2
- 229910019142 PO4 Inorganic materials 0.000 title 1
- 239000012459 cleaning agent Substances 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title 1
- 239000010452 phosphate Substances 0.000 title 1
- 238000005201 scrubbing Methods 0.000 title 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 239000003599 detergent Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000004851 dishwashing Methods 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 150000004690 nonahydrates Chemical class 0.000 abstract 1
- 150000004686 pentahydrates Chemical class 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Stable, bifunctional, phosphate-free detergent tablets for use in dishwashing machines contain silicate, low-foam nonionic tensides, organic complex builders, bleaches and water. The organic complex builder is a granular alkaline detergent additive, consisting of (a) sodium salts of at least one (meth)acrylic acid homopolymer or copolymer, (b) sodium carbonate, (c) sodium sulphate, and (d) water. The silicate is anhydrous sodium metasilicate and its penta- and/or nonahydrate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4010524A DE4010524A1 (en) | 1990-04-02 | 1990-04-02 | STABLE, BIFUNCTIONAL, PHOSPHATE-FREE DETERGENT TABLETS FOR THE MACHINE DISHWASHER |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2068575T3 true ES2068575T3 (en) | 1995-04-16 |
Family
ID=6403554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91906795T Expired - Lifetime ES2068575T3 (en) | 1990-04-02 | 1991-03-25 | TABLETS OF CLEANING AGENTS FREE OF PHOSPHATE, BIFUNCTIONAL, STABLE FOR MACHINE SCRUBBING OF THE TABLEWARE. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0523095B1 (en) |
| AT (1) | ATE118540T1 (en) |
| DE (2) | DE4010524A1 (en) |
| ES (1) | ES2068575T3 (en) |
| WO (1) | WO1991015568A1 (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4112075A1 (en) * | 1991-04-12 | 1992-10-15 | Henkel Kgaa | METHOD FOR PRODUCING STABLE, BIFUNCTIONAL, PHOSPATE AND METASILICATE-FREE LOW-ALKALINE DETERGENT TABLETS FOR THE MACHINE DISHWASHER |
| DE4121307A1 (en) * | 1991-06-27 | 1993-01-07 | Henkel Kgaa | METHOD FOR THE PRODUCTION OF STABLE, BIFUNCTIONAL, PHOSPHATE AND METASILICATE-FREE LOW-ALKALINE DETERGENT TABLETS FOR THE MACHINE DISHWASHER |
| DE4213036A1 (en) * | 1992-04-21 | 1993-10-28 | Henkel Kgaa | Stable, free-flowing granulate of alkaline cleaning additive - contg. (meth)acrylic] acid (co)polymer, sodium silicate, sodium carbonate or sodium sulphate, sequestering agent and water |
| DE4228786A1 (en) * | 1992-08-29 | 1994-03-03 | Henkel Kgaa | Dishwashing liquid with selected builder system |
| DE69408530T2 (en) * | 1993-04-01 | 1998-05-28 | Unilever Nv | SOLID DETERGENT BRIQUETTES |
| DE4315048A1 (en) * | 1993-04-01 | 1994-10-06 | Henkel Kgaa | Process for the production of stable, bifunctional, phosphate, metasilicate and polymer-free, low-alkaline detergent tablets for automatic dishwashing |
| CA2211229C (en) * | 1995-02-17 | 2007-01-09 | Unilever Plc | Solid detergent block of compressed granular material |
| US6194367B1 (en) | 1995-03-01 | 2001-02-27 | Charvid Limited Liability Co. | Non-caustic cleaning composition comprising peroxygen compound and specific silicate and method of making the same in free-flowing, particulate form |
| US5663132A (en) * | 1995-03-01 | 1997-09-02 | Charvid Limited Liability Company | Non-caustic composition comprising peroxygen compound and metasilicate and cleaning methods for using same |
| US6034048A (en) * | 1995-03-01 | 2000-03-07 | Charvid Limited Liability Co. | Non-caustic cleaning composition using an alkali salt |
| US5900395A (en) * | 1996-12-23 | 1999-05-04 | Lever Brothers Company | Machine dishwashing tablets containing an oxygen bleach system |
| US5837663A (en) * | 1996-12-23 | 1998-11-17 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing tablets containing a peracid |
| BR9704788A (en) * | 1997-09-23 | 1999-09-08 | Unilever Nv | Process for increasing the dissolution of detergent tablets for dishwashers, combination of detergent composition with packaging system, and, packaging |
| EP1642960B1 (en) * | 2004-10-01 | 2007-10-31 | Unilever N.V. | Detergent compositions in tablet form |
| DE102013100195B4 (en) * | 2013-01-10 | 2025-10-30 | Budich International Gmbh | Cleaning tablet with integrated pre-cleaner system, manufacturing process and use |
| WO2018205240A1 (en) * | 2017-05-12 | 2018-11-15 | The Procter & Gamble Company | A method for making particles |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3390092A (en) * | 1965-03-30 | 1968-06-25 | Fmc Corp | Dishwashing detergent preparations containing sodium or potassium dichloroisocyanurate |
| DE2435479A1 (en) * | 1974-07-24 | 1976-02-12 | Henkel & Cie Gmbh | Cleansing compsns for use in dish-washing machines - contg. water-soluble alkali metal silicate and water-soluble alkali metal polyacrylate |
| DE3447291A1 (en) * | 1984-12-24 | 1986-06-26 | Henkel KGaA, 4000 Düsseldorf | PHOSPHATE-FREE AGENT FOR MACHINE DISHWASHER |
| CA1297376C (en) * | 1985-11-01 | 1992-03-17 | David Philip Jones | Detergent compositions, components therefor, and processes for theirpreparation |
| DE3541145A1 (en) * | 1985-11-21 | 1987-05-27 | Henkel Kgaa | UNIFORMED DETERGENT TABLETS FOR MACHINE DISHWASHER |
| DE3634813A1 (en) * | 1986-10-13 | 1988-04-14 | Henkel Kgaa | DETERGENT TABLETS FOR MACHINE DISHWASHER |
| GB2234980A (en) * | 1989-07-25 | 1991-02-20 | Unilever Plc | Detergent composition for machine dishwashers |
-
1990
- 1990-04-02 DE DE4010524A patent/DE4010524A1/en not_active Withdrawn
-
1991
- 1991-03-25 ES ES91906795T patent/ES2068575T3/en not_active Expired - Lifetime
- 1991-03-25 DE DE59104634T patent/DE59104634D1/en not_active Expired - Fee Related
- 1991-03-25 WO PCT/EP1991/000568 patent/WO1991015568A1/en not_active Ceased
- 1991-03-25 AT AT91906795T patent/ATE118540T1/en not_active IP Right Cessation
- 1991-03-25 EP EP91906795A patent/EP0523095B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE118540T1 (en) | 1995-03-15 |
| WO1991015568A1 (en) | 1991-10-17 |
| EP0523095B1 (en) | 1995-02-15 |
| EP0523095A1 (en) | 1993-01-20 |
| DE59104634D1 (en) | 1995-03-23 |
| DE4010524A1 (en) | 1991-10-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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