ES2076768T3 - PROCEDURE FOR OBTAINING TABLETS OF CLEANING AGENTS FOR MECHANICAL SCRUBBING OF THE TABLEWARE. - Google Patents
PROCEDURE FOR OBTAINING TABLETS OF CLEANING AGENTS FOR MECHANICAL SCRUBBING OF THE TABLEWARE.Info
- Publication number
- ES2076768T3 ES2076768T3 ES92912460T ES92912460T ES2076768T3 ES 2076768 T3 ES2076768 T3 ES 2076768T3 ES 92912460 T ES92912460 T ES 92912460T ES 92912460 T ES92912460 T ES 92912460T ES 2076768 T3 ES2076768 T3 ES 2076768T3
- Authority
- ES
- Spain
- Prior art keywords
- builders
- tableware
- procedure
- meth
- tablets
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000012459 cleaning agent Substances 0.000 title abstract 2
- 238000005201 scrubbing Methods 0.000 title 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 150000001447 alkali salts Chemical class 0.000 abstract 2
- 239000007844 bleaching agent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 102000004190 Enzymes Human genes 0.000 abstract 1
- 108090000790 Enzymes Proteins 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- 238000004851 dishwashing Methods 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 239000003205 fragrance Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Disclosed is a method of producing phosphate-free and metasilicate-free low-alkali cleaning-agent tablets for machine dishwashing, the tablets consisting of solid alkali salts of at least one homopolymer or copolymer of (meth)acrylic acid, which may be in the form of granules, builders, low-foam surfactants, bleaching agents and, optionally, enzymes, bleach activators, fragrances and colourings. In this method, the sodium carbonate acting as one of the builders is used in anhydrous form. It indergoes mixing, either alone or together with the other builders and the solid alkali salt of (meth)acrylic acid, with the quantity of water necessary for partial hydration of the anhydrous carbonate, i.e. approximately 5 to 40 % by weight. The remaining components of the mixture are then added and the mixture compressed into tablet form.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4121307A DE4121307A1 (en) | 1991-06-27 | 1991-06-27 | METHOD FOR THE PRODUCTION OF STABLE, BIFUNCTIONAL, PHOSPHATE AND METASILICATE-FREE LOW-ALKALINE DETERGENT TABLETS FOR THE MACHINE DISHWASHER |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2076768T3 true ES2076768T3 (en) | 1995-11-01 |
Family
ID=6434910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92912460T Expired - Lifetime ES2076768T3 (en) | 1991-06-27 | 1992-06-19 | PROCEDURE FOR OBTAINING TABLETS OF CLEANING AGENTS FOR MECHANICAL SCRUBBING OF THE TABLEWARE. |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0591282B1 (en) |
| AT (1) | ATE127835T1 (en) |
| DE (2) | DE4121307A1 (en) |
| DK (1) | DK0591282T3 (en) |
| ES (1) | ES2076768T3 (en) |
| WO (1) | WO1993000419A1 (en) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5898025A (en) * | 1992-09-25 | 1999-04-27 | Henkel Kommanditgesellschaft Auf Aktien | Mildly alkaline dishwashing detergents |
| DE4232170C2 (en) * | 1992-09-25 | 1999-09-16 | Henkel Kgaa | Weakly alkaline dish detergent |
| DE4315048A1 (en) * | 1993-04-01 | 1994-10-06 | Henkel Kgaa | Process for the production of stable, bifunctional, phosphate, metasilicate and polymer-free, low-alkaline detergent tablets for automatic dishwashing |
| CA2159605C (en) * | 1993-04-01 | 1998-12-15 | Guido Clemens Van Den Brom | Solid detergent briquettes |
| WO1995001416A1 (en) * | 1993-07-01 | 1995-01-12 | The Procter & Gamble Company | Machine dishwashing composition containing oxygen bleach and paraffin oil and benzotriazole compound silver tarnishing inhibitors |
| US5698504A (en) * | 1993-07-01 | 1997-12-16 | The Procter & Gamble Company | Machine dishwashing composition containing oxygen bleach and paraffin oil and benzotriazole compound silver tarnishing inhibitors |
| US5824630A (en) * | 1993-07-16 | 1998-10-20 | The Procter & Gamble Company | Machine dishwashing composition containing oxygen bleach and paraffin oil and nitrogen compound silver tarnishing inhibitors |
| DE69328679T2 (en) * | 1993-07-16 | 2001-01-11 | The Procter & Gamble Company, Cincinnati | Detergent compositions for dishwashers |
| BR9407538A (en) * | 1993-09-13 | 1997-08-26 | Diversey Corp | Process bar detergent for manufacture and use |
| US5759976A (en) * | 1993-09-13 | 1998-06-02 | Diversey Lever, Inc. | Process for forming tableted high-caustic detergent |
| ES2118561T5 (en) † | 1994-01-25 | 2002-03-16 | Unilever Nv | PROCEDURE FOR THE PREPARATION OF DETERGENT PADS. |
| DE4408718A1 (en) * | 1994-03-15 | 1995-09-21 | Henkel Kgaa | Breakage and storage stable, polyfunctional cleaning tablets, process for their preparation and their use |
| GB2303635A (en) * | 1995-07-25 | 1997-02-26 | Procter & Gamble | Detergent compositions in compacted solid form |
| US6063747A (en) * | 1995-07-25 | 2000-05-16 | The Procter & Gamble Company | Detergent compositions in compacted solid form |
| US5726142A (en) * | 1995-11-17 | 1998-03-10 | The Dial Corp | Detergent having improved properties and method of preparing the detergent |
| US5962389A (en) * | 1995-11-17 | 1999-10-05 | The Dial Corporation | Detergent having improved color retention properties |
| DE19605688A1 (en) * | 1996-02-16 | 1997-08-21 | Henkel Kgaa | Transition metal complexes as activators for peroxygen compounds |
| US6235695B1 (en) | 1996-04-01 | 2001-05-22 | Henkel Kommanditgesellschaft Auf Aktien | Cleaning agent with oligoammine activator complexes for peroxide compounds |
| DE19620411A1 (en) | 1996-04-01 | 1997-10-02 | Henkel Kgaa | Transition metal amine complexes as activators for peroxygen compounds |
| DE19616693A1 (en) * | 1996-04-26 | 1997-11-06 | Henkel Kgaa | Enol esters as bleach activators for detergents and cleaning agents |
| US5900395A (en) * | 1996-12-23 | 1999-05-04 | Lever Brothers Company | Machine dishwashing tablets containing an oxygen bleach system |
| US5837663A (en) * | 1996-12-23 | 1998-11-17 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing tablets containing a peracid |
| DE19713852A1 (en) | 1997-04-04 | 1998-10-08 | Henkel Kgaa | Activators for peroxygen compounds in detergents and cleaning agents |
| DE19714657C1 (en) * | 1997-04-09 | 1999-01-07 | Benckiser Nv | Water soluble, water softening builder |
| DE19824743A1 (en) * | 1998-06-03 | 1999-12-09 | Henkel Kgaa | Fracture-stable and quick-dissolving detergent tablets |
| EP1043388B1 (en) * | 1999-03-29 | 2001-12-19 | DALLI-WERKE WÄSCHE-UND KÖRPERPFLEGE GmbH & Co.KG. | Machine dishwashing tablets containing a granular disintegrant |
| DE50304955D1 (en) * | 2003-06-28 | 2006-10-19 | Dalli Werke Gmbh & Co Kg | Alpha olefin and alpha olefin cellulose granules as disintegrants |
| EP2190969B1 (en) * | 2007-05-04 | 2014-08-20 | Ecolab Inc. | Pressed, self-solidifying, solid cleaning compositions and methods of making them |
| US7893012B2 (en) * | 2007-05-04 | 2011-02-22 | Ecolab Inc. | Solidification matrix |
| MX2010003825A (en) | 2007-10-18 | 2010-04-27 | Ecolab Inc | CLEANING COMPOSITIONS SOLIDS, SELF-SOLIDIFICABLE, COMPRESSED, AND METHODS TO DO THEM. |
| DE102008060469A1 (en) * | 2008-12-05 | 2010-06-10 | Henkel Ag & Co. Kgaa | Automatic dishwashing tablet |
| FR3047741B1 (en) * | 2016-02-11 | 2019-06-07 | S.A. Gerlon | PROCESS FOR MANUFACTURING UNI-DOSE TABLETS |
| DE102017212561A1 (en) | 2017-07-21 | 2019-01-24 | Henkel Ag & Co. Kgaa | Dishwashing detergent containing citrate dihydrate and anhydrate |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1120819A (en) * | 1977-06-01 | 1982-03-30 | Jurgen W.K. Gromer | Detergent tablet |
| DE3541145A1 (en) * | 1985-11-21 | 1987-05-27 | Henkel Kgaa | UNIFORMED DETERGENT TABLETS FOR MACHINE DISHWASHER |
| DE3634813A1 (en) * | 1986-10-13 | 1988-04-14 | Henkel Kgaa | DETERGENT TABLETS FOR MACHINE DISHWASHER |
| DE3827895A1 (en) * | 1988-08-17 | 1990-02-22 | Henkel Kgaa | PROCESS FOR PREPARING PHOSPHATE-REDUCED DETERGENT TABLETS |
| AU647736B2 (en) * | 1989-04-24 | 1994-03-31 | Unilever Plc | Detergent compositions |
| GB2234980A (en) * | 1989-07-25 | 1991-02-20 | Unilever Plc | Detergent composition for machine dishwashers |
| DE3937469A1 (en) * | 1989-11-10 | 1991-05-16 | Henkel Kgaa | GRANULAR, ALKALINE, PHOSPHATE-FREE CLEANING ADDITIVE |
| DE4010524A1 (en) * | 1990-04-02 | 1991-10-10 | Henkel Kgaa | STABLE, BIFUNCTIONAL, PHOSPHATE-FREE DETERGENT TABLETS FOR THE MACHINE DISHWASHER |
-
1991
- 1991-06-27 DE DE4121307A patent/DE4121307A1/en not_active Withdrawn
-
1992
- 1992-06-19 EP EP92912460A patent/EP0591282B1/en not_active Expired - Lifetime
- 1992-06-19 DE DE59203697T patent/DE59203697D1/en not_active Expired - Fee Related
- 1992-06-19 WO PCT/EP1992/001387 patent/WO1993000419A1/en not_active Ceased
- 1992-06-19 DK DK92912460.0T patent/DK0591282T3/en active
- 1992-06-19 AT AT92912460T patent/ATE127835T1/en not_active IP Right Cessation
- 1992-06-19 ES ES92912460T patent/ES2076768T3/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE127835T1 (en) | 1995-09-15 |
| WO1993000419A1 (en) | 1993-01-07 |
| DE4121307A1 (en) | 1993-01-07 |
| EP0591282A1 (en) | 1994-04-13 |
| EP0591282B1 (en) | 1995-09-13 |
| DE59203697D1 (en) | 1995-10-19 |
| DK0591282T3 (en) | 1996-01-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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