ES2070302T3 - Un procedimiento para la sintesis de caucho de poli-dieno mediante polimerizacion en solucion de alto contenido de solidos. - Google Patents

Un procedimiento para la sintesis de caucho de poli-dieno mediante polimerizacion en solucion de alto contenido de solidos.

Info

Publication number
ES2070302T3
ES2070302T3 ES90630175T ES90630175T ES2070302T3 ES 2070302 T3 ES2070302 T3 ES 2070302T3 ES 90630175 T ES90630175 T ES 90630175T ES 90630175 T ES90630175 T ES 90630175T ES 2070302 T3 ES2070302 T3 ES 2070302T3
Authority
ES
Spain
Prior art keywords
polymerization
rubber
solids
dissolution
reaction area
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90630175T
Other languages
English (en)
Inventor
Robert William Stachowiak
Anthony Joseph Puccio
Thomas John Eberhart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Application granted granted Critical
Publication of ES2070302T3 publication Critical patent/ES2070302T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

ELASTOMEROS SINTETICOS SON GENERALMENTE FABRICADOS PARA SU VENTA, EMPLEANDO TECNICAS DE POLIMERACION DE EMULSION O POLIMERACION DE DISOLUCION. EN DICHAS TECNICAS DE POLIMERACION DE DISOLUCION, ES DESEABLE OPERAR CON EL CONTENIDO DE SOLIDOS MAS ALTO, QUE ES PRACTICO. COMO REGLA GENERAL NO ES PRACTICO PREPARAR DICHO CAUCHO POR POLIMERIZACION DE DISOLUCION EN CONTENIDOS SOLIDOS DE MAS DE UN 20 %. SIN EMBARGO, ESTA INVENCION DESCUBRE UNA TECNICA PARA PREPARAR DICHOS CAUCHOS, POR LA POLIMERIZACION DE DISOLUCION DE SOLIDOS ALTOS, EN CONTENIDOS EXTREMADAMENTE ALTOS EN SOLIDOS. ESTA TECNICA OFRECE GRANDES VENTAJAS ASOCIADAS CON LA ELIMINACION DE GRANDES CANTIDADES DE DISOLVENTES ORGANICOS. ESTA INVENCION SE REFIERE MAS ESPECIFICAMENTE A UN PROCESO PARA LA SINTESIS DE CAUCHO POLYDIENE, POR LA POLIMERIZACION CONTINUA DE SOLIDOS ALTOS, QUE COMPRENDE: (1) CARGANDO CONTINUAMENTE POR LO MENOS UN MONOMERO DIENE, UN COMPUESTO LITIO-ORGANICO AL MENOS Y DE 4 A ALREDEDOR DE 50 PHM DE POR LO MENOS UN DISOLVENTE ORGANICO EN UNA ZONA DE REACCION; (2) PERMITIENDO POLIMERIZAR A LOS MONOMEROS A UN CAMBIO DE POR LO MENOS UN 90 %, MIENTRAS QUE LAS CONDICIONES DE UTILIZACION DE DICHA ZONA DE REACCION, TENGAN SUFICIENTE ENFRIAMIENTO POR EVAPORACION, PARA MANTENER UNA TEMPERATURA QUE VAYA DE ALREDEDOR DE 10 ALREDEDOR DE 150 C Y, (3) RETIRANDO CONTINUAMENTE DICHO CAUCHO DE POLYDIENE DE LA ZONA DE REACCION.
ES90630175T 1989-10-23 1990-10-10 Un procedimiento para la sintesis de caucho de poli-dieno mediante polimerizacion en solucion de alto contenido de solidos. Expired - Lifetime ES2070302T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/425,655 US4965327A (en) 1989-10-23 1989-10-23 Synthesis of polydiene rubber by high solids solution polymerization

Publications (1)

Publication Number Publication Date
ES2070302T3 true ES2070302T3 (es) 1995-06-01

Family

ID=23687480

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90630175T Expired - Lifetime ES2070302T3 (es) 1989-10-23 1990-10-10 Un procedimiento para la sintesis de caucho de poli-dieno mediante polimerizacion en solucion de alto contenido de solidos.

Country Status (7)

Country Link
US (1) US4965327A (es)
EP (1) EP0425425B1 (es)
JP (1) JP3035329B2 (es)
AU (1) AU632021B2 (es)
CA (1) CA2019159C (es)
DE (1) DE69017583T2 (es)
ES (1) ES2070302T3 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5371267A (en) * 1990-09-22 1994-12-06 Bayer Aktiengesellschaft Substituted amino acid amide derivatives their preparation and use
US5229472A (en) * 1991-07-04 1993-07-20 Shell Oil Company Anionic extruder polymerization process
JPH0725906A (ja) * 1993-05-11 1995-01-27 Idemitsu Petrochem Co Ltd スチレン系重合体の製造方法
DE4327495A1 (de) * 1993-08-16 1995-02-23 Basf Ag Verfahren zur Herstellung von anionisch polymerisierbaren Vinylverbindungen
US5717040A (en) * 1993-08-16 1998-02-10 Basf Aktiengesellschaft Continuous process for polymerizing anionically polymerizable vinyl compounds
US6835778B2 (en) * 1995-08-29 2004-12-28 Chevron Phillips Chemical Company Lp Conjugated diene/monovinylarene block copolymers blends
US20050166551A1 (en) * 2004-02-02 2005-08-04 Keane J. A. Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer
JP5111101B2 (ja) * 2004-03-02 2012-12-26 株式会社ブリヂストン バルク重合プロセス
JP4805971B2 (ja) * 2008-05-07 2011-11-02 ピーピージー・インダストリーズ・オハイオ・インコーポレイテッド 水分検出システムおよびその使用方法
EP3023439B1 (en) * 2013-07-17 2018-02-07 Asahi Kasei Kabushiki Kaisha Method for producing polymer
KR101960726B1 (ko) 2015-10-22 2019-03-22 주식회사 엘지화학 폴리부타디엔의 제조 방법
KR101946482B1 (ko) 2015-10-22 2019-02-11 주식회사 엘지화학 폴리부타디엔의 제조 장치
WO2017135398A1 (ja) * 2016-02-04 2017-08-10 日産化学工業株式会社 ポリマーの製造方法
DE102023124134A1 (de) * 2023-09-07 2025-03-13 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein Gasphasenpolymerisation mit homogenen Katalysator- oder Initiatorsystemen

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT293013B (de) * 1968-04-25 1971-09-27 Bayer Ag Verfahren zur Herstellung von Segmentcopolymerisaten aus 1,3-Dienen und vinylaromatischen Verbindungen
US3770710A (en) * 1971-08-23 1973-11-06 Firestone Tire & Rubber Co Bulk polymerization of diolefins
US4189555A (en) * 1974-12-23 1980-02-19 Compagnie Generale Des Etablissements Michelin Continuous solution polymerization process
US4859748A (en) * 1982-04-02 1989-08-22 The Dow Chemical Company Process for anionic polymerization in a continuous stirred tank reactor
IT1191614B (it) * 1985-05-15 1988-03-23 Enichem Elastomers Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene
IN173082B (es) * 1986-02-19 1994-02-05 Goodyear Tire & Rubber

Also Published As

Publication number Publication date
EP0425425A3 (en) 1991-07-17
EP0425425A2 (en) 1991-05-02
CA2019159A1 (en) 1991-04-23
JPH03153702A (ja) 1991-07-01
JP3035329B2 (ja) 2000-04-24
US4965327A (en) 1990-10-23
AU6489190A (en) 1991-04-26
CA2019159C (en) 1999-10-12
DE69017583T2 (de) 1995-08-31
EP0425425B1 (en) 1995-03-08
AU632021B2 (en) 1992-12-10
DE69017583D1 (de) 1995-04-13

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