ES2070326T3 - Cicloalquilacion selectiva del naftaleno sobre zeolitas. - Google Patents

Cicloalquilacion selectiva del naftaleno sobre zeolitas.

Info

Publication number
ES2070326T3
ES2070326T3 ES90910513T ES90910513T ES2070326T3 ES 2070326 T3 ES2070326 T3 ES 2070326T3 ES 90910513 T ES90910513 T ES 90910513T ES 90910513 T ES90910513 T ES 90910513T ES 2070326 T3 ES2070326 T3 ES 2070326T3
Authority
ES
Spain
Prior art keywords
pct
zeolite
sec
degrees
naphthalene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90910513T
Other languages
English (en)
Inventor
Jonis Solofo
Patrice Moreau
Patrick Genest
Annie Finiels
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michelin Recherche et Technique SA Switzerland
Original Assignee
Michelin Recherche et Technique SA Switzerland
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michelin Recherche et Technique SA Switzerland filed Critical Michelin Recherche et Technique SA Switzerland
Application granted granted Critical
Publication of ES2070326T3 publication Critical patent/ES2070326T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Artificial Filaments (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Fats And Perfumes (AREA)
  • Pyrane Compounds (AREA)

Abstract

PROCESO PARA CICLOALQUILAR EL NAFTALENO CON AL MENOS UN GRUPO CICLICO CARACTERIZADO POR LOS SIGUIENTES PUNTOS: A) SE UTILIZA COMO CATALIZADOR UNA CEOLITA DE ESTRUCTURA FAUJASITA QUE TIENE ABERTURAS DE POROS SUPERIORES A 6,7 *, SIENDO SUPERIOR LA RELACION SILICE/ALUMININA DE ESTA CEOLITA SUPERIOR A 2,5 Y SIENDO INFERIOR SU TASA RESIDUAL EN ION(ES) ALCALIN(OS) A 3%; LA REACCION SE EFECTUA EN CONTINUO EN FASE HETEROGENA LIQUIDA/ SOLIDA A UNA TEMPERATURA COMPRENDIDA ENTRE 20 C Y 250 C, BAJO UNA PRESION COMO MAXIMO IGUAL A 30 BARES NAFTALENOS CICLOALQUILADOS OBTENIDOS POR ESTE PROCESO, EN PARTICULAR EL DICICLOHEXIL-2, 6 NAFTALENO.
ES90910513T 1989-07-26 1990-07-23 Cicloalquilacion selectiva del naftaleno sobre zeolitas. Expired - Lifetime ES2070326T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8910322A FR2650273B1 (fr) 1989-07-26 1989-07-26 Cycloalkylation de composes aromatiques sur zeolithes

Publications (1)

Publication Number Publication Date
ES2070326T3 true ES2070326T3 (es) 1995-06-01

Family

ID=9384331

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90910513T Expired - Lifetime ES2070326T3 (es) 1989-07-26 1990-07-23 Cicloalquilacion selectiva del naftaleno sobre zeolitas.

Country Status (12)

Country Link
US (1) US5292978A (es)
EP (1) EP0435984B1 (es)
JP (1) JP2856907B2 (es)
KR (1) KR0182611B1 (es)
AT (1) ATE120165T1 (es)
AU (1) AU631673B2 (es)
BR (1) BR9006869A (es)
CA (1) CA2034503C (es)
DE (1) DE69018048T2 (es)
ES (1) ES2070326T3 (es)
FR (1) FR2650273B1 (es)
WO (1) WO1991001959A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2659648B1 (fr) * 1990-03-13 1993-02-12 Michelin Rech Tech Procede pour preparer un produit aromatique alkyle avec une zeolithe d'alkylation et une zeolithe de dealkylation.
FR2778577B1 (fr) 1998-05-18 2000-07-13 Look Fixations Sa Vis de reglage de precompression pour fixation de ski
US9238599B2 (en) 2011-12-07 2016-01-19 Exxonmobil Chemical Patents Inc. Alkylaromatic process
CN108516919B (zh) * 2018-03-21 2021-04-13 吉林化工学院 一种萘的环已基衍生物的制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE638756C (es) *
US2229018A (en) * 1938-09-29 1941-01-14 Dow Chemical Co Poly-cyclohexyl-naphthalenes
US2904607A (en) * 1957-01-29 1959-09-15 Exxon Research Engineering Co Alkylation of aromatics
US3515680A (en) * 1966-09-29 1970-06-02 Air Prod & Chem Contact masses containing faujasite
US3513108A (en) * 1967-11-30 1970-05-19 Mobil Oil Corp Hydrothermally stable catalyst and method for its preparation
ES369229A1 (es) * 1968-07-09 1971-05-01 Shell Int Research Un procedimiento para la preparacion de compuestos aromati-cos alcohilados.
US3641177A (en) * 1969-11-26 1972-02-08 Exxon Research Engineering Co Alkylation of aromatic hydrocarbons
US3773652A (en) * 1970-10-13 1973-11-20 Texaco Development Corp Jet fuel manufacture
DE2208363A1 (de) * 1972-02-23 1973-09-13 Union Rheinische Braunkohlen Verfahren zur alkylierung von naphthalin
US3786106A (en) * 1972-10-04 1974-01-15 Phillips Petroleum Co Cycloalkylaromatic production
JPH0640442B2 (ja) * 1983-12-30 1994-05-25 日本石油化学株式会社 新規な電気絶縁油
FR2659648B1 (fr) * 1990-03-13 1993-02-12 Michelin Rech Tech Procede pour preparer un produit aromatique alkyle avec une zeolithe d'alkylation et une zeolithe de dealkylation.
US5118896A (en) * 1990-10-31 1992-06-02 Amoco Corporation Aromatic alkylation process using large macropore, small particle size, zeolite catalyst

Also Published As

Publication number Publication date
BR9006869A (pt) 1991-08-27
EP0435984B1 (fr) 1995-03-22
FR2650273A1 (fr) 1991-02-01
CA2034503C (fr) 2001-04-24
ATE120165T1 (de) 1995-04-15
KR0182611B1 (en) 1999-05-15
DE69018048T2 (de) 1995-08-03
FR2650273B1 (fr) 1992-12-24
US5292978A (en) 1994-03-08
EP0435984A1 (fr) 1991-07-10
DE69018048D1 (de) 1995-04-27
AU6030790A (en) 1991-03-11
CA2034503A1 (fr) 1991-01-27
WO1991001959A1 (fr) 1991-02-21
KR920701085A (ko) 1992-08-11
AU631673B2 (en) 1992-12-03
JP2856907B2 (ja) 1999-02-10
JPH04500814A (ja) 1992-02-13

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