ES2070479T3 - Procedimiento para la produccion de dioxido de cloro. - Google Patents
Procedimiento para la produccion de dioxido de cloro.Info
- Publication number
- ES2070479T3 ES2070479T3 ES91850202T ES91850202T ES2070479T3 ES 2070479 T3 ES2070479 T3 ES 2070479T3 ES 91850202 T ES91850202 T ES 91850202T ES 91850202 T ES91850202 T ES 91850202T ES 2070479 T3 ES2070479 T3 ES 2070479T3
- Authority
- ES
- Spain
- Prior art keywords
- chlorine dioxide
- reaction vessel
- production
- reducing agent
- zone located
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title abstract 8
- 239000004155 Chlorine dioxide Substances 0.000 title abstract 4
- 235000019398 chlorine dioxide Nutrition 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000003638 chemical reducing agent Substances 0.000 abstract 2
- 239000012429 reaction media Substances 0.000 abstract 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/026—Preparation from chlorites or chlorates from chlorate ions in the presence of a peroxidic compound, e.g. hydrogen peroxide, ozone, peroxysulfates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Catalysts (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Ultra Sonic Daignosis Equipment (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Paper (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
UN PROCESO PARA LA PRODUCCION DE DIOXIDO DE CLORO AL REACCIONAR, EN UN VASO DE REACCION, UN CLORATO METALICO ALCALINO, UN ACIDO MINERAL Y UN AGENTE REDUCTOR EN UNA PROPORCION TAL QUE SE PRODUZCA DIOXIDO DE CLORO EN UN MEDIO DE REACCION QUE SE MANTIENE A UNA TEMPERATURA DE ALREDEDOR DE 50 A 100 C Y A UNA ACIDEZ COMPRENDIDA DENTRO DE LA GAMA DE ALREDEDOR DE 2 A 5 N. EL MEDIO DE REACCION ESTA SOMETIDO A PRESION SUBATMOSFERICA SUFICIENTE PARA EVAPORAR EL AGUA, A UNA MEZCLA DE DIOXIDO DE CLORO, DE OXIGENO Y DE VAPOR DE AGUA QUE SE RETIRA DE UNA ZONA DE EVAPORACION SITUADA EN EL VASO DE REACCION, SE PRECIPITA UN SULFATO METALICO ALCALINO EN UNA ZONA DE CRISTALIZACION SITUADA EN EL VASO DE REACCION. A MEDIDA QUE SE UTILIZA EL PEROXIDO DE HIDROGENO COMO AGENTE REDUCTOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9002801A SE500042C2 (sv) | 1990-08-31 | 1990-08-31 | Förfarande för kontinuerlig framställning av klordioxid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2070479T3 true ES2070479T3 (es) | 1995-06-01 |
Family
ID=20380261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91850202T Expired - Lifetime ES2070479T3 (es) | 1990-08-31 | 1991-08-20 | Procedimiento para la produccion de dioxido de cloro. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5091166A (es) |
| EP (1) | EP0473559B1 (es) |
| JP (1) | JPH0742090B2 (es) |
| AT (1) | ATE120429T1 (es) |
| CA (1) | CA2028549C (es) |
| DE (1) | DE69108482D1 (es) |
| ES (1) | ES2070479T3 (es) |
| FI (1) | FI107911B (es) |
| NO (1) | NO309321B1 (es) |
| PT (1) | PT98814B (es) |
| SE (1) | SE500042C2 (es) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5348683A (en) * | 1990-02-06 | 1994-09-20 | Olin Corporation | Chloric acid - alkali metal chlorate mixtures and chlorine dioxide generation |
| US5322598A (en) * | 1990-02-06 | 1994-06-21 | Olin Corporation | Chlorine dioxide generation using inert load of sodium perchlorate |
| SE511003C2 (sv) * | 1992-03-16 | 1999-07-19 | Eka Chemicals Ab | Förfarande och apparat för framställning av svavelsyra och alkalimetallhydroxid |
| US5273733A (en) * | 1992-04-14 | 1993-12-28 | Eka Nobel Inc. | Process for the production of chlorine dioxide |
| US5486344A (en) * | 1992-06-09 | 1996-01-23 | Eka Nobel Inc. | Method of producing chlorine dioxide |
| US5366714A (en) * | 1992-06-09 | 1994-11-22 | Sterling Canada Inc. | Hydrogen peroxide-based chlorine dioxide process |
| CA2148462C (en) * | 1992-11-09 | 1999-08-31 | Herbert C. Scribner | Metathesis of acidic by-product of chlorine dioxide generating process |
| US5376350A (en) * | 1992-12-10 | 1994-12-27 | Eka Nobel Ab | Plug flow process for the production of chlorine dioxide |
| US5487881A (en) * | 1993-02-26 | 1996-01-30 | Eka Nobel Inc. | Process of producing chlorine dioxide |
| US5380517B1 (en) * | 1993-02-26 | 1999-01-19 | Eka Nobel Inc | Process for continuously producing chlorine dioxide |
| US5478446A (en) * | 1993-07-02 | 1995-12-26 | Eka Nobel Inc. | Electrochemical process |
| SE501684C2 (sv) * | 1993-10-07 | 1995-04-24 | Eka Nobel Ab | Förfarande och anordning att framställa klorsyra |
| US5399332A (en) * | 1993-10-20 | 1995-03-21 | Sterling Canada, Inc. | Dynamic leaching procedure for metathesis |
| SE513568C2 (sv) | 1994-03-18 | 2000-10-02 | Eka Chemicals Ab | Förfarande för framställning av klordioxid |
| NZ272769A (en) * | 1994-08-18 | 1996-03-26 | Eka Nobel Inc | Process for producing chlorine dioxide by reducing chlorate in acidic reaction medium |
| SE9402856L (sv) * | 1994-08-26 | 1995-11-27 | Eka Nobel Ab | Process of producing chlorine dioxide |
| US5599518A (en) * | 1994-12-01 | 1997-02-04 | Olin Corporation | Catalytic process for chlorine dioxide generation from chloric acid |
| WO1998013295A1 (en) * | 1996-09-27 | 1998-04-02 | International Paper Company | Method for producing chlorine dioxide using methanol and hydrogen peroxide as reducing agents |
| CA2268173A1 (en) * | 1996-09-27 | 1998-04-02 | Timothy R. Hammond | Method for producing chlorine dioxide using methanol, chloride, and hydrogen peroxide as reducing agents |
| US5895638A (en) * | 1997-03-20 | 1999-04-20 | Akzo Nobel N.V. | Method of producing chlorine dioxide |
| CA2242685C (en) * | 1997-08-01 | 2004-09-28 | Sterling Canada, Inc. | Nitric acid based chlorine dioxide generation process |
| CA2273667C (en) | 1998-06-09 | 2009-03-17 | Sterling Canada, Inc. | High purity alkali metal chlorite and method of manufacture |
| US6322768B1 (en) | 1998-09-29 | 2001-11-27 | International Paper Company | Recovery of chlorine dioxide from gas streams |
| US6287533B1 (en) | 1999-09-20 | 2001-09-11 | Mohammed N. I. Khan | Production of chlorine dioxide by chemical reduction of ammonium chlorate in aqueous acidic solution |
| CA2333247C (en) | 2000-02-01 | 2010-07-20 | Sterling Canada, Inc. | A method of improving yield of chlorine dioxide generation processes |
| US6752904B2 (en) | 2000-02-09 | 2004-06-22 | Akzo Nobel N.V. | Process for removal of lignin from lignocellulosic material |
| US6855294B2 (en) * | 2000-11-22 | 2005-02-15 | Resonance, Inc. | Apparatus and methods for efficient generation of chlorine dioxide |
| ATE489331T1 (de) * | 2000-12-21 | 2010-12-15 | Superior Plus Lp | Auf wasserstoffperoxid basierendes verfahren zur erzeugung von chlordioxid |
| US6790427B2 (en) | 2001-06-25 | 2004-09-14 | Eka Chemicals, Inc. | Process for producing chlorine dioxide |
| US20030095917A1 (en) * | 2001-07-27 | 2003-05-22 | Debra Wilcox | Chemical composition and process |
| WO2005047646A1 (en) | 2003-05-31 | 2005-05-26 | Des Enhanced Recovery Limited | Apparatus and method for recovering fluids from a well and/or injecting fluids into a well |
| US7695692B2 (en) * | 2003-08-06 | 2010-04-13 | Sanderson William D | Apparatus and method for producing chlorine dioxide |
| CN100471791C (zh) * | 2004-02-23 | 2009-03-25 | 阿克佐诺贝尔公司 | 二氧化氯的生产方法 |
| JP2005330159A (ja) * | 2004-05-21 | 2005-12-02 | Mitsubishi Gas Chem Co Inc | 食塩から化学パルプの無塩素漂白用薬品の製造方法 |
| CA2589714C (en) † | 2004-12-06 | 2010-04-06 | Akzo Nobel N.V. | Process and apparatus for producing chlorine dioxide |
| US20060120946A1 (en) * | 2004-12-06 | 2006-06-08 | Akzo Nobel N.V. | Chemical process and apparatus |
| DE602005019778D1 (de) * | 2004-12-06 | 2010-04-15 | Akzo Nobel Nv | Chemisches verfahren und produktionseinheit |
| ZA200803849B (en) * | 2005-11-10 | 2009-09-30 | Akzo Nobel Nv | Process for production of chlorine dioxide |
| US20090232903A1 (en) * | 2005-12-16 | 2009-09-17 | Sanderson William D | Biocide compositions |
| WO2007078838A2 (en) * | 2005-12-16 | 2007-07-12 | Sanderson William D | Solid biocide composition and sealed biocide article |
| WO2008085122A1 (en) * | 2007-01-12 | 2008-07-17 | Akzo Nobel N.V. | Process for the production of chlorine dioxide |
| TWI447065B (zh) * | 2007-07-13 | 2014-08-01 | Akzo Nobel Nv | 二氧化氯之製造方法 |
| US7666384B2 (en) * | 2008-01-17 | 2010-02-23 | Sanderson William D | Stable chlorine dioxide tablet |
| SA109300539B1 (ar) * | 2008-10-06 | 2012-04-07 | اكزو نوبل أن . في | عملية لأنتاج ثانى أكسيد الكلور |
| PT2443059E (pt) * | 2009-06-16 | 2015-12-01 | Akzo Nobel Nv | Processo para a produção de dióxido de cloro |
| MX340592B (es) | 2010-01-18 | 2016-07-15 | Akzo Nobel Chemicals Int B V * | Proceso para la produccion de dioxido de cloro. |
| CN107673310A (zh) | 2010-07-08 | 2018-02-09 | 阿克苏诺贝尔化学品国际有限公司 | 生产二氧化氯的方法 |
| US20200039822A1 (en) | 2016-10-13 | 2020-02-06 | Evonik Corporation | Hydrogen peroxide composition and method for producing chlorine dioxide |
| US11535541B2 (en) | 2017-02-27 | 2022-12-27 | Ecolab Usa Inc. | Method for onsite production of chlorine dioxide |
| TWI792727B (zh) | 2017-03-24 | 2023-02-11 | 美商藝康美國公司 | 低風險的二氧化氯現場產生系統 |
| AR111541A1 (es) | 2017-08-17 | 2019-07-24 | Ecolab Usa Inc | Sistema de generación in situ de dióxido de cloro de bajo riesgo |
| US11970393B2 (en) | 2018-07-05 | 2024-04-30 | Ecolab Usa Inc. | Decomposition mediation in chlorine dioxide generation systems through sound detection and control |
| BR112021001902A2 (pt) | 2018-08-02 | 2021-04-27 | Evonik Corporation | misturas de peróxido de hidrogênio e clorato estabilizadas |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2332181A (en) * | 1941-07-15 | 1943-10-19 | Mathieson Alkali Works Inc | Manufacture of chlorine dioxide |
| DE835439C (de) * | 1941-07-15 | 1952-03-31 | Electro Chimie Metal | Verfahren zur Herstellung von Chlordioxyd |
| FR997858A (fr) * | 1945-08-10 | 1952-01-11 | Electro Chimie Soc D | Procédé pour la fabrication du bioxyde de chlore |
| US2768877A (en) * | 1953-12-01 | 1956-10-30 | Cardox Corp | Chlorine dioxide containing composition and process for manufacture thereof |
| US2833624A (en) * | 1956-10-02 | 1958-05-06 | Du Pont | Production of chlorine dioxide |
| US3386915A (en) * | 1964-03-18 | 1968-06-04 | Solvay | Process for the manufacturing of chlorine dioxide in solution and the use of the solution thus obtained |
| US3563702A (en) * | 1968-03-05 | 1971-02-16 | Hooker Chemical Corp | Production of chlorine dioxide |
| CA1080434A (en) * | 1976-03-19 | 1980-07-01 | Erco Industries Limited | High efficiency chlorine dioxide production using hc1 as acid |
| JPS5366892A (en) * | 1976-11-27 | 1978-06-14 | Osaka Soda Co Ltd | Production of chlorine dioxide |
| US4298426A (en) * | 1979-06-15 | 1981-11-03 | Weyerhaeuser Company | Method and apparatus for treating pulp with oxygen in a multi-stage bleaching sequence |
| JPS5953205B2 (ja) * | 1981-05-19 | 1984-12-24 | 日本カ−リツト株式会社 | 高純度の二酸化塩素を製造する方法 |
| JPS638203A (ja) * | 1986-06-26 | 1988-01-14 | Japan Carlit Co Ltd:The | 高純度の二酸化塩素を製造する方法 |
-
1990
- 1990-08-31 SE SE9002801A patent/SE500042C2/sv unknown
- 1990-09-04 US US07/576,949 patent/US5091166A/en not_active Expired - Lifetime
- 1990-10-25 CA CA002028549A patent/CA2028549C/en not_active Expired - Lifetime
-
1991
- 1991-08-20 ES ES91850202T patent/ES2070479T3/es not_active Expired - Lifetime
- 1991-08-20 EP EP91850202A patent/EP0473559B1/en not_active Expired - Lifetime
- 1991-08-20 AT AT91850202T patent/ATE120429T1/de not_active IP Right Cessation
- 1991-08-20 DE DE69108482T patent/DE69108482D1/de not_active Expired - Lifetime
- 1991-08-26 NO NO913343A patent/NO309321B1/no not_active IP Right Cessation
- 1991-08-27 JP JP3239004A patent/JPH0742090B2/ja not_active Expired - Lifetime
- 1991-08-28 FI FI914050A patent/FI107911B/fi not_active IP Right Cessation
- 1991-08-29 PT PT98814A patent/PT98814B/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0742090B2 (ja) | 1995-05-10 |
| FI107911B (fi) | 2001-10-31 |
| FI914050L (fi) | 1992-03-01 |
| CA2028549C (en) | 1998-10-27 |
| PT98814A (pt) | 1992-07-31 |
| EP0473559A1 (en) | 1992-03-04 |
| SE9002801L (sv) | 1992-03-01 |
| JPH04231304A (ja) | 1992-08-20 |
| SE500042C2 (sv) | 1994-03-28 |
| CA2028549A1 (en) | 1992-03-01 |
| EP0473559B1 (en) | 1995-03-29 |
| NO913343D0 (no) | 1991-08-26 |
| NO309321B1 (no) | 2001-01-15 |
| SE9002801D0 (sv) | 1990-08-31 |
| DE69108482D1 (de) | 1995-05-04 |
| ATE120429T1 (de) | 1995-04-15 |
| NO913343L (no) | 1992-03-02 |
| PT98814B (pt) | 1999-02-26 |
| FI914050A0 (fi) | 1991-08-28 |
| US5091166A (en) | 1992-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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