ES2071035T3 - Procedimiento de membrana para la separacion de liquidos organicos. - Google Patents

Procedimiento de membrana para la separacion de liquidos organicos.

Info

Publication number
ES2071035T3
ES2071035T3 ES90310398T ES90310398T ES2071035T3 ES 2071035 T3 ES2071035 T3 ES 2071035T3 ES 90310398 T ES90310398 T ES 90310398T ES 90310398 T ES90310398 T ES 90310398T ES 2071035 T3 ES2071035 T3 ES 2071035T3
Authority
ES
Spain
Prior art keywords
alcohol
pressure
porous
separation layer
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90310398T
Other languages
English (en)
Inventor
Mordechai Pasternak Sr
Craig Roget Bartels Sr
John Reale Jr
Vatsal Mukundlal Shah
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texaco Development Corp
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Application granted granted Critical
Publication of ES2071035T3 publication Critical patent/ES2071035T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/08—Purification; Separation; Stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/362—Pervaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1212—Coextruded layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/38—Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals
    • B01D71/381—Polyvinylalcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/40—Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B01D71/401—Polymers based on the polymerisation of acrylic acid, e.g. polyacrylate
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/34—Separation; Purification; Stabilisation; Use of additives
    • C07C41/36—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/786—Separation; Purification; Stabilisation; Use of additives by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

UNA COMPOSICION DE CARGA QUE CONTENGA (I) UN ALCOHOL QUE TENGA MENOS DE TRES ATOMOS DE CARBONO Y (II) UN OXIGENADO SELECCIONADO DE ETERES ORGANICOS, ALDEHIDOS, QUETONES, Y ESTERES SE PASA EN CONTACTO CON UN PRIMER LADO DE UNA CAPA DE SEPARAION DE MEMBRANA NO POROSA QUE CONSTA DE UNA MEZCLA DE ALCOHOL DE POLIVINILO Y UN ACIDO POLIACRILICO SOBRE UNA CAPA DE SOPORTE DE POLIACRILONITILO; CON UNA CAIDA DE PRESION A LO LARGO DE LA CAPA SEPARADORA NO POROSA DESDE EL PRIMER LADO (PRESION ALTA) HASTA EL SEGUNDO LADO (PRESION BAJA). AL MENOS UNA PORCION DE ALCOHOL DE LA COMPOSICION DE CARGA Y UNA PORCION MENOR DE OXIGENADO PASA MEDIANTE PERVAPORACION A TRAVES DE LA CAPA DE SEPARACION NO POROSA COMO UNA MEZCLA POBRE QUE CONTIENE MAS ALCOHOL Y MENOS OXIGENADO QUE LOS PRESENTES EN DICHA COMPOSICION DE CARGA, DEJANDO UN LIQUIDO RICO QUE CONTIENE MENOS ALCOHOL Y MAS OXIGENADO QUE LOS PRESENTES EN DICHA COMPOSICION DE CARGA; LA MEZCLA POBRE, EN FASE DE VAPOR A UNA PRESION EN QUE SU PRESION DE VAPOR SE RECUPERA CUANDO PENETRA DESDE EL LADO DE PRESION BAJA DE LA CAPA DE SEPARACION NO POROSA
ES90310398T 1989-10-16 1990-09-21 Procedimiento de membrana para la separacion de liquidos organicos. Expired - Lifetime ES2071035T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/421,878 US4960519A (en) 1989-10-16 1989-10-16 Membrane process for separation of organic liquids

Publications (1)

Publication Number Publication Date
ES2071035T3 true ES2071035T3 (es) 1995-06-16

Family

ID=23672427

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90310398T Expired - Lifetime ES2071035T3 (es) 1989-10-16 1990-09-21 Procedimiento de membrana para la separacion de liquidos organicos.

Country Status (6)

Country Link
US (1) US4960519A (es)
EP (1) EP0423949B1 (es)
JP (1) JPH03137919A (es)
CA (1) CA2020532A1 (es)
DE (1) DE69017826T2 (es)
ES (1) ES2071035T3 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5093003A (en) * 1989-10-16 1992-03-03 Exxon Research And Engineering Company Halogenated polyurethanes
US5160353A (en) * 1990-08-30 1992-11-03 E. I. Du Pont De Nemours & Company Gas separation membrane with ultrathin layer
US5248427A (en) * 1990-09-15 1993-09-28 Basf Aktiengesellschaft Removal of water from mixtures with alcohols and/or carboxylic acids and/or carboxylic esters
IT1252070B (it) * 1991-11-25 1995-05-29 Enichem Sintesi Procedimento per la preparazione di carbonati alchilici
DE4320629C2 (de) * 1992-06-24 1996-03-07 Byk Gulden Lomberg Chem Fab Verfahren und Vorrichtung zur Rückgewinnung von Lösungsmitteln aus Abluft
DE4234521C1 (de) * 1992-10-13 1994-02-24 Carbone Ag Verfahren zur Herstellung einer Komposit-Plasmamembran und ihre Verwendung
DE4234525A1 (de) * 1992-10-13 1994-04-14 Bayer Ag Verfahren zur Abtrennung von Alkanolen von sauerstoffhaltigen organischen Verbindungen mit höherer Kohlenstoffzahl
US5230801A (en) * 1992-11-02 1993-07-27 Exxon Research And Engineering Company Recovery of alcohols from n-paraffins by pervaporation
DE4239243A1 (de) * 1992-11-21 1994-05-26 Basf Ag Verfahren zur Trennung eines Gemisches aus Methanol und Tetrahydrofuran in seine Bestandteile
US5320754A (en) * 1992-12-18 1994-06-14 Hoechst Celanese Corp. Pan composite membranes
DE4319570A1 (de) * 1993-06-14 1994-12-15 Bayer Ag Verfahren und Abtrennung von Alkanolen von weiteren organischen Verbindungen mit höherer Kohlenstoffzahl
DE4342713A1 (de) * 1993-12-15 1995-06-22 Bayer Ag Verfahren zur Abtrennung von Methanol aus einem Gemisch von Dimethylcarbonat und Methanol
DE4410763C1 (de) * 1994-03-28 1995-05-11 Carbone Ag Pervaporationsmembranen und ihre Verwendung
US5993515A (en) * 1996-05-14 1999-11-30 New Jersey Institute Of Technology Apparatus and process for selectively removing a component from a multicomponent aqueous solution by pervaporation
RU2166984C2 (ru) * 1998-06-15 2001-05-20 Институт высокомолекулярных соединений РАН Способ получения полимерных мультислойных первапорационных мембран
US6620958B2 (en) * 2001-06-26 2003-09-16 Exxonmobil Chemical Patents Inc. Use of membranes to separate organic liquids having different polarities
CN100493688C (zh) * 2006-01-26 2009-06-03 中国科学院大连化学物理研究所 一种聚乙烯醇/壳聚糖共混膜的制备方法
CN100482329C (zh) * 2006-02-15 2009-04-29 中国科学院大连化学物理研究所 一种用于渗透汽化分离的壳聚糖中空纤维膜的制备方法
US8017016B2 (en) 2006-07-07 2011-09-13 Sims Carl W Method and apparatus for pervaporation control in chromatographic systems
CN100551505C (zh) * 2007-03-21 2009-10-21 清华大学 一种用于分离甲醇/碳酸二甲酯共沸物的分离膜及其制备方法
DE102009002130A1 (de) 2009-04-02 2010-10-14 Wacker Chemie Ag Membranen auf Basis von Polyvinylalkohol
IT1405068B1 (it) 2010-06-11 2013-12-16 Univ Bologna Alma Mater Produzione di aldeidi per ossidazione in ambiente acquoso con recupero selettivo del prodotto mediante pervaporazione
WO2012038110A1 (de) 2010-09-20 2012-03-29 Sulzer Chemtech Ag Membran mit einer porenfreien trennschicht, sowie verwendung und verfahren zur herstellung einer membran
US8668763B2 (en) 2011-03-25 2014-03-11 Idex Health & Science Llc Apparatus for pervaporation control in liquid degassing systems
US8430949B2 (en) * 2011-03-25 2013-04-30 Idex Health & Science Llc Apparatus for pervaporation control in liquid degassing systems
US8440003B2 (en) 2011-03-25 2013-05-14 Idex Health & Science, Llc Apparatus for pervaporation control in liquid degassing systems
KR101708211B1 (ko) 2014-12-24 2017-02-21 주식회사 포스코 투과증발을 이용한 디메틸 카보네이트의 분리 방법 및 설비
CN113069933B (zh) * 2021-03-26 2022-10-14 东南大学 一种分离n,n-二甲基甲酰胺/水混合物的有机/无机复合膜及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4188418A (en) * 1972-08-09 1980-02-12 Lever Brothers Company Separation process
US4082659A (en) * 1974-04-30 1978-04-04 Hoechst Aktiengesellschaft Process for concentrating latices
US4774365A (en) * 1987-11-25 1988-09-27 Air Products And Chemicals, Inc. Pervaporation process for separating alcohols from ethers
US4798674A (en) * 1988-03-10 1989-01-17 Texaco Inc. Separation of organic liquids
US4910344A (en) * 1989-02-01 1990-03-20 Texaco Inc. Treatment of compositions containing water and organic oxygenates

Also Published As

Publication number Publication date
CA2020532A1 (en) 1991-04-17
DE69017826D1 (de) 1995-04-20
JPH03137919A (ja) 1991-06-12
EP0423949A2 (en) 1991-04-24
EP0423949A3 (en) 1991-08-28
DE69017826T2 (de) 1995-07-13
US4960519A (en) 1990-10-02
EP0423949B1 (en) 1995-03-15

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