ES2078385T3 - Microgeles cationicos y su uso en electrodeposicion. - Google Patents
Microgeles cationicos y su uso en electrodeposicion.Info
- Publication number
- ES2078385T3 ES2078385T3 ES91109620T ES91109620T ES2078385T3 ES 2078385 T3 ES2078385 T3 ES 2078385T3 ES 91109620 T ES91109620 T ES 91109620T ES 91109620 T ES91109620 T ES 91109620T ES 2078385 T3 ES2078385 T3 ES 2078385T3
- Authority
- ES
- Spain
- Prior art keywords
- dispersion
- cationic
- electrodepposition
- mixture
- microgel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000006185 dispersion Substances 0.000 abstract 7
- 238000000034 method Methods 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4488—Cathodic paints
- C09D5/4492—Cathodic paints containing special additives, e.g. grinding agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4473—Mixture of polymers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
- Colloid Chemistry (AREA)
Abstract
SE DESCRIBE UNA DISPERSION DE MICROGEL CATIONICO Y EL USO DE LA DISPERSION EN EL METODO DE ELECTRODEPOSICION CATIONICA. LA DISPERSION SE PREPARA POR UN PROCESO QUE INCLUYE LA DISPERSION EN UN MEDIO ACUOSO DE UNA MEZCLA DE UN PRODUCTO DE REACCION DE POLIEPOXIDO-AMINA CATIONICA Y UN AGENTE DE ENLACE EN CRUZ POLIEPOXIDO, Y EL CALENTAMIENTO DE LA MEZCLA HASTA UNA TEMPERATURA SUFICIENTE PARA ENLAZAR EN CRUZ LA MEZCLA Y FORMAR LA DISPERSION DE MICROGEL CATIONICO. LA DISPERSION PUEDE FORMULARSE CON RESINAS CATIONICAS NO GELADAS PARA FORMAR UNA DISPERSION DE RESINA ACUOSA QUE ES ADECUADA PARA SU USO EN EL PROCESO DE ELECTRODEPOSICION CATIONICA PROPORCIONADO PARA LA COBERTURA DE EXTREMO MEJORADA Y EL CONTROL DEL CRATER.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/543,501 US5096556A (en) | 1990-06-25 | 1990-06-25 | Cationic microgels and their use in electrodeposition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2078385T3 true ES2078385T3 (es) | 1995-12-16 |
Family
ID=24168331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91109620T Expired - Lifetime ES2078385T3 (es) | 1990-06-25 | 1991-06-12 | Microgeles cationicos y su uso en electrodeposicion. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5096556A (es) |
| EP (1) | EP0463474B1 (es) |
| JP (2) | JP2604508B2 (es) |
| KR (1) | KR940009035B1 (es) |
| AR (1) | AR246542A1 (es) |
| AT (1) | ATE126254T1 (es) |
| AU (1) | AU629479B2 (es) |
| BR (1) | BR9102648A (es) |
| CA (1) | CA2044987C (es) |
| DE (1) | DE69111920T2 (es) |
| ES (1) | ES2078385T3 (es) |
| FI (1) | FI101975B (es) |
| PT (1) | PT98090B (es) |
| ZA (1) | ZA914304B (es) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5204385A (en) * | 1990-11-27 | 1993-04-20 | Reichhold Chemicals, Inc. | Water reducible epoxy resin curing agent |
| US5854312A (en) * | 1992-04-21 | 1998-12-29 | Air Products And Chemicals, Inc. | Aqueous hardeners for epoxy resin systems |
| US5380781A (en) * | 1992-07-27 | 1995-01-10 | Kansai Paint Co., Ltd. | Cationically electrodepositable fine particles derived from alkoxysilane-modified epoxy resins and cationic electrodeposition paint composition comprising the same |
| WO1994013867A1 (en) * | 1992-12-07 | 1994-06-23 | Roelofs, Andreas, Henricus, Johannes | Adhesive metal foil and laminates comprising said metal foil |
| US5506284A (en) * | 1993-02-26 | 1996-04-09 | Basf Corporation | Electrodeposition coating composition comprising crosslinked microparticles |
| DE4314297A1 (de) * | 1993-04-30 | 1994-11-03 | Hoechst Ag | Wäßrige Kunstharzdispersionen |
| US5362772A (en) * | 1993-07-09 | 1994-11-08 | E. I. Du Pont De Nemours And Company | Crosslinked microgel for cathodic electrocoating compositions |
| US5371120A (en) * | 1993-07-19 | 1994-12-06 | E. I. Du Pont De Nemours And Company | Crosslinked microgel for cathodic electrocoating compositions |
| US5356960A (en) * | 1993-08-11 | 1994-10-18 | E. I. Du Pont De Nemours And Company | Cathodic electrocoating compositions containing an anticrater agent |
| US5407976A (en) * | 1993-10-27 | 1995-04-18 | E. I. Du Pont De Nemours And Company | Isocyanate crosslinked microgel for cathodic electrocoating compositions |
| US5767191A (en) * | 1994-10-25 | 1998-06-16 | Ppg Industries, Inc. | Electrodepositable coating compositions and method for improved cure response |
| KR100219974B1 (ko) * | 1994-10-25 | 1999-09-01 | 파블릭크 헬렌 에이 | 경화 반응성을 향상시킨 전착성 코팅 조성물 |
| US5582704A (en) * | 1994-11-04 | 1996-12-10 | Ppg Industries, Inc. | Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition |
| US5633297A (en) * | 1994-11-04 | 1997-05-27 | Ppg Industries, Inc. | Cationic resin containing capped isocyanate groups suitable for use in electrodeposition |
| DE4446439A1 (de) * | 1994-12-23 | 1996-06-27 | Hoechst Ag | Polymer-Dispersionen auf Basis eines kationischen Polyurethans |
| US5721088A (en) * | 1995-12-20 | 1998-02-24 | Ppg Industries, Inc. | Electrodepositable photoimageable compositions with improved edge coverage |
| US5630922A (en) * | 1995-12-26 | 1997-05-20 | Ppg Industries, Inc. | Electrodepositable coating composition containing diorganotin dicarboxylates |
| GB9611118D0 (en) | 1996-05-29 | 1996-07-31 | Ici Plc | Dispersions |
| US5820987A (en) * | 1996-08-21 | 1998-10-13 | Ppg Industries, Inc. | Cationic electrocoating compositions, method of making, and use |
| US5804051A (en) * | 1996-08-29 | 1998-09-08 | Ppg Industries, Inc. | Electrodepositable coating compositions containing hydroxamic acid and derivatives thereof, and their use in a method of electrodeposition |
| US5908912A (en) * | 1996-09-06 | 1999-06-01 | Ppg Industries Ohio, Inc. | Electrodepositable coating composition containing bismuth and amino acid materials and electrodeposition method |
| US5750596A (en) * | 1996-12-23 | 1998-05-12 | E. I. Du Pont De Nemours And Company | Cathodic electrocoating compositions containing an anticrater agent |
| US5723519A (en) * | 1997-02-25 | 1998-03-03 | E. I. Du Pont De Nemours And Company | Cathodic electrocoating compositions containing an anticrater agent |
| US6017432A (en) * | 1997-07-03 | 2000-01-25 | Ppg Industries Ohio, Inc. | Electrodepositable coating compositions and their use in a method of cationic electrodeposition |
| US6017431A (en) * | 1997-07-17 | 2000-01-25 | Ppg Industries Ohio, Inc. | Cationic electrodepositable coating composition and bath thereof and process for retarding the growth of bacteria for such a bath |
| US5859154A (en) * | 1997-09-26 | 1999-01-12 | Ppg Industries, Inc. | Resinous composition of phosphatized polyester polymers and coating compositions for improved adhesion |
| KR100530907B1 (ko) * | 1997-12-31 | 2006-06-23 | 주식회사 케이씨씨 | 양이온 마이크로겔 수분산액의 제조 방법 및 이를 함유한 전착도료 조성물 |
| KR100591468B1 (ko) | 1998-08-03 | 2006-06-20 | 코그니스 코포레이션 | 폴리아민과 페놀-알데히드의 반응에 의해 제조된 에폭시경화제 |
| US6333051B1 (en) | 1998-09-03 | 2001-12-25 | Supratek Pharma, Inc. | Nanogel networks and biological agent compositions thereof |
| JP2001131472A (ja) * | 1999-11-01 | 2001-05-15 | Kansai Paint Co Ltd | カチオン電着塗料用樹脂組成物 |
| US6437055B1 (en) | 2000-04-07 | 2002-08-20 | Ppg Industries Ohio, Inc. | Electrodepositable coating from gelled epoxy-polyester and amine |
| US6417292B1 (en) | 2000-04-07 | 2002-07-09 | Ppg Industries Ohio, Inc. | Electrodepositable coating compositions including ungelled reaction products of epoxy functional polyesters and amines coated substrates and methods of electrocoating using the same |
| WO2001092377A1 (en) * | 2000-05-27 | 2001-12-06 | Q-Sys Co., Ltd. | Electrically conductive microgel and method for preparing the same |
| US7000313B2 (en) * | 2001-03-08 | 2006-02-21 | Ppg Industries Ohio, Inc. | Process for fabricating circuit assemblies using electrodepositable dielectric coating compositions |
| US6951707B2 (en) * | 2001-03-08 | 2005-10-04 | Ppg Industries Ohio, Inc. | Process for creating vias for circuit assemblies |
| US6713587B2 (en) | 2001-03-08 | 2004-03-30 | Ppg Industries Ohio, Inc. | Electrodepositable dielectric coating compositions and methods related thereto |
| WO2003070825A2 (en) * | 2002-02-15 | 2003-08-28 | Ppg Industries Ohio, Inc. | Waterborne compositions containing copolymers of isobutylene |
| US7132477B2 (en) * | 2002-02-15 | 2006-11-07 | Ppg Industries Ohio, Inc. | Powder coating compositions |
| US6784248B2 (en) * | 2002-02-15 | 2004-08-31 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing alternating copolymers of isobutylene type monomers |
| US20060213685A1 (en) * | 2002-06-27 | 2006-09-28 | Wang Alan E | Single or multi-layer printed circuit board with improved edge via design |
| US6824959B2 (en) | 2002-06-27 | 2004-11-30 | Ppg Industries Ohio, Inc. | Process for creating holes in polymeric substrates |
| AU2003248743A1 (en) * | 2002-06-27 | 2004-01-19 | Ppg Industries Ohio, Inc. | Single or multi-layer printed circuit board with recessed or extended breakaway tabs and method of manufacture thereof |
| DE10326147A1 (de) * | 2003-06-06 | 2005-03-03 | Byk-Chemie Gmbh | Epoxid-Addukte und deren Salze als Dispergiermittel |
| CN2662813Y (zh) * | 2003-12-12 | 2004-12-15 | 际诺思(厦门)轻工制品有限公司 | 一种改良的折叠式马桶座 |
| US20060228556A1 (en) * | 2005-04-08 | 2006-10-12 | Fenn David R | Electrodepositable coating compositions and methods for their production |
| US20070015873A1 (en) * | 2005-07-13 | 2007-01-18 | Fenn David R | Electrodepositable aqueous resinous dispersions and methods for their preparation |
| KR100755415B1 (ko) * | 2005-12-30 | 2007-09-04 | (주)디피아이 홀딩스 | 양이온성 전착도료 조성물 및 그 제조 방법 |
| JP4788436B2 (ja) * | 2006-03-29 | 2011-10-05 | 日本電気株式会社 | 無線リソース割り当て方法及びそれを用いる無線リソース割り当て装置並びに基地局 |
| US20110160346A1 (en) * | 2006-03-31 | 2011-06-30 | Applied Nanotech Holdings, Inc. | Dispersion of carbon nanotubes by microfluidic process |
| US20070276077A1 (en) * | 2006-04-05 | 2007-11-29 | Nano-Proprietary, Inc. | Composites |
| US8283403B2 (en) * | 2006-03-31 | 2012-10-09 | Applied Nanotech Holdings, Inc. | Carbon nanotube-reinforced nanocomposites |
| US8129463B2 (en) * | 2006-03-31 | 2012-03-06 | Applied Nanotech Holdings, Inc. | Carbon nanotube-reinforced nanocomposites |
| US20080090951A1 (en) * | 2006-03-31 | 2008-04-17 | Nano-Proprietary, Inc. | Dispersion by Microfluidic Process |
| US8445587B2 (en) * | 2006-04-05 | 2013-05-21 | Applied Nanotech Holdings, Inc. | Method for making reinforced polymer matrix composites |
| US8057654B2 (en) * | 2008-03-19 | 2011-11-15 | Ppg Industries Ohio, Inc. | Electrodeposition of dielectric coatings on semiconductive substrates |
| US20120015209A1 (en) | 2010-07-19 | 2012-01-19 | Ford Global Technologies, Llc | Wheels Having Oxide Coating And Method of Making The Same |
| US9598588B2 (en) | 2012-05-16 | 2017-03-21 | Ppg Industries Ohio, Inc. | Cationic electrodepositable coating compositions capable of forming low gloss coatings |
| US9505937B2 (en) | 2012-05-16 | 2016-11-29 | Ppg Industries Ohio, Inc. | Anionic electrodepositable coating compositions capable of forming low gloss coatings |
| DE102012020742A1 (de) * | 2012-10-23 | 2014-04-24 | Oerlikon Trading Ag, Trübbach | Mit einer eingebetteten PVD-Schicht beschichtetes Kunststoffteil |
| US9068089B2 (en) | 2013-03-15 | 2015-06-30 | Ppg Industries Ohio, Inc. | Phenolic admix for electrodepositable coating composition containing a cyclic guanidine |
| CN105331270B (zh) * | 2015-12-02 | 2018-04-06 | 立邦涂料(中国)有限公司 | 一种阳离子微凝胶、制备方法及其用途 |
| JP6795435B2 (ja) * | 2017-03-23 | 2020-12-02 | 日本ペイント・オートモーティブコーティングス株式会社 | エポキシ粘性剤およびカチオン電着塗料組成物 |
| CN106905664B (zh) * | 2017-04-10 | 2020-03-17 | 立邦涂料(中国)有限公司 | 一种功能聚胺改性的微凝胶、制备方法及其用途 |
| JP6714752B1 (ja) * | 2019-04-25 | 2020-06-24 | 関西ペイント株式会社 | カチオン電着塗料組成物 |
| US12351735B2 (en) * | 2019-04-25 | 2025-07-08 | Kansai Paint Co., Ltd. | Cationic electrodeposition coating composition |
| US20210269667A1 (en) * | 2020-02-27 | 2021-09-02 | Axalta Coating Systems Ip Co., Llc | Electrocoating composition |
| US20210371678A1 (en) | 2020-05-28 | 2021-12-02 | Axalta Coating Systems Ip Co., Llc | Electrocoating composition |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3761371A (en) * | 1970-12-21 | 1973-09-25 | Ford Motor Co | Electrodeposition of coating materials comprising particulate elastomers |
| US4136070A (en) * | 1977-10-31 | 1979-01-23 | E. I. Du Pont De Nemours And Company | Cathodic electrodeposition of paints |
| DE3014733A1 (de) * | 1980-04-17 | 1981-10-29 | Akzo Gmbh, 5600 Wuppertal | Wasserdispergierbare kationische harze |
| US4468307A (en) * | 1981-09-14 | 1984-08-28 | Ppg Industries, Inc. | Method of cationic electrodeposition |
| US4560714A (en) * | 1982-12-16 | 1985-12-24 | Celanese Corporation | Water-swellable crosslinked polymeric microgel particles and aqueous dispersions of organic film-forming resins containing the same |
| DE3325061A1 (de) * | 1983-07-12 | 1985-01-24 | Basf Farben + Fasern Ag, 2000 Hamburg | Stickstoffbasische gruppen tragendes kunstharz, dessen herstellung und verwendung |
| JPH0676567B2 (ja) * | 1986-06-16 | 1994-09-28 | 関西ペイント株式会社 | カチオン電着塗料用樹脂組成物 |
| JPS6341570A (ja) * | 1986-08-06 | 1988-02-22 | Nippon Paint Co Ltd | 電着塗料組成物 |
| JPS6348367A (ja) * | 1986-08-18 | 1988-03-01 | Kansai Paint Co Ltd | 電着塗料組成物 |
| JPS6465173A (en) * | 1987-09-04 | 1989-03-10 | Nippon Paint Co Ltd | Preparation of aqueous dispersion of fine cationic gel particle |
| CA1301393C (en) * | 1986-11-28 | 1992-05-19 | Yasuyuki Tsuchiya | Cationic micro gel particle dispersion and a coating composition therefrom |
| JPS63169398A (ja) * | 1987-01-07 | 1988-07-13 | Nippon Paint Co Ltd | 複層電着塗装方法 |
| CA1312684C (en) * | 1987-01-30 | 1993-01-12 | Mitsuo Yamada | Electrodeposition coating composition containing modified epoxy resin having chargeable groups |
| EP0282000B1 (en) * | 1987-03-11 | 1993-06-09 | Kansai Paint Co., Ltd. | Cationically electrodepositable finely divided gelled polymer and cationically electrodepositable coating composition containing same |
| DE3720955A1 (de) * | 1987-06-25 | 1989-01-05 | Basf Lacke & Farben | Stickstoffbasische gruppen tragendes kunstharz, dessen herstellung und verwendung |
| JP2890594B2 (ja) * | 1989-01-26 | 1999-05-17 | 大日本インキ化学工業株式会社 | 水性樹脂組成物 |
-
1990
- 1990-06-25 US US07/543,501 patent/US5096556A/en not_active Expired - Lifetime
-
1991
- 1991-05-31 AU AU78063/91A patent/AU629479B2/en not_active Expired
- 1991-06-05 ZA ZA914304A patent/ZA914304B/xx unknown
- 1991-06-12 AT AT91109620T patent/ATE126254T1/de not_active IP Right Cessation
- 1991-06-12 DE DE69111920T patent/DE69111920T2/de not_active Expired - Lifetime
- 1991-06-12 ES ES91109620T patent/ES2078385T3/es not_active Expired - Lifetime
- 1991-06-12 EP EP91109620A patent/EP0463474B1/en not_active Expired - Lifetime
- 1991-06-13 FI FI912855A patent/FI101975B/fi active IP Right Grant
- 1991-06-19 CA CA002044987A patent/CA2044987C/en not_active Expired - Lifetime
- 1991-06-21 AR AR91320000A patent/AR246542A1/es active
- 1991-06-21 JP JP3150514A patent/JP2604508B2/ja not_active Expired - Lifetime
- 1991-06-24 KR KR1019910010475A patent/KR940009035B1/ko not_active Expired - Lifetime
- 1991-06-24 BR BR919102648A patent/BR9102648A/pt not_active IP Right Cessation
- 1991-06-25 PT PT98090A patent/PT98090B/pt not_active IP Right Cessation
-
1995
- 1995-03-29 JP JP7072165A patent/JP2543332B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5096556A (en) | 1992-03-17 |
| ATE126254T1 (de) | 1995-08-15 |
| EP0463474A2 (en) | 1992-01-02 |
| ZA914304B (en) | 1993-02-24 |
| PT98090B (pt) | 1998-11-30 |
| FI912855A0 (fi) | 1991-06-13 |
| PT98090A (pt) | 1992-04-30 |
| FI101975B1 (fi) | 1998-09-30 |
| FI101975B (fi) | 1998-09-30 |
| FI912855L (fi) | 1991-12-26 |
| JPH04226171A (ja) | 1992-08-14 |
| EP0463474A3 (en) | 1992-04-22 |
| CA2044987C (en) | 1999-05-04 |
| JPH07268063A (ja) | 1995-10-17 |
| JP2543332B2 (ja) | 1996-10-16 |
| KR940009035B1 (ko) | 1994-09-29 |
| JP2604508B2 (ja) | 1997-04-30 |
| DE69111920D1 (de) | 1995-09-14 |
| AU629479B2 (en) | 1992-10-01 |
| KR920000885A (ko) | 1992-01-29 |
| CA2044987A1 (en) | 1991-12-26 |
| AR246542A1 (es) | 1994-08-31 |
| EP0463474B1 (en) | 1995-08-09 |
| BR9102648A (pt) | 1992-01-21 |
| DE69111920T2 (de) | 1996-05-02 |
| AU7806391A (en) | 1992-01-30 |
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