ES2081868T3 - Procedimiento para la preparacion de 2-(2',4'-dihidroxifenil)-4,6-diaril-s-triazinas. - Google Patents

Procedimiento para la preparacion de 2-(2',4'-dihidroxifenil)-4,6-diaril-s-triazinas.

Info

Publication number
ES2081868T3
ES2081868T3 ES90107370T ES90107370T ES2081868T3 ES 2081868 T3 ES2081868 T3 ES 2081868T3 ES 90107370 T ES90107370 T ES 90107370T ES 90107370 T ES90107370 T ES 90107370T ES 2081868 T3 ES2081868 T3 ES 2081868T3
Authority
ES
Spain
Prior art keywords
formula
compound
procedure
xilol
triazinas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90107370T
Other languages
English (en)
Inventor
Kurt Dr Burdeska
Franz Dr Guenter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Application granted granted Critical
Publication of ES2081868T3 publication Critical patent/ES2081868T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D251/00Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/22Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to two ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D251/00Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/24Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to three ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D251/00Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/38Sulfur atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

EL INVENTO SE REFIERE A UN PROCEDIMIENTO PARA PRODUCIR EL 2-(2'',4''DIHIDROXIFENILO)-4,6-DIARILO-S-TRIAZINENO DE FORMULA (1). DICHO PROCEDIMIENTO CONSISTE EN HACER REACCIONAR UN COMPUESTO DE FORMULA (4) CON UN BENZOL SUSTITUIDO DEL COMPUESTO DE FORMULA (5) MEDIANTE UN ACIDO DE LEWIS Y EN PRESENCIA DE XILOL O TOLUOL, PARA OBTENER UN COMPUESTO DE FORMULA (2); TRATAR A (2) CON CLORO O CLORURO DE SULFORILO, EN PRESENCIA DE TOLUOL O XILOL, PARA OBTENER UN COMPUESTO DE FORMULA (3) Y HACER REACCIONAR A (3) CON 1,3DIHIDROXIBENZOL, MEDIANTE UN ACIDO DE LEWIS Y EN PRESENCIA DE TOLUOL, XILOL O MEZCLAS DE ISOMEROS DE XILOL, PARA OBTENER UN COMPUESTO DE FORMULA (1).
ES90107370T 1989-04-21 1990-04-18 Procedimiento para la preparacion de 2-(2',4'-dihidroxifenil)-4,6-diaril-s-triazinas. Expired - Lifetime ES2081868T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH153689 1989-04-21

Publications (1)

Publication Number Publication Date
ES2081868T3 true ES2081868T3 (es) 1996-03-16

Family

ID=4212720

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90107370T Expired - Lifetime ES2081868T3 (es) 1989-04-21 1990-04-18 Procedimiento para la preparacion de 2-(2',4'-dihidroxifenil)-4,6-diaril-s-triazinas.

Country Status (10)

Country Link
US (2) US5084570A (es)
EP (1) EP0395938B1 (es)
JP (1) JP2857219B2 (es)
KR (1) KR0143990B1 (es)
AT (1) ATE133164T1 (es)
BR (1) BR9001844A (es)
CA (1) CA2014886A1 (es)
DE (1) DE59010061D1 (es)
ES (1) ES2081868T3 (es)
ZA (1) ZA902997B (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59209837D1 (de) * 1991-01-31 2000-06-15 Ciba Sc Holding Ag Verfahren zur Herstellung von 2-(2',4'-Dihydroxyphenyl)-4,6-diaryl-s-triazinen
TW222292B (es) * 1991-02-21 1994-04-11 Ciba Geigy Ag
ES2069402T3 (es) * 1991-03-27 1995-05-01 Ciba Geigy Ag Polimeros de metacrilato de metilo estabilizados.
US5298030A (en) * 1992-02-21 1994-03-29 Ciba-Geigy Corporation Process for the photochemical and thermal stabilization of undyed and dyed or printed polyester fiber materials
EP0584044B1 (de) * 1992-08-18 1997-07-16 Ciba SC Holding AG Verfahren zur photochemischen und thermischen Stabilisierung von ungefärbten und gefärbten Polyesterfasermaterialien
US5370988A (en) * 1994-02-28 1994-12-06 Minnesota Mining And Manufacturing Company Print stabilizers and antifoggants for photothermography
US5585422A (en) * 1995-09-20 1996-12-17 Ciba-Geigy Corporation Hybrid s-triazine light stabilizers substituted by benzotriazole or benzophenone moieties and compositions stabilized therewith
DE19735900A1 (de) * 1997-08-19 1999-02-25 Beiersdorf Ag Kosmetische oder dermatologische Lichtschutzmittel, welche gelöste Triazinderivate und polymere UV-Filtersubstanzen auf Siliconbasis enthalten
DE19735899A1 (de) * 1997-08-19 1999-02-25 Beiersdorf Ag Wirkstoffkombinationen aus einer oder mehreren grenzflächenaktiven Substanzen und oligomeren oder polymeren UV-Filtersubstanzen mit periodisch sich wiederholenden Si-0-Gruppen
DE19735901A1 (de) * 1997-08-19 1999-02-25 Beiersdorf Ag Kosmetische oder dermatologische Lichtschutzmittel, welche als Festkörper vorliegende UV-Filtersubstanzen und polymere UV-Filtersubstanzen auf Siliconbasis enthalten
EP0941989B1 (en) 1998-03-02 2009-07-08 Ciba Holding Inc. Process for the preparation of 2,4-diaryl-6-o-hydroxyphenyl-1,3,5-triazine derivatives in the presence of a protic acid catalyst
US6297377B1 (en) 1998-06-22 2001-10-02 Cytec Technology Corporation Benzocycle-substituted triazine and pyrimidine ultraviolet light absorbers
EP1089986B1 (en) 1998-06-22 2005-03-30 Ciba SC Holding AG Poly-trisaryl-1,3,5-triazine carbamate ultraviolet light absorbers
US6239276B1 (en) 1998-06-22 2001-05-29 Cytec Technology Corporation Non-yellowing para-tertiary-alkyl phenyl substituted triazine and pyrimidine ultraviolet light absorbers
DE19830902A1 (de) 1998-07-10 2000-01-13 Hoechst Schering Agrevo Gmbh Verfahren zur Herstellung von 2-Amino-4-chlor-1,3,5-triazinen
JP2002524451A (ja) * 1998-09-04 2002-08-06 サイテク・テクノロジー・コーポレーシヨン 2−(2−ヒドロキシ−4−アルコキシフェニル)−4、6−ビスアリール−1、3、5−トリアジンの製造方法
KR20010073101A (ko) 1998-09-04 2001-07-31 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 2-하이드록시-4-알콕시페닐 또는 2,4-디하이드록시페닐치환된 1,3,5-트리아진 uv 흡수제의 제조방법
JP2002524452A (ja) 1998-09-04 2002-08-06 サイテク・テクノロジー・コーポレーシヨン 2−(2,4−ジヒドロキシフェニル)もしくは2−(2,4−ジアルコキシフェニル)−4,6−ビスアリール−1,3,5−トリアジンの製造方法
TWI259182B (en) 1998-11-17 2006-08-01 Cytec Tech Corp Process for preparing triazines using a combination of Lewis acids with reaction promoters
US6867250B1 (en) 2000-10-30 2005-03-15 Cytec Technology Corp. Non-yellowing ortho-dialkyl aryl substituted triazine ultraviolet light absorbers
US6727300B2 (en) 2000-11-03 2004-04-27 Cytec Technology Corp. Polymeric articles containing hindered amine light stabilizers based on multi-functional carbonyl compounds
US6492521B2 (en) 2000-11-03 2002-12-10 Cytec Technology Corp. Hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
US6414155B1 (en) 2000-11-03 2002-07-02 Cytec Technology Corp. Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
US6545156B1 (en) 2000-11-03 2003-04-08 Cytec Technology Corp. Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
US6632944B2 (en) 2001-06-22 2003-10-14 Cytec Technology Corp. Process for isolation of monophenolic-bisaryl triazines
US6855269B2 (en) 2001-11-09 2005-02-15 Cytec Technology Corp. Phenyl ether-substituted hydroxyphenyl triazine ultraviolet light absorbers
EP2573076B1 (en) 2008-06-04 2014-08-20 Adeka Corporation Method for producing 2,4,6-tris(hydroxyphenyl)-1,3,5-triazine compound
ES2463674T3 (es) 2009-01-19 2014-05-28 Basf Se Pigmentos negros orgánicos y su preparación

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL275368A (es) * 1961-03-06
US3118887A (en) * 1961-03-06 1964-01-21 American Cyanamid Co O-hydroxy substituted tris aryl-s-triazines
BE639330A (es) * 1962-10-30
CH484695A (de) * 1962-10-30 1970-01-31 Ciba Geigy Verwendung von neuen Hydroxyphenyl-1,3,5-triazinen als Ultraviolettschutzmittel ausserhalb der Textilindustrie

Also Published As

Publication number Publication date
EP0395938B1 (de) 1996-01-17
BR9001844A (pt) 1991-06-18
KR0143990B1 (ko) 1998-07-15
KR900016162A (ko) 1990-11-12
JPH02292267A (ja) 1990-12-03
US5084570A (en) 1992-01-28
ATE133164T1 (de) 1996-02-15
US5106972A (en) 1992-04-21
ZA902997B (en) 1990-12-28
JP2857219B2 (ja) 1999-02-17
CA2014886A1 (en) 1990-10-21
EP0395938A2 (de) 1990-11-07
EP0395938A3 (de) 1991-12-04
DE59010061D1 (de) 1996-02-29

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