ES2081868T3 - Procedimiento para la preparacion de 2-(2',4'-dihidroxifenil)-4,6-diaril-s-triazinas. - Google Patents
Procedimiento para la preparacion de 2-(2',4'-dihidroxifenil)-4,6-diaril-s-triazinas.Info
- Publication number
- ES2081868T3 ES2081868T3 ES90107370T ES90107370T ES2081868T3 ES 2081868 T3 ES2081868 T3 ES 2081868T3 ES 90107370 T ES90107370 T ES 90107370T ES 90107370 T ES90107370 T ES 90107370T ES 2081868 T3 ES2081868 T3 ES 2081868T3
- Authority
- ES
- Spain
- Prior art keywords
- formula
- compound
- procedure
- xilol
- triazinas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 abstract 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- 239000002841 Lewis acid Substances 0.000 abstract 2
- 150000007517 lewis acids Chemical class 0.000 abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/22—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to two ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/24—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to three ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/38—Sulfur atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Catalysts (AREA)
Abstract
EL INVENTO SE REFIERE A UN PROCEDIMIENTO PARA PRODUCIR EL 2-(2'',4''DIHIDROXIFENILO)-4,6-DIARILO-S-TRIAZINENO DE FORMULA (1). DICHO PROCEDIMIENTO CONSISTE EN HACER REACCIONAR UN COMPUESTO DE FORMULA (4) CON UN BENZOL SUSTITUIDO DEL COMPUESTO DE FORMULA (5) MEDIANTE UN ACIDO DE LEWIS Y EN PRESENCIA DE XILOL O TOLUOL, PARA OBTENER UN COMPUESTO DE FORMULA (2); TRATAR A (2) CON CLORO O CLORURO DE SULFORILO, EN PRESENCIA DE TOLUOL O XILOL, PARA OBTENER UN COMPUESTO DE FORMULA (3) Y HACER REACCIONAR A (3) CON 1,3DIHIDROXIBENZOL, MEDIANTE UN ACIDO DE LEWIS Y EN PRESENCIA DE TOLUOL, XILOL O MEZCLAS DE ISOMEROS DE XILOL, PARA OBTENER UN COMPUESTO DE FORMULA (1).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH153689 | 1989-04-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2081868T3 true ES2081868T3 (es) | 1996-03-16 |
Family
ID=4212720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90107370T Expired - Lifetime ES2081868T3 (es) | 1989-04-21 | 1990-04-18 | Procedimiento para la preparacion de 2-(2',4'-dihidroxifenil)-4,6-diaril-s-triazinas. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5084570A (es) |
| EP (1) | EP0395938B1 (es) |
| JP (1) | JP2857219B2 (es) |
| KR (1) | KR0143990B1 (es) |
| AT (1) | ATE133164T1 (es) |
| BR (1) | BR9001844A (es) |
| CA (1) | CA2014886A1 (es) |
| DE (1) | DE59010061D1 (es) |
| ES (1) | ES2081868T3 (es) |
| ZA (1) | ZA902997B (es) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0497734B1 (de) * | 1991-01-31 | 2000-05-10 | Ciba SC Holding AG | Verfahren zur Herstellung von 2-(2',4'-Dihydroxyphenyl)-4,6-diaryl-s-triazinen |
| TW222292B (es) * | 1991-02-21 | 1994-04-11 | Ciba Geigy Ag | |
| EP0506615B1 (de) * | 1991-03-27 | 1995-02-22 | Ciba-Geigy Ag | Stabilisierte Methylmethacrylat-Polymere |
| US5298030A (en) * | 1992-02-21 | 1994-03-29 | Ciba-Geigy Corporation | Process for the photochemical and thermal stabilization of undyed and dyed or printed polyester fiber materials |
| DE59306916D1 (de) * | 1992-08-18 | 1997-08-21 | Ciba Geigy Ag | Verfahren zur photochemischen und thermischen Stabilisierung von ungefärbten und gefärbten Polyesterfasermaterialien |
| US5370988A (en) * | 1994-02-28 | 1994-12-06 | Minnesota Mining And Manufacturing Company | Print stabilizers and antifoggants for photothermography |
| US5585422A (en) * | 1995-09-20 | 1996-12-17 | Ciba-Geigy Corporation | Hybrid s-triazine light stabilizers substituted by benzotriazole or benzophenone moieties and compositions stabilized therewith |
| DE19735899A1 (de) * | 1997-08-19 | 1999-02-25 | Beiersdorf Ag | Wirkstoffkombinationen aus einer oder mehreren grenzflächenaktiven Substanzen und oligomeren oder polymeren UV-Filtersubstanzen mit periodisch sich wiederholenden Si-0-Gruppen |
| DE19735900A1 (de) * | 1997-08-19 | 1999-02-25 | Beiersdorf Ag | Kosmetische oder dermatologische Lichtschutzmittel, welche gelöste Triazinderivate und polymere UV-Filtersubstanzen auf Siliconbasis enthalten |
| DE19735901A1 (de) * | 1997-08-19 | 1999-02-25 | Beiersdorf Ag | Kosmetische oder dermatologische Lichtschutzmittel, welche als Festkörper vorliegende UV-Filtersubstanzen und polymere UV-Filtersubstanzen auf Siliconbasis enthalten |
| DE69941073D1 (de) | 1998-03-02 | 2009-08-20 | Ciba Holding Inc | Verfahren zur Herstellung von 2,4-Diaryl-6-o-hydroxyphenyl-1,3,5-triazin Derivaten in Anwesenheit eines Protonensäure-Katalysators |
| US6239276B1 (en) | 1998-06-22 | 2001-05-29 | Cytec Technology Corporation | Non-yellowing para-tertiary-alkyl phenyl substituted triazine and pyrimidine ultraviolet light absorbers |
| US6297377B1 (en) | 1998-06-22 | 2001-10-02 | Cytec Technology Corporation | Benzocycle-substituted triazine and pyrimidine ultraviolet light absorbers |
| JP2002518489A (ja) | 1998-06-22 | 2002-06-25 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | ポリ(トリスアリール−1,3,5−トリアジン=カルバマート)紫外光吸収剤 |
| DE19830902A1 (de) * | 1998-07-10 | 2000-01-13 | Hoechst Schering Agrevo Gmbh | Verfahren zur Herstellung von 2-Amino-4-chlor-1,3,5-triazinen |
| AU5700699A (en) * | 1998-09-04 | 2000-03-27 | Cytec Technology Corp. | Process for making 2-(2-hydroxy-4-alkoxyphenyl)-4,6-bisaryl-1,3,5-triazines |
| CN1184211C (zh) | 1998-09-04 | 2005-01-12 | Cytec技术有限公司 | 制备2-(2,4-二羟苯基)或2-(2,4-二烷氧基苯基)-4,6-双芳基-1,3,5-三嗪的方法 |
| EP1109793A1 (en) | 1998-09-04 | 2001-06-27 | Ciba SC Holding AG | Process for making 2-hydroxy-4-alkoxyphenyl or 2,4-dihydroxyphenyl substituted 1,3,5-triazine uv absorbers |
| TWI259182B (en) | 1998-11-17 | 2006-08-01 | Cytec Tech Corp | Process for preparing triazines using a combination of Lewis acids with reaction promoters |
| US6867250B1 (en) | 2000-10-30 | 2005-03-15 | Cytec Technology Corp. | Non-yellowing ortho-dialkyl aryl substituted triazine ultraviolet light absorbers |
| US6545156B1 (en) | 2000-11-03 | 2003-04-08 | Cytec Technology Corp. | Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6414155B1 (en) | 2000-11-03 | 2002-07-02 | Cytec Technology Corp. | Oligomeric hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6727300B2 (en) | 2000-11-03 | 2004-04-27 | Cytec Technology Corp. | Polymeric articles containing hindered amine light stabilizers based on multi-functional carbonyl compounds |
| US6492521B2 (en) | 2000-11-03 | 2002-12-10 | Cytec Technology Corp. | Hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same |
| US6632944B2 (en) | 2001-06-22 | 2003-10-14 | Cytec Technology Corp. | Process for isolation of monophenolic-bisaryl triazines |
| US6855269B2 (en) | 2001-11-09 | 2005-02-15 | Cytec Technology Corp. | Phenyl ether-substituted hydroxyphenyl triazine ultraviolet light absorbers |
| BRPI0913343B1 (pt) | 2008-06-04 | 2018-01-23 | Adeka Corporation | Método para produção do composto 2,4,6-tri (hidroxifenil)-1,3,5-triazina |
| KR101773621B1 (ko) | 2009-01-19 | 2017-08-31 | 바스프 에스이 | 유기 흑색 안료 및 이의 제조 방법 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3118887A (en) * | 1961-03-06 | 1964-01-21 | American Cyanamid Co | O-hydroxy substituted tris aryl-s-triazines |
| NL275368A (es) * | 1961-03-06 | |||
| CH484695A (de) * | 1962-10-30 | 1970-01-31 | Ciba Geigy | Verwendung von neuen Hydroxyphenyl-1,3,5-triazinen als Ultraviolettschutzmittel ausserhalb der Textilindustrie |
| BE639329A (es) * | 1962-10-30 |
-
1990
- 1990-04-18 AT AT90107370T patent/ATE133164T1/de not_active IP Right Cessation
- 1990-04-18 EP EP90107370A patent/EP0395938B1/de not_active Expired - Lifetime
- 1990-04-18 ES ES90107370T patent/ES2081868T3/es not_active Expired - Lifetime
- 1990-04-18 DE DE59010061T patent/DE59010061D1/de not_active Expired - Fee Related
- 1990-04-18 US US07/510,494 patent/US5084570A/en not_active Expired - Lifetime
- 1990-04-19 CA CA002014886A patent/CA2014886A1/en not_active Abandoned
- 1990-04-19 KR KR1019900005462A patent/KR0143990B1/ko not_active Expired - Fee Related
- 1990-04-20 ZA ZA902997A patent/ZA902997B/xx unknown
- 1990-04-20 JP JP2103290A patent/JP2857219B2/ja not_active Expired - Fee Related
- 1990-04-20 BR BR909001844A patent/BR9001844A/pt unknown
-
1991
- 1991-08-05 US US07/739,963 patent/US5106972A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02292267A (ja) | 1990-12-03 |
| US5106972A (en) | 1992-04-21 |
| KR0143990B1 (ko) | 1998-07-15 |
| BR9001844A (pt) | 1991-06-18 |
| KR900016162A (ko) | 1990-11-12 |
| DE59010061D1 (de) | 1996-02-29 |
| US5084570A (en) | 1992-01-28 |
| EP0395938A3 (de) | 1991-12-04 |
| CA2014886A1 (en) | 1990-10-21 |
| EP0395938B1 (de) | 1996-01-17 |
| ATE133164T1 (de) | 1996-02-15 |
| EP0395938A2 (de) | 1990-11-07 |
| JP2857219B2 (ja) | 1999-02-17 |
| ZA902997B (en) | 1990-12-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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